间羟苯甲酸4-羟化酶吸收波谱研究

间羟苯甲酸４羟化酶吸收波谱研究首都医科大学生物化学教研室陈瑞细川桂一赵慧芳黄如彬间羟苯甲酸（ＭＯＢ）是植物木质素的组分，是需氧土壤菌假单孢菌（Ｐｓｅｕｄｏｍｏｎａｓ，Ｐｓ．）和丛毛单孢菌（Ｃｏｍａｍｏｎａｓ，Ｃｏ．）通用代谢途径的芳香族底物。它的...

油砂波谱专题数据库的设计与开发

为建立并进一步完善油砂波谱专题数据库,采用C#语言与SQL Server2008数据库设计并开发了油砂波谱专题数据库,实现了对海量油砂波谱的数据管理,同时将在青海野外采集的90组油砂波谱数据用于数据库测试,可实现对波谱吸收特征参数即吸收波段波长位置、深度、宽度、斜率、面积和对称度进行用户自定义分析;同时也可对未知实测油砂波谱曲线与已知油砂波谱库曲线进行匹配,并得到相匹配的相关系数,达到了数据库的设计要求。

Determination of Chromium and Zinc in Soil by Microwave Digestion and Flame Atomic Absorption Spectrometry

[Objective] The aim was to develop a rapid, simple method for determination of chromium and zinc in soil samples by flame atomic absorption spectrometry.[Method] The method for determination of Cr and Zn in soil by combined flame atomic absorption spectrometry and microwave digestion was used. [Result] The concentration curve was linear within the range of 0-0.8 mg/L for Cr and 0-0.8 mg/L for Zn, the detection limits of Cr and Zn was 0.0025 mg/L and 0.002 3 mg/L, respectively. Recoveries of 102.4%-103.2% for Cr and 97.7%-98.3% for Zn were obtained for there soil samples. [Conclusion] The proposed method has the advantages of simple operation, high sensitivity, and high efficiency; it was successfully used for determination of Cr and Zn in soil samples.

Determination of Cadmium and Lead in Sugarcane by Graphite Furnace Atomic Absorption Spectrometer with Zeeman Correction

[Objective] The aim was to develop a rapid,simple method for determination of cadmium and lead in sugarcane samples by graphite furnace atomic absorption spectrometry.[Method] The method for determination of Cd and Pb in sugarcane by combined graphite furnace atomic absorption spectrometry and microwave digestion was used.[Result] The concentration curve was linear within the range of 0-0.80 μg/L the detection limits of Cd and Pb was 0.015 and 0.030 μg/L,respectively.The precision for elevenfold determination of Cd and of Pb at the 0.40 μg/L level were 1.8% and 2.3%（RSD）,respectively.Recoveries of 96.7%-98.2% for Cd and 104.6%-106.7% for Pb were obtained for two sugarcane samples and one certified reference material.[Conclusion] The proposed method has the advantages of simple operation,high sensitivity,and high efficiency;it was successfully used for determination of Cd and Pb in sugarcane samples.

Conditions of synthesis for PpIX

The characteristics of ALA absorption spectra under different conditions are studied with spectrometers. The results indicate that the wavelength of ALA,corresponding to the strongest absorption peak, is 282 nm under different conditions. The content of PplX synthesized is in direct proportion to the density of Jurkat cells. The most suitable culture time is 8 hours in order to synthesize more PplX. FCS has a block effect on the synthesis of PpIX.

Hermiticity of Hamiltonian Matrix using the Fourier Basis Sets in Bond-Bond-Angle and Radau Coordinates

In quantum calculations a transformed Hamiltonian is often used to avoid singularities in a certain basis set or to reduce computation time. We demonstrate for the Fourier basis set that the Hamiltonian can not be arbitrarily transformed. Otherwise, the Hamiltonian matrix becomes non-hermitian, which may lead to numerical problems. Methods for cor- rectly constructing the Hamiltonian operators are discussed. Specific examples involving the Fourier basis functions for a triatomic molecular Hamiltonian （J=0） in bond-bond angle and Radau coordinates are presented. For illustration, absorption spectra are calculated for the OC10 molecule using the time-dependent wavepacket method. Numerical results indicate that the non-hermiticity of the Hamiltonian matrix may also result from integration errors. The conclusion drawn here is generally useful for quantum calculation using basis expansion method using quadrature scheme.

Research on the sensitivity for the coal mine gas concentration detection by laser spectrum absorption

Because of the former gas chemistry examination method defects, tunable diode laser absorption spectrum technology （TDLAS） was used. It used an isolated absorption spectrum of the gas molecule to measure the gas absorption spectrum in order to distinguish the gas conveniently. The second harmonic （20 was measured in this system. Due to the fact which the harmonious signal is proportional to the concentration of the absorption gas, the gas concentration may be obtained through examining harmonious signal. The theoretical analysis and the experimental result indicate that under the same level of pressure, survey with the signal-to-noise ratio（SNR） of 2fsignal increases the accuracy by one order of magnitude and may reach 10 ^-3 and the sensitivity may reach the 10^-6 level compared to that of direct absorption. 5% methane density and a 30 cm absorption cell were used in the experiment. It has several advantages including high sensitivity, best resolution, and faster response and so on. The gas concentration monitoring of coal mine may be accomplished.

Aroma Properties of Selected Local Spices of Akwa Ibom State of Nigeria

Some famous local spices were selected to determine their potentials in terms of their aroma and utilization. They included Tea Bush （Ocimum basilicum）, Guinea Black Pepper （Piper guineense）, African Pepper （Xylopia aethiopica）, Alden Tree （Tetrapleura tetraptera） and the African Meg Nut or Onion Tree （Blighia unijugata）. Essential oils were extracted from the samples and used for aroma absorption test in a uv-visible spectrometer V2.03. The intensity of aroma was indicated at some peak values of absorption at particular wavelengths. The compounds responsible for the aroma at this peak values were identified by matching their wavelengths with those of known compounds at similar wavelengths of absorption. Thus, a compound such as Quinoline that has hot strong aroma and little bleaching effect was proved to be present in Guinea black pepper ;at the wavelength of 313.0 nm. Benzene with hot strong aroma and flammable effect was also indicated in this spice at the wavelength of 253.0 rim. Proximate analysis carried out showed that these spices have high nutritive values. Some of them such as Guinea black pepper, African Nutmeg and Ethiopian （African） pepper had high ether extract of 20.01, 25.97 and 31.25 respectively, and could be regarded as oil seeds, they contain much of essential oils.

High-Accurate Transparent Boundary Conditions for Time-Dependent Quantum Wave Packet Method

Complex absorbing potential is usually required in a time-dependent wave packet method to accomplish the calculation in a truncated region.Usually it works effectively but becomes inefficient when the wave function involves translational energy of broad range,particularly involving ultra-low energy.In this work,a new transparent boundary condition(TBC)is proposed for the time-dependent wave packet method.It in principle is of spectral accuracy when typical discrete variable representations are applied.The prominent merit of the new TBC is that its accuracy is insensitive to the translational energy distribution of the wave function,in contrast with the complex absorbing potential.Application of the new TBC is given to one-dimensional particle wave packet scatterings from a barrier with a potential well,which supports resonances states.

An all optical fiber gas sensor of NH3 and CO based on based on the spectral absorption and harmonic detection

An all optical fiber gas sensor is presented to detect the concentration of NH3 and CO. Based on the spectral absorption, The wideband light source is used to reflect two narrowband spectra by fiber grating of different duty. and piezoelectric ceramics to obtain narrowband output light. The high sensitivity detection can be measured from the second harmonic signal. The two narrowband spectra are corresponding to the absorption spectra of NH3 and CO. Concentration detection are realized by the detection of variety of light intensity. Sensitivity is proved and cost is reduced.

光照热辐射作用研究

依据光源的黑体辐射作用,通过结合辐射波谱、材料的吸收波谱中的热作用波段,设计实验以获得衡量热辐射作用的参考照度值来避免能量的聚集,造成零件温度过高而烧熔等问题。

Spectral Absorption Gas Sensor Based on Anti-Resonant Reflecting Optical Waveguide

An air-silica microstructure optical fiber based on the anti-resonant reflecting optical waveguide （ARROW） principle was used to develop a spectral absorption gas sensor. The ARROW fiber has an air core and an air cladding layer. An ARROW fiber with a length of 725mm was used to construct a sensing system to detect acetylene gas. The gas was injected into the fiber from one end of the fiber. The transmission spectra were collected using an optical spectrum analyzer. The results indicate that the system can detect the gas of different concentrations and has the good system linearity. The response time of the system is about 200 s.

Water Vapor Detection System Based on Scanning Spectra

Scanning the absorption spectral line of water vapor through wavelength around 1368.597nm is successfully used to measure the value of micro-moisture content. The synchronous superposition average of original signal algorithm based on labview is innovated and applied to detecting weak spectrum absorption signal instead of low pass filter. Two data processing methods are used to get the concentration of water vapor in ppm： one is a general formula method which has newly deduced a general formula to calculate the concentration of gas with temperature and beam intensity ratio when the pressure is equal to or greater than 1 atm; the other is engineering calibration method which is proved to have high resolution and accuracy with the fitted curve of beam intensity ratio and concentration in ppm when the temperature changes form 258K to 305K and the pressure ranges from 1 atm to 5 atm.