A novel 800nm Bragg mirror type of semiconductor saturable absorption mirror wit h low temperature method and surface state method combined absorber is presented .With which passive Kerr lens mode locking of Ti∶Al 2...A novel 800nm Bragg mirror type of semiconductor saturable absorption mirror wit h low temperature method and surface state method combined absorber is presented .With which passive Kerr lens mode locking of Ti∶Al 2O 3 laser pumped by argo n ion laser is realized,which produces pulses as short as 40fs.The spectrum band width is 56nm,which means that it can support the modelocking of 20fs.The pulse frequency is 97.5MHz;average output power is 300mW at the pump power of 4.45W.展开更多
The analytic response theory at density functional theory level is applied to investigate onephoton and two-photon absorption properties of a series of recently synthesized pyrene-core derivatives. The theoretical res...The analytic response theory at density functional theory level is applied to investigate onephoton and two-photon absorption properties of a series of recently synthesized pyrene-core derivatives. The theoretical results show that there are a few charge-transfer states for each compound in the lower energy region. The one-photon absorption properties of the five investigated compounds are highly consistent with those given by experimental measurements. The two-photon absorption intensities of the compounds are greatly enhanced with the increments of the molecular sizes, in which the two-photon absorption cross section of the four-branched compound is about 5.6 times of that of the mono-branched molecule. Fhrthermore, it is shown that the two-photon absorption properties are sensitive to the geometrical arrangements.展开更多
H_(2)S is one of the most important characteristic decomposition components of SF_(6)insulated gas,and the detection of trace H_(2)S is significant for early fault diagnosis of gas insulated electrical equipment.A 157...H_(2)S is one of the most important characteristic decomposition components of SF_(6)insulated gas,and the detection of trace H_(2)S is significant for early fault diagnosis of gas insulated electrical equipment.A 1578 nm wavelength distributed feedback diode laser(DFB-DL)based cavity ring-down spectroscopy(CRDS)experimental platform is developed to monitor the concentrations of H_(2)S in SF_(6)and SF_(6)/N_(2)mixture carrier gas.The detection sensitivity is higher than 1×10^(-6).The absorption cross section parameterσis vital for calculating the concentration.With repeated experiments using standard gas samples,parameterσof H_(2)S in pure SF_(6)and SF_(6)/N_(2)mixture carrier with different mixing ratios is calibrated.Compared with the simulatedσvalues,the influence of carrier gas on the broadening of spectral profile is discussed.The variation of absorption cross sectionσwith different carrier gas mixing ratios is studied as well,so that the calculation of the concentration in the carrier gas of any mixing ratio is possible.Thus,the application of CRDS in trace component detection of gas insulated electrical equipment is promising.展开更多
This paper focuses on the mechanism of interfacial mass transfer of a single bubble, based on the chemical potential driving force, an approach for calculating interfacial concentration in practical process is propose...This paper focuses on the mechanism of interfacial mass transfer of a single bubble, based on the chemical potential driving force, an approach for calculating interfacial concentration in practical process is proposed. The absorption processes of bubble under both quiescent and mobile conditions are analyzed and discussed respectively. For a stationary absorption, only in the case of liquid bulk concentration near saturated value, the interfacial concentration could close to the equilibrium value ; For a moving bubble, under ordinary operating condition (Yo〉l), the interfacial concentration is far from its equilibrium. Only under bulk concentration near saturated value or a smaller Yo(Yo〈0.1) which may involve the complication of additional resistance at interface induced by surface contamination or surfactant added, the interfacial concentration could be approximate to equilibrium value. The interfacial concentration close to the interface on liquid side for a single CO2 bubble absorbed by methanol is measured using a modern optical instrumentation in which the laser holographic interference method is adopted with a real-time and amplification technique. Experimental results show that the interfacial concentration decreases significantly with increasing Re and is far from the equilibrium one in a larger Re range. Experiments validate the proposed model.展开更多
The photoabsorption cross sections of condensed atoms and molecules have proven to be dependent not only on the imaginary parts but also on the real parts of the polarizabilities due to the strong interatomie interact...The photoabsorption cross sections of condensed atoms and molecules have proven to be dependent not only on the imaginary parts but also on the real parts of the polarizabilities due to the strong interatomie interactions in condensed environment. The real parts of the polarizabilities calculated usually by using the famous Kramers-Kronig transformation (KKT) from the photoabsorption cross sections of the isolated atoms are very sensitive to the accuracy of the implementation method of the infinite integral in the KKT. The influence of the integral instability of the KKT and the real part of the polarizability on the variation of the photoabsorption cross sections with the number density and the structure of the condensed matter has been studied in the present work for the first time. The conclusion is that the integration method with interpolation has given more reasonable results than the direct truncation method if some appropriate interpolation functions have been used. Some notes and conclusions have also been given for the applications of the alternative coupled expressions of photoabsorption cross sections.展开更多
The effect of different surfactants(n-octyltrimethylammonium bromide(OTABr),sodium dodecyl benzene sulfonate(SDBS) and Tween 80) with different critical micelle concentrations(CMC) on the CO_2 absorption into aqueous ...The effect of different surfactants(n-octyltrimethylammonium bromide(OTABr),sodium dodecyl benzene sulfonate(SDBS) and Tween 80) with different critical micelle concentrations(CMC) on the CO_2 absorption into aqueous solutions in a bubble column is analyzed in the present work.The presence of these surfactants increased the gas-liquid interfacial area,and decreased the liquid phase mass transfer coefficient,but with significant different extent.The results indicated that the CMC can be a key parameter affecting the mass transfer of CO_2 absorption into a dilute aqueous solution of a surfactant.Sardeing's model was used to fit the experimental data successfully by re-correlating the parameters.展开更多
In order to selectively separate chalcopyrite from pyrite,the effect of organic depressant lignosulfonate calcium(LSC) on the flotation separation of chalcopyrite from pyrite was investigated by flotation tests. The d...In order to selectively separate chalcopyrite from pyrite,the effect of organic depressant lignosulfonate calcium(LSC) on the flotation separation of chalcopyrite from pyrite was investigated by flotation tests. The depression mechanism was studied by Fourier-transform-infrared(FTIR) analysis. The flotation tests of single mineral show that LSC can depress the flotation of pyrite in a certain pH range,but it has little effect on chalcopyrite flotation. Flotation separation of a mixture of chalcopyrite and pyrite can be completed to obtain a copper concentrate grade up to 24.73% with a recovery of 80.36%. IR analysis shows that LSC and butyl xanthate compete in absorption on pyrite surface,and there exists an LSC characteristic peak on pyrite surface. There is little adsorption of LSC on chalcopyrite.展开更多
The adsorption behavior of symmetric triblock copolymers, Am/2BnAm/2, from a nonselective solvent at solid-liquid interface has been studied by Monte Carlo simulations on a simple lattice model. Either segment A or se...The adsorption behavior of symmetric triblock copolymers, Am/2BnAm/2, from a nonselective solvent at solid-liquid interface has been studied by Monte Carlo simulations on a simple lattice model. Either segment A or segment B is attractive, while the other is non-attractive to the surface. Influences of the adsorption energy, bulk concentration, chain composition and chain length on the microstructure of adsorbed layers are presented. The results show that the total surface coverage and the adsorption amount increases monotonically as the bulk concentration increases. The larger the adsorption energy and the higher the fraction of adsorbing segments, the higher the total surface coverage is exhibited. The product of surface coverage and the proportion of non-attractive segments are nearly independent of the chain length, and the logarithm of the adsorption amount is a linear function of the reciprocal of the reduced temperature. When the adsorption energy is larger, the adsorption amount exhibits a maximum as the fraction of adsorbing segment increases. The adsorption isotherms of copolymers with different length of non-attractive segments can be mapped onto a single curve under given adsorption energy. The adsorption layer thickness decreases as the adsorption energy and the fraction of adsorbing segments increases, but it increases as the length of non-attractive segments increases. The tails mainly govern the adsorption layer thickness.展开更多
Studies were initiated for two consecutive years to find out the effect of time of transplanting and seedlings hill^-l on the productivity of rice in Dera Ismail Khan district of North West Frontier Province (NWFP),...Studies were initiated for two consecutive years to find out the effect of time of transplanting and seedlings hill^-l on the productivity of rice in Dera Ismail Khan district of North West Frontier Province (NWFP), Pakistan. The experiment was laid out in a randomized complete block design with split plot arrangements. Main plots consisted of four transplanting dates viz. 20th and 27th of June and 4th and 1 lth of July while sub-plots contained 1, 2, 3 or 4 seedlings hill^-1. Among transplanting dates, June 20th planted crop gave highest paddy yield and net return with I seedling hill^-1. It explains that the use of more seedlings hill^-1 not only adds to cost but is also a mere wastage of natural resources. Based on research findings, we conclude that the use of I seedling hill^-1 is most appropriate for timely sowing otherwise 4 seedlings hill^-1 should be used to compensate for the yield gap in late transplanted rice.展开更多
Presence of different terms with various values can alter the thermal behavior of the nanofluids flow over porous surfaces.The aim of this research is to study the influence of nanoparticles volume fraction,nanopartic...Presence of different terms with various values can alter the thermal behavior of the nanofluids flow over porous surfaces.The aim of this research is to study the influence of nanoparticles volume fraction,nanoparticles type,suction or injection,the heat generation or absorption,the Eckert number,thermal and velocity slip parameters,and radiation on the velocity and temperature fields on the flow and heat transfer over a porous flat plate.Four different types of nanoparticles including metal nanoparticles (Cu),metal oxide nanoparticles (Al2O3) and carbon-based nanomaterials (MWCNTs and SWCNTs) which were dispersed in the water (as based fluid) are studied.The governing equations are converted into the ordinary differential equations using similarity solution and solved numerically by the RKF45 algorithm.The results of the simulations showed a contradiction with the results of other researchers who expressed that using nanoparticles with higher thermal conductivity and volume fraction led to increasing heat transfer rate in nanofluids;this study proves that,in some cases,boosting the volume fraction of nanoparticles has a potential to decrease the heat transfer rate due to significant changes in values of some parameters including radiation,heat generation,and viscous dissipation.展开更多
Two-photon fluorescence dyes have shown promising applications in biomedical imaging.However,the substitution site effect on geometric structures and photophysical properties of fluorescence dyes is rarely illustrated...Two-photon fluorescence dyes have shown promising applications in biomedical imaging.However,the substitution site effect on geometric structures and photophysical properties of fluorescence dyes is rarely illustrated in detail.In this work,a series of new lipid droplets detection dyes are designed and studied,molecular optical properties and non-radiative transitions are analyzed.The intramolecular weak interaction and electron-hole analysis reveal its inner mechanisms.All dyes are proven to possess excellent photophysical properties with high fluorescence quantum efficiency and large stokes shift as well as remarkable two-photon absorption cross section.Our work reasonably elucidates the experimental measurements and the effects of substitution site on two-photon absorption and excited states properties of lipid droplets detection NAPBr dyes are highlighted,which could provide a theoretical perspective for designing efficient organic dyes for lipid droplets detection in biology and medicine fields.展开更多
By means of the nuclear parton distribution studied only with lepton deep-inelastic scattering experimental data, the J/ψ "normal nuclear absorption" and energy loss effects are studied in a GIauber formalism at HE...By means of the nuclear parton distribution studied only with lepton deep-inelastic scattering experimental data, the J/ψ "normal nuclear absorption" and energy loss effects are studied in a GIauber formalism at HERA and RHIC energies. Assuming that the absorption cross section σabs increases with the charmonium-nucleon center of mass energy, the results reveal a significant dependence of the aabs on rapidity g at RHIC energies. The initial-state energy loss effect, which is found important only at HERA energies, is also considered, and its influence should be eliminated when we studied the absorption effect at low collision energies. Finally, we also present the theoretical prediction for LHC.展开更多
文摘A novel 800nm Bragg mirror type of semiconductor saturable absorption mirror wit h low temperature method and surface state method combined absorber is presented .With which passive Kerr lens mode locking of Ti∶Al 2O 3 laser pumped by argo n ion laser is realized,which produces pulses as short as 40fs.The spectrum band width is 56nm,which means that it can support the modelocking of 20fs.The pulse frequency is 97.5MHz;average output power is 300mW at the pump power of 4.45W.
文摘The analytic response theory at density functional theory level is applied to investigate onephoton and two-photon absorption properties of a series of recently synthesized pyrene-core derivatives. The theoretical results show that there are a few charge-transfer states for each compound in the lower energy region. The one-photon absorption properties of the five investigated compounds are highly consistent with those given by experimental measurements. The two-photon absorption intensities of the compounds are greatly enhanced with the increments of the molecular sizes, in which the two-photon absorption cross section of the four-branched compound is about 5.6 times of that of the mono-branched molecule. Fhrthermore, it is shown that the two-photon absorption properties are sensitive to the geometrical arrangements.
基金supported in part by the National Key R&D Program of China(No.2021YFF0603100)in part by the Leading Innovation and Entrepreneurship Team in Zhejiang Province(No.2019R01014)
文摘H_(2)S is one of the most important characteristic decomposition components of SF_(6)insulated gas,and the detection of trace H_(2)S is significant for early fault diagnosis of gas insulated electrical equipment.A 1578 nm wavelength distributed feedback diode laser(DFB-DL)based cavity ring-down spectroscopy(CRDS)experimental platform is developed to monitor the concentrations of H_(2)S in SF_(6)and SF_(6)/N_(2)mixture carrier gas.The detection sensitivity is higher than 1×10^(-6).The absorption cross section parameterσis vital for calculating the concentration.With repeated experiments using standard gas samples,parameterσof H_(2)S in pure SF_(6)and SF_(6)/N_(2)mixture carrier with different mixing ratios is calibrated.Compared with the simulatedσvalues,the influence of carrier gas on the broadening of spectral profile is discussed.The variation of absorption cross sectionσwith different carrier gas mixing ratios is studied as well,so that the calculation of the concentration in the carrier gas of any mixing ratio is possible.Thus,the application of CRDS in trace component detection of gas insulated electrical equipment is promising.
基金Supported by the National Natural Science Foundation of China(No. 20176036).
文摘This paper focuses on the mechanism of interfacial mass transfer of a single bubble, based on the chemical potential driving force, an approach for calculating interfacial concentration in practical process is proposed. The absorption processes of bubble under both quiescent and mobile conditions are analyzed and discussed respectively. For a stationary absorption, only in the case of liquid bulk concentration near saturated value, the interfacial concentration could close to the equilibrium value ; For a moving bubble, under ordinary operating condition (Yo〉l), the interfacial concentration is far from its equilibrium. Only under bulk concentration near saturated value or a smaller Yo(Yo〈0.1) which may involve the complication of additional resistance at interface induced by surface contamination or surfactant added, the interfacial concentration could be approximate to equilibrium value. The interfacial concentration close to the interface on liquid side for a single CO2 bubble absorbed by methanol is measured using a modern optical instrumentation in which the laser holographic interference method is adopted with a real-time and amplification technique. Experimental results show that the interfacial concentration decreases significantly with increasing Re and is far from the equilibrium one in a larger Re range. Experiments validate the proposed model.
基金Supported by the Natural Science Foundations of Ludong University under Grant Nos.22270301 and L20072804
文摘The photoabsorption cross sections of condensed atoms and molecules have proven to be dependent not only on the imaginary parts but also on the real parts of the polarizabilities due to the strong interatomie interactions in condensed environment. The real parts of the polarizabilities calculated usually by using the famous Kramers-Kronig transformation (KKT) from the photoabsorption cross sections of the isolated atoms are very sensitive to the accuracy of the implementation method of the infinite integral in the KKT. The influence of the integral instability of the KKT and the real part of the polarizability on the variation of the photoabsorption cross sections with the number density and the structure of the condensed matter has been studied in the present work for the first time. The conclusion is that the integration method with interpolation has given more reasonable results than the direct truncation method if some appropriate interpolation functions have been used. Some notes and conclusions have also been given for the applications of the alternative coupled expressions of photoabsorption cross sections.
基金Supported by the National Natural Science Foundation of China(20736005)
文摘The effect of different surfactants(n-octyltrimethylammonium bromide(OTABr),sodium dodecyl benzene sulfonate(SDBS) and Tween 80) with different critical micelle concentrations(CMC) on the CO_2 absorption into aqueous solutions in a bubble column is analyzed in the present work.The presence of these surfactants increased the gas-liquid interfacial area,and decreased the liquid phase mass transfer coefficient,but with significant different extent.The results indicated that the CMC can be a key parameter affecting the mass transfer of CO_2 absorption into a dilute aqueous solution of a surfactant.Sardeing's model was used to fit the experimental data successfully by re-correlating the parameters.
基金Project(2006AA06Z120) supported by High-Technology Research and Development Program of ChinaProject(1343-74334000028) supported by the Graduate Student Education Innovation Project of Central South University, China
文摘In order to selectively separate chalcopyrite from pyrite,the effect of organic depressant lignosulfonate calcium(LSC) on the flotation separation of chalcopyrite from pyrite was investigated by flotation tests. The depression mechanism was studied by Fourier-transform-infrared(FTIR) analysis. The flotation tests of single mineral show that LSC can depress the flotation of pyrite in a certain pH range,but it has little effect on chalcopyrite flotation. Flotation separation of a mixture of chalcopyrite and pyrite can be completed to obtain a copper concentrate grade up to 24.73% with a recovery of 80.36%. IR analysis shows that LSC and butyl xanthate compete in absorption on pyrite surface,and there exists an LSC characteristic peak on pyrite surface. There is little adsorption of LSC on chalcopyrite.
基金the National Natural Science Foundation of China (No. 20025618, No. 20236010) Shanghai Municipal Education Commission of China.
文摘The adsorption behavior of symmetric triblock copolymers, Am/2BnAm/2, from a nonselective solvent at solid-liquid interface has been studied by Monte Carlo simulations on a simple lattice model. Either segment A or segment B is attractive, while the other is non-attractive to the surface. Influences of the adsorption energy, bulk concentration, chain composition and chain length on the microstructure of adsorbed layers are presented. The results show that the total surface coverage and the adsorption amount increases monotonically as the bulk concentration increases. The larger the adsorption energy and the higher the fraction of adsorbing segments, the higher the total surface coverage is exhibited. The product of surface coverage and the proportion of non-attractive segments are nearly independent of the chain length, and the logarithm of the adsorption amount is a linear function of the reciprocal of the reduced temperature. When the adsorption energy is larger, the adsorption amount exhibits a maximum as the fraction of adsorbing segment increases. The adsorption isotherms of copolymers with different length of non-attractive segments can be mapped onto a single curve under given adsorption energy. The adsorption layer thickness decreases as the adsorption energy and the fraction of adsorbing segments increases, but it increases as the length of non-attractive segments increases. The tails mainly govern the adsorption layer thickness.
文摘Studies were initiated for two consecutive years to find out the effect of time of transplanting and seedlings hill^-l on the productivity of rice in Dera Ismail Khan district of North West Frontier Province (NWFP), Pakistan. The experiment was laid out in a randomized complete block design with split plot arrangements. Main plots consisted of four transplanting dates viz. 20th and 27th of June and 4th and 1 lth of July while sub-plots contained 1, 2, 3 or 4 seedlings hill^-1. Among transplanting dates, June 20th planted crop gave highest paddy yield and net return with I seedling hill^-1. It explains that the use of more seedlings hill^-1 not only adds to cost but is also a mere wastage of natural resources. Based on research findings, we conclude that the use of I seedling hill^-1 is most appropriate for timely sowing otherwise 4 seedlings hill^-1 should be used to compensate for the yield gap in late transplanted rice.
文摘Presence of different terms with various values can alter the thermal behavior of the nanofluids flow over porous surfaces.The aim of this research is to study the influence of nanoparticles volume fraction,nanoparticles type,suction or injection,the heat generation or absorption,the Eckert number,thermal and velocity slip parameters,and radiation on the velocity and temperature fields on the flow and heat transfer over a porous flat plate.Four different types of nanoparticles including metal nanoparticles (Cu),metal oxide nanoparticles (Al2O3) and carbon-based nanomaterials (MWCNTs and SWCNTs) which were dispersed in the water (as based fluid) are studied.The governing equations are converted into the ordinary differential equations using similarity solution and solved numerically by the RKF45 algorithm.The results of the simulations showed a contradiction with the results of other researchers who expressed that using nanoparticles with higher thermal conductivity and volume fraction led to increasing heat transfer rate in nanofluids;this study proves that,in some cases,boosting the volume fraction of nanoparticles has a potential to decrease the heat transfer rate due to significant changes in values of some parameters including radiation,heat generation,and viscous dissipation.
基金This work was supported by the National Natural Science Foundation of China(No.11804196 and No.11904210)the Project funded by China Postdoctoral Science Foundation(No.2018M642689)the Open Fund of Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates,(South China University of Technology)(No.2019B030301003).
文摘Two-photon fluorescence dyes have shown promising applications in biomedical imaging.However,the substitution site effect on geometric structures and photophysical properties of fluorescence dyes is rarely illustrated in detail.In this work,a series of new lipid droplets detection dyes are designed and studied,molecular optical properties and non-radiative transitions are analyzed.The intramolecular weak interaction and electron-hole analysis reveal its inner mechanisms.All dyes are proven to possess excellent photophysical properties with high fluorescence quantum efficiency and large stokes shift as well as remarkable two-photon absorption cross section.Our work reasonably elucidates the experimental measurements and the effects of substitution site on two-photon absorption and excited states properties of lipid droplets detection NAPBr dyes are highlighted,which could provide a theoretical perspective for designing efficient organic dyes for lipid droplets detection in biology and medicine fields.
文摘By means of the nuclear parton distribution studied only with lepton deep-inelastic scattering experimental data, the J/ψ "normal nuclear absorption" and energy loss effects are studied in a GIauber formalism at HERA and RHIC energies. Assuming that the absorption cross section σabs increases with the charmonium-nucleon center of mass energy, the results reveal a significant dependence of the aabs on rapidity g at RHIC energies. The initial-state energy loss effect, which is found important only at HERA energies, is also considered, and its influence should be eliminated when we studied the absorption effect at low collision energies. Finally, we also present the theoretical prediction for LHC.