基于鞋腔湿度的皮鞋舒适性主观评价方法

选择常见的4种面料、2种里料、1种内底和2种鞋垫材料互相搭配，生产出16类皮鞋各10双，合计160双255号（二型半）胶粘满帮男皮鞋作为样品鞋。选择了10位身高（170±5）cm，年龄为19～23岁，无脚病、脚型正常、脚长和脚跖围符合样品鞋号型、身体健康、有较强的理解和敏锐感觉的大学生作为受试者，并尽量保证南北方籍的比例相当。通过受试者对样品鞋进行试穿，并对试穿后的样品鞋面料的透水气性、吸水气性测试指标与主观舒适性评价进行对比。结果显示，基于鞋腔湿度的皮鞋舒适性主观评价是可行和准确的。

The Effect of Hydrophobic Modification of Zeolites on CO2 Absorption Enhancement

Two methods of the modification of zeolite were employed： framework element modification and surface coating, and the influence of the zeolites before and after modification on the CO2 absorption was investigated. It was found that although hydrophobicity of zeolite could be obtained by means of the surficial organic coating in the method of surface coating _mod!fication, partial channel of zeolite would be plugged, as a result, leading to the surface area reducing greatly. Distinctively, the framework element modification method could maintain not only complete lattice structure and adsorption capability of zeolite, but would also obtain a good hydrophobic property. Consequently, significant enhancement on gas absorption by this modified zeolite was achieved and up to a maximum enhancement factor of 2.62. This shows that the solid particles with good enhancement role to gas absorption need not only good adsorptive capability but also certain hydrophobicity. An unsteady heterogeneous model was employed to predict enhancement factor and the calculated results agree well with the experimental data.

A simplified adsorption model for water vapor adsorption on activated carbon

A simplified model was developed to describe the water vapor adsorption on activated carbon. The development of the simplified model was started from the original model proposed by DO and his co-workers. Two different kinds of carbon materials were prepared for water vapor adsorption, and the adsorption experiments were conducted at different temperatures(20-50 °C) and relative humidities(5%-99%) to test the model. It is shown that the amount of adsorbed water vapor in micropore decreases with the temperature increasing, and the water molecules form larger water clusters around the functional group as the temperature is up to a higher value. The simplified model describes reasonably well for all the experimental data. According to the fitted values, the parameters of simplified model were represented by the temperature and then the model was used to calculate the water vapor adsorption amount at 25 °C and 35 °C. The results show that the model can get relatively accurate values to calculate the water vapor adsorption on activated carbon.

High rank coalbed methane desorption characteristic and its application in production in Qinshui basin

Based on spontaneous desorption characteristic, the correlation of desorption time and gas content was analyzed and the application of it in production was researched. The desorption of high rank coalbed methane in Qinshui basin was periodic, and isotope fractionation effect also exists in the process. △δ^13C1 can be used to distinguish the stabilization of coalbed methane wells, associated with desorption rate, the individual well recoverable reserves can be calculated. Economically recoverable time can be predicted according to the logarithmic relationship between desorption gas content per ton and desorption time. The error between predicted result and numerical simulation result is only 1.5%.

Adsorption Refrigeration Performance of Shaped MIL-101-Water Working Pair

A new metal-organic framework of MIL-101 was synthesized by hydrothermal method and the powder prepared was pressed into a desired shape. The effects of molding on specific surface area and pore structure were investigated using a nitrogen adsorption method. The water adsorption isotherms were obtained by high vacuum gravimetric method, the desorption temperature of water on shaped MIL-101 was measured by thermo gravimetric analyzer, and the adsorption refrigeration performance of shaped MIL-101-water working pair was studied on the simulation device of adsorption refrigeration cycle system. The results indicate that an apparent hysteresis loop ap-pears in the nitrogen adsorption/desorption isotherms when the forming pressure is 10 MPa. The equilibrium ad-sorption capacity of water is up to 0.95 kg·kg^-1 at the forming pressure of 3 MPa （MIL-101-3）. The desorption peak temperature of water on MIL-101-3 is 82℃, which is 7 ℃ lower than that of silica gel, and the desorption temperature is no more than 100 ℃. At the evaporation temperature of 10 ℃, the refrigeration capacity of MIL-101-3-water is 1059 kJ·kg^-1, which is 2.24 times higher than that of silica gel-water working pair. Thus MIL-101-water working pair presents an excellent adsorption refrigeration performance.

Influence of Water Vapor on Silica Membrane： Adsorption Properties and Percolation Effect

The influence of water vapor on silica membrane with pore size of ,-4A has been investigated in terms of adsorption properties and percolation effect at 50 and 90 ℃. Two methods are employed： spectroscopic ellipsometry for water vapor adsorption and gas permeation of binary mixture of helium and H2O The adsorption behaviors on the silica membrane comply with the first-order Langmuir isotherm. The investigation demonstrates that helium flux through the silica membrane decreases dramatically in presence of H20 molecules. The transport of gas molecules through such small pores is believed not to be continuous any more, whereas it is reasonably assumed that the gas molecules hop from one occupied site to another unoccupied one under the potential gradient. When the coverage of H20 molecules on the silica surface increases, the dramatic decrease of helium flux could be related to percolation effect, where the adsorbed H20 molecules on the silica surface block the hopping of helium molecules.

Geomechanical and water vapor absorption characteristics of clay-bearing soft rocks at great depth

The geological and physico-mechanical properties characterization of deep soft rocks is one of the critical scientific issues for deep soft rock engineering. In the present study, X-ray diffraction(XRD) analysis,scanning electron microscope(SEM), and mercury intrusion porosimetry experiments were carried out to investigate the mineral compositions, microstructure and porosity characteristics of the 13 claybearing soft rock samples collected from a deep coal mine in China. Water vapor absorption and uniaxial compressive experiments were also performed to examine water absorption characteristics and waterinduced strength degradation effect of the investigated deep soft rock samples. The results show that the dominant mineral components in mudstone, coarse sandstone and fine sandstone samples were calcite, quartz and clay respectively. The contents of clay minerals in all samples were relatively high and ranged from 12.3%(N-4) to 56.5%(XS-1). Water vapor absorption processes of all the soft rock samples follow an exponential law which is very similar to the water vapor absorption behavior of conglomerate samples reported in our earlier study. Correlation analyses also suggested that there were good positive correlation relationships between water absorptivity and clay minerals for both mudstone and sandstone samples. Furthermore, it was found that vapor absorption was not correlated with the porosity for mudstone, however, positive correlation relationship was found between them for sandstone. Correlation analysis between UCS, modulus of elasticity and water content demonstrated that both of them tend to decrease with the increase of their water content due to water absorption.

Mathematical Simulation of Lithium Bromide Solution Laminar Falling Film Evaporation in Vertical Tube

For utilization of the residual heat of flue gas to drive the absorption chillers,a lithium-bromide falling film in vertical tube type generator is presented.A mathematical model was developed to simulate the heat and mass coupled problem of laminar falling film evaporation in vertical tube.In the model,the factor of mass transfer was taken into account in heat transfer performance calculation.The temperature and concentration fields were calculated.Some tests were conducted for the factors such as Re number,heating flux,the inlet concentration and operating pressure which can affect the heat and mass transfer performance in laminar falling film evaporation.The heat transfer performance is enhanced with the increasing of heat flux.An increasing inlet concentration can weaken the heat transfer performance.The operating pressure hardly affects on heat and mass transfer.The bigger inlet Re number means weaker heat transfer effects and stronger mass transfer.The mass transfer obviously restrains the heat transfer in the falling film solution.The relation between dimensionless heat transfer coefficient and the inlet Re number is obtained.