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熔盐法制备CuFeMnO_4光吸热材料的研究 被引量:1
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作者 王勇兵 刘贵山 +2 位作者 刘洋 高文元 郝洪顺 《人工晶体学报》 EI CAS CSCD 北大核心 2015年第9期2560-2563,2589,共5页
以KOH、KNO3为熔盐,Cu(NO3)2·3H2O、Fe(NO3)3·9H2O、50wt%Mn(NO3)2为原料,研究了金属离子配比及合成温度对熔盐法制备CuFeMnO4粉体的影响,采用XRD和FESEM进行物相及微观形貌的测试分析,利用自行设计测试装置对CuFeMnO4涂层的... 以KOH、KNO3为熔盐,Cu(NO3)2·3H2O、Fe(NO3)3·9H2O、50wt%Mn(NO3)2为原料,研究了金属离子配比及合成温度对熔盐法制备CuFeMnO4粉体的影响,采用XRD和FESEM进行物相及微观形貌的测试分析,利用自行设计测试装置对CuFeMnO4涂层的吸热性能进行评价。研究结果表明,CuFeMnO4粉体主晶相为尖晶石型,当金属离子配比为Fe3+∶Cu2+∶Mn2+=1∶0.5∶1时,可有效地抑制杂相的生成;合成温度为700℃时,晶体成核均匀,晶粒尺寸较小。该粉体制成涂料涂覆在铝板上,可使铝板的吸热温度提高22℃,增强了吸热效果。 展开更多
关键词 熔盐法 CuFeMnO4 尖晶石 吸热温度
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纳米Ag/ZnO复合粉体降低釉料熔融温度及节能分析 被引量:2
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作者 郭小燕 许绿丝 廖坤添 《能源与环境》 2012年第6期22-23,27,共3页
采用自制的纳米Ag/ZnO复合粉体用于釉料中,制备抗菌自洁净陶瓷。通过对釉料的热变化过程以及影像烧结分析,得知当纳米Ag/ZnO复合粉体添加量为5%可降低长石类熔融吸热温度77℃,可使釉料烧结熔融温度降低85℃,加宽釉料熔融温度范围17℃。... 采用自制的纳米Ag/ZnO复合粉体用于釉料中,制备抗菌自洁净陶瓷。通过对釉料的热变化过程以及影像烧结分析,得知当纳米Ag/ZnO复合粉体添加量为5%可降低长石类熔融吸热温度77℃,可使釉料烧结熔融温度降低85℃,加宽釉料熔融温度范围17℃。熔融温度范围的加宽有利于釉料的均化及应用。而且纳米Ag/ZnO复合粉体可降低白釉熔融吸热量,起到显著的节能效果。 展开更多
关键词 纳米AG ZnO复合粉体 降温烧结 熔融温度吸热
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单体正构烷烃及其混合物的热性能比较 被引量:4
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作者 韦一良 吴高明 《化工新型材料》 CAS CSCD 2004年第9期32-34,共3页
使用差示扫描量热法从吸热温度范围及吸热量大小两个方面研究了单体正构烷烃及其混合物的热性能 ,实验结果表明 ,单体正构烷烃与正构烷烃混合物的热性能明显不同 ,正构烷烃中碳原子数的数目及其分布 ,对相变材料用石蜡的吸热温度范围及... 使用差示扫描量热法从吸热温度范围及吸热量大小两个方面研究了单体正构烷烃及其混合物的热性能 ,实验结果表明 ,单体正构烷烃与正构烷烃混合物的热性能明显不同 ,正构烷烃中碳原子数的数目及其分布 ,对相变材料用石蜡的吸热温度范围及吸热量大小影响很大 ,石蜡中正构烷烃种类越少 ,正构烷烃含量越高 。 展开更多
关键词 差示扫描量热法 吸热温度 吸热 正构烷烃 热性能 DSC曲线
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有限时间实际蒸汽动力循环热力性能优化 被引量:2
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作者 赵东旭 余敏 +1 位作者 陈丽超 杨茉 《上海理工大学学报》 CAS 北大核心 2010年第4期329-332,共4页
基于有限时间热力学的理论,根据平均温度法建立循环模型,得出在保持无因次功率PN为定值的条件下,使无因次熵产率Sσ达最小的最佳温差方程.分析了实际蒸汽动力循环反映温差的各无量纲量x、y、α和性能参数比β等对循环性能的影响.研究结... 基于有限时间热力学的理论,根据平均温度法建立循环模型,得出在保持无因次功率PN为定值的条件下,使无因次熵产率Sσ达最小的最佳温差方程.分析了实际蒸汽动力循环反映温差的各无量纲量x、y、α和性能参数比β等对循环性能的影响.研究结果表明,在循环不可逆损失一定时,可采用提高高低温热源温度比α、降低性能参数比β的方法来提高功率PN. 展开更多
关键词 实际蒸汽动力循环 平均吸热温度 平均放热温度 无因次熵产率 无因次功率
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OPTIMUM OF PRESSURE RATIOS OF MULTI-STAGE RECIPROCATING COMPRESSOR WITH PRACTICAL INTER-COOLING 被引量:1
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作者 刘卫华 昂海松 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI 2002年第2期177-181,共5页
The optimum pressure ratio distribution of a multistage reciprocating compressor is presented based on the assumption, i.e. the inter stage cooling is perfect and there are no pressure losses. The optimization of the... The optimum pressure ratio distribution of a multistage reciprocating compressor is presented based on the assumption, i.e. the inter stage cooling is perfect and there are no pressure losses. The optimization of the two or three stage pressure ratio is analyzed in two cases of constant heat transfer rate for the inter cooler or constant inter stage inlet temperature, based on the minimum of the sum of theoretical compression power at each stage about a multi stage reciprocating compressor. Furthermore, with an example of two stage compressor the influence on the sum of the power of each stage is analyzed when practical pressure ratio deviates from the optimum value. It is obtained that under different cooling conditions the optimum pressure ratio distribution of the multi stage compression is various, and the change of the optimum pressure ratio within a small range has little influence on the sum of the power each stage. For the two stage compression, this range can be represented as ε 1=(0 96~1 06)ε 1j . 展开更多
关键词 inter cooler multi stage compressor pressure ratio OPTIMUM
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Investigation into the surface active groups of coal 被引量:1
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作者 徐精彩 薛韩玲 +2 位作者 邓军 文虎 张辛亥 《Journal of Coal Science & Engineering(China)》 2001年第1期88-96,共9页
The oxidation heat of coal is the direct reason leading to coal spontaneous combustion. When coal is exposed in oxygen atmosphere, the physical adsorption and chemisorption happened, and then which resulting chemical ... The oxidation heat of coal is the direct reason leading to coal spontaneous combustion. When coal is exposed in oxygen atmosphere, the physical adsorption and chemisorption happened, and then which resulting chemical reaction followed heat between coal and oxygen. Owing to the complexity and uncertain of molecular structure of coal,it was only reduced that bridge bonds, side chains and O 2 containing functional groups in coal may be prone to oxidation in last year, but not to deeply investigate into the structures and the type of the active radicals. In this paper, according to the last achievements in coal structure research, the hypomethylether bond, hypoalkyl bond of α carbon atom with hydroxyl and α carbon atom with hypomethy side chain and hypomethyl bonds linking up two aromatic hydrocarbon in bridge bonds, and methoxy,aldehyde and alkyls of α carbon atom with hydroxy in side bonds are inferred to be free radical easily to lead to oxidize coal under the ambient temperature and pressure. The order from strong to weak of oxide activation of the seven surface active groups is aldehyde side chains, hypomethylether bonds, hypoalkyl bonds of α carbon atom with hydroxyl, hypoalkyl bonds of α carbon atom with hypomethyl, hypomethyl bonds linking up two aromatic hydrocarbon,methoxy, alkyls side chains of α carbon atom with hydroxyl. Because of the two unsaturated molecular tracks of O 2, unpaired electron clouds of the part of surface active groups of coal enter molecular tracks of O 2 to lead to chemisorb on the conjugate effect and induced effect of surface active groups, and then chemical reaction followed heat happens in them. On the basis of change of bond energy, weighted average method is adopted to count the reaction heat value of each mol CO,CO 2 and H 2O. The property of coal spontaneous combustion is different for the different number and oxidability of the active structure in the coal resulting in the different oxidation heat. 展开更多
关键词 coal spontaneous combustion surface active group oxidation reaction reactive heat
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合成橡胶工业
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《石油石化节能与减排》 1995年第11期36-39,共4页
TQ330.3 9511221橡胶防护蜡组成的DSC研究[刊]/于雅琴(抚顺石油化工研究院)//抚顺石油化工研究院院报.-1994,7(4).-60~65探讨了石蜡及微晶蜡的组成与DSC曲线的最高吸热峰温度之间的关系。通过国内外橡胶防护蜡的DSC结果对比,表明该院... TQ330.3 9511221橡胶防护蜡组成的DSC研究[刊]/于雅琴(抚顺石油化工研究院)//抚顺石油化工研究院院报.-1994,7(4).-60~65探讨了石蜡及微晶蜡的组成与DSC曲线的最高吸热峰温度之间的关系。通过国内外橡胶防护蜡的DSC结果对比,表明该院研制的产品与国外产品的组成相似。研究结果证明,石蜡的碳原子数分布最高峰的碳数与其DSC曲线的最高吸热峰温度的变化趋势相一致。 展开更多
关键词 合成橡胶工业 石油化工 橡胶防护蜡 吸热温度 橡胶工业制品 特种橡胶制品 国外产品 顺丁橡胶 石蜡 高岭土
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Effects of thermal transport properties on temperature distribution within silicon wafer
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作者 王爱华 牛义红 +1 位作者 陈铁军 P.F.HSU 《Journal of Central South University》 SCIE EI CAS 2014年第4期1402-1410,共9页
A combined conduction and radiation heat transfer model was used to simulate the heat transfer within wafer and investigate the effect of thermal transport properties on temperature non-uniformity within wafer surface... A combined conduction and radiation heat transfer model was used to simulate the heat transfer within wafer and investigate the effect of thermal transport properties on temperature non-uniformity within wafer surface. It is found that the increased conductivities in both doped and undoped regions help reduce the temperature difference across the wafer surface. However, the doped layer conductivity has little effect on the overall temperature distribution and difference. The temperature level and difference on the top surface drop suddenly when absorption coefficient changes from 104 to 103 m-1. When the absorption coefficient is less or equal to 103 m-1, the temperature level and difference do not change much. The emissivity has the dominant effect on the top surface temperature level and difference. Higher surface emissivity can easily increase the temperature level of the wafer surface. After using the improved property data, the overall temperature level reduces by about 200 K from the basis case. The results will help improve the current understanding of the energy transport in the rapid thermal processing and the wafer temperature monitor and control level. 展开更多
关键词 silicon wafer thermal transport properties temperature distribution radiation heat transfer
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A numerical investigation in buoyancy effects on micro jet diffusion flame
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作者 LIU Lei ZHAO Ming +2 位作者 CHEN Yi-kun FAN Ai-wu LI Dan 《Journal of Central South University》 SCIE EI CAS CSCD 2020年第3期867-875,共9页
The buoyancy effect on micro hydrogen jet flames in still air was numerially studied.The results show that when the jet velocity is relatively large(V≥0.2 m/s),the flame height,width and temperature decrease,whereas ... The buoyancy effect on micro hydrogen jet flames in still air was numerially studied.The results show that when the jet velocity is relatively large(V≥0.2 m/s),the flame height,width and temperature decrease,whereas the peak OH mass fraction increases significantly under normal gravity(g=9.8 m/s^2).For a very low jet velocity(e.g.,V=0.1 m/s),both the peak OH mass fraction and flame temperature under g=9.8 m/s^2 are lower than the counterparts under g=0 m/s^2.Analysis reveals that when V≥0.2 m/s,fuel/air mixing will be promoted and combustion will be intensified due to radial flow caused by the buoyancy effect.However,the flame temperature will be slightly decreased owing to the large amount of entrainment of cold air into the reaction zone.For V=0.1 m/s,since the heat release rate is very low,the entrainment of cold air and fuel leakage from the rim of tube exit lead to a significant drop of flame temperature.Meanwhile,the heat loss rate from fuel to inner tube wall is larger under g=9.8 m/s^2 compared to that under g=0 m/s^2.Therefore,the buoyancy effect is overall negative at very low jet velocities. 展开更多
关键词 micro jet diffusion flame buoyancy effect flame structure flame temperature air entrainment preheating effect
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A Mechanical and Experimental Study on the Heat Loss of Solar Evacuated Tube 被引量:1
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作者 赵惠忠 刘震炎 +3 位作者 张敏 黄晨 王丽慧 邹志军 《Journal of Shanghai Jiaotong university(Science)》 EI 2009年第1期52-57,共6页
The experimental system of heat loss of all-glass evacuated solar collector tubes(evacuated tube) is firstly designed and constructed,which uses electric heater as thermal resource.The equilibrium temperatures are les... The experimental system of heat loss of all-glass evacuated solar collector tubes(evacuated tube) is firstly designed and constructed,which uses electric heater as thermal resource.The equilibrium temperatures are less than±1℃during the test.and the temperature differences of up/middle/low node in the tube are less than 1℃,3℃,and 7℃respectively.The heat loss of evacuated tube increases about 2.7%with vacuum state of 0.01--1 mPa,and it has the best performance at tube temperature of 20--280℃.The invalidation tube(>200 mPa) has the biggest heat loss that increases linearly with the tube temperature.The evacuated tubes with the vacuum of 0.01-1 mPa are suitable for most solar adsorption refrigeration. 展开更多
关键词 all-glass evacuated solar collector tube adsorption refrigeration vacuum state heat loss equilibrium temperature
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The Study on the Heat Transfer Characteristics of Oxygen Fuel Combustion Boiler
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作者 WU Haibo LIU Zhaohui LIAO Haiyan 《Journal of Thermal Science》 SCIE EI CAS CSCD 2016年第5期470-475,共6页
According to 350 MW and 600 MW boilers,under oxygen fuel condition,through the reasonable control of the primary and secondary flow and the correct option and revision of mathematical model,the temperature distributio... According to 350 MW and 600 MW boilers,under oxygen fuel condition,through the reasonable control of the primary and secondary flow and the correct option and revision of mathematical model,the temperature distribution,heat flux distribution and absorption heat distribution,etc.was obtained which compared with those under air condition.Through calculation,it is obtained that the primary and secondary flow mixed well,good tangentially fired combustion in furnace was formed,the temperature under air condition obviously higher than the temperature under O26 condition.The adiabatic flame temperature of wet cycle was slightly higher than that of dry cycle.The maximum heat load appeared on the waterwall around the burner area.The heat load gradually decreased along the furnace height up and down in burner area.The heat absorption capacity of the furnace under O26 was lower than that under the air condition.The heat absorption capacity of the platen heating surface under 026 was equal to that under air condition.And the heat absorbing capacity of waterwall under O26 was about 7%~12% less than that under air condition. 展开更多
关键词 Large-scale boiler Oxygen fuel combustion Heat transfer characteristics Numerical calculation
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