2D carbon ribbon/Al_(2)O_(3) was synthesized with two-dimensional metal organic frameworks 2D-MOFs as precursors using the solvothermal and calcination methods.Batch experiments of adsorption parameters such as pH,liq...2D carbon ribbon/Al_(2)O_(3) was synthesized with two-dimensional metal organic frameworks 2D-MOFs as precursors using the solvothermal and calcination methods.Batch experiments of adsorption parameters such as pH,liquid/solid ratio,adsorption kinetics,adsorption thermodynamics,and anions competitions were investigated to understand the adsorptive behavior of fluoride on carbon ribbon/Al_(2)O_(3) and nitrogen-doped carbon ribbon/Al_(2)O_(3).The adsorption of fluoride on carbon ribbon/Al_(2)O_(3) could be described as the chemical and multilayer adsorption,while the adsorption of fluoride on nitrogen-doped carbon ribbon/Al_(2)O_(3) followed the chemical and monolayer adsorption phenomenon.The fluoride on nitrogen-doped carbon ribbon/Al_(2)O_(3) had a much faster adsorption rate of 3.1×10^(−7) m/s than carbon ribbon/Al_(2)O_(3),which was 1.2×10^(−7) m/s.The nitrogen-doping on carbon ribbon enhances structural defects and improves the adsorption performance of fluoride.Also,the diacetylene linkages(—C≡C—)and pyridinic-N were studied to understand their influences on removing fluoride.The result indicates that carbon ribbon and nitrogen-doped ribbon could serve as good adsorbents for removing fluoride.展开更多
A series of porous resins (PYR) with different content of pyridyl group were prepared,and their physical structure and adsorption properties on the stevia glycosides werestudied in detail. Afler the selective adsorpti...A series of porous resins (PYR) with different content of pyridyl group were prepared,and their physical structure and adsorption properties on the stevia glycosides werestudied in detail. Afler the selective adsorption of PYR resins, the rebaudioside A couldbe separated hem the other components of the stevia glycosides, and a new methodforobtaining pure rebaudioside A is reported.展开更多
基金the financial supports from the Key R&D Program of Hunan Province,China(No.2018SK2026)the National Key R&D Program of China(No.2018YFC1802204)the National Natural Science Foundation of China(No.51634010).
文摘2D carbon ribbon/Al_(2)O_(3) was synthesized with two-dimensional metal organic frameworks 2D-MOFs as precursors using the solvothermal and calcination methods.Batch experiments of adsorption parameters such as pH,liquid/solid ratio,adsorption kinetics,adsorption thermodynamics,and anions competitions were investigated to understand the adsorptive behavior of fluoride on carbon ribbon/Al_(2)O_(3) and nitrogen-doped carbon ribbon/Al_(2)O_(3).The adsorption of fluoride on carbon ribbon/Al_(2)O_(3) could be described as the chemical and multilayer adsorption,while the adsorption of fluoride on nitrogen-doped carbon ribbon/Al_(2)O_(3) followed the chemical and monolayer adsorption phenomenon.The fluoride on nitrogen-doped carbon ribbon/Al_(2)O_(3) had a much faster adsorption rate of 3.1×10^(−7) m/s than carbon ribbon/Al_(2)O_(3),which was 1.2×10^(−7) m/s.The nitrogen-doping on carbon ribbon enhances structural defects and improves the adsorption performance of fluoride.Also,the diacetylene linkages(—C≡C—)and pyridinic-N were studied to understand their influences on removing fluoride.The result indicates that carbon ribbon and nitrogen-doped ribbon could serve as good adsorbents for removing fluoride.
文摘A series of porous resins (PYR) with different content of pyridyl group were prepared,and their physical structure and adsorption properties on the stevia glycosides werestudied in detail. Afler the selective adsorption of PYR resins, the rebaudioside A couldbe separated hem the other components of the stevia glycosides, and a new methodforobtaining pure rebaudioside A is reported.
