To study the effects of CBM （coal bed methane） temperature-rising desorption, isothermal adsorption/desorption experiments on three ranks （anthracite, coking coal and lignite） of coal at different temperatures wer...To study the effects of CBM （coal bed methane） temperature-rising desorption, isothermal adsorption/desorption experiments on three ranks （anthracite, coking coal and lignite） of coal at different temperatures were designed based on the traditional CBM decompression desorption. The experimental results indicate that temperature-rising desorption is more effec- tive in high-rank coal, and ever-increasing temperature of high-rank coal reservoir can reduce the negative effects of coal ma- trix shrinkage in the process of production and improve the permeability of the coal reservoir as well. It is also revealed that the technique of temperature-rising desorption applied in higher-rank coal reservoir can enhance CBM recovery ratio. This study provided theoretical support for the application of temperature-rising desorption technique in practical discharging and mining projects, which can effectively tackle the gas production bottleneck problem.展开更多
The present study investigated the removal of inorganic arsenic from Pinctada martensii enzymatic hydrolysate through unmodified resin （D296） and Zr（IV）-loaded chelating resin （Zr-D401）. By loading Zr to macropo...The present study investigated the removal of inorganic arsenic from Pinctada martensii enzymatic hydrolysate through unmodified resin （D296） and Zr（IV）-loaded chelating resin （Zr-D401）. By loading Zr to macroporous chelating resin D401, the as exchange adsorption active sites are generated. This transforms D401 from a material that does not have the arsenic adsorption capacity into a material that has excellent arsenic exchange adsorption capacity. The static adsorption experiments were conducted to investigate the optimal removal condition for D296 and Zr-D401. The experimental results show that： the optimum condition for D296 is that T= 25℃, pH= 5, resin additive amount= 1 g （50 mL）-1, and contact time = 10 h, the corresponding arsenic removal rate being 65.7%, and protein loss being 2.33%; the optimum condition for Zr-D401 is that T=25 ℃, pH = 8, resin additive amount= 1 g （50 mL）-1, and contact time=10 h, the corresponding arsenic removal rate being 70.3%, and protein loss being 4.65%. These results show that both of the two resins are effective in arsenic removal for preserving useful substance. Our research provides scientific evidence and advances in the processing technology for heavy metal removal in shellfish.展开更多
An experimental system for monitoring the acoustic signals generated in coal during gas sorption and/or desorption was designed and the acoustic signals were observed under different gas pressures. The experimental re...An experimental system for monitoring the acoustic signals generated in coal during gas sorption and/or desorption was designed and the acoustic signals were observed under different gas pressures. The experimental results show that signals generated by the coal during gas adsorption are attenuated over time. Also, the signals are not continuous but are impulsive. The intensity of the signals generated during gas desorption is far smaller than that observed during adsorption. The signal seen during desorption remains essentially stable. Cycles of sorption and desorption cause acoustic emission signals that exhibit a memory effect, which depends upon the maximum gas pressure the sample was exposed to in earlier cycles. Lower pressures in subsequent cycles, compared to the maximum adsorption pressure in previous cycles, cause both the energy and impulse frequency to be lower than previously. On the contrary, a gas adsorption pressure that exceeds the maximum pressure seen by the sample during earlier cycles causes both the energy and impulse frequency to be high.展开更多
Quantitative description of desorption stages of coalbed methane is an important basis to objectively understand the production of coalbed methane well,to diagnose the production state,and to optimize the management o...Quantitative description of desorption stages of coalbed methane is an important basis to objectively understand the production of coalbed methane well,to diagnose the production state,and to optimize the management of draining and collection of coalbed methane.A series of isothermal adsorption experiments were carried out with 12 anthracite samples from 6 coalbed methane wells located in the south of the Qinshui Basin,based on the results of isothermal adsorption experiments,and an analytical model was developed based on the Langmuir sorption theory.With the model,a numerical method that adopts equivalent desorption rate and its curve was established,which can be used to characterize the staged desorption of coalbed methane.According to the experimental and numerical characterizations,three key pressure points determined by the equivalent desorption rate curvature that defines pressure-declining desorption stage,have been proposed and confirmed,namely,start-up pressure,transition pressure and sensitive pressure.By using these three key pressure points,the process of coalbed methane desorption associated with isothermal adsorption experiments can be divided into four stages,i.e.,zero desorption stage,slow desorption stage,transition desorption stage,and sensitive desorption stage.According to analogy analysis,there are differences and similarities between the processes of coalbed methane desorption identified by isothermal adsorption experiments and observed in gas production.Moreover,it has been found that larger Langmuir volume and ratio of Langmuir constants are beneficial to earlier advent of steady production stage,whereas it is also possible that the declining production stage may occur ahead of schedule.展开更多
文摘To study the effects of CBM （coal bed methane） temperature-rising desorption, isothermal adsorption/desorption experiments on three ranks （anthracite, coking coal and lignite） of coal at different temperatures were designed based on the traditional CBM decompression desorption. The experimental results indicate that temperature-rising desorption is more effec- tive in high-rank coal, and ever-increasing temperature of high-rank coal reservoir can reduce the negative effects of coal ma- trix shrinkage in the process of production and improve the permeability of the coal reservoir as well. It is also revealed that the technique of temperature-rising desorption applied in higher-rank coal reservoir can enhance CBM recovery ratio. This study provided theoretical support for the application of temperature-rising desorption technique in practical discharging and mining projects, which can effectively tackle the gas production bottleneck problem.
基金supported by National Key Technologies R&D Program of China(2008 BAD94B08)
文摘The present study investigated the removal of inorganic arsenic from Pinctada martensii enzymatic hydrolysate through unmodified resin （D296） and Zr（IV）-loaded chelating resin （Zr-D401）. By loading Zr to macroporous chelating resin D401, the as exchange adsorption active sites are generated. This transforms D401 from a material that does not have the arsenic adsorption capacity into a material that has excellent arsenic exchange adsorption capacity. The static adsorption experiments were conducted to investigate the optimal removal condition for D296 and Zr-D401. The experimental results show that： the optimum condition for D296 is that T= 25℃, pH= 5, resin additive amount= 1 g （50 mL）-1, and contact time = 10 h, the corresponding arsenic removal rate being 65.7%, and protein loss being 2.33%; the optimum condition for Zr-D401 is that T=25 ℃, pH = 8, resin additive amount= 1 g （50 mL）-1, and contact time=10 h, the corresponding arsenic removal rate being 70.3%, and protein loss being 4.65%. These results show that both of the two resins are effective in arsenic removal for preserving useful substance. Our research provides scientific evidence and advances in the processing technology for heavy metal removal in shellfish.
基金provide by the National Natural Science Foundation of China (Nos. 40804070, 50904067 and51104156)the Research Fund of The State Key Laboratory of Coal Resources and Mine Safety in CUMT (No. SKLCRSM09X01)+2 种基金the International Scientific and Technological Cooperation Projects(No. 2008DFB70100)the Foundation for the Author of National Excellent Doctoral Dissertation of China (No. 201055)the Program for New Century Excellent Talents in University (No. NCET-10-0768)
文摘An experimental system for monitoring the acoustic signals generated in coal during gas sorption and/or desorption was designed and the acoustic signals were observed under different gas pressures. The experimental results show that signals generated by the coal during gas adsorption are attenuated over time. Also, the signals are not continuous but are impulsive. The intensity of the signals generated during gas desorption is far smaller than that observed during adsorption. The signal seen during desorption remains essentially stable. Cycles of sorption and desorption cause acoustic emission signals that exhibit a memory effect, which depends upon the maximum gas pressure the sample was exposed to in earlier cycles. Lower pressures in subsequent cycles, compared to the maximum adsorption pressure in previous cycles, cause both the energy and impulse frequency to be lower than previously. On the contrary, a gas adsorption pressure that exceeds the maximum pressure seen by the sample during earlier cycles causes both the energy and impulse frequency to be high.
基金supported by National KeyBasic Research Program of China (Grant No. 2009CB219605)Key Project of National Natural Science Foundation of China (Grant No.40730422)Grand Science and Technology Special Project of China(Grant No. 2011ZX05034-04)
文摘Quantitative description of desorption stages of coalbed methane is an important basis to objectively understand the production of coalbed methane well,to diagnose the production state,and to optimize the management of draining and collection of coalbed methane.A series of isothermal adsorption experiments were carried out with 12 anthracite samples from 6 coalbed methane wells located in the south of the Qinshui Basin,based on the results of isothermal adsorption experiments,and an analytical model was developed based on the Langmuir sorption theory.With the model,a numerical method that adopts equivalent desorption rate and its curve was established,which can be used to characterize the staged desorption of coalbed methane.According to the experimental and numerical characterizations,three key pressure points determined by the equivalent desorption rate curvature that defines pressure-declining desorption stage,have been proposed and confirmed,namely,start-up pressure,transition pressure and sensitive pressure.By using these three key pressure points,the process of coalbed methane desorption associated with isothermal adsorption experiments can be divided into four stages,i.e.,zero desorption stage,slow desorption stage,transition desorption stage,and sensitive desorption stage.According to analogy analysis,there are differences and similarities between the processes of coalbed methane desorption identified by isothermal adsorption experiments and observed in gas production.Moreover,it has been found that larger Langmuir volume and ratio of Langmuir constants are beneficial to earlier advent of steady production stage,whereas it is also possible that the declining production stage may occur ahead of schedule.
