The effect of Mn substitution for partial Fe in RFe 11Ti on structure and magnetic properties of compounds was researched. RFe 7Mn 4Ti samples (R=Y,Tb,Dy,Ho,Er) were prepared by means of vacuum arc-melting and s...The effect of Mn substitution for partial Fe in RFe 11Ti on structure and magnetic properties of compounds was researched. RFe 7Mn 4Ti samples (R=Y,Tb,Dy,Ho,Er) were prepared by means of vacuum arc-melting and subsequent vacuum annealing. The structure and magnetic properties of RFe 7Mn 4Ti compounds were investigated by X-ray powder diffraction and magnetic measurements. The following conclusions were obtained: all the RFe tMn 4Ti compounds crystallize in the ThMn 12-type structure. The lattice constants and the unit-cell volume changed with the increase of atomic number for R=Y, Tb, Dy, Ho, and Er. The compensation characters appear for the DyFe 7Mn 4Ti and HoFe 7Mn 4Ti compounds, and the compensation temperatures were about 123 K and 90 K, respectively. The Curie temperature, the saturation magnetization, and saturation moment of RFe 7Mn 4Ti compounds were given.展开更多
The protecting requirements and functional connectivity of species in isolated habitat patches are crucial factors of eco-network planning.This study aimed to improve the method of eco-network planning for species con...The protecting requirements and functional connectivity of species in isolated habitat patches are crucial factors of eco-network planning.This study aimed to improve the method of eco-network planning for species conservation.Ecoprofiling was used to group the species by similar behavior types,namely,choice of ecosystem,area requirement,and short distance dispersal abilities.A least-cost model was used to simulate the optimal corridor location to maintain functional connectivity.A combination of ecoprofile and least-cost model was hired to develop an eco-network that promoted species conservation.A case study was also conducted in Beijing,China.In addition to the required ecosystem,habitat area is an important parameter for habitat extraction.Habitat area can remove noise habitat patches because of lacking area.Short-distance dispersal can be used to identify corridor requirements and avoid unnecessary building requirements.Species with various dispersal abilities exhibit significant differences in terms of corridor length and location requirement.Habitat isolation is the main threat for weakly mobile species,and habitat loss is the major risk of mobile species protection.Different species groups also exhibit distinct landscape pattern demands for an eco-network,and the eco-network planning based on specific species can not protect other species.We proposed that a combination of ecoprofile and least-cost model improved the efficiency of species conservation by eco-network planning.展开更多
Considering the two-dimension(2 D) characteristic and the unknown optimal trajectory problem of the batch processes, an integrated model predictive control-iterative learning control(MPC-ILC) for batch processes is pr...Considering the two-dimension(2 D) characteristic and the unknown optimal trajectory problem of the batch processes, an integrated model predictive control-iterative learning control(MPC-ILC) for batch processes is proposed in this paper. Firstly, the batch-axis information and time-axis information are combined into one quadratic performance index. It implies the integration of ILC and MPC algorithm idea, which leads to superior tracking performance and better robustness against disturbance and uncertainty. To address the problem of the unknown optimal trajectory, both time-varying prediction horizon and end product quality control are employed. Moreover, an integrated 2 D just-in-time learning(JITL) model is used to improve the predictive accuracy. Furthermore, rigorous description and proof are presented to prove the convergence and tracking performance of the proposed MPC-ILC strategy. The simulation results show the effectiveness of the proposed method.展开更多
This work addresses the saturation influence of control voltage on the occurring of self-excited vibration of maglev vehicle-bridge interaction system, which greatly degrades the stability of the levitation control, d...This work addresses the saturation influence of control voltage on the occurring of self-excited vibration of maglev vehicle-bridge interaction system, which greatly degrades the stability of the levitation control, decreases the ride comfort, and restricts the cost of the whole system. Firstly, the interaction model of vehicle-bridge system is developed. Based on the interaction model, the relationship between the control voltage and vibration frequency is solved. Then, the variation of the effective direct component and fundamental harmonic are discussed. Furthermore, from the perspective of energy transmission between the levitation system and bridge, the principle underlying the self-excited vibration is explored, and the influence on the stability is discussed. Finally, in terms of the variation of the characteristic roots, the influence is analyzed further and some conclusions are obtained. This study provides a theoretical guidance for mastering the self-excited vibration problems.展开更多
It is difficult to determine the optimal weight on bit (WOB) of the double-driven bottomhole assembly (DD-BHA, with double stabilizers and a bent housing positive displacement motor (PDM)) which is employed during ver...It is difficult to determine the optimal weight on bit (WOB) of the double-driven bottomhole assembly (DD-BHA, with double stabilizers and a bent housing positive displacement motor (PDM)) which is employed during vertical and fast drilling. High WOB leads to well deviation out of control, and low WOB leads to low rate of penetration (ROP). So considering the rock physical properties, the anisotropy index function of polycrystalline diamond compact (PDC) bit was derived with the structure and cutting performance parameters of the bit, and the effect of natural hole deviation tendencies on the performance of DD-BHA resisting deviation was represented. The concept of elliptic deformation ratio was used to characterize the performance of DD-BHA resisting deviation. Eventually, a model calculating the critical WOB was established. By comparing the model predictions with the measured hole angle changes in the field, the results show that the model predictions are accurate with error less than 5.8%, which can meet the operational requirements in the projects. Furthermore, the model was adopted to justify and guide the operating conditions and parameters during drilling, which shows that the optimum WOB predicted by the model can not only control deviation but also improve ROP effectively. The model is independent on the formation characteristics of blocks, so it can be expanded widely to other oilfields.展开更多
Cell membrane fusion is a fundamental biological process involved in a number of cellular living functions. Regarding this, divalent cations can induce fusion of the lipid bilayers through binding and bridging of diva...Cell membrane fusion is a fundamental biological process involved in a number of cellular living functions. Regarding this, divalent cations can induce fusion of the lipid bilayers through binding and bridging of divalent cations to the charged lipids, thus leading to the cell membrane fusion. However, the elaborate mechanism of cell membrane fusion induced by divalent cations is still needed to be elucidated.Here, surface/interface sensitive sum frequency generation vibrational spectroscopy(SFG-VS) and dynamic light scattering(DLS) were applied in this research to study the responses of phospholipid monolayer to the exposure of divalent metal ions i.e.Ca^(2+)and Mg^(2+). According to the particle size distribution results measured by DLS experiments, it was found that Ca^(2+)could induce inter-vesicular fusion while Mg^(2+)could not. An octadecyltrichlorosilane self-assembled monolayer(OTS SAM)-lipid monolayer system was designed to model the cell membrane for the SFG-VS experiment. Ca^(2+)could interact with the lipid POO_(2)^(-)head groups more strongly, resulting in cell membrane fusion more easily, in comparison with Mg^(2+). No specific interaction between the two metal cations and the C=O groups was observed. However, the C=O orientations changed more after Ca^(2+)-PO2-binding than Mg^(2+)mediation on lipid monolayer. Meanwhile, Ca^(2+)could induce dehydration of the lipids(which should be related to the strong Ca^(2+)-PO_(2)^(-)interaction), leading to the reduced hindrance for cell membrane fusion.展开更多
A novel quantitative structure-property relationship (QSPR) model for estimating the solution surface tension of 92 organic compounds at 20℃ was developed based on newly introduced atom-type topological indices. Th...A novel quantitative structure-property relationship (QSPR) model for estimating the solution surface tension of 92 organic compounds at 20℃ was developed based on newly introduced atom-type topological indices. The data set contained non-polar and polar liquids, and saturated and unsaturated compounds. The regression analysis shows that excellent result is obtained with multiple linear regression. The predictive power of the proposed model was discussed using the leave-one-out (LOO) cross-validated (CV) method. The correlation coefficient (R) and the leave-one-out cross-validation correlation coefficient (Rcv) of multiple linear regression model are 0.991 4 and 0.991 3, respectively. The new model gives the average absolute relative deviation of 1.81% for 92 substances. The result demonstrates that novel topological indices based on the equilibrium electro-negativity of atom and the relative bond length are useful model parameters for QSPR analysis of compounds.展开更多
In order to examine and analyze the effects of integration of land surface models with TOPMODEL and different approaches for the integration on the model simulation of water and energy balances,the coupled models have...In order to examine and analyze the effects of integration of land surface models with TOPMODEL and different approaches for the integration on the model simulation of water and energy balances,the coupled models have been developed,which incorporate TOPMODEL into the Simplified Biosphere Model(SSiB) with different approaches(one divides a basin into a number of zones according to the distribution of topographic index,and the other only divides the basin into saturated and unsaturated zones).The coupled models are able to(but SSiB is not able to) take into account the impacts of topography variation and vertical heterogeneity of soil saturated hydraulic conductivity on horizontal distribution of soil moisture and in turn on water and energy balances within the basin(or a grid cell).By using the coupled models and SSiB model itself,the daily hydrological components such as runoffs are simulated and final results are analyzed carefully.Simulated daily results of hydrological components produced by both SSiB and coupled models show that(i) There is significant difference between results of soil wetness,its vertical distribution and seasonal variation,water and energy balance,and daily runoff in the basin predicted by SSiB and by the coupled models.The land surface model currently used such as SSiB is likely to misrepresent real feature of water and energy balances in the basin.(ii) Compared with the results for the basin predicted by SSiB,the coupled models predict more strong vertical and seasonal changes in soil wetness,higher evaporation and lower runoff,and improve the base flow simulation obviously.(iii) Comparing the results for the basin predicted by two coupled models with different integration approach and SSiB one by one,the results of daily runoffs and soil wetness predicted by the two coupled models are quite similar.It means,for the coupled models,the approach by dividing a region being considered into more subzones may have limited effects on improving runoff simulation results.The scheme only to divide the region into saturated and unsaturated zones may be a convenient and effective scheme.But then,if the results from the two coupled models for the basin are carefully compared,the simulated results by the coupled model with dividing the basin into more subzones will show higher evaporation and surface runoff but lower subsurface flow,lower total runoff,and lower ground water level averaged for five years.展开更多
Variable selection is an important research topic in modern statistics, traditional variable selection methods can only select the mean model and(or) the variance model, and cannot be used to select the joint mean, va...Variable selection is an important research topic in modern statistics, traditional variable selection methods can only select the mean model and(or) the variance model, and cannot be used to select the joint mean, variance and skewness models. In this paper, the authors propose the joint location, scale and skewness models when the data set under consideration involves asymmetric outcomes,and consider the problem of variable selection for our proposed models. Based on an efficient unified penalized likelihood method, the consistency and the oracle property of the penalized estimators are established. The authors develop the variable selection procedure for the proposed joint models, which can efficiently simultaneously estimate and select important variables in location model, scale model and skewness model. Simulation studies and body mass index data analysis are presented to illustrate the proposed methods.展开更多
文摘The effect of Mn substitution for partial Fe in RFe 11Ti on structure and magnetic properties of compounds was researched. RFe 7Mn 4Ti samples (R=Y,Tb,Dy,Ho,Er) were prepared by means of vacuum arc-melting and subsequent vacuum annealing. The structure and magnetic properties of RFe 7Mn 4Ti compounds were investigated by X-ray powder diffraction and magnetic measurements. The following conclusions were obtained: all the RFe tMn 4Ti compounds crystallize in the ThMn 12-type structure. The lattice constants and the unit-cell volume changed with the increase of atomic number for R=Y, Tb, Dy, Ho, and Er. The compensation characters appear for the DyFe 7Mn 4Ti and HoFe 7Mn 4Ti compounds, and the compensation temperatures were about 123 K and 90 K, respectively. The Curie temperature, the saturation magnetization, and saturation moment of RFe 7Mn 4Ti compounds were given.
基金Under the auspices of National Natural Science Foundation of China(No.41271198)
文摘The protecting requirements and functional connectivity of species in isolated habitat patches are crucial factors of eco-network planning.This study aimed to improve the method of eco-network planning for species conservation.Ecoprofiling was used to group the species by similar behavior types,namely,choice of ecosystem,area requirement,and short distance dispersal abilities.A least-cost model was used to simulate the optimal corridor location to maintain functional connectivity.A combination of ecoprofile and least-cost model was hired to develop an eco-network that promoted species conservation.A case study was also conducted in Beijing,China.In addition to the required ecosystem,habitat area is an important parameter for habitat extraction.Habitat area can remove noise habitat patches because of lacking area.Short-distance dispersal can be used to identify corridor requirements and avoid unnecessary building requirements.Species with various dispersal abilities exhibit significant differences in terms of corridor length and location requirement.Habitat isolation is the main threat for weakly mobile species,and habitat loss is the major risk of mobile species protection.Different species groups also exhibit distinct landscape pattern demands for an eco-network,and the eco-network planning based on specific species can not protect other species.We proposed that a combination of ecoprofile and least-cost model improved the efficiency of species conservation by eco-network planning.
基金Supported by the National Natural Science Foundation of China(61374044)Shanghai Science Technology Commission(15510722100,16111106300)Shanghai Municipal Education Commission(14ZZ088)
文摘Considering the two-dimension(2 D) characteristic and the unknown optimal trajectory problem of the batch processes, an integrated model predictive control-iterative learning control(MPC-ILC) for batch processes is proposed in this paper. Firstly, the batch-axis information and time-axis information are combined into one quadratic performance index. It implies the integration of ILC and MPC algorithm idea, which leads to superior tracking performance and better robustness against disturbance and uncertainty. To address the problem of the unknown optimal trajectory, both time-varying prediction horizon and end product quality control are employed. Moreover, an integrated 2 D just-in-time learning(JITL) model is used to improve the predictive accuracy. Furthermore, rigorous description and proof are presented to prove the convergence and tracking performance of the proposed MPC-ILC strategy. The simulation results show the effectiveness of the proposed method.
基金Projects(11302252,11202230)supported by the National Natural Science Foundation of China
文摘This work addresses the saturation influence of control voltage on the occurring of self-excited vibration of maglev vehicle-bridge interaction system, which greatly degrades the stability of the levitation control, decreases the ride comfort, and restricts the cost of the whole system. Firstly, the interaction model of vehicle-bridge system is developed. Based on the interaction model, the relationship between the control voltage and vibration frequency is solved. Then, the variation of the effective direct component and fundamental harmonic are discussed. Furthermore, from the perspective of energy transmission between the levitation system and bridge, the principle underlying the self-excited vibration is explored, and the influence on the stability is discussed. Finally, in terms of the variation of the characteristic roots, the influence is analyzed further and some conclusions are obtained. This study provides a theoretical guidance for mastering the self-excited vibration problems.
基金Projects(50804040,51004082)supported by the National Natural Science Foundation of China
文摘It is difficult to determine the optimal weight on bit (WOB) of the double-driven bottomhole assembly (DD-BHA, with double stabilizers and a bent housing positive displacement motor (PDM)) which is employed during vertical and fast drilling. High WOB leads to well deviation out of control, and low WOB leads to low rate of penetration (ROP). So considering the rock physical properties, the anisotropy index function of polycrystalline diamond compact (PDC) bit was derived with the structure and cutting performance parameters of the bit, and the effect of natural hole deviation tendencies on the performance of DD-BHA resisting deviation was represented. The concept of elliptic deformation ratio was used to characterize the performance of DD-BHA resisting deviation. Eventually, a model calculating the critical WOB was established. By comparing the model predictions with the measured hole angle changes in the field, the results show that the model predictions are accurate with error less than 5.8%, which can meet the operational requirements in the projects. Furthermore, the model was adopted to justify and guide the operating conditions and parameters during drilling, which shows that the optimum WOB predicted by the model can not only control deviation but also improve ROP effectively. The model is independent on the formation characteristics of blocks, so it can be expanded widely to other oilfields.
基金supported by the National Natural Science Foundation of China (No.21773028)the Fundamental Research Funds for the Central Universities。
文摘Cell membrane fusion is a fundamental biological process involved in a number of cellular living functions. Regarding this, divalent cations can induce fusion of the lipid bilayers through binding and bridging of divalent cations to the charged lipids, thus leading to the cell membrane fusion. However, the elaborate mechanism of cell membrane fusion induced by divalent cations is still needed to be elucidated.Here, surface/interface sensitive sum frequency generation vibrational spectroscopy(SFG-VS) and dynamic light scattering(DLS) were applied in this research to study the responses of phospholipid monolayer to the exposure of divalent metal ions i.e.Ca^(2+)and Mg^(2+). According to the particle size distribution results measured by DLS experiments, it was found that Ca^(2+)could induce inter-vesicular fusion while Mg^(2+)could not. An octadecyltrichlorosilane self-assembled monolayer(OTS SAM)-lipid monolayer system was designed to model the cell membrane for the SFG-VS experiment. Ca^(2+)could interact with the lipid POO_(2)^(-)head groups more strongly, resulting in cell membrane fusion more easily, in comparison with Mg^(2+). No specific interaction between the two metal cations and the C=O groups was observed. However, the C=O orientations changed more after Ca^(2+)-PO2-binding than Mg^(2+)mediation on lipid monolayer. Meanwhile, Ca^(2+)could induce dehydration of the lipids(which should be related to the strong Ca^(2+)-PO_(2)^(-)interaction), leading to the reduced hindrance for cell membrane fusion.
基金Projects(20775010,21075011) supported by the National Natural Science Foundation of ChinaProject(2008AA05Z405) supported by the National High Technology Research and Development Program of China+2 种基金Project(09JJ3016) supported by Hunan Provincial Natural Science Foundation,ChinaProject(09C066) supported by Scientific Research Fund of Hunan Provincial Education Department,ChinaProject(2010CL01) supported by the Foundation of Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation,China
文摘A novel quantitative structure-property relationship (QSPR) model for estimating the solution surface tension of 92 organic compounds at 20℃ was developed based on newly introduced atom-type topological indices. The data set contained non-polar and polar liquids, and saturated and unsaturated compounds. The regression analysis shows that excellent result is obtained with multiple linear regression. The predictive power of the proposed model was discussed using the leave-one-out (LOO) cross-validated (CV) method. The correlation coefficient (R) and the leave-one-out cross-validation correlation coefficient (Rcv) of multiple linear regression model are 0.991 4 and 0.991 3, respectively. The new model gives the average absolute relative deviation of 1.81% for 92 substances. The result demonstrates that novel topological indices based on the equilibrium electro-negativity of atom and the relative bond length are useful model parameters for QSPR analysis of compounds.
基金supported by National Natural Science Foundation of China(Grant Nos.41075060 and 41030106)
文摘In order to examine and analyze the effects of integration of land surface models with TOPMODEL and different approaches for the integration on the model simulation of water and energy balances,the coupled models have been developed,which incorporate TOPMODEL into the Simplified Biosphere Model(SSiB) with different approaches(one divides a basin into a number of zones according to the distribution of topographic index,and the other only divides the basin into saturated and unsaturated zones).The coupled models are able to(but SSiB is not able to) take into account the impacts of topography variation and vertical heterogeneity of soil saturated hydraulic conductivity on horizontal distribution of soil moisture and in turn on water and energy balances within the basin(or a grid cell).By using the coupled models and SSiB model itself,the daily hydrological components such as runoffs are simulated and final results are analyzed carefully.Simulated daily results of hydrological components produced by both SSiB and coupled models show that(i) There is significant difference between results of soil wetness,its vertical distribution and seasonal variation,water and energy balance,and daily runoff in the basin predicted by SSiB and by the coupled models.The land surface model currently used such as SSiB is likely to misrepresent real feature of water and energy balances in the basin.(ii) Compared with the results for the basin predicted by SSiB,the coupled models predict more strong vertical and seasonal changes in soil wetness,higher evaporation and lower runoff,and improve the base flow simulation obviously.(iii) Comparing the results for the basin predicted by two coupled models with different integration approach and SSiB one by one,the results of daily runoffs and soil wetness predicted by the two coupled models are quite similar.It means,for the coupled models,the approach by dividing a region being considered into more subzones may have limited effects on improving runoff simulation results.The scheme only to divide the region into saturated and unsaturated zones may be a convenient and effective scheme.But then,if the results from the two coupled models for the basin are carefully compared,the simulated results by the coupled model with dividing the basin into more subzones will show higher evaporation and surface runoff but lower subsurface flow,lower total runoff,and lower ground water level averaged for five years.
基金supported by the National Natural Science Foundation of China under Grant Nos.11261025,11561075the Natural Science Foundation of Yunnan Province under Grant No.2016FB005the Program for Middle-aged Backbone Teacher,Yunnan University
文摘Variable selection is an important research topic in modern statistics, traditional variable selection methods can only select the mean model and(or) the variance model, and cannot be used to select the joint mean, variance and skewness models. In this paper, the authors propose the joint location, scale and skewness models when the data set under consideration involves asymmetric outcomes,and consider the problem of variable selection for our proposed models. Based on an efficient unified penalized likelihood method, the consistency and the oracle property of the penalized estimators are established. The authors develop the variable selection procedure for the proposed joint models, which can efficiently simultaneously estimate and select important variables in location model, scale model and skewness model. Simulation studies and body mass index data analysis are presented to illustrate the proposed methods.