Within the model, a definition of novel saturation and dilution degree is presented. A novel expression of equilibrium constant is derived by including interactions between components to reversible processes running b...Within the model, a definition of novel saturation and dilution degree is presented. A novel expression of equilibrium constant is derived by including interactions between components to reversible processes running between the components particles under a dynamic equilibrium. For partition equilibria, three types of basic processes are proposed and corresponding partition isotherms were derived. The isotherms are applied to the components partition between two phases for main heterogenous systems types. For construction and prediction ternary phase diagrams, a new method, the Component Binding by Saturation Model (CBSM) method, is proposed. Applying the partition isotherms derived, new extraction, evaporation and adsorption isotherms are expressed. Directly, or after an approximation, from the new adsorption isotherms, well-known adsorption isotherms are obtained.展开更多
In the present paper, the effect of variable fluid properties (density, viscosity, thermal conductivity and specific heat) on the convection in the classical Rayleigh-Benard problem is investigated. The investigatio...In the present paper, the effect of variable fluid properties (density, viscosity, thermal conductivity and specific heat) on the convection in the classical Rayleigh-Benard problem is investigated. The investigation concerns water, air, and engine oil by taking into account the variation of fluid properties with temperature. The results are obtained by numerically solving the governing equations, using the SIMPLE algorithm and covering large temperature differences. It is found that the critical Rayleigh number increases as the temperature difference increases considering all fluid properties variable. However, when the fluid properties are kept constant, calculated at the mean temperature, and only density is considered variable, the critical Rayleigh number either decreases or remains constant.展开更多
文摘Within the model, a definition of novel saturation and dilution degree is presented. A novel expression of equilibrium constant is derived by including interactions between components to reversible processes running between the components particles under a dynamic equilibrium. For partition equilibria, three types of basic processes are proposed and corresponding partition isotherms were derived. The isotherms are applied to the components partition between two phases for main heterogenous systems types. For construction and prediction ternary phase diagrams, a new method, the Component Binding by Saturation Model (CBSM) method, is proposed. Applying the partition isotherms derived, new extraction, evaporation and adsorption isotherms are expressed. Directly, or after an approximation, from the new adsorption isotherms, well-known adsorption isotherms are obtained.
文摘In the present paper, the effect of variable fluid properties (density, viscosity, thermal conductivity and specific heat) on the convection in the classical Rayleigh-Benard problem is investigated. The investigation concerns water, air, and engine oil by taking into account the variation of fluid properties with temperature. The results are obtained by numerically solving the governing equations, using the SIMPLE algorithm and covering large temperature differences. It is found that the critical Rayleigh number increases as the temperature difference increases considering all fluid properties variable. However, when the fluid properties are kept constant, calculated at the mean temperature, and only density is considered variable, the critical Rayleigh number either decreases or remains constant.