大跨度桥梁振型的测试研究

针对大跨度桥梁固有频率和振形的测试和数据处理过程,简要给出了处理步骤的理论依据。在参照现有方案的同时,针对铜陵长江大桥的特点和测试的要求,采用了以微型计算机为基础的测试系统,并对测试和数据处理步骤做了很多改进和调整。文章最终给出了铜陵长江大桥主跨部分垂直方向上的前五阶对称振型。

海南滨海粉细砂路基压实工艺与质量控制

海南滨海粉细砂路基的压实及质量检测是施工中的技术难题。结合海南环岛旅游公路项目,提出滨海粉细砂路基的压实质量检测方法,铺筑试验路段,研究滨海粉细砂路基的压实工艺及压实质量。结果表明:滨海粉细砂地基压实适宜采用在碎石土垫层上进行冲压和振压相结合的方式;粉细砂路堤可随挖随填、快速填筑,采用双钢轮压路机压实,压实厚度不宜超过20 cm,振动碾压遍数不宜小于4;压实质量可采用预埋土样盒的检测方法,压实度控制标准为不宜小于88%。试验路段的工程效果良好。

一种小型矢量阵优化波束方法研究

在小型声纳平台中由于单个矢量水听器所含的振速传感器具有自然指向性,其组成的矢量阵较传统水听器阵有优越性,但单个矢量水听器的自然指向性波束较宽,组成的矢量阵的-3dB束宽和旁瓣级不够理想。该文利用单个矢量传感器的声压、振速信息联合处理形成较好指向性,并用于矢量阵获得良好的阵列效果,同时分析了该方法对线阵和圆阵的影响。仿真结果表明当线阵的阵元间距和圆阵半径都为0．5米时,矢量阵接收低频信号所形成的波束图中-3dB束宽在以25°内,第一旁瓣级低于-60dB,这证明了该文的方法是有效的。

Bulk-Silicon Resonant Accelerometer

Resonant accelerometer is designed,which includes two double-ended tuning forks,a proof mass,four-leverage system amplifying inertial force,and drive/sense combs.Each tuning fork is electrostatically actuated and sensed at resonance using comb electrodes.The device is fabricated using MEMS bulk-silicon technology,whose sensitive degree is 27 3Hz/g,and the resolution is 167 8μg.

感动情怀

不知在您生命成长的旅程里可曾有过仅仅因为一个人、一首歌的感动而深深地融动和振憾了您内心深处的那份狂热,并不惜一切地去坚守这份感动,以致永远、永远……真的,赵传的一曲《我是一只小小鸟》就这样并非青春岁月里盲目崇拜的冲动而闯进了我的生命里。——十余年前的那个雪花飘飞的年末,我挥别了与雪花共舞的海鸥,挥别了苦心努力后拥有的优越的位置,背着满怀的希翼融入了十万南下大军的天涯寻梦,一路的风尘过后,在琼州海峡上渐渐清晰的那个所谓大特区,原来是如此的形象。

党支书领路有方聂渡村发了树财

浚县小河乡聂渡村过去是全乡有名的穷村,七十年代中期,党支部书记和振圣为治穷,挖掘本村路多,渠多、荒坑多的优势。利用村上50亩不打粮食的盐碱地建起了苗圃。树苗出圃后,陆续在路旁,渠边,荒坑里植树二万多棵。1985年,聂渡村的树支逐渐成了材。

Laser Linewidth and Spectral Resolution in Infrared Scanning Sum Frequency Generation Vibrational Spectroscopy System

Sum frequency generation vibrational spectroscopy （SFG-VS） is a robust technique for inter- facial investigation at molecular level. The performance of SFG-VS mostly depends on the spectral resolution of the SFG system. In this research, a simplified function was deduced to calculate the spectral resolution of picosecond SFG system and the lineshape of SFG spectra based on the Guassian shaped functions of IR beam and visible beam. The function indicates that the lineshpe of SFG spectra from nonresonant samples can be calculated by the Guassian widths of both IR beam and visible beam. And the Voigt lineshape of SFG spectra from vibrational resonant samples can be calculated by the Homogeneous broadening （Lorentzian width） and Inhomogeneous broadening （Guassian width） of vibrational modes, as well as the Guassian widths of both IR beam and visible beam. Such functions were also applied to verify the spectral resolution of the polarization-resolved and frequency-resolved picosecond SFG-VS system which was developed by our group recently. It is shown that the linewidths of IR beams that generated from current laser system are about 1.5 cm-1. The calculated spectral resolution of current picosecond IR scanning SFG-VS system is about 4.6 cm-1, which is consist with he spctral resolution shown in the spectra of cholesterol monolayer （3.5-5 cm-1）.

Methanol Adsorption on TiO2 Film Studied by Sum Frequency Generation Vibrational Spectroscopy

A broadband infrared surface sum frequency generation vibrational spectroscopy （SFG-VS） and an in situ UV excitation setup devoted to studying surface photocatalysis have been constructed. With a home-made compact high vacuum cell, organic contaminants on TiO2 thin film surface prepared by RF magnetron sputtering were in situ removed under 266 nm irradiation in 10 kPa 02 atmosphere. We obtained the methanol spectrum in the CH3 stretching vibration region on TiO2 surface with changing the methanol pressure at room temperature. Features of both molecular and dissociative methanol, methoxy, adsorbed on this surface were resolved. The CH3 symmetric stretching vibration frequency and Fermi resonance of molecular methanol is red-shifted by about 6-8 cm-1 from low to high coverage. Moreover, the recombination of dissociative methanol and H on Surfaces in vacuum was also observed. Our results suggest two equilibria exist： between molecular methanol in the gas phase and that on surfaces, and between molecular methanol and dissociative methanol on surfaces.

A Highly Sensitive Femtosecond Time-Resolved Sum Frequency Generation Vibrational Spectroscopy System with Simultaneous Measurement of Multiple Polarization Combinations

Characterization of real-time and ultrafast motions of the complex molecules at surface and interface is critical to understand how interracial molecules function. It requires to develop surface-sensitive, fast-identification, and time-resolved techniques. In this study, we employ several key technical procedures and successfully develop a highly sensitive femtosecond time-resolved sum frequency generation vibrational spectroscopy （SFG-VS） system. This system is able to measure the spectra with two polarization combinations （ssp and ppp, or psp and ssp） simultaneously. It takes less than several seconds to collect one spectrum. To the best of our knowledge, it is the fastest speed of collecting SFG spectra reported by now. Using the time-resolved measurement, ultrafast vibrational dynamics of the N-H mode of α-helical peptide at water interface is determined. It is found that the membrane environment does not affect the N-H vibrational relaxation dynamics. It is expected that the time-resolved SFG system will play a vital role in the deep understanding of the dynamics and interaction of the complex molecules at surface and interface. Our method may also provide an important technical proposal for the people who plan to develop time-resolved SFG systems with simultaneous measurement of multiple polarization combinations.

Cross-Propagation Sum-Frequency Generation Vibrational Spectroscopy

Here we report the theory formulation and the experiment realization of sum-frequency generation vibrational spectroscopy （SFG-VS） in the cross-propagation （XP） geometry or configuration. In the XP-SFG-VS, the visible and the infrared （IR） beams in the SFG experiment are delivered to the same location on the surface from visible and IR incident planes perpendicular to each other, avoiding the requirement to have windows or optics to be transparent to both the visible and IR frequencies. Therefore, the XP geometry is applicable to study surfaces in the enclosed vacuum or high pressure chambers with far infrared （FIR） frequencies that can directly access the metal oxide and other lower frequency surface modes, with much broader selection of visible and IR transparent window materials. The potential applications include surface science, material science, fundamental catalytic sciences, as well as low temperature molecular sciences, etc.

Effects of wheelset vibration on initiation and evolution of rail short-pitch corrugation

The initiation and evolution of short-pitch corrugation in Beijing metro line 4 was studied from the viewpoint of wheelset vibration.A three-dimensional elastic model was set up.Numerical simulations were undertaken with this model to analyze the corrugation by the wheelset vertical vibration and torsional vibration.Based on numerical results,the relation between rail corrugation and wheelset vibration,and the relation between the position of electromotor and wheelset vibration were indicated.It is found that avoiding the wheelset-rail resonance is one method of controlling the rail short-pitch corrugation and solving the vibration and noise problem in metro lines.

Theoretical Study on Optical Properties of Oligofluorenes

We present theoretical investigations on structure-property correlations in fluorenone （FLO） and benzothiadiazole （BT） substituted oligofluorenes （OFLs） derived mainly from the chain morphology, thermal vibration and conjugated extent. Both the vertical absorptions and the vibrationally-resolved absorption and fluorescence spectra have been calculated by the com- bination of ab initio and time-dependent density functional theory. By properly taking into account of the anharmonic torsion potentials in the OFLs, we have reasonably reproduced the experimentally observed spectroscopic features. Both FLO and BT on-chain chemical defects acting as charge-trapping sites for singlet excitations, are responsible for long wave absorption and emission species, and thus alter the blue light-emitting properties of OFLs. As temperature decreases, the electronic spectral lineshapes of FLO-substituted oligomers become more structured. The lineshapes of BT-substituted oligomers are always smooth and featureless because of less low collective modes resonance. A more gentle excited poten-tial energy surface of BT-mixed molecules can enhance electronic delocalization and achieve bigger red shifts.

Investigation of a Design Modification for Double Helical Gears Reducing Vibration and Noise

To reduce vibration and noise and increase transmission efficiency, a three segment method for modifying the pinion profile was proposed. Cutter surface equations were deduced by changing the shape of the cutter-edge, substituting three segment parabolas for the line. The influence of longitudinal tooth modifications on tooth surface load distributions was discussed. Transmission error minimization and uniformity of tooth surface load distribution were chosen as optimization goals and the modified parameters were obtained by applying the complex method. Finally, an experiment comparing the loaded transmission error, vibration, and noise both before and after modifications was carried out. The results indicate that the modified design is reliable.

Quantitative Interpretation of Polarization SFG Vibrational Spectra of Air/Methanol Interface

Even though in IR and Raman spectra of liquid methanol there is always an apparent feature for the asymmetric stretching mode of the CH3 group around 2970 cm^-1, this feature has not been observed in the Sum Frequency Generation Vibrational Spectroscopy （SFG-VS） in any polarizations from the air/methanol interface. Here we present a treatment based on a corrected bond additivity model to quantitatively interpret the SFG-VS of the air/methanol interface from the IR and Raman spectra of liquid methanol.

Absolute Orientation of Molecules with Competing Hydrophilic Head Groups at the Air/Water Interface Probed with Sum Frequency Generation Vibrational Spectroscopy

The constructive or destructive spectral interference between the molecular groups oriented up and down at the interface in the sum-frequency generation （SFG） spectra provides a direct measurement of the absolute orientation of these molecular groups. This simple approach can be employed to interrogate absolute molecular orientations other than using the complex absolute phase measurement in the SFG studies. We used the -CN group in the p-cyanophenol （PCP） molecule as the internal phase standard, and we measured the phases of the SFG fields of the -CN groups in the 3,5-dimethyl-4-hydroxy-benzonitrile （35DMHBN） and 2,6-dimethyl-4-hydroxy-benzonitrile （26DMHBN） at the air/water interface by measuring the SFG spectra of the aqueous surfaces of the mixtures of the PCP, 35DMHBN, and 26DMHBN solutions. The results showed that the 35DMHBN had its -CN group pointing into the aqueous phase; while the 26DMHBN, similar to the PCP, had its -CN group pointing away from the aqueous phase. The tilt angles of the -CN group for both the 35DMHBN and 26DMHBN molecules at the air/water interface were around 25°-45° from the interface normal. These results provided insights on the understanding of the detailed balance of the competing factors, such as solvation of the polar head groups, hydrogen bonding and hydrophobic effects, etc., on influencing the absolute molecular orientation at the air/water interface.

Sum Frequency Generation Vibrational Spectra of Perovskite Nanocrystals at the Single-Nanocrystal and Ensemble Levels

Determination of molecular structures of organicinorganic hybrid perovskite(OIHP)nanocrystals at the single-nanocrystal and ensemble levels is essential to understanding the mechanisms responsible for their size-dependent optoelectronic properties and the nanocrystal assembling process,but its detection is still a bit challenging.In this study,we demonstrate that femtosecond sum frequency generation(SFG)vibrational spectroscopy can provide a highly sensitive tool for probing the molecular structures of nanocrystals with a size comparable to the Bohr diameter(∼10 nm)at the single-nanocrystal level.The SFG signals are monitored using the spectral features of the phenyl group in(RMBA)PbBr_(3) and(R-MBA)_(2)PbI_(4) nanocrystals(MBA:methyl-benzyl-ammonium).It is found that the SFG spectra exhibit a strong resonant peak at 3067±3 cm^(−1)(ν2 mode)and a weak shoulder peak at 3045±4 cm^(−1)(ν_(7a) mode)at the ensemble level,whereas a peak of theν2 mode and a peak at 3025±3 cm^(−1)(ν20b mode)at the single-nanocrystal level.The nanocrystals at the single-nanocrystal level tend to lie down on the surface,but stand up as the ensemble number and the averaged sizes increase.This finding may provide valuable information on the structural origins for size-dependent photo-physical properties and photoluminescence blinking dynamics in nanocrystals.

Sum Frequency Spectroscopy Studies on Cell Membrane Fusion Induced by Divalent Cations

Cell membrane fusion is a fundamental biological process involved in a number of cellular living functions. Regarding this, divalent cations can induce fusion of the lipid bilayers through binding and bridging of divalent cations to the charged lipids, thus leading to the cell membrane fusion. However, the elaborate mechanism of cell membrane fusion induced by divalent cations is still needed to be elucidated.Here, surface/interface sensitive sum frequency generation vibrational spectroscopy(SFG-VS) and dynamic light scattering(DLS) were applied in this research to study the responses of phospholipid monolayer to the exposure of divalent metal ions i.e.Ca^(2+)and Mg^(2+). According to the particle size distribution results measured by DLS experiments, it was found that Ca^(2+)could induce inter-vesicular fusion while Mg^(2+)could not. An octadecyltrichlorosilane self-assembled monolayer(OTS SAM)-lipid monolayer system was designed to model the cell membrane for the SFG-VS experiment. Ca^(2+)could interact with the lipid POO_(2)^(-)head groups more strongly, resulting in cell membrane fusion more easily, in comparison with Mg^(2+). No specific interaction between the two metal cations and the C=O groups was observed. However, the C=O orientations changed more after Ca^(2+)-PO2-binding than Mg^(2+)mediation on lipid monolayer. Meanwhile, Ca^(2+)could induce dehydration of the lipids(which should be related to the strong Ca^(2+)-PO_(2)^(-)interaction), leading to the reduced hindrance for cell membrane fusion.

Unified Treatment of Screening Coulomb and Anharmonic Oscillator Potentials in Arbitrary Dimensions

A mapping is obtained relating radial screened Coulomb systems with low screening parameters to radial anharmonic oscillators in N-dimensional space. Using the formalism of supersymmetric quantum mechanics, it is shown that exact solutions of these potentials exist when the parameters satisfy certain constraints.

Quantitative Surface Chirality Detection with Sum Frequency Generation Vibrational Spectroscopy： Twin Polarization Angle Approach

Here we report a novel twin polarization angle （TPA） approach in the quantitative chirality detection with the surface sum-frequency generation vibrational spectroscopy （SFG-VS）. Generally, the achiral contribution dominates the surface SFG-VS signal, and the pure chiral signal is usually two or three orders of magnitude smaller. Therefore, it has been difficult to make quantitative detection and analysis of the chiral contributions to the surface SFG- VS signal. In the TPA method, by varying together the polarization angles of the incoming visible light and the sum frequency signal at fixed s or p polarization of the incoming infrared beam, the polarization dependent SFG signal can give not only direct signature of the chiral contribution in the total SFG-VS signal, but also the accurate measurement of the chiral and achiral components in the surface SFG signal. The general description of the TPA method is presented and the experiment test of the TPA approach is also presented for the SFG-VS from the S- and R-limonene chiral liquid surfaces. The most accurate degree of chiral excess values thus obtained for the 2878 cm^-1 spectral peak of the S- and R-limonene liquid surfaces are （23.7±0.4）% and （-25.4±1.3）%, respectively.