Co(NO3)2, N carbazolyacetic acid and 4,4′ bipyridyl can give rise to a novel coordination polymer [Co2(Cabo)2(NO3)2(4,4′ bipy)2]n using a fritted U tube. Single crystal X ray diffraction displays in the complex, eac...Co(NO3)2, N carbazolyacetic acid and 4,4′ bipyridyl can give rise to a novel coordination polymer [Co2(Cabo)2(NO3)2(4,4′ bipy)2]n using a fritted U tube. Single crystal X ray diffraction displays in the complex, each Co? is six coordinated by two N atoms from different 4,4′ bipyridyl ligands, two O atoms of the bridge from two N carbazolyacetic acid and two O atoms of one nitrate anion to form a distorted octahedral. Two O atoms of the carboxyl group act as bridge to link two Co? atoms. The resulting structure is a ladder polymer. CCDC: 211713.展开更多
A novel technique of immobilizing indicator dyes by electrostatic adsorption and covalent bonding to fabricate optical sensors was developed.3-Amino-9-ethylcarbazole(AEC)was attached to the outmost surface of quartz g...A novel technique of immobilizing indicator dyes by electrostatic adsorption and covalent bonding to fabricate optical sensors was developed.3-Amino-9-ethylcarbazole(AEC)was attached to the outmost surface of quartz glass slide via aminosilanizing the slide,crosslinking chitosan,adsorbing Au nanoparticle,self-assembling HS(CH2)11OH,and coupling AEC.Thus, an AEC-immobilized optical sensor was obtained.The sensor exhibits a wide linear response range from 7.0×10- 7to 1.0×10 -4 mol/L and a correlation coefficient of 0.995 9 for the detection of 2-nitrophenol.The detection limit and response time of the sensor are 1.0×10- 7mol/L and less than 10 s,respectively.The fluorescence intensity of the used sensor can be restored to the blank value by simply rinsing with blank buffer.A very effective matrix for immobilizing indicator dye is provided by the proposed technique, which is adaptable to other indicator dyes with amino groups besides AEC.展开更多
文摘Co(NO3)2, N carbazolyacetic acid and 4,4′ bipyridyl can give rise to a novel coordination polymer [Co2(Cabo)2(NO3)2(4,4′ bipy)2]n using a fritted U tube. Single crystal X ray diffraction displays in the complex, each Co? is six coordinated by two N atoms from different 4,4′ bipyridyl ligands, two O atoms of the bridge from two N carbazolyacetic acid and two O atoms of one nitrate anion to form a distorted octahedral. Two O atoms of the carboxyl group act as bridge to link two Co? atoms. The resulting structure is a ladder polymer. CCDC: 211713.
基金Project(20775010)supported by the National Natural Science Foundation of ChinaProject(208095)supported by the Key Project ofMinistry of Education,China+1 种基金Project(07A006)supported by the Scientific Research Fund of Hunan Provincial Education Department,ChinaProject(07JJ3020)supported by Hunan Provincial Natural Science Foundation of China
文摘A novel technique of immobilizing indicator dyes by electrostatic adsorption and covalent bonding to fabricate optical sensors was developed.3-Amino-9-ethylcarbazole(AEC)was attached to the outmost surface of quartz glass slide via aminosilanizing the slide,crosslinking chitosan,adsorbing Au nanoparticle,self-assembling HS(CH2)11OH,and coupling AEC.Thus, an AEC-immobilized optical sensor was obtained.The sensor exhibits a wide linear response range from 7.0×10- 7to 1.0×10 -4 mol/L and a correlation coefficient of 0.995 9 for the detection of 2-nitrophenol.The detection limit and response time of the sensor are 1.0×10- 7mol/L and less than 10 s,respectively.The fluorescence intensity of the used sensor can be restored to the blank value by simply rinsing with blank buffer.A very effective matrix for immobilizing indicator dye is provided by the proposed technique, which is adaptable to other indicator dyes with amino groups besides AEC.
