The chlorodibenzyltin dithiopiperidylcarbamate was synthesized by the reaction of dibenzyltin dichloride with dithiopiperidylcarbamate and was characterized by elemental analysis, IR and 1H NMR. The crystal structure ...The chlorodibenzyltin dithiopiperidylcarbamate was synthesized by the reaction of dibenzyltin dichloride with dithiopiperidylcarbamate and was characterized by elemental analysis, IR and 1H NMR. The crystal structure was determined by X ray single crystal diffraction. The crystallographic data are as follows: monoclinic, space group P21, a=0.63464(13)nm, b=1.9110(4)nm, c=0.87367(17)nm, β=97.67(3)°, Z=2, V=1.0501(4)nm3, Dc=1.571g·cm-3, μ=1.546mm-1, F(000)=500, R=0.0209, wR=0.0381 [I ≥2σ(I)]. The str uctures consist of discrete molecules containing five coordinate tin atoms in a seriously distorted trigonal bipyramidal configuration. The molecules are packed in the unit cell in one dimensional chain complex through a weak interaction between the chlorine atom, the sulfur atom and one of the other sulfurs of an adjacent molecule. CCDC: 180034.展开更多
The bismuth complex with dithiopiperdylcarbamate [Bi(S2CNC5H10)2(NO3)]··0.5H2O was synthesized. The crystal and molecular structure were determined by X-ray single crystal diffraction. The crystal belongs to...The bismuth complex with dithiopiperdylcarbamate [Bi(S2CNC5H10)2(NO3)]··0.5H2O was synthesized. The crystal and molecular structure were determined by X-ray single crystal diffraction. The crystal belongs to monoiclinic with space group C2/c, a=3.140(2) nm, b=1.176 4(9) nm, c=2.021 6(15) nm, β=103.081(12)°, V=5.713(7) nm3, Z=8, F(000)=3 064, Dc=1.815 g·cm-3, μ=6.502mm-1. The final R1=0.033 2, wR2=0.040 3. In the complex, the bismuth atom is eight-coordinated in a capped distorted pentagonal bipyramidal geometry. CCDC: 222655.展开更多
文摘The chlorodibenzyltin dithiopiperidylcarbamate was synthesized by the reaction of dibenzyltin dichloride with dithiopiperidylcarbamate and was characterized by elemental analysis, IR and 1H NMR. The crystal structure was determined by X ray single crystal diffraction. The crystallographic data are as follows: monoclinic, space group P21, a=0.63464(13)nm, b=1.9110(4)nm, c=0.87367(17)nm, β=97.67(3)°, Z=2, V=1.0501(4)nm3, Dc=1.571g·cm-3, μ=1.546mm-1, F(000)=500, R=0.0209, wR=0.0381 [I ≥2σ(I)]. The str uctures consist of discrete molecules containing five coordinate tin atoms in a seriously distorted trigonal bipyramidal configuration. The molecules are packed in the unit cell in one dimensional chain complex through a weak interaction between the chlorine atom, the sulfur atom and one of the other sulfurs of an adjacent molecule. CCDC: 180034.
文摘The bismuth complex with dithiopiperdylcarbamate [Bi(S2CNC5H10)2(NO3)]··0.5H2O was synthesized. The crystal and molecular structure were determined by X-ray single crystal diffraction. The crystal belongs to monoiclinic with space group C2/c, a=3.140(2) nm, b=1.176 4(9) nm, c=2.021 6(15) nm, β=103.081(12)°, V=5.713(7) nm3, Z=8, F(000)=3 064, Dc=1.815 g·cm-3, μ=6.502mm-1. The final R1=0.033 2, wR2=0.040 3. In the complex, the bismuth atom is eight-coordinated in a capped distorted pentagonal bipyramidal geometry. CCDC: 222655.
