Roof disaster has always been an important factor restricting coal mine safety production.Acidic effect can reform the rock mass structure to weaken the macroscopic strength characteristics,which is an effective way t...Roof disaster has always been an important factor restricting coal mine safety production.Acidic effect can reform the rock mass structure to weaken the macroscopic strength characteristics,which is an effective way to control the hard limestone roof.In this study,the effects of various factors on the reaction characteristics and mechanical properties of limestone were analyzed.The results show that the acid with stronger hydrogen production capacity after ionization(pK_(a)<0)has more prominent damage to the mineral grains of limestone.When pKa increases from−8.00 to 15.70,uniaxial compressive strength and elastic modulus of limestone increase by 117.22%and 75.98%.The influence of acid concentration is manifested in the dissolution behavior of mineral crystals,the crystal defects caused by large-scale acid action will lead to the deterioration of limestone strength,and the strength after 15%concentration reformation can be reduced by 59.42%.The effect of acidification time on limestone has stages and is the most obvious in the initial metathesis reaction stage(within 60 min).The key to the strength damage of acidified limestone is the participation of hydrogen ions in the reaction system.Based on the analytic hierarchy process method,the influence weights of acid type,acid concentration and acidification time on strength are 24.30%,59.54% and 16.16%,respectively.The research results provide theoretical support for the acidification control of hard limestone roofs in coal mines.展开更多
The failure characteristics of thermal treated surrounding rocks should be studied to evaluate the stability and safety of deep ground engineering under high-ground-temperature and high-ground-stress conditions.The fa...The failure characteristics of thermal treated surrounding rocks should be studied to evaluate the stability and safety of deep ground engineering under high-ground-temperature and high-ground-stress conditions.The failure process of the inner walls of fine-grained granite specimens at different temperatures(25–600℃)was analyzed using a true-triaxial test system.The failure process,peak intensity,overall morphology(characteristics after failure),rock fragment characteristics,and acoustic emission(AE)characteristics were analyzed.The results showed that for the aforementioned type of granite specimens,the trend of the failure stress conditions changed with respect to the critical temperature(200℃).When the temperature was less than 200℃,the initial failure stress increased,final failure stress increased,and failure severity decreased.When the temperature exceeded 200℃,the initial failure stress decreased,final failure stress decreased,and failure severity increased.When the temperature was 600℃,the initial and final failure stresses of the specimens decreased by 60.93%and 19.77%compared with those at 200℃,respectively.The numerical results obtained with the software RFPA3D-Thermal were used to analyze the effect of temperature on the specimen and reveal the mechanism of the failure process in the deep tunnel surrounding rock.展开更多
Background,aim,and scope Environmentally persistent free radicals(EPFRs)have received significant attention due to their longer lifetime and stable existence in various environments.The strong environmental migration ...Background,aim,and scope Environmentally persistent free radicals(EPFRs)have received significant attention due to their longer lifetime and stable existence in various environments.The strong environmental migration ability of particulate matter allows EPFRs to migrate over long-distance transport,thereby impacting the quality of the local atmospheric environment.Additionally,EPFRs can also adhere to atmospheric particles and interact with typical gaseous pollutants to affect atmospheric chemical reactions.EPFRs can produce some reactive organic species,promoting oxidative stress in the human body,damaging biological macromolecules and ultimately affecting the organism health.EPFRs are considered as a novel type of pollutant that affects human health.Despite their significance,there are few literatures available on the characteristics and fate behaviors of EPFRs up to date.Therefore,supplemental reviews are crucial for providing comprehensive understanding of EPFRs.Materials and methods This review summarizes the characteristics of EPFRs in particulate matter,outlines the generation mechanism and influencing factors of EPFRs,and the impacts of EPFRs on environmental quality and organism health.Results The content of EPFRs in particulate matter ranges from 1017 to 1020 spins∙g−1.Due to the strong mobility of atmospheric particulate matter,the long-term exposure to high levels of EPFRs may aggravate the impact of particulate matter on human health.The interaction between EPFRs and typical gaseous pollutants can alter their fate and influence atmospheric chemical reactions.EPFRs are mainly produced by transition metal elements and substituted aromatic hydrocarbons through electron transfer.Additionally,the chemical bond rupture of organic substances through heat treatment or ultraviolet radiation can also produce EPFRs,and heterogeneous reactions are capable producing them as well.The production of EPFRs is not only influenced by transition metal elements and precursors,but also by various environmental factors such as oxygen,temperature,light radiation,and relative humidity.Discussion EPFRs in atmospheric particulates matters are usually rich in fine particulates with obvious seasonal and regional variations.They can easily enter the human respiratory tract and lungs with inhalable particulates,thereby increasing the risk of exposure.Additionally,EPFRs in atmospheric particulates can interact with some typical gaseous pollutants,impacting the life and fate of EPFRs in the atmosphere,and alter atmospheric chemical reactions.Traditionally,EPFRs are generated by transition metal elements and substituted aromatic hydrocarbons undergoing electron transfer in the post-flame and cool-zone regions of combustion systems and other thermal processes to remove HCl,H2O or CO groups,ultimately produce semiquinones,phenoxyls,and cyclopentadienyls.Recent studies have indicated that EPFRs can also be generated under the conditions of without transition metal elemental.Organics can also produce EPFRs through chemical bond rupture during heat treatment or light radiation conditions,as well as through some heterogeneous reactions and photochemical secondary generation of EPFRs.The presence or absence of oxygen has different effects on the type and yield of EPFRs.The concentration,type,and crystal type of transition metal elements will affect the type,content,and atmospheric lifetime of EPFRs.It is generally believed that the impact of transition metal element types on EPFRs is related to the oxidation-reduction potential.The combustion temperature or heat treatment process significantly affects the type and amount of EPFRs.Factors such as precursor loading content,pH conditions,light radiation and relative humidity also influence the generation of EPFRs.EPFRs can interact with pollutants in the environment during their migration and transformation process in environmental medium.This process accelerates the degradation of pollutants and plays a crucial role in the migration and transformation of organic pollutants in environmental media.The reaction process of EPFRs may lead to the production of reactive oxygen species(ROS)such as∙OH,which can induce oxidative stress,inflammation and immune response to biological lung cells and tissues,leading to chronic respiratory and cardiopulmonary dysfunction,cardiovascular damage and neurotoxic effects,ultimately impacting the health of organisms.Conclusions The interaction mechanism between EPFRs in particulate matter and gaseous pollutants remains unclear.Furthermore,research on the generation mechanism of EPFRs without the participation of transition metals is not comprehensive,and the detection of EPFRs is limited to simple qualitative categories and lack accurate qualitative analysis.Recommendations and perspectives Further research should be conducted on the generation mechanism,measurement techniques,migration pathways,and transformation process of EPFRs.It is also important to explore the interaction between EPFRs in atmospheric particulate matter and typical gaseous pollutants.展开更多
[Objective] The aim of this study was to reveal the distribution of rapeseed clubfoot disease in Hubei Province and to assess the yield loss caused by the pathogen, Plasmodiophora brassicae. [Method] Field surveys wer...[Objective] The aim of this study was to reveal the distribution of rapeseed clubfoot disease in Hubei Province and to assess the yield loss caused by the pathogen, Plasmodiophora brassicae. [Method] Field surveys were conducted in Shayang, Dangyang, Zhijiang, Yidu and Changyang of Hubei Province during 2009- 2011. Clubfoot disease of rapeseed samples from the surveyed locations were con- firmed by PCR detection and plants infection experiment. The factors of yield and plot yields influenced by clubroot disease were determined in plot experiment. [Re- salt] Rapeseed clubroots were confirmed in Zhijiang and Dangyang and not found in Shayang and Yidu. Clubroot was found in cruciferous vegetables but not in rapeseed d in Changyang. Infection of P. brassicae significantly decreased of the first effective branch numbers of rapeseed, effective pod number per plant, seed number per pod and 1 000-grain weight. Yield of infected rapeseed decreased by 56.4% over non-infected control. [Conclusion] Rapeseed clubroot disease mainly distributed in Zhijiang and Dangyang of Hubei Province. The disease had an economic impact on rapeseed production.展开更多
Global climate warming has discernable impacts on various natural systems and biological systems. As the most fragile ecosystem,agriculture is subjected to the most direct impacts from climate change. Of these impacts...Global climate warming has discernable impacts on various natural systems and biological systems. As the most fragile ecosystem,agriculture is subjected to the most direct impacts from climate change. Of these impacts,the first one is the change in agricultural climate resources,which directly affects agricultural cultivation structure and crop variety distribution and finally results in the change in crop yield. Here,we review the advances in the impacts of climate change on crop yield,agricultural climate resources and China's agricultural cropping system and crop variety distribution pattern,and prospect the countermeasures for agricultural production in order to meet the future climate change,and several issues must be given high priority.展开更多
[Objective] This study aimed to analyze the temporal-spatial variation of Inner Mongolian grassland degradation during past three decades. [Method] The dis- tribution characteristics of grassland were described by lan...[Objective] This study aimed to analyze the temporal-spatial variation of Inner Mongolian grassland degradation during past three decades. [Method] The dis- tribution characteristics of grassland were described by land use types supervised classification with TM/ETM. Then, temporal-spatial changes of grassland coverage were quantified by the mean of maximum vegetation coverage in last 30 years. Lastly, the grassland degradation reasons were explored through statistic analysis between the grassland coverage and precipitation, temperature and grazing intensity. [Result] The grassland degradation index of Inner Mongolia was increased from 1.38 to 1.68, and the smallest was 1.28 in 2005s. Grassland degradation and improve- ment were concurrent after 1980s, but grassland degradation was the major change trend for Inner Mongolia grassland. The area of grassland degradation was enlarged from 18.08×10^4 km2 in 1980s to 22.47×10^4 km2 in 2010s on the whole and distribu- tion range was shifted from central-eastern to west in Inner Mongolia that mainly distributed on Hulun Buir and Xilin Gol grassland in 1980s and Ordos and Alax grassland in 2010s. The grassland area of degradation had a rising trend form 1980s to 1995s, then reduced to 10.8x104 km2 in 2005s, and decreased in 2010s, which mainly speared in the west of Xilin Gol grassland. [Conclusion] Inner Mongo-lian grassland degradation were become more seriously in last 30 years because that temperature, precipitation and graze intensities change, which not performance on decreasing coverage but grassland areas.展开更多
Six kinds of galena with different impurities were synthesized and the effects of impurities on the floatability of galena were investigated. The thermodynamic and kinetic parameters on the galena surface were measure...Six kinds of galena with different impurities were synthesized and the effects of impurities on the floatability of galena were investigated. The thermodynamic and kinetic parameters on the galena surface were measured using microcalorimetry, and the adsorption configuration and energy of butyl xanthate on the surfaces of galena with different impurities were simulated by density functional theory. Flotation experiments showed that Ag and Bi significantly promoted the recovery of galena, while Zn, Sb, Mn, and Cu reduced the recovery of the flotation. Microthermokinetic results indicated that the absolute value of xanthate adsorption heat was directly proportional to the flotation recovery of galena. Adsorption heat and reaction rate coefficients of xanthate on galena containing Ag or Bi were larger than those on pure galena, but smaller on galena containing Cu or Sb. Additionally, the relationship between the heat of unsaturated adsorption of xanthate and the adsorption energy of impurity atom on galena surface was investigated.展开更多
基金Project(2021YFC2902102)supported by the National Key Research and Development Program of ChinaProject(52374142)supported by the National Natural Science Foundation of ChinaProject(JSTU-2022-066)supported by the Young Talent Support Project of Jiangsu Association for Science and Technology,China。
文摘Roof disaster has always been an important factor restricting coal mine safety production.Acidic effect can reform the rock mass structure to weaken the macroscopic strength characteristics,which is an effective way to control the hard limestone roof.In this study,the effects of various factors on the reaction characteristics and mechanical properties of limestone were analyzed.The results show that the acid with stronger hydrogen production capacity after ionization(pK_(a)<0)has more prominent damage to the mineral grains of limestone.When pKa increases from−8.00 to 15.70,uniaxial compressive strength and elastic modulus of limestone increase by 117.22%and 75.98%.The influence of acid concentration is manifested in the dissolution behavior of mineral crystals,the crystal defects caused by large-scale acid action will lead to the deterioration of limestone strength,and the strength after 15%concentration reformation can be reduced by 59.42%.The effect of acidification time on limestone has stages and is the most obvious in the initial metathesis reaction stage(within 60 min).The key to the strength damage of acidified limestone is the participation of hydrogen ions in the reaction system.Based on the analytic hierarchy process method,the influence weights of acid type,acid concentration and acidification time on strength are 24.30%,59.54% and 16.16%,respectively.The research results provide theoretical support for the acidification control of hard limestone roofs in coal mines.
基金Project(52174098)supported by the National Natural Science Foundation of ChinaProject(2022JJ20063)supported by the Natural Science Foundation of Hunan Province,ChinaProject(2023CXQD011)supported by the Fundamental Research Funds for the Central Universities,China。
文摘The failure characteristics of thermal treated surrounding rocks should be studied to evaluate the stability and safety of deep ground engineering under high-ground-temperature and high-ground-stress conditions.The failure process of the inner walls of fine-grained granite specimens at different temperatures(25–600℃)was analyzed using a true-triaxial test system.The failure process,peak intensity,overall morphology(characteristics after failure),rock fragment characteristics,and acoustic emission(AE)characteristics were analyzed.The results showed that for the aforementioned type of granite specimens,the trend of the failure stress conditions changed with respect to the critical temperature(200℃).When the temperature was less than 200℃,the initial failure stress increased,final failure stress increased,and failure severity decreased.When the temperature exceeded 200℃,the initial failure stress decreased,final failure stress decreased,and failure severity increased.When the temperature was 600℃,the initial and final failure stresses of the specimens decreased by 60.93%and 19.77%compared with those at 200℃,respectively.The numerical results obtained with the software RFPA3D-Thermal were used to analyze the effect of temperature on the specimen and reveal the mechanism of the failure process in the deep tunnel surrounding rock.
文摘Background,aim,and scope Environmentally persistent free radicals(EPFRs)have received significant attention due to their longer lifetime and stable existence in various environments.The strong environmental migration ability of particulate matter allows EPFRs to migrate over long-distance transport,thereby impacting the quality of the local atmospheric environment.Additionally,EPFRs can also adhere to atmospheric particles and interact with typical gaseous pollutants to affect atmospheric chemical reactions.EPFRs can produce some reactive organic species,promoting oxidative stress in the human body,damaging biological macromolecules and ultimately affecting the organism health.EPFRs are considered as a novel type of pollutant that affects human health.Despite their significance,there are few literatures available on the characteristics and fate behaviors of EPFRs up to date.Therefore,supplemental reviews are crucial for providing comprehensive understanding of EPFRs.Materials and methods This review summarizes the characteristics of EPFRs in particulate matter,outlines the generation mechanism and influencing factors of EPFRs,and the impacts of EPFRs on environmental quality and organism health.Results The content of EPFRs in particulate matter ranges from 1017 to 1020 spins∙g−1.Due to the strong mobility of atmospheric particulate matter,the long-term exposure to high levels of EPFRs may aggravate the impact of particulate matter on human health.The interaction between EPFRs and typical gaseous pollutants can alter their fate and influence atmospheric chemical reactions.EPFRs are mainly produced by transition metal elements and substituted aromatic hydrocarbons through electron transfer.Additionally,the chemical bond rupture of organic substances through heat treatment or ultraviolet radiation can also produce EPFRs,and heterogeneous reactions are capable producing them as well.The production of EPFRs is not only influenced by transition metal elements and precursors,but also by various environmental factors such as oxygen,temperature,light radiation,and relative humidity.Discussion EPFRs in atmospheric particulates matters are usually rich in fine particulates with obvious seasonal and regional variations.They can easily enter the human respiratory tract and lungs with inhalable particulates,thereby increasing the risk of exposure.Additionally,EPFRs in atmospheric particulates can interact with some typical gaseous pollutants,impacting the life and fate of EPFRs in the atmosphere,and alter atmospheric chemical reactions.Traditionally,EPFRs are generated by transition metal elements and substituted aromatic hydrocarbons undergoing electron transfer in the post-flame and cool-zone regions of combustion systems and other thermal processes to remove HCl,H2O or CO groups,ultimately produce semiquinones,phenoxyls,and cyclopentadienyls.Recent studies have indicated that EPFRs can also be generated under the conditions of without transition metal elemental.Organics can also produce EPFRs through chemical bond rupture during heat treatment or light radiation conditions,as well as through some heterogeneous reactions and photochemical secondary generation of EPFRs.The presence or absence of oxygen has different effects on the type and yield of EPFRs.The concentration,type,and crystal type of transition metal elements will affect the type,content,and atmospheric lifetime of EPFRs.It is generally believed that the impact of transition metal element types on EPFRs is related to the oxidation-reduction potential.The combustion temperature or heat treatment process significantly affects the type and amount of EPFRs.Factors such as precursor loading content,pH conditions,light radiation and relative humidity also influence the generation of EPFRs.EPFRs can interact with pollutants in the environment during their migration and transformation process in environmental medium.This process accelerates the degradation of pollutants and plays a crucial role in the migration and transformation of organic pollutants in environmental media.The reaction process of EPFRs may lead to the production of reactive oxygen species(ROS)such as∙OH,which can induce oxidative stress,inflammation and immune response to biological lung cells and tissues,leading to chronic respiratory and cardiopulmonary dysfunction,cardiovascular damage and neurotoxic effects,ultimately impacting the health of organisms.Conclusions The interaction mechanism between EPFRs in particulate matter and gaseous pollutants remains unclear.Furthermore,research on the generation mechanism of EPFRs without the participation of transition metals is not comprehensive,and the detection of EPFRs is limited to simple qualitative categories and lack accurate qualitative analysis.Recommendations and perspectives Further research should be conducted on the generation mechanism,measurement techniques,migration pathways,and transformation process of EPFRs.It is also important to explore the interaction between EPFRs in atmospheric particulate matter and typical gaseous pollutants.
基金Supported by the Industry Technology System of Rapeseed in China(nycytx-005)Special Fund for Agro-scientific Research in the Public Interest(201003029)National Key Technology Research and Development Program of the Ministry of Science and Technology of China(2010BAD01B04)~~
文摘[Objective] The aim of this study was to reveal the distribution of rapeseed clubfoot disease in Hubei Province and to assess the yield loss caused by the pathogen, Plasmodiophora brassicae. [Method] Field surveys were conducted in Shayang, Dangyang, Zhijiang, Yidu and Changyang of Hubei Province during 2009- 2011. Clubfoot disease of rapeseed samples from the surveyed locations were con- firmed by PCR detection and plants infection experiment. The factors of yield and plot yields influenced by clubroot disease were determined in plot experiment. [Re- salt] Rapeseed clubroots were confirmed in Zhijiang and Dangyang and not found in Shayang and Yidu. Clubroot was found in cruciferous vegetables but not in rapeseed d in Changyang. Infection of P. brassicae significantly decreased of the first effective branch numbers of rapeseed, effective pod number per plant, seed number per pod and 1 000-grain weight. Yield of infected rapeseed decreased by 56.4% over non-infected control. [Conclusion] Rapeseed clubroot disease mainly distributed in Zhijiang and Dangyang of Hubei Province. The disease had an economic impact on rapeseed production.
基金Supported by Special Fund for Meteorology-scientific Research in the Public Interest (GYHY201106020)Special Fund for Climate Change from China Meteorological Administration (CCSF-09-12)~~
文摘Global climate warming has discernable impacts on various natural systems and biological systems. As the most fragile ecosystem,agriculture is subjected to the most direct impacts from climate change. Of these impacts,the first one is the change in agricultural climate resources,which directly affects agricultural cultivation structure and crop variety distribution and finally results in the change in crop yield. Here,we review the advances in the impacts of climate change on crop yield,agricultural climate resources and China's agricultural cropping system and crop variety distribution pattern,and prospect the countermeasures for agricultural production in order to meet the future climate change,and several issues must be given high priority.
基金Supported by National Program on Key Basic Research Project of China (2011CB403206)National Key Technology Research and Development Program during the 12~(th) Five-year Plan Period of China(2012BAC19B04)~~
文摘[Objective] This study aimed to analyze the temporal-spatial variation of Inner Mongolian grassland degradation during past three decades. [Method] The dis- tribution characteristics of grassland were described by land use types supervised classification with TM/ETM. Then, temporal-spatial changes of grassland coverage were quantified by the mean of maximum vegetation coverage in last 30 years. Lastly, the grassland degradation reasons were explored through statistic analysis between the grassland coverage and precipitation, temperature and grazing intensity. [Result] The grassland degradation index of Inner Mongolia was increased from 1.38 to 1.68, and the smallest was 1.28 in 2005s. Grassland degradation and improve- ment were concurrent after 1980s, but grassland degradation was the major change trend for Inner Mongolia grassland. The area of grassland degradation was enlarged from 18.08×10^4 km2 in 1980s to 22.47×10^4 km2 in 2010s on the whole and distribu- tion range was shifted from central-eastern to west in Inner Mongolia that mainly distributed on Hulun Buir and Xilin Gol grassland in 1980s and Ordos and Alax grassland in 2010s. The grassland area of degradation had a rising trend form 1980s to 1995s, then reduced to 10.8x104 km2 in 2005s, and decreased in 2010s, which mainly speared in the west of Xilin Gol grassland. [Conclusion] Inner Mongo-lian grassland degradation were become more seriously in last 30 years because that temperature, precipitation and graze intensities change, which not performance on decreasing coverage but grassland areas.
基金Projects(51464006,51164001)supported by the National Natural Science Foundation of ChinaProject(GJR201147-12)supported by Guangxi Higher Education Institutes Talent Highland Innovation Team Scheme,ChinaProject(2012MDZD038)supported by the Key Scientific Research Project of Guangxi University for Nationalities,China
文摘Six kinds of galena with different impurities were synthesized and the effects of impurities on the floatability of galena were investigated. The thermodynamic and kinetic parameters on the galena surface were measured using microcalorimetry, and the adsorption configuration and energy of butyl xanthate on the surfaces of galena with different impurities were simulated by density functional theory. Flotation experiments showed that Ag and Bi significantly promoted the recovery of galena, while Zn, Sb, Mn, and Cu reduced the recovery of the flotation. Microthermokinetic results indicated that the absolute value of xanthate adsorption heat was directly proportional to the flotation recovery of galena. Adsorption heat and reaction rate coefficients of xanthate on galena containing Ag or Bi were larger than those on pure galena, but smaller on galena containing Cu or Sb. Additionally, the relationship between the heat of unsaturated adsorption of xanthate and the adsorption energy of impurity atom on galena surface was investigated.