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基于工业装置探究甲醇制烯烃反应机理 被引量:20
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作者 吴秀章 《石化技术与应用》 CAS 2013年第5期363-369,383,共8页
甲醇制烯烃(MTO)反应机理主要有串联型机理和并联型机理2大类,目前大多数试验证据支持并联型机理即"烃池"机理。MTO工艺于2010年在中国神华集团首次实现了商业化运行。在该180万t/a MTO工业装置运行过程中,首次在反应产物中... 甲醇制烯烃(MTO)反应机理主要有串联型机理和并联型机理2大类,目前大多数试验证据支持并联型机理即"烃池"机理。MTO工艺于2010年在中国神华集团首次实现了商业化运行。在该180万t/a MTO工业装置运行过程中,首次在反应产物中发现了微量多甲基苯、乙基苯、异丙基苯等芳烃物质,支持了MTO反应是按照"烃池"机理发生的观点,并在生产过程中运用"烃池"机理指导该商业化装置的运转。 展开更多
关键词 甲醇 烯烃 甲醇制烯烃(MTO) MTO反应机理 SAPO-34分子筛 "烃池"机理 商业化装置
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Commercial Application of the MIP-CGP Technology for Olefin Reduction in FCC Unit 被引量:1
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作者 Su Wensheng 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2009年第1期25-30,共6页
The refinery of Yanshan Petrochemical Company has twice retrofitted a 2.0-Mt/a RFCC unit with the MIP-CGP technology aimed at maximization of isoparaffins/clean gasoline and increased output of propylene. By modifying... The refinery of Yanshan Petrochemical Company has twice retrofitted a 2.0-Mt/a RFCC unit with the MIP-CGP technology aimed at maximization of isoparaffins/clean gasoline and increased output of propylene. By modifying the riser reactor with addition of the second reaction zone coupled with an added external catalyst cooler outside the regenerator and adoption of the CGP catalyst to control the cracking depth the refiners have realized the target of reducing olefin content in gasoline and increasing the yield of LPG. The results of retrofitting the RFCC unit have revealed that after revamp of FCC unit the yield of LPG was increased by 7.31%, the conversion rate was increased by 9.06%, and the total liquid yield was decreased by 0.3%. After revamp of the RFCC unit the olefin content in gasoline was reduced by 19.5 v%, and the RON rating of gasoline was increased by 0.7 units to meet the demand of Beijing municipality for manufacture of the Olympic clean gasoline. 展开更多
关键词 fluid catalytic cracking olefins reduction TECHNOLOGY APPLICATION
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Study on Commercial Application of FP-DSN Sulfur Transfer Additive in FCC Unit 被引量:2
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作者 Gao Siming Han Rongxian Chen Desheng(SINOPEC Qingdao Petrochemical Company,Qingdao 266043) 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2009年第2期15-19,共5页
The FCC unit with addition of various inventories of the FP-DSN type sulfur transfer additive was tested in a commercial scale. The effect of the sulfur transfer additive was analyzed by investigating the indicators r... The FCC unit with addition of various inventories of the FP-DSN type sulfur transfer additive was tested in a commercial scale. The effect of the sulfur transfer additive was analyzed by investigating the indicators related with the regenerator flue gas composition,the dry gas composition before desulfurization,the LPG composition before desulfurization,the acid gas,and the yield of gasoline and diesel. The test results indicated that the sulfur was trans ferred from the feed stream into the dry gas,LPG and acid gas,and the sulfur transfer effect was obvious only when the inventory of sulfur transfer additive exceeded over 2.0% of total FCC catalyst inventory. 展开更多
关键词 catalytic cracking unit sulfur transfer additive commercial application
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