Applications of airtight concrete grouting to road tunnels

Road tunnel excavation often traverses coal strata, which is at risk of firedamp explosion that usually results in disaster. Airtight concrete grouting is popularly used in this kind of tunnel project. Based on the essential theory of mechanics of fluids in porous media, the principle of improving concrete airtight property and its influential factors are investigated. The proportioning tests and monitoring method for airtight concrete are introduced, which is illustrated by a case study applied to the project of the Huayinshan Tunnel. It is proved by engineering practices that the achievement of this research work is beneficial to tunneling project across coal strata.

New method for plugging channeling in oil field by nitrogen foam

In order to present a new method for plugging channeling in oil field,the injection modes and validity period of foam system which plugged the formation water layer were studied by means of the experimental model which simulated the real conditions of oil wells existing channeling.Above all,the influence factors including reservoir pressure,permeability,oil saturation and gas-to-liquid ratio were studied through dynamic experiment.Then,in light of the technology characteristics of foam injection in oil field,the comparison between gas-liquid and liquid-gas injection modes was studied.The result shows that the gas-liquid injection mode can ensure the foam injectivity and plugging performance.The plugging validity of nitrogen foam injected into the formation water layer was evaluated in different plugging pressure gradients by the dynamic method which is more reasonable than the static evaluation method in laboratory.The research demonstrates that the plugging validity period of foam decreases with plugging pressure gradient increasing.If the plugging pressure gradient is 0.15 MPa/m,the validity period is 160 h.Finally,a empirical equation and a plate about the plugging validity and the plugging pressure gradient were obtained for forecasting the validity period of foam.

Transparent conductive PVP/AgNWs films for flexible organic light emitting diodes by spraying method

In this study, a simple spraying method is used to prepare the transparent conductive films （TCFs） based on Ag nanowires （AgNWs）. Polyvinylpyrrolidone （PVP） is introduced to modify the interface of substrate. The transmittance and bending performance are improved by optimizing the number of spraying times and the solution concentration and controlling the annealing time. The spraying times of 20, the concentration of 2 mg/mL and the annealing time of 10 min are chosen to fabricate the PVP/AgNWs films. The transmittance of PVP/AgNWs films is 53.4%----67.9% at 380---780 nm, and the sheet resistance is 30 f~/n which is equivalent to that of commercial indium tin oxide （1TO）. During cyclic bending tests to 500 cycles with bending radius of 5 ram, the changes of resistivity are negligible. The performance of PVP/AgNW transparent electrodes has little change after being exposed to the normal environment for 1 000 h. The adhesion to polymeric substrate and the ability to endure bending stress in AgNWs network films are both significantly improved by introducing PVP. Spraying method makes AgNWs form a stratified structure on large-area polymer substrates, and the vacuum annealing method is used to weld the AgNWs together at junctions and substrates, which can improve the electrical conductivity. The experimental results indicate that PVP/AgNW transpar- ent electrodes can be used as transparent conductive electrodes in flexible organic light emitting diodes （OLEDs）.