Abstract: In order to improve the surface hardness and wear resistance of magnesium, Al-13%Si (mass fraction) alloy coating was deposited on pure magnesium by droplet spraying process. The microstructure was studie...Abstract: In order to improve the surface hardness and wear resistance of magnesium, Al-13%Si (mass fraction) alloy coating was deposited on pure magnesium by droplet spraying process. The microstructure was studied by electron probe microanalysis and X-ray diffraction. The micro-hardness and wear resistance of coating were investigated in comparison with those of the substrate. It is found that the coating layer is composed of a-Al cellular due to rapid solidification. Formation mechanism of the coating is due to the obstruction of diffusion by in-situ formed Mg2Si in interracial layer. The coating exhibits higher hardness compared to that of the Mg substrate. As result of its high hardness, the wear resistance of the coating layer is about ten times that of the substrate. The droplet spraying process demonstrates that the magnesium surface can be strengthened by using the existing Al-Si alloys.展开更多
The spray behaviors of the combined trapezoid spray tray(CTST) have a significant effect on the gas-liquid interface. In this paper, the spray process of CTST in a column, 570 mm in diameter, was experimentally invest...The spray behaviors of the combined trapezoid spray tray(CTST) have a significant effect on the gas-liquid interface. In this paper, the spray process of CTST in a column, 570 mm in diameter, was experimentally investigated by using a high-speed camera, and a theoretical model of the average droplet size was established according to the unstable wave theory. The results demonstrated that gas velocity passing through the hole is the key factor affecting the spray angle, which increases gradually with an increase in the gas velocity. When the gas velocity exceeds 7.5 m/s, the spray angle becomes stable at around 55°. The average flow velocity of the liquid sheet at the spray-hole increases significantly with an increase in the gas velocity, and decreases slightly with an increase in the liquid flow rate; moreover, it increases from the bottom of spray hole upward to the top. The density of liquid drops distribution in the spray area can be described by the RosinRammler function. In addition, the liquid drops are mainly concentrated in the area of spray angle ranging from 20° to 40°, and they gradually become uniform with the increase in the gas velocity and the liquid flow rate. The average liquid drop size deceases with an increase in the gas velocity, and increases slightly with an increasing liquid flow rate. In the normal working range, the average liquid drop size is about 1.0 mm to 2.5 mm in diameter.展开更多
With the TiB2−SiC powders after spray granulation and vacuum calcination as raw materials,the TiB2−SiC coating was prepared by supersonic atmospheric plasma spraying(SAPS).The effects of spraying power and spraying di...With the TiB2−SiC powders after spray granulation and vacuum calcination as raw materials,the TiB2−SiC coating was prepared by supersonic atmospheric plasma spraying(SAPS).The effects of spraying power and spraying distance on the properties of the TiB2−SiC coating were investigated and the fabrication processing of SAPS was optimized.The results show that the sprayed powders after calcination have a uniform particle size distribution,good sphericity and enhanced fluidity.The coating prepared by the calcined powders has a dense structure and high deposition efficiency.When the calcined TiB2−SiC powders are used and the spraying power is 95 kW and the spraying distance is 150 mm during supersonic plasma spraying,the obtained TiB2−SiC coating behaves the best comprehensive performance with the porosity,microhardness,bonding strength and resistivity equal to 5.6%,3.57 GPa,18.3 MPa and 10.8 mΩ·cm,respectively.展开更多
A new brush plating process with a soluble anode of nickel was introduced. TDY112 brush plating solution was used on the No.20 carbon steel substrate. It has the higher deposit velocity, better properties and lower co...A new brush plating process with a soluble anode of nickel was introduced. TDY112 brush plating solution was used on the No.20 carbon steel substrate. It has the higher deposit velocity, better properties and lower cost. Scanning electronic microscopy(SEM), optical microscope, microhardness test and wear test were adopted to detect the surface quality and the properties of the coating, such as micrograph, microstructure, micro-hardness wear resistance and adherence between the coating and the substrate. The experimental results showed that the suitable technological parameters to be used, the coatings had better the surface quality, higher hardness and wear resistance.展开更多
This work aims at developing an automatic system for the control of the APS (air plasma spraying) plasma process in which some instability phenomena are present. APS is a versatile technique to produce coatings of p...This work aims at developing an automatic system for the control of the APS (air plasma spraying) plasma process in which some instability phenomena are present. APS is a versatile technique to produce coatings of powder material at high deposition rates. Using this technique, powder particles are injected into a plasma jet, where they are melted and accelerated towards a substrate. The coating microstructures and properties depend strongly on the characteristics of the plasma jet, which can be controlled by the adjustment of the process parameters. However, the imeractions among the spray variables, render optimization and control of this process are quite complex. Understanding relationships between coating properties and process parameters is mandatory to optimize the process technique and the product quality. We are interested in this work to build an on-line control model for the APS process based on the elements of artificial intelligence and to build an emulator that replicates the dynamic behavior of the process as closely as possible.展开更多
In this experimental study, chromium oxide powder was sprayed on a low-carbon steel substrate using the atmospheric plasma spray process. The current and standoff distances(SODs) were varied to study their effect on t...In this experimental study, chromium oxide powder was sprayed on a low-carbon steel substrate using the atmospheric plasma spray process. The current and standoff distances(SODs) were varied to study their effect on the fracture toughness of the coatings. Theoretically, as the arc current increases, the melting of the ceramic oxide should increase and this in turn should lead to the formation of a dense coating. However,it was observed that if the arc power is too high and because the particle size of the powder is small(approximately 30 μm), the particles tend to fly away from the plasma core. Similarly, an appropriate SOD should provide the particles with more melting time, thus resulting in a dense coating. On the other hand, a larger SOD leads to the solidification of the molten particles before the droplets can reach the substrate. All these effects may lead to substantial variation in the fracture toughness of the coating. The present paper attempts to correlate the plasma spraying parameters and microstructure of the coating with the fracture toughness and other primary coating properties.展开更多
As a new green and environmental material, bio-activated cementitious material is attracting extensive attention. This study confirmed that the bio-activated cementitious material could mineralize and cement fugitive ...As a new green and environmental material, bio-activated cementitious material is attracting extensive attention. This study confirmed that the bio-activated cementitious material could mineralize and cement fugitive dust into the cal- cite-consolidation-layer based on CO2 capture and utilization. The results illustrated that treatment processes (non-pressure spraying, pressure spraying, non-pressure blending and pressure blending) had a strong effect on the microstructure and prop- erties of calcite-consolidation-layer. According to the analysis of X-ray diffraction (XRD) and Fourier transform infrared (FTIR), calcite was prepared by bio-activated cementitious material during the cementation process. Meanwhile, scanning electron microscopy (SEM) and thermogravimetric-differenfial scanning calorimetry (TG-DSC) were adopted to measure the corresponding variation of porous characteristics and calcite content caused by different treatment processes. The results indi- cated that the microstructure of calcite-consolidation-layer from the spraying process had lower porosity and higher content of calcite than from blending processes. In addition, the mechanical properties of calcite-consolidation-layer were also tested. The hardness and compressive strength, which reached 19.5 GPa and 0.6 MPa, respectively, of calcite-consolidation-layer from the pressure spraying process were higher than those from the other three treatment processes. Compared with the non-treatment process, the four treatment processes had superior wind erosion resistance. Under the wind speed of 12 m/s, the mass loss of calcite-consolidation-layer from the pressure spraying process decreased from 2150.2 to 23.8 g/(m^2 h).展开更多
基金Project(KZJ-48)supported by the Science and Technology Development Program of Qingdao,ChinaProject(51208288)supported by the National Natural Science Foundation of ChinaProject(BS2011CL032)supported by the Research Award Fund for Outstanding Youngand Middle-aged Scientists of Shandong Province,China
文摘Abstract: In order to improve the surface hardness and wear resistance of magnesium, Al-13%Si (mass fraction) alloy coating was deposited on pure magnesium by droplet spraying process. The microstructure was studied by electron probe microanalysis and X-ray diffraction. The micro-hardness and wear resistance of coating were investigated in comparison with those of the substrate. It is found that the coating layer is composed of a-Al cellular due to rapid solidification. Formation mechanism of the coating is due to the obstruction of diffusion by in-situ formed Mg2Si in interracial layer. The coating exhibits higher hardness compared to that of the Mg substrate. As result of its high hardness, the wear resistance of the coating layer is about ten times that of the substrate. The droplet spraying process demonstrates that the magnesium surface can be strengthened by using the existing Al-Si alloys.
基金supported by the Science and Technology Research and Development Plan of Hebei Province, China (12276710D)
文摘The spray behaviors of the combined trapezoid spray tray(CTST) have a significant effect on the gas-liquid interface. In this paper, the spray process of CTST in a column, 570 mm in diameter, was experimentally investigated by using a high-speed camera, and a theoretical model of the average droplet size was established according to the unstable wave theory. The results demonstrated that gas velocity passing through the hole is the key factor affecting the spray angle, which increases gradually with an increase in the gas velocity. When the gas velocity exceeds 7.5 m/s, the spray angle becomes stable at around 55°. The average flow velocity of the liquid sheet at the spray-hole increases significantly with an increase in the gas velocity, and decreases slightly with an increase in the liquid flow rate; moreover, it increases from the bottom of spray hole upward to the top. The density of liquid drops distribution in the spray area can be described by the RosinRammler function. In addition, the liquid drops are mainly concentrated in the area of spray angle ranging from 20° to 40°, and they gradually become uniform with the increase in the gas velocity and the liquid flow rate. The average liquid drop size deceases with an increase in the gas velocity, and increases slightly with an increasing liquid flow rate. In the normal working range, the average liquid drop size is about 1.0 mm to 2.5 mm in diameter.
基金The authors are grateful for the financial supports from Guangdong Academy of Sciences Project(2018GDASCX-0402)of China,Yunnan Science and Technology Plan Project of China(2018IC080)the Natural Science Foundation of Hunan Province of China(2018JJ2524).
文摘With the TiB2−SiC powders after spray granulation and vacuum calcination as raw materials,the TiB2−SiC coating was prepared by supersonic atmospheric plasma spraying(SAPS).The effects of spraying power and spraying distance on the properties of the TiB2−SiC coating were investigated and the fabrication processing of SAPS was optimized.The results show that the sprayed powders after calcination have a uniform particle size distribution,good sphericity and enhanced fluidity.The coating prepared by the calcined powders has a dense structure and high deposition efficiency.When the calcined TiB2−SiC powders are used and the spraying power is 95 kW and the spraying distance is 150 mm during supersonic plasma spraying,the obtained TiB2−SiC coating behaves the best comprehensive performance with the porosity,microhardness,bonding strength and resistivity equal to 5.6%,3.57 GPa,18.3 MPa and 10.8 mΩ·cm,respectively.
文摘A new brush plating process with a soluble anode of nickel was introduced. TDY112 brush plating solution was used on the No.20 carbon steel substrate. It has the higher deposit velocity, better properties and lower cost. Scanning electronic microscopy(SEM), optical microscope, microhardness test and wear test were adopted to detect the surface quality and the properties of the coating, such as micrograph, microstructure, micro-hardness wear resistance and adherence between the coating and the substrate. The experimental results showed that the suitable technological parameters to be used, the coatings had better the surface quality, higher hardness and wear resistance.
文摘This work aims at developing an automatic system for the control of the APS (air plasma spraying) plasma process in which some instability phenomena are present. APS is a versatile technique to produce coatings of powder material at high deposition rates. Using this technique, powder particles are injected into a plasma jet, where they are melted and accelerated towards a substrate. The coating microstructures and properties depend strongly on the characteristics of the plasma jet, which can be controlled by the adjustment of the process parameters. However, the imeractions among the spray variables, render optimization and control of this process are quite complex. Understanding relationships between coating properties and process parameters is mandatory to optimize the process technique and the product quality. We are interested in this work to build an on-line control model for the APS process based on the elements of artificial intelligence and to build an emulator that replicates the dynamic behavior of the process as closely as possible.
文摘In this experimental study, chromium oxide powder was sprayed on a low-carbon steel substrate using the atmospheric plasma spray process. The current and standoff distances(SODs) were varied to study their effect on the fracture toughness of the coatings. Theoretically, as the arc current increases, the melting of the ceramic oxide should increase and this in turn should lead to the formation of a dense coating. However,it was observed that if the arc power is too high and because the particle size of the powder is small(approximately 30 μm), the particles tend to fly away from the plasma core. Similarly, an appropriate SOD should provide the particles with more melting time, thus resulting in a dense coating. On the other hand, a larger SOD leads to the solidification of the molten particles before the droplets can reach the substrate. All these effects may lead to substantial variation in the fracture toughness of the coating. The present paper attempts to correlate the plasma spraying parameters and microstructure of the coating with the fracture toughness and other primary coating properties.
基金supported by the National Nature Science Foundation of China(Grant No.51372038)the Key Research and Development Program of Jiangsu Science and Technology Department(Grant No.BE2015678)+1 种基金the Science and Technology Research Program of Jiangsu Transport Department(Grant No.2015T32)the Scientific Research Foundation of Graduate School of Southeast University(Grant No.YBJJ1566)
文摘As a new green and environmental material, bio-activated cementitious material is attracting extensive attention. This study confirmed that the bio-activated cementitious material could mineralize and cement fugitive dust into the cal- cite-consolidation-layer based on CO2 capture and utilization. The results illustrated that treatment processes (non-pressure spraying, pressure spraying, non-pressure blending and pressure blending) had a strong effect on the microstructure and prop- erties of calcite-consolidation-layer. According to the analysis of X-ray diffraction (XRD) and Fourier transform infrared (FTIR), calcite was prepared by bio-activated cementitious material during the cementation process. Meanwhile, scanning electron microscopy (SEM) and thermogravimetric-differenfial scanning calorimetry (TG-DSC) were adopted to measure the corresponding variation of porous characteristics and calcite content caused by different treatment processes. The results indi- cated that the microstructure of calcite-consolidation-layer from the spraying process had lower porosity and higher content of calcite than from blending processes. In addition, the mechanical properties of calcite-consolidation-layer were also tested. The hardness and compressive strength, which reached 19.5 GPa and 0.6 MPa, respectively, of calcite-consolidation-layer from the pressure spraying process were higher than those from the other three treatment processes. Compared with the non-treatment process, the four treatment processes had superior wind erosion resistance. Under the wind speed of 12 m/s, the mass loss of calcite-consolidation-layer from the pressure spraying process decreased from 2150.2 to 23.8 g/(m^2 h).