Acceleration of gas hydrate formation is important in preventing coal and gas outbursts and is based on a hydration mechanism. It becomes therefore necessary to investigate the effect of surfactants, acting as acceler...Acceleration of gas hydrate formation is important in preventing coal and gas outbursts and is based on a hydration mechanism. It becomes therefore necessary to investigate the effect of surfactants, acting as accelerants for hydrate formation, on induction time. We experimented with three types of a Tween solution with equal concentrations of 0.001 mol/L (T40, T40/T80 (1:1), T40/T80 (4:1)). By means of visual experimental equipment, developed by us, we measured generalized induction time using a Direct Observation Method. The experimental data were analyzed combined with a mass transfer model and a hydrate crystal nuclei growth model. Our major conclusions are as follows: 1) solubilization of surfactants produces supersaturated gas molecules, which promotes the mass transfer from a bulk phase to hydrates and provides the driving force for the complexation between host molecules (water) and guest molecules in a gas hydrate formation process; 2) when the solution of the surfactant concentration exceeds the critical micelle concentration (CMC), the surfactant in an aqueous solution will transform to micelles. Most of the gas molecules are bound to form clusters with water molecules, which promotes the formation of crystal nuclei of gas hydrates; 3) the surfactant T40 proved to have more notable effects on the promotion of crystal nuclei formation and on shortening the induction time, compared with T40/T80 (1:1) and T40/T80 (4:1).展开更多
Measured to control serious coal-gas outburst in coal seam were analyzed by theory and experimented in test site.A new technique to distress the coal-bed and drain methane,called hydraulic slotting,was described in de...Measured to control serious coal-gas outburst in coal seam were analyzed by theory and experimented in test site.A new technique to distress the coal-bed and drain methane,called hydraulic slotting,was described in detail,and the mechanism of hydrau- lic slotting was put forward and analyzed.The characteristic parameter of hydraulic slotting was given in Jiaozuo mining area and the characteristic of validity,adaptability and secu- rity was evaluated.The results show that the stress surrounding the strata and the gas in coal seam is released efficiently and thoroughly while new techniques are taken,as slot- ting at heading face by high pressure large diameter jet.The resistance to coal and gas outbursts is increased dramatically once the area of slotting is increased to a certain size. In the process of driving 2 000 m tunnel by hydraulic slotting excavation,coal and gas outburst never occurre.The technique could be used to prevent and control potential coal-gas outburst in the proceeding of tunnel driving,and the speed tunneling could be as high as more than 2 times.展开更多
The design and accomplishment of shotcrete robot is presented in this paper. This shotcrete robot is the first robot for underground coal mine in our country. It is a specific machine used for spraying concrete in und...The design and accomplishment of shotcrete robot is presented in this paper. This shotcrete robot is the first robot for underground coal mine in our country. It is a specific machine used for spraying concrete in underground coal mine. It has many advantages such as simple structure convenient operation and high reliability. The on-site experiments indicate that the sprayed layer is even, at the same time, the quantity of rebound and dust content decrease largely. The robot can satisfy the requirement of shotcrete process completely.展开更多
Coal and gas outburst is a complicated dynamic phenomenon in coal mines, Multi-factor Pattern Recognition is based on the relevant data obtained from research achievements of Geo-dynamic Division, With the help of spa...Coal and gas outburst is a complicated dynamic phenomenon in coal mines, Multi-factor Pattern Recognition is based on the relevant data obtained from research achievements of Geo-dynamic Division, With the help of spatial data management, the Neuron Network and Cluster algorithm are applied to predict the danger probability of coal and gas outburst in each cell of coal mining district. So a coal-mining district can be divided into three areas: dangerous area, minatory area, and safe area. This achievement has been successfully applied for regional prediction of coal and gas outburst in Hualnan mining area in China.展开更多
Analyzed the situations and characteristics of thin coal seam mining and its mining technologies,and introduced the mining innovation technology used by Tianchen Coal Mine of Zhaozhuang Coal Company of China.This inno...Analyzed the situations and characteristics of thin coal seam mining and its mining technologies,and introduced the mining innovation technology used by Tianchen Coal Mine of Zhaozhuang Coal Company of China.This innovation technology combined the fully mechanized mining with individual props,and the working face of mining is over length,irregular form and double units.The rotational adjusting mining technology on thin coal seam is also practiced in this new mining technology.The detail technologies,such as outlays of working face and ways,mining methods,equipments of cutting,transporting and sporting,have been introduced.So that,using the synthetic and creative mining tech- nologies,Tianchen Coal Mine solves the mining problems of thin coal seam successfully.展开更多
In this paper, the desulphurisation of high sulphur low-rank coal is proposed as a raw material for pulverised coal injection technology. Therefore, the influence of oxidant linear velocity and the size of the coal gr...In this paper, the desulphurisation of high sulphur low-rank coal is proposed as a raw material for pulverised coal injection technology. Therefore, the influence of oxidant linear velocity and the size of the coal grain was investigated in a fluidised bed. The hydrodynamic parameters of the fluidised bed including: porosity, Sherwood criterion (diffusion Nusselt number), and mass transfer coefficient (external surface) were calculated. Furthermore, the study examined the effects of intensity and efficiency on the desulphurised coal properties; organic matter, ash, and volatile matter contents. The key changes during the conversion of pyritic sulphur and coal organic matter were subsequently examined. The results showed that the sulphur content (St^d 3.16 wt%) of the low-rank coal, was transformed to (St^d 〈 1.5 wt%) after desulfurization. Other enhanced properties were: V^daf ≤ 38.0 wt%; A^d 〈 10.0 wt%, now suitable for pulverised coal injection technology.展开更多
A field experiment was conducted in 2009 and 2010 growing seasons, to study the effect of foliar application of iron-chelated "Fe-EDTA" at concentration 0, 100 and 200 mg/L on the seasonal dynamic of mineral composi...A field experiment was conducted in 2009 and 2010 growing seasons, to study the effect of foliar application of iron-chelated "Fe-EDTA" at concentration 0, 100 and 200 mg/L on the seasonal dynamic of mineral composition of N, P, K, Fe and Zn in petioles and berries of Halwani Lebanon and Kamali grape cultivars, grown on a calcareous soil in Mosul region, Iraq. The results revealed that the foliar application of 200 mg Fe/L caused a significant increase of N, P, K, Fe and Zn concentrations in petioles and berries compared with the control for both seasons. Additionally, the N, P, K, Fe and Zn concentration in petioles were high at the beginning of the growth season, whereas, decrease towards in the end of the growth season in both cultivars and seasons. While the N, P, K, Fe and Zn in berry content was increased towards from berry set to veraison and ripening stage in both cultivars and seasons. So there are various element contents in the cultivars.展开更多
In order to improve the utilization rate of foam,an arc jet nozzle was designed for precise dust control.Through theoretical analysis,the different demands of foam were compared amongst arc jets,flat jets and full con...In order to improve the utilization rate of foam,an arc jet nozzle was designed for precise dust control.Through theoretical analysis,the different demands of foam were compared amongst arc jets,flat jets and full cone jets when the dust source was covered identically by foam.It is proved that foam consumption was least when an arc jet was used.Foam production capability of an arc jet nozzle under different conditions was investigated through experiments.The results show that with the gas liquid ratio(GLR)increasing,the spray state of an arc jet nozzle presents successively water jet,foam jet and mist.Under a reasonable working condition range of foam production and a fixed GLR,foam production quantity increases at first,and then decreases with the increase of liquid supply quantity.When the inner diameter of the nozzle is 14 mm,the best GLR is 30 and the optimum liquid supply quantity is0.375 m^3/h.The results of field experiments show that the total dust and respirable dust suppression efficiency of arc jet nozzles is 85.8%and 82.6%respectively,which are 1.39 and 1.37 times higher than the full cone nozzles and 1.20 and 1.19 times higher than the fiat nozzles.展开更多
The paper describes mechacal properties and deformation features of shaft adjoining rocks in gliding tectonic ground and presents the shaft-supporting procedure of smooth-wall cushion blasting,preliminary bolting and ...The paper describes mechacal properties and deformation features of shaft adjoining rocks in gliding tectonic ground and presents the shaft-supporting procedure of smooth-wall cushion blasting,preliminary bolting and shotcreting and pouring reioforced coocrete liner in one-time-whole-section on the basis of adjoining rock deformations measured dynamically site. Field measurements of the pressur exerted on shaft wall show that this supponing procedare has enough safety reserve to meet the safety requirements in mining production.展开更多
基金Projects 50374037 and 50574038 supported by the National Natural Science Foundation of ChinaB2007-10 by the Provincial Natural Science Foundation of Heilongjiang
文摘Acceleration of gas hydrate formation is important in preventing coal and gas outbursts and is based on a hydration mechanism. It becomes therefore necessary to investigate the effect of surfactants, acting as accelerants for hydrate formation, on induction time. We experimented with three types of a Tween solution with equal concentrations of 0.001 mol/L (T40, T40/T80 (1:1), T40/T80 (4:1)). By means of visual experimental equipment, developed by us, we measured generalized induction time using a Direct Observation Method. The experimental data were analyzed combined with a mass transfer model and a hydrate crystal nuclei growth model. Our major conclusions are as follows: 1) solubilization of surfactants produces supersaturated gas molecules, which promotes the mass transfer from a bulk phase to hydrates and provides the driving force for the complexation between host molecules (water) and guest molecules in a gas hydrate formation process; 2) when the solution of the surfactant concentration exceeds the critical micelle concentration (CMC), the surfactant in an aqueous solution will transform to micelles. Most of the gas molecules are bound to form clusters with water molecules, which promotes the formation of crystal nuclei of gas hydrates; 3) the surfactant T40 proved to have more notable effects on the promotion of crystal nuclei formation and on shortening the induction time, compared with T40/T80 (1:1) and T40/T80 (4:1).
基金National Nature Science Foundation of China(50534070)International Science and Technology Cooperation and Communion Key Project of Ministry Science and Technology of China(2005DFA61030)+1 种基金Natural Science Foundation of Henan Province(200510460014)Coal Mine Gas and Fire Prevention and Control Key Laboratory Foundation of Henan Province(HKLGF200708)
文摘Measured to control serious coal-gas outburst in coal seam were analyzed by theory and experimented in test site.A new technique to distress the coal-bed and drain methane,called hydraulic slotting,was described in detail,and the mechanism of hydrau- lic slotting was put forward and analyzed.The characteristic parameter of hydraulic slotting was given in Jiaozuo mining area and the characteristic of validity,adaptability and secu- rity was evaluated.The results show that the stress surrounding the strata and the gas in coal seam is released efficiently and thoroughly while new techniques are taken,as slot- ting at heading face by high pressure large diameter jet.The resistance to coal and gas outbursts is increased dramatically once the area of slotting is increased to a certain size. In the process of driving 2 000 m tunnel by hydraulic slotting excavation,coal and gas outburst never occurre.The technique could be used to prevent and control potential coal-gas outburst in the proceeding of tunnel driving,and the speed tunneling could be as high as more than 2 times.
文摘The design and accomplishment of shotcrete robot is presented in this paper. This shotcrete robot is the first robot for underground coal mine in our country. It is a specific machine used for spraying concrete in underground coal mine. It has many advantages such as simple structure convenient operation and high reliability. The on-site experiments indicate that the sprayed layer is even, at the same time, the quantity of rebound and dust content decrease largely. The robot can satisfy the requirement of shotcrete process completely.
基金Project 2001BA803B0404 supported by National Key Technologies R&D Program of the 10th Five-Year Plan of China
文摘Coal and gas outburst is a complicated dynamic phenomenon in coal mines, Multi-factor Pattern Recognition is based on the relevant data obtained from research achievements of Geo-dynamic Division, With the help of spatial data management, the Neuron Network and Cluster algorithm are applied to predict the danger probability of coal and gas outburst in each cell of coal mining district. So a coal-mining district can be divided into three areas: dangerous area, minatory area, and safe area. This achievement has been successfully applied for regional prediction of coal and gas outburst in Hualnan mining area in China.
基金the Natural Science Fund of China(70771060)the Production Safety and Supervision of Management Bureau of China(04-116)+3 种基金the National Soft Science Planed Program(2004DGQ3D090)and(2006GXQ3D154)the Natural Science Fund of Shandong Province(Y2006H10)the Social Science Planning Program of Shandong Province(06BJJ005)the Soft-science Planed Program of Shandong Province(2007RKA134)
文摘Analyzed the situations and characteristics of thin coal seam mining and its mining technologies,and introduced the mining innovation technology used by Tianchen Coal Mine of Zhaozhuang Coal Company of China.This innovation technology combined the fully mechanized mining with individual props,and the working face of mining is over length,irregular form and double units.The rotational adjusting mining technology on thin coal seam is also practiced in this new mining technology.The detail technologies,such as outlays of working face and ways,mining methods,equipments of cutting,transporting and sporting,have been introduced.So that,using the synthetic and creative mining tech- nologies,Tianchen Coal Mine solves the mining problems of thin coal seam successfully.
文摘In this paper, the desulphurisation of high sulphur low-rank coal is proposed as a raw material for pulverised coal injection technology. Therefore, the influence of oxidant linear velocity and the size of the coal grain was investigated in a fluidised bed. The hydrodynamic parameters of the fluidised bed including: porosity, Sherwood criterion (diffusion Nusselt number), and mass transfer coefficient (external surface) were calculated. Furthermore, the study examined the effects of intensity and efficiency on the desulphurised coal properties; organic matter, ash, and volatile matter contents. The key changes during the conversion of pyritic sulphur and coal organic matter were subsequently examined. The results showed that the sulphur content (St^d 3.16 wt%) of the low-rank coal, was transformed to (St^d 〈 1.5 wt%) after desulfurization. Other enhanced properties were: V^daf ≤ 38.0 wt%; A^d 〈 10.0 wt%, now suitable for pulverised coal injection technology.
文摘A field experiment was conducted in 2009 and 2010 growing seasons, to study the effect of foliar application of iron-chelated "Fe-EDTA" at concentration 0, 100 and 200 mg/L on the seasonal dynamic of mineral composition of N, P, K, Fe and Zn in petioles and berries of Halwani Lebanon and Kamali grape cultivars, grown on a calcareous soil in Mosul region, Iraq. The results revealed that the foliar application of 200 mg Fe/L caused a significant increase of N, P, K, Fe and Zn concentrations in petioles and berries compared with the control for both seasons. Additionally, the N, P, K, Fe and Zn concentration in petioles were high at the beginning of the growth season, whereas, decrease towards in the end of the growth season in both cultivars and seasons. While the N, P, K, Fe and Zn in berry content was increased towards from berry set to veraison and ripening stage in both cultivars and seasons. So there are various element contents in the cultivars.
基金supported by the National Natural Science Foundation of China(No.51474216)
文摘In order to improve the utilization rate of foam,an arc jet nozzle was designed for precise dust control.Through theoretical analysis,the different demands of foam were compared amongst arc jets,flat jets and full cone jets when the dust source was covered identically by foam.It is proved that foam consumption was least when an arc jet was used.Foam production capability of an arc jet nozzle under different conditions was investigated through experiments.The results show that with the gas liquid ratio(GLR)increasing,the spray state of an arc jet nozzle presents successively water jet,foam jet and mist.Under a reasonable working condition range of foam production and a fixed GLR,foam production quantity increases at first,and then decreases with the increase of liquid supply quantity.When the inner diameter of the nozzle is 14 mm,the best GLR is 30 and the optimum liquid supply quantity is0.375 m^3/h.The results of field experiments show that the total dust and respirable dust suppression efficiency of arc jet nozzles is 85.8%and 82.6%respectively,which are 1.39 and 1.37 times higher than the full cone nozzles and 1.20 and 1.19 times higher than the fiat nozzles.
文摘The paper describes mechacal properties and deformation features of shaft adjoining rocks in gliding tectonic ground and presents the shaft-supporting procedure of smooth-wall cushion blasting,preliminary bolting and shotcreting and pouring reioforced coocrete liner in one-time-whole-section on the basis of adjoining rock deformations measured dynamically site. Field measurements of the pressur exerted on shaft wall show that this supponing procedare has enough safety reserve to meet the safety requirements in mining production.