The binuclear complex [Cu2(TS)(H2O)]·CH3OH , where TS denotes the binucleating ligand derived from the schiff base N,N′ bis(3 carboxylsalidene)trimethylenediamine, was obtained from the self decomposition of mon...The binuclear complex [Cu2(TS)(H2O)]·CH3OH , where TS denotes the binucleating ligand derived from the schiff base N,N′ bis(3 carboxylsalidene)trimethylenediamine, was obtained from the self decomposition of mononuclear complex Na2CuTS·H2O. It crystallizes in the monoclinic system, space group P21/c. The lattice parameters are a=11.935(2)?,b=15.667(3)?,c=11.621(2)?,β=111.60(3)°,V=2020.2(7)?3, Z=4 with R=0.0467. The structure is made of binuclear units, in which two copper atoms are bridged by two phenolic oxygen atoms. The "inside"copper atom is coordinated by two nitrogens, two phenolic oxygens in a planar coordination site, the copper atom deviates from the mean plane by 0.47?. The "outside"copper atom is five coordinated by two phenolic oxygen atoms?two equatorial carboxyl oxygen atoms and one axial water oxygen atom in a distorted tetragonal cone site, the copper atom is pulled out of the equatorial plane by 0.46?.展开更多
The title compound has been prepared and characterized by elemental analyses, infrared and raman spectra, and thermal analyses. The crystal structure of Bis [di(N′-ethyl-N-piperazinly-carbodithioato-S,S′) Zinc(Ⅱ)] ...The title compound has been prepared and characterized by elemental analyses, infrared and raman spectra, and thermal analyses. The crystal structure of Bis [di(N′-ethyl-N-piperazinly-carbodithioato-S,S′) Zinc(Ⅱ)] complexes, [Zn2(S2CNC4H8NC2H5)4], was determined by X-ray diffraction methods. The compound crystallizes in Monoclinic system, space group P21 / c, with lattice and some related parameters a=0.886(18), b=1.955(4), c=1.196(2) nm, β=106.03(3)°, V=1.991 3(7) nm3, Z=2, Mr=888.12, Dc=1.481 g·cm-3, F(000)=928, R=0.054 3 and wR=0.227 6. In crystal structure of the binuclear zinc complexes is built up of centro-symmetric dimeric entities. The coordination sphere of zinc(Ⅱ) ions is best described as a distorted tetragonal-pyramid. The IR spectral data are in agreement with the structural data. The thermal analytical data indicate that it decomposed completely at the temperature of 652.5 °C, leaving Zn. CCDC: 286177.展开更多
文摘The binuclear complex [Cu2(TS)(H2O)]·CH3OH , where TS denotes the binucleating ligand derived from the schiff base N,N′ bis(3 carboxylsalidene)trimethylenediamine, was obtained from the self decomposition of mononuclear complex Na2CuTS·H2O. It crystallizes in the monoclinic system, space group P21/c. The lattice parameters are a=11.935(2)?,b=15.667(3)?,c=11.621(2)?,β=111.60(3)°,V=2020.2(7)?3, Z=4 with R=0.0467. The structure is made of binuclear units, in which two copper atoms are bridged by two phenolic oxygen atoms. The "inside"copper atom is coordinated by two nitrogens, two phenolic oxygens in a planar coordination site, the copper atom deviates from the mean plane by 0.47?. The "outside"copper atom is five coordinated by two phenolic oxygen atoms?two equatorial carboxyl oxygen atoms and one axial water oxygen atom in a distorted tetragonal cone site, the copper atom is pulled out of the equatorial plane by 0.46?.
文摘The title compound has been prepared and characterized by elemental analyses, infrared and raman spectra, and thermal analyses. The crystal structure of Bis [di(N′-ethyl-N-piperazinly-carbodithioato-S,S′) Zinc(Ⅱ)] complexes, [Zn2(S2CNC4H8NC2H5)4], was determined by X-ray diffraction methods. The compound crystallizes in Monoclinic system, space group P21 / c, with lattice and some related parameters a=0.886(18), b=1.955(4), c=1.196(2) nm, β=106.03(3)°, V=1.991 3(7) nm3, Z=2, Mr=888.12, Dc=1.481 g·cm-3, F(000)=928, R=0.054 3 and wR=0.227 6. In crystal structure of the binuclear zinc complexes is built up of centro-symmetric dimeric entities. The coordination sphere of zinc(Ⅱ) ions is best described as a distorted tetragonal-pyramid. The IR spectral data are in agreement with the structural data. The thermal analytical data indicate that it decomposed completely at the temperature of 652.5 °C, leaving Zn. CCDC: 286177.
