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含1-(4′-氟苄基)-2-硝基吡啶鎓离子的四氯合铜配合物的合成及晶体结构
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作者 庄晓梅 蔡镇锋 +5 位作者 刘小平 杨乐敏 韩松 熊亚红 周家容 倪春林 《化学研究》 CAS 2011年第4期24-28,共5页
利用CuCl2和[4′-FBz-2-NO2Py]Cl([4′-FBz-2-NO2Py]+为1-(4′-氟苄基)-2-硝基吡啶鎓离子,其中Py为吡啶)在含盐酸的甲醇中直接反应,得到了一种新的离子对配合物[4′-FBz-2-NO2Py]2[CuCl4].利用元素分析、红外光谱、电子喷雾质谱、X射线... 利用CuCl2和[4′-FBz-2-NO2Py]Cl([4′-FBz-2-NO2Py]+为1-(4′-氟苄基)-2-硝基吡啶鎓离子,其中Py为吡啶)在含盐酸的甲醇中直接反应,得到了一种新的离子对配合物[4′-FBz-2-NO2Py]2[CuCl4].利用元素分析、红外光谱、电子喷雾质谱、X射线衍射等表征了其组成和结构.结果表明,合成的配合物为单斜晶系,空间群P-1,晶胞参数为a=0.790 9(1)nm,b=2.304 8(2)nm,c=1.596 1(2)nm,β=92.21(1)°,V=2.907 3(5)nm3,Z=4,最终一致性因子R1=0.049 1,wR2=0.136 9.配合物由2个[4′-FBz-2-NO2Py]+阳离子和1个四面体形的[CuCl4]2-阴离子组成,阳离子通过硝基上的O原子与吡啶环之间的p…π作用形成二聚体,阴、阳离子通过C-H…Cl氢键形成网状结构. 展开更多
关键词 四氯阴离子 苄基吡啶鎓离子 晶体结构
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四氯合铜(Ⅱ)-苄基吡啶季铵盐的合成和晶体结构 被引量:1
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作者 林菁华 周海练 +5 位作者 刘湘粤 蔡镇锋 吴展鹏 韩松 周家容 倪春林 《化学研究》 CAS 2012年第1期75-79,共5页
合成了1种含四氯合铜配阴离子的季铵盐[Bz6HPy][BzPy][CuCl4]([Bz6HPy]+和[BzPy]+分别为苄基六氢吡啶和苄基吡啶的鎓离子).利用元素分析仪、红外光谱仪、电子喷雾质谱仪和X射线衍射仪表征了合成产物的组成和结构.结果表明,合成的季铵盐... 合成了1种含四氯合铜配阴离子的季铵盐[Bz6HPy][BzPy][CuCl4]([Bz6HPy]+和[BzPy]+分别为苄基六氢吡啶和苄基吡啶的鎓离子).利用元素分析仪、红外光谱仪、电子喷雾质谱仪和X射线衍射仪表征了合成产物的组成和结构.结果表明,合成的季铵盐为正交晶系,空间群Pbca,晶胞参数为a=1.581 8(2)nm,b=1.762 5(2)nm,c=1.841 7(3)nm,V=5.134 5(5)nm3,Z=8,Dc=1.428g/cm3,GOOF=1.042,R1=0.051 2,wR2=0.143 7.该季铵盐分子由1个四面体形的[CuCl42]-阴离子,1个[Bz6HPy]+阳离子和1个[BzPy]+阳离子组成;相邻两个[BzPy]+阳离子之间通过吡啶环之间的π…π堆积作用形成二聚体,而阴、阳离子之间经由C-H…Cl和N-H…Cl氢键作用形成网状结构. 展开更多
关键词 四氯(ii)阴离子 六氢吡啶 苄基吡啶离子 晶体结构
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四溴合铜(Ⅱ)-对溴苄基吡啶鎓盐的合成和晶体结构
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作者 庄晓梅 周东东 +5 位作者 杨乐敏 郑园 熊亚红 刘小平 周家容 倪春林 《化学研究与应用》 CAS CSCD 北大核心 2011年第9期1240-1245,共6页
通过CuBr2和[4-BrBzPy]Br([4-BrBzPy]+为1-(4'-溴苄基)吡啶鎓离子;Py为吡啶)直接在含氢溴酸的乙腈中反应得到了一种新的吡啶鎓盐[4-BrBzPy]2[CuBr4]。用元素分析、红外光谱、电子喷雾质谱和X-射线衍射表征了其组成和结构。所合成的... 通过CuBr2和[4-BrBzPy]Br([4-BrBzPy]+为1-(4'-溴苄基)吡啶鎓离子;Py为吡啶)直接在含氢溴酸的乙腈中反应得到了一种新的吡啶鎓盐[4-BrBzPy]2[CuBr4]。用元素分析、红外光谱、电子喷雾质谱和X-射线衍射表征了其组成和结构。所合成的吡啶鎓盐由1个四面体形的[CuBr4]2-阴离子和和2个[4-BrBzPy]+阳离子组成。其中阳离子通过苯环之间的π…π堆积作用形成准一维的柱,并通过C-H…Br氢键与[CuBr4]2-阴离子相连。 展开更多
关键词 四溴阴离子 对溴苄基吡啶鎓离子 晶体结构 弱相互作用
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四氯合钴(Ⅱ)-4-氯苄基吡啶季铵盐的制备及其晶体结构和抗菌性能
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作者 吴展鹏 刘湘粤 +5 位作者 蔡镇锋 殷文涛 谢晓丹 韩松 周家容 倪春林 《化学研究》 CAS 2013年第4期375-379,共5页
合成了1种含四氯合钴配阴离子的4-氯苄基吡啶季铵盐[4-ClBzPy]2[CoCl4];利用元素分析仪、X射线单晶衍射仪以及紫外光谱仪和红外光谱仪等分析了其组成、晶体结构及光谱学性质;利用电导仪测定了[4-ClBzPy]2[CoCl4]的电导,并检测了其对金... 合成了1种含四氯合钴配阴离子的4-氯苄基吡啶季铵盐[4-ClBzPy]2[CoCl4];利用元素分析仪、X射线单晶衍射仪以及紫外光谱仪和红外光谱仪等分析了其组成、晶体结构及光谱学性质;利用电导仪测定了[4-ClBzPy]2[CoCl4]的电导,并检测了其对金黄色葡萄球菌和大肠杆菌的抗菌活性.结果表明,合成的[4-ClBzPy]2[CoCl4]季铵盐为单斜晶系,P2(1)/c空间群,晶胞参数为a=0.769 5(13)nm,b=1.895 1(3)nm,c=0.946 3(15)nm,β=93.183(2)°,V=1.378 0(4)nm3,Z=2,Dc=1.470g/cm3,GOOF=1.007,R1=0.041 8,wR2=0.100 2.与此同时,季铵盐[4-ClBzPy]2[CoCl4]对金黄色葡萄球菌和大肠杆菌均具有较好的抗菌活性. 展开更多
关键词 四氯阴离子 季铵盐 制备 晶体结构 抗菌性能
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配合物颜色的实验探究
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作者 袁天祥 《课程教育研究(学法教法研究)》 2020年第11期271-271,共1页
通过对人教版化学选修三课本实验——观察几种离子在水溶液中颜色,让学生更加充分认识配合物和配位键。相比较课本实验单一、简单,思维价值不高,该实验重点探讨了铜离子在与不同配体形成配合物时所表现出来的颜色。一方面更好的帮助学... 通过对人教版化学选修三课本实验——观察几种离子在水溶液中颜色,让学生更加充分认识配合物和配位键。相比较课本实验单一、简单,思维价值不高,该实验重点探讨了铜离子在与不同配体形成配合物时所表现出来的颜色。一方面更好的帮助学生认知到离子颜色的多样性,另一方面结合平衡移动的思想解释了浓度改变导致离子颜色发生变化的原因,联系了学生学习过的化学基本原理,提升了学生的高阶思维能力。 展开更多
关键词 离子 四氨离子 四氯离子 离子 金属 轨道分裂能
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利用二次球形配位构筑疏水型隧道框架结构 被引量:3
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作者 袁雷 郭放 +3 位作者 张爽 胡志泉 夏芳 郭文生 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2007年第10期1897-1901,共5页
质子化N,N,N′,N′-四苄基乙二胺(L)可与[MCl4]2-(M=Mn,Co,Cu)形成二次球形配合物.通过N—H…Cl相互作用构筑了1D带状和2D层状框架结构,层中配体L的苄基通过C—H…Cl相互作用分别采取水平和垂直取向,使1D带状和2D层状呈现凸凹交替排列.... 质子化N,N,N′,N′-四苄基乙二胺(L)可与[MCl4]2-(M=Mn,Co,Cu)形成二次球形配合物.通过N—H…Cl相互作用构筑了1D带状和2D层状框架结构,层中配体L的苄基通过C—H…Cl相互作用分别采取水平和垂直取向,使1D带状和2D层状呈现凸凹交替排列.通过层间凸凹部位的C—H…H—C相互作用,形成了层间空穴,进而构筑成了3D疏水型隧道框架结构,乙醇分子能够填充于隧道之中.在L.2H+.[CuBr4]2-晶体中,由于[CuBr4]2-没有与配体L的苄基形成C—H…Br氢键,使配体L的苄基采取了同向取向.因而,形成的2D层状框架结构是平展的,未形成3D疏水型隧道框架结构,也未发现与乙醇分子的包结现象. 展开更多
关键词 N N N′ N′-四苄基乙二胺 晶体工程 二次球形 四氯锰/钴/ 四溴
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四异硫氰合钴(Ⅱ)-4-氯苄基喹啉季铵盐的合成及其晶体结构
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作者 陈瑜 陈倩仪 +3 位作者 陈木河 陈晓树 周家容 倪春林 《化学研究》 CAS 2012年第5期31-35,共5页
合成了1种含异硫氰合钴配阴离子和4-氯苄基喹啉鎓离子的季铵盐[4ClBzQl]2[Co(NCS)4]([4ClBzQl]+为4-氯苄基喹啉鎓离子);利用元素分析仪、红外光谱仪、紫外-可见光谱仪、电子喷雾质谱仪和X射线衍射仪表征了其组成和结构.结果表明,合成的... 合成了1种含异硫氰合钴配阴离子和4-氯苄基喹啉鎓离子的季铵盐[4ClBzQl]2[Co(NCS)4]([4ClBzQl]+为4-氯苄基喹啉鎓离子);利用元素分析仪、红外光谱仪、紫外-可见光谱仪、电子喷雾质谱仪和X射线衍射仪表征了其组成和结构.结果表明,合成的季铵盐为三斜晶系,空间群P-1,晶胞参数为a=1.062 3(1)nm,b=1.406 9(2)nm,c=1.429 2(2)nm,α=67.11(1)°,β=72.60(1)°,γ=79.24(1)°,V=1.871 7(4)nm3,Z=2,Dc=1.421g/cm3,GOOF=1.017,R1=0.040 0,wR2=0.095 2.标题化合物分子由1个四面体形的[Co(NCS)4]2-阴离子和2个[4ClBzQl]+阳离子组成;π…π、p…π堆积作用和C-H…N、C-H…S氢键作用促进了晶体的稳定性. 展开更多
关键词 异硫氰阴离子 四氯苄基喹啉鎓离子 晶体结构
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Synthesis, crystal structure and magnetic properties of novel copper compound Cu(phen)(m-CBA)_2
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作者 周建良 霍艳 +4 位作者 王敏敏 王圆圆 古映莹 易小艺 张寿春 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2011年第12期2660-2664,共5页
A novel compound Cu(phen)(m-CBA)2 was synthesized with m-chlorobenzoic acid(m-CBA), 1,10-phenanthroline(phen) and Cu(OAc)2·H2O. It was characterized by IR, UV, elemental analyses and X-ray crystallograp... A novel compound Cu(phen)(m-CBA)2 was synthesized with m-chlorobenzoic acid(m-CBA), 1,10-phenanthroline(phen) and Cu(OAc)2·H2O. It was characterized by IR, UV, elemental analyses and X-ray crystallography. It crystallizes in the monoclinic crystal system with C2/c space group, a=2.9699(4) nm, b=1.15452(2) nm, c=1.5335(2) nm, β=111.118(2)°, V=4.905 1(1) nm3, Z=8, F(000)=2 328, R1=0.072 8, wR2=0.223 4 [I2σ(I)]. Structure analysis shows that the copper center coordinates with two nitrogen atoms from one 1,10-phenanthroline molecule, two oxygen atoms from two m-chlorobenzoic acid molecules, giving a distorted squared planar coordination geometry. This novel compound shows paramagnetic interactions between copper centers. 展开更多
关键词 copper ii compound conventional synthesis crystal structure magnetic properties
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绿色荧光晶态材料的制备与性能实验设计
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作者 倪春林 陈克来 +2 位作者 甘智豪 冯婷婷 周家容 《实验室研究与探索》 CAS 北大核心 2020年第12期83-87,109,共6页
设计了基于绿色荧光晶态材料的制备与性能的研究性实验。以氯化苄、三(4-甲氧基)苯基膦和氯化锰等为原料,采用溶剂热、超声辐射法和溶剂挥发法制备了四氯合锰-苄基三(4-甲氧基)苯基季鏻盐[BzT(4-MeO)PP]2[MnCl4]晶态材料。用元素分析、... 设计了基于绿色荧光晶态材料的制备与性能的研究性实验。以氯化苄、三(4-甲氧基)苯基膦和氯化锰等为原料,采用溶剂热、超声辐射法和溶剂挥发法制备了四氯合锰-苄基三(4-甲氧基)苯基季鏻盐[BzT(4-MeO)PP]2[MnCl4]晶态材料。用元素分析、红外光谱、紫外-可见光谱、X-射线粉末衍射和单晶衍射仪等手段进行了表征。结果表明,晶态材料属于三斜晶系,P-1空间群;一个不对称单元中含有2个[BzT(4-MeO)PP]^+阳离子和一个四氯合锰[MnCl4]^2-配阴离子,阳离子之间存在C—H…O氢键,而阳离子与阴离子通过C—H…Cl氢键相连。在360 nm紫外光照射下,晶态材料展现绿色荧光。 展开更多
关键词 四氯阴离子 季鏻盐 晶态材料 绿色荧光
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A Pyridine-copper Inclusion Complex of a New Tripodal Ligand
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作者 范承 马成丙 +2 位作者 陈昌源 陈锋 刘秋田 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2003年第6期657-660,共4页
A pyridine-copper inclusion complex with [Cu(py)4Cl]+ core was prepared in the presence of tripodal ligand tbst {tbst = 1,3,5-tris(2-benzimidazol)sulfanylmethyl-2,4,6-trimethyl- benzene}, and its structure has been de... A pyridine-copper inclusion complex with [Cu(py)4Cl]+ core was prepared in the presence of tripodal ligand tbst {tbst = 1,3,5-tris(2-benzimidazol)sulfanylmethyl-2,4,6-trimethyl- benzene}, and its structure has been determined. It crystallizes in triclinic, space group P with a = 9.0822(2), b = 17.6026(4), c = 18.7156(4) ? a = 93.40, b = 91.2980(1), g = 91.5560(1), V = 2984.81(1) 3, C58H63Cl2CuN11O4S3, Mr = 1208.81, Z = 2, F(000) = 1262, Dc = 1.345 g/cm3, m = 0.615 mm-1, R = 0.0713 and wR = 0.1307 for 7798 observed reflections (I > 2s(I)). X-ray analysis reveals that the uncoordinated tbst and pyridine as guest molecules are included in the complex with formula {[Cu(py)4Cl]Cl}(tbst)(py)4H2O. The tbst, pyridine, aqua and Cl- anion in the com- plex form extensive hydrogen-bonding interactions, building up a quasi-dinuclear structure. 展开更多
关键词 Cu(Ⅱ) complex crystal structure tripodal ligand
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Novel Thermally-Accessible Structural Changes of Chiral and Some Related Cu(ll) Complexes
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作者 Satoshi Ehara Takashiro Akitsu 《Journal of Chemistry and Chemical Engineering》 2014年第10期929-941,共13页
A mononuclear chiral copper(ll) complex, [Cu(RRchxn)2(C(CN)3)2]'H20 (RRchxn = (1R, 2R)-diaminocyclohexane) (RRchxnH), and its deuterated compound, [Cu(RRchxn)2(C(CN)3)z].D20 (RRchxnD), and their... A mononuclear chiral copper(ll) complex, [Cu(RRchxn)2(C(CN)3)2]'H20 (RRchxn = (1R, 2R)-diaminocyclohexane) (RRchxnH), and its deuterated compound, [Cu(RRchxn)2(C(CN)3)z].D20 (RRchxnD), and their isomers, [Cu(trchxn)2(C(CN)3)2]'H20 (trchxn = trans-l,2-diaminocyclohexane) (trchxnH) and [Cu(trchxn)2(C(CN)3)2]'D20 (trchxnD) have been prepared and characterized by means of 1R (infrared), electronic, and CD (circular dichroism) spectra, magnetic susceptibility, and variable-temperature X-ray crystallography as single crystals or powder. Interestingly, depending on grain size of samples, RRchxnH exhibits the monoclinic form and the orthorhombic form, which are distinguished by systematic absence and powder XRD (X-ray diffraction) patterns clearly. Although single crystals did not exhibit phase transition, powder XRD patterns of RRchxnH and weakly hydrogen bonded RRchxnD emerged low-temperature phase of monoclinic in the orthorhombic patterns only around 200-220 K. However, as a control, powder XRD patterns of both trchxnH and trchxnD did not exhibit such phase transition clearly. 展开更多
关键词 Copper(lI) complexes crystal structures temperature-dependence XRD chirality.
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Metal complexes of a novel bis-β-diketone-type ligand and its copper(Ⅱ) complexes of two-photon biological imaging 被引量:2
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作者 ZHOU ShuangSheng XUE Xuan +1 位作者 JIANG Bo TIAN YuPeng 《Science China Chemistry》 SCIE EI CAS 2012年第3期334-340,共7页
A curcumin derivative ligand,1,7-bis(3-methoxyl-4-acetoxyl)phenyl-1,6-heptadiene-3,5-diketone (diacetylcurcumin,abbreviated as HL),and its Cu and Ni complexes have been synthesized and fully characterized by elemental... A curcumin derivative ligand,1,7-bis(3-methoxyl-4-acetoxyl)phenyl-1,6-heptadiene-3,5-diketone (diacetylcurcumin,abbreviated as HL),and its Cu and Ni complexes have been synthesized and fully characterized by elemental analyses,IR,1 HNMR and molar conductivity.The resulting complexes exhibit two-photon excited fluorescence (TPEF) in DMF,and have been proven to be potentially useful for two-photon microscopy imaging in living cells.In addition,cytotoxicity tests showed that the low-micromolar concentrations of ML 2 did not cause significant reduction in cell viability over a period of at least 24 h and should be safe for further biological studies. 展开更多
关键词 diacetylcurcumin complexes two-photon fluorescence cell imaging
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Investigation on tribological behaviors of the modified UHMWPE with different structures of Schiff base copper complexes
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作者 WU Li GAO XinLei GAO WanZhen 《Science China(Technological Sciences)》 SCIE EI CAS 2013年第12期3033-3039,共7页
Investigation on the law of tribological modifying activity influenced by structure of additives will make prediction and design of materials tribological behaviors possible.Four types of diamine Schiff base Cu(II)com... Investigation on the law of tribological modifying activity influenced by structure of additives will make prediction and design of materials tribological behaviors possible.Four types of diamine Schiff base Cu(II)complexes as additives for modifying UHMWPE are synthesized,they are respectively:Cu(II)complex with ethlenediamion-N,N′-bis(salicylidene),Cu(II)complex with 1,6-hexanediamine-N,N′-bis(salicylidene),Cu(II)complex with 1,2-cyclohexanediamion-N,N′-bis(salicylidene)and Cu(II)complex with 1,2-phenylendiamion-N,N′-bis(salicylidene).Friction coefficient of the modified UHMWPE/Ti6Al4V is studied using a reciprocating friction and wear tester between line/surface contacts sliding in reciprocating under the condition of boundary lubrication with 25 vol% calf serum deionized water solution,at the same time volume loss of wear of the polymers is measured.3D topographies of the worn surfaces of the polymers and images of the worn surfaces of titanium alloys against the polymers are investigated respectively by CWLM and SEM.How the structural unit R of Schiff base copper complexes in the modified UHMWPE influences their tribological modifying activity is also discussed.Results show that the smaller the group R is,the higher the modifying activity is obtained,and the open chain is more reactive than that of alkyl and aromatic ring.Therefore,the Cu(II)complex with ethlenediamion-N,N′-bis(salicylidene)has the highest tribological modifying activity as its R group is the smallest and open. 展开更多
关键词 UHMWPE tribological behaviors Schiff base Cu(ii complexes structure
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Synthesis, characterization, crystal structure and antitumor activities of a novel demethylcantharidato bridged copper(Ⅱ) phenanthroline complex
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作者 YIN FuLing ZHU JingJing +2 位作者 HAO Jian CUI JingRong YANG JunJiao 《Science China Chemistry》 SCIE EI CAS 2013年第4期481-489,共9页
A new polymeric demethylcantharidato (DCA) bridged copper(II) phenanthroline (phen) complex ([Cu(DCA)(phen)]n-nH20) has been synthesized and characterized by elemental analysis, IR and electronic spectra s... A new polymeric demethylcantharidato (DCA) bridged copper(II) phenanthroline (phen) complex ([Cu(DCA)(phen)]n-nH20) has been synthesized and characterized by elemental analysis, IR and electronic spectra studies, molar conductivity measure- ment, and single crystal X-ray diffraction. The complex crystallizes in the orthorhombic space group Pbca with crystallo- graphic data: a -- 12.4537(4)/~, b = 9.3897(5) A, c = 30.1264(10) A, and Z = 8. In the crystal structure, the octahedral coordi- nated copper(II) ions are bridged by demethylcantharidate ligands into a one-dimensional zigzag-like structure with the Cu'"Cu separation of 6.1719/~, along with phen ligands attached to both sides of the chain altematively. Interdigitation of the chelating phen ligands of two neighboring chains via hydrophobic interaction and van der Waals forces along ac plane forms two-dimensional polymeric bilayers with discrete water sandwich layer between the adjacent polymeric bilayers. The evalua- tion of the cytotoxic activity of the copper(II) complex against HCT-8 (colorectal carcinoma), A549 (pulmonary carcinoma), HeLa (cervical cancer), HepG2 (hepatocarcinoma), BGC-823 (gastric carcinoma), and MCF-7 (breast adenocarcinoma) cell lines revealed that it is a potent cytotoxic agent, superior to Na2DCA and phen against HeLa, HepG2 and BGC-823 cells. 展开更多
关键词 demethylcantharidato-bridge polymeric copper(ii complex crystal structure cytotoxic activity
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A highly selective colorimetric sensor for Hg^(2+) based on a copper (Ⅱ) complex of thiosemicarbazone in aqueous solutions
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作者 WEI TaiBao LI JunJian +4 位作者 BAI CuiBing LIN Qi YAO Hong XIE YongQiang ZHANG YouMing 《Science China Chemistry》 SCIE EI CAS 2013年第7期923-927,共5页
By applying an indirect strategy, a new copper (II) complex of a thiosemicarbazone L has been successfully developed as a colorimetric cbemosensor for the sensitive detection of mercury (II) ions. In the presence ... By applying an indirect strategy, a new copper (II) complex of a thiosemicarbazone L has been successfully developed as a colorimetric cbemosensor for the sensitive detection of mercury (II) ions. In the presence of copper (II) ions, the colorless so- lution of L became yellow; however, upon the addition of traces of mercury (II) ions, the yellow color faded to colorless im- mediately. Other ions, including Fe3+, Ag+, Ca2+, Zn2+, Pb2+, Cd2+, Ni2+, Co2+, Cr3+ and Mg2+ had a negligible influence on the probe behavior. The detection limits were 5.0×10^-6 M and 3.0×10^-7 M of Hg2+ using the visual color changes and UV-vis changes respectively. Test strips based on Cu-L were fabricated, which could act as a convenient and efficient Hg2+ test kits. 展开更多
关键词 copper complex colorimetric sensor mercury cation aqueous solutions
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