Compact molecular packing with short π-π stacking and large π-overlap in organic semiconductors is desirable for efficient charge transport and high carrier mobility. Thus charge transport anisotropy along differen...Compact molecular packing with short π-π stacking and large π-overlap in organic semiconductors is desirable for efficient charge transport and high carrier mobility. Thus charge transport anisotropy along different directions is commonly observed in organic semiconductors. Interestingly, in this article, we found that comparable charge transport property were achieved based on the single crystals of a bis-fused tetrathiafulvalene derivative （EM-TTP） compound along two interaction directions, that is, the multiple strong S…S intermolecular interactions and the π-π stacking direction, with the measured electrical conductivity and hole mobility of 0.4 S cm-1, 0.94 cm2 V i s 1 and 0.2 S cm-1, 0.65 cm2 V-1 s-1, respectively. This finding provides us a new molecular design concept for developing novel organic semiconductors with isotropic charge transport property through the synergistic effect of multiple intermolecular interactions （such as π-π interactions） and π-π stacking.展开更多
基金supported by the National Natural Science Foundation of China(21272033)Innovation Fund of State Key Laboratory of Electronic Thin Films and Integrated Devices,China(CXJJ201104)Beijing National Laboratory for Molecular Sciences,China(BNLMS)~~
基金supported by the Ministry of Science and Technology of China(2016YFB0401100,2013CB933403,2013CB933504)the National Natural Science Foundation of China(51633006,91433115,51222306,91222203,91233205,21472116)+3 种基金Chinese Academy of Sciences(XDB12030300)Beijing NOVA Programmer(Z131101000413038)Beijing Local College Innovation Team Improve Plan(IDHT20140512)Youth Innovation Promotion Association CAS
文摘Compact molecular packing with short π-π stacking and large π-overlap in organic semiconductors is desirable for efficient charge transport and high carrier mobility. Thus charge transport anisotropy along different directions is commonly observed in organic semiconductors. Interestingly, in this article, we found that comparable charge transport property were achieved based on the single crystals of a bis-fused tetrathiafulvalene derivative （EM-TTP） compound along two interaction directions, that is, the multiple strong S…S intermolecular interactions and the π-π stacking direction, with the measured electrical conductivity and hole mobility of 0.4 S cm-1, 0.94 cm2 V i s 1 and 0.2 S cm-1, 0.65 cm2 V-1 s-1, respectively. This finding provides us a new molecular design concept for developing novel organic semiconductors with isotropic charge transport property through the synergistic effect of multiple intermolecular interactions （such as π-π interactions） and π-π stacking.
