With reference to the recent achivements about the structure, spectra and kinetics of light_harvesting complex (LHCⅡ) in PSⅡ of higher plants, a four_level model was provided to simulate the energy transfer process ...With reference to the recent achivements about the structure, spectra and kinetics of light_harvesting complex (LHCⅡ) in PSⅡ of higher plants, a four_level model was provided to simulate the energy transfer process from LHC Ⅱ to the reaction center. On the basis of this model, a set of rate equation was established. Analysis of its algebra solution led to a general picture of energy transfer process in LHC Ⅱ of higher plants and the strong interaction among pigment molecules in this process. Based on the spectra, kinetics and biological structural data providing some information of energy transfer path and energy dissipation mechanism, it has been found that energy transfer mainly happened between the pigments whose energy level was most closely adjacent, the loss of energy had a close relation to the process of energy transfer and tended to increase with the decrease of energy level. The protective mechanism of antenna system was also discussed.展开更多
We adopt a dynamical algebraic method to study a four-level excited-doublet atom model and obtain the explicit expressions of the time-evolution operator and the density operator for the system. The nonclassical effec...We adopt a dynamical algebraic method to study a four-level excited-doublet atom model and obtain the explicit expressions of the time-evolution operator and the density operator for the system. The nonclassical effects of the system, such as collapses and revivals of the atomic inversion and squeezing of the radiation field, are also discussed.展开更多
Y and inverted Y-type four-level schemes for optical quantum coherence systems,which may be intuitivelyconsidered to be very simple,have not been studied intensively till now.In this paper,we present the multiformity ...Y and inverted Y-type four-level schemes for optical quantum coherence systems,which may be intuitivelyconsidered to be very simple,have not been studied intensively till now.In this paper,we present the multiformity ofthese two types of schemes by considering that they can be classified into nine possible level styles as the second-ordersub-schemes using laser fields.Further we point out the complexity of their more than one hundred realistic configurationsas the third-order four-level sub-schemes that may appear in the optical quantum coherence experiments.Throughoutthis paper we review which configurations have been studied in some research aspects and which ones not,accordingto our knowledge,in order to be propitious to next steps of theoretical and experimental investigations,especially forapplications in the fields of quantum optics,quantum information science,laser spectroscopy,and so on.展开更多
The propagation of a weak probe field in a four-level N-type quantum system in the presence of spontaneously generated coherence(SGC) is theoretically investigated. The optical properties of the system are studied and...The propagation of a weak probe field in a four-level N-type quantum system in the presence of spontaneously generated coherence(SGC) is theoretically investigated. The optical properties of the system are studied and it is shown that the group velocity of light pulse can be controlled by relative phase of applied fields. By changing the relative phase of applied fields, the group velocity of light pulse changes from transparent subluminal to the transparent superluminal light propagation. Thus, the phase-controlled absorption-free superluminal light propagation is obtained without applying an incoherent laser fields to the system. The propagation of a weak probe light pulse is studied by solving the Maxwell's wave equation on numerical grid in space and time. Moreover, we study the third order self- and cross-Kerr susceptibility of probe field and calculate the nonlinear cross-phase shift for different values of intensity of applied fields. In addition, we take into account the effect of Doppler broadening on the light pulse propagation and it is found that a suitable choice of laser propagation directions allows us to preserve our results even in the presence of Doppler effect. It is demonstrated that by increasing the Doppler width of distribution to the room temperature,the dispersion changes from transparent subluminal to transparent superluminal light propagation which is our major motivation for this work.展开更多
A hydrophilic radical polymer, poly(2,2,6,6-teteramethylpiperidinyloxyl-4-yl acrylamide) (PTAm), was synthesized via oxidation of the corresponding precursor polymer, poly(2,2,6,6-teteramethylpiperidine-4-yl acry...A hydrophilic radical polymer, poly(2,2,6,6-teteramethylpiperidinyloxyl-4-yl acrylamide) (PTAm), was synthesized via oxidation of the corresponding precursor polymer, poly(2,2,6,6-teteramethylpiperidine-4-yl acrylamide). Electrochemical properties of the PTAm layer were characterized in three aqueous electrolytes of sodium chloride (NaCl), sodium tetrafluoroborate (NaBF4), and sodium hexafluorophosphate (NaPF6) to optimize its activity as an organic cathode. The counter anion species significantly affected the capacity and the cycle performance of the PTAm layer. The PTAm layer in the presence of BF4? displayed quantitative redox capacity beyond 1 μm layer thickness and maintained the discharging capacity of 110 mAh g-1 (97% vs. the calculated capacity) even after 1000 cycle charging/discharging, which could be ascribed to its appropriate affinity to the aqueous electrolyte without any dissolution into the electrolyte. A totally organic-based rechargeable cell was fabricated using PTAm and poly(N-4,4'-bipyridinium-N-decamethylene dibromide) as the cathode and the anode, respectively, and the aqueous electrolyte of NaBF4. The cell gave a plateau voltage at 1.2 V both on charging and discharging and an excellent charging/discharging cyclability of >2000 with high coulombic efficiency of >95%.展开更多
Based on a two-qubit isotropic Heisenberg XXX model with a constant external magnetic field,we construct a four-level entangled quantum heat engine(QHE).The expressions for several thermodynamic quantities such as the...Based on a two-qubit isotropic Heisenberg XXX model with a constant external magnetic field,we construct a four-level entangled quantum heat engine(QHE).The expressions for several thermodynamic quantities such as the heat transferred,the work and efficiency are derived.Moreover,the influence of the entanglement on the thermodynamic quantities is investigated analytically and numerically.Several interesting features of the variation of the heat transferred,the work and the efficiency with the concurrences of the thermal entanglement of different thermal equilibrium states are obtained.展开更多
文摘With reference to the recent achivements about the structure, spectra and kinetics of light_harvesting complex (LHCⅡ) in PSⅡ of higher plants, a four_level model was provided to simulate the energy transfer process from LHC Ⅱ to the reaction center. On the basis of this model, a set of rate equation was established. Analysis of its algebra solution led to a general picture of energy transfer process in LHC Ⅱ of higher plants and the strong interaction among pigment molecules in this process. Based on the spectra, kinetics and biological structural data providing some information of energy transfer path and energy dissipation mechanism, it has been found that energy transfer mainly happened between the pigments whose energy level was most closely adjacent, the loss of energy had a close relation to the process of energy transfer and tended to increase with the decrease of energy level. The protective mechanism of antenna system was also discussed.
基金The project supported by National Natural Science Foundation of China under Grant Nos. 10174066 and 10275055
文摘We adopt a dynamical algebraic method to study a four-level excited-doublet atom model and obtain the explicit expressions of the time-evolution operator and the density operator for the system. The nonclassical effects of the system, such as collapses and revivals of the atomic inversion and squeezing of the radiation field, are also discussed.
基金Supported by the Research Starting Funds of Tianjin Polytechnic University under Grant Nos.20080033 and 20070010
文摘Y and inverted Y-type four-level schemes for optical quantum coherence systems,which may be intuitivelyconsidered to be very simple,have not been studied intensively till now.In this paper,we present the multiformity ofthese two types of schemes by considering that they can be classified into nine possible level styles as the second-ordersub-schemes using laser fields.Further we point out the complexity of their more than one hundred realistic configurationsas the third-order four-level sub-schemes that may appear in the optical quantum coherence experiments.Throughoutthis paper we review which configurations have been studied in some research aspects and which ones not,accordingto our knowledge,in order to be propitious to next steps of theoretical and experimental investigations,especially forapplications in the fields of quantum optics,quantum information science,laser spectroscopy,and so on.
文摘The propagation of a weak probe field in a four-level N-type quantum system in the presence of spontaneously generated coherence(SGC) is theoretically investigated. The optical properties of the system are studied and it is shown that the group velocity of light pulse can be controlled by relative phase of applied fields. By changing the relative phase of applied fields, the group velocity of light pulse changes from transparent subluminal to the transparent superluminal light propagation. Thus, the phase-controlled absorption-free superluminal light propagation is obtained without applying an incoherent laser fields to the system. The propagation of a weak probe light pulse is studied by solving the Maxwell's wave equation on numerical grid in space and time. Moreover, we study the third order self- and cross-Kerr susceptibility of probe field and calculate the nonlinear cross-phase shift for different values of intensity of applied fields. In addition, we take into account the effect of Doppler broadening on the light pulse propagation and it is found that a suitable choice of laser propagation directions allows us to preserve our results even in the presence of Doppler effect. It is demonstrated that by increasing the Doppler width of distribution to the room temperature,the dispersion changes from transparent subluminal to transparent superluminal light propagation which is our major motivation for this work.
基金supported by Grants-in-Aid for Scientific Research (19105003)Global COE Program at Waseda University from MEXT, JapanResearch Project "Radical Polymers" at Advanced Research Institute for Science & Engineering, Waseda University
文摘A hydrophilic radical polymer, poly(2,2,6,6-teteramethylpiperidinyloxyl-4-yl acrylamide) (PTAm), was synthesized via oxidation of the corresponding precursor polymer, poly(2,2,6,6-teteramethylpiperidine-4-yl acrylamide). Electrochemical properties of the PTAm layer were characterized in three aqueous electrolytes of sodium chloride (NaCl), sodium tetrafluoroborate (NaBF4), and sodium hexafluorophosphate (NaPF6) to optimize its activity as an organic cathode. The counter anion species significantly affected the capacity and the cycle performance of the PTAm layer. The PTAm layer in the presence of BF4? displayed quantitative redox capacity beyond 1 μm layer thickness and maintained the discharging capacity of 110 mAh g-1 (97% vs. the calculated capacity) even after 1000 cycle charging/discharging, which could be ascribed to its appropriate affinity to the aqueous electrolyte without any dissolution into the electrolyte. A totally organic-based rechargeable cell was fabricated using PTAm and poly(N-4,4'-bipyridinium-N-decamethylene dibromide) as the cathode and the anode, respectively, and the aqueous electrolyte of NaBF4. The cell gave a plateau voltage at 1.2 V both on charging and discharging and an excellent charging/discharging cyclability of >2000 with high coulombic efficiency of >95%.
基金supported by the National Natural Science Foundation of China (Grant No. 11065008)
文摘Based on a two-qubit isotropic Heisenberg XXX model with a constant external magnetic field,we construct a four-level entangled quantum heat engine(QHE).The expressions for several thermodynamic quantities such as the heat transferred,the work and efficiency are derived.Moreover,the influence of the entanglement on the thermodynamic quantities is investigated analytically and numerically.Several interesting features of the variation of the heat transferred,the work and the efficiency with the concurrences of the thermal entanglement of different thermal equilibrium states are obtained.