This paper mainly investigated the antimony recovery from antimony-bearing dusts through reduction roasting process after the dust firstly oxidation roasted.CO–CO2 mixture gas was used as reducing agent,and the antim...This paper mainly investigated the antimony recovery from antimony-bearing dusts through reduction roasting process after the dust firstly oxidation roasted.CO–CO2 mixture gas was used as reducing agent,and the antimony-containing phase was reduced into Sb4O6,volatilized into smoke,and finally recovered through the cooling cylinder.The antimony recovery rate increased from 66.00 wt%to 73.81 wt%in temperature range of 650 to 800°C,and decreased with temperature increased further to 900°C due to the reduction of Sb4O6 to the nonvolatile Sb.Similarly,the CO partial pressure also played a double role in this test.Under optimized conditions of roasting temperature of 800°C,CO partial pressure of 7.5 vol%and roasting time of 120 min,98.40 wt%of arsenic removal rate and 80.40 wt%antimony recovery rate could be obtained.In addition,the“As2O3”product could be used for preparing ferric arsenate which realized the harmless treatment of it.展开更多
Disassembly and recycling of E-waste creates a series of environmental problems. The selection of a technologically reliable, environmentally friendly, economically affordable and socially acceptable recycling technol...Disassembly and recycling of E-waste creates a series of environmental problems. The selection of a technologically reliable, environmentally friendly, economically affordable and socially acceptable recycling technology for E-waste is a significant question. This study establishes a Monte-Carlo mathematical model of cost minimization, given the constraints of environmentally sound handling of the e-waste, in the context of Crystal Ball risk assessment and evaluation software. By following the streams of the different treatment processes, which consist of various technologies including disassembly, recycling and disposal, the econom-ics of various possibilities were identified and the optimal recycling technology proposed. The key factors of the proposed scenarios were determined by using sensitivity analysis. The results of this study show that, for discarded refrigerators, the operating life span plays the key role. The model supports maintenance and resale of the short lived refrigerators. For the longer lived refrigerators material recycling is recommended by the model. Sensitivity analysis shows that purchase cost, plastic sale price, condenser sale price and disassembly costs are the main effects. This study provides a significant technical support for policy making in E-waste management.展开更多
Titanium aluminum(TiAl)scraps with a high oxygen content were treated with yttrium(Y)in a liquid chemical deoxidization process for recycling.The Gibbs free energy and the equilibrium constant of the deoxidization rea...Titanium aluminum(TiAl)scraps with a high oxygen content were treated with yttrium(Y)in a liquid chemical deoxidization process for recycling.The Gibbs free energy and the equilibrium constant of the deoxidization reaction were calculated,and the effects of the yttrium content and the system pressure on the oxygen content in the product were determined.The results showed that the oxygen in TiAl scraps could be removed by yttrium,and the oxygen content of the deoxidized TiAl scraps had only 10%of the original content after deoxidization.Furthermore,the oxygen content of the deoxidized TiAl scraps was decreased with the increase of yttrium addition.The higher the chamber pressure,the greater the oxygen content in the final TiAl alloys.These results were consistent with calculated values.The microstructure of the deoxidized alloys was akin to that of the original material;however,Y_(2)O_(3) particles were observed in the deoxidized alloys.展开更多
The copper consumption by the Chinese cable industry amounted to 354×104 t in 2006, taking over 70 % of the total copper consumption in China in that year. At present, making copper rod directly from recovered sc...The copper consumption by the Chinese cable industry amounted to 354×104 t in 2006, taking over 70 % of the total copper consumption in China in that year. At present, making copper rod directly from recovered scrap copper and saving copper with aluminum have become topics of general interests in the Chinese cable industry. The quality of the copper conductors in the industry is declining, resulting in sharp decrease in the rate of qualified wire and cable products. More and more copper wires are drawn from the rods made directly from scrap copper. The manufacturers know well some of the wires or rods are unqualified products though, they continue to use or produce products not complying with standards in order to make profits. Now the consumption of copper-clad-aluminum and copper-clad-steel is growing gradually. In 2006, the consumption of copper-clad-aluminum in China amounted to ca. 5×104 t. But in some applications, neither the common understanding between buyer and supplier nor the results of feasibility study are achieved in the product orientation and technical/economic feasibility in terms of saving copper with aluminum. This paper presents the status-quo, problems arisen and suggestions in terms of making copper rod directly from recovered scrap copper and saving copper with aluminum, in a view to promote these two topics of general interests to go toward a virtuous circle.展开更多
An optimal design of wastewater reuse for a University is concerned in this paper. The raw water and the capacity of wastewater reuse were determined according to the wastewater characteristic of a university; the tre...An optimal design of wastewater reuse for a University is concerned in this paper. The raw water and the capacity of wastewater reuse were determined according to the wastewater characteristic of a university; the treatment process was chosen by building a cost-benefit model; and the modeling test was performed about the operation effect of the proposed project and the recommended water quality of reclaimed water. It is estimated that 3.4×10^5 m^3/a tap water and 6.1×10^5 Yuan/a will be saved if the project was put into operation and the proposed project will reduce the total quantity of pollutant efficiently and bring lots of social and economic benefits.展开更多
Management of solid wastes has become a critical issue for almost all the major cities in Nigeria. Although the responsibility for solid waste management remains primarily with the local government councils, several o...Management of solid wastes has become a critical issue for almost all the major cities in Nigeria. Although the responsibility for solid waste management remains primarily with the local government councils, several other stakeholders are playing significant roles in the system. In Zaria, the scavengers, waste pickers and collectors eke out a living by collecting waste and selling recyclable materials out of the urban solid wastes. The paper utilized data collected using questionnaire survey, in-depth discussion guides and open-ended interviews to examine the socio-economic characteristics, the functions, aspects of involvement of children, the working conditions and problems of waste collectors and pickers in Zaria. The paper found that the sector is the only means of solid waste collection in several sections of the town and is a source of livelihood for the poor. The activities help in realizing the aim of modern waste management, that is to move up the solid waste management hierarchy by reducing reliance on disposal and increasing recycling. In spite of these important functions, informal waste collection and recycling are associated with problems of unsanitary conditions and health risks to the communities and the waste collectors. Recommendations have been made to integrate the informal sector into the formal waste management by incorporating the employment needs of the urban poor and enhancing the efficiency of government in addressing the main problems.展开更多
The temperature is 56.5℃when acetone gas is rectified during the production of powdery phospholipid. If heat exchanger is added, heat energy that is reclaimed can be used by other heaters. On the basis of exchange ho...The temperature is 56.5℃when acetone gas is rectified during the production of powdery phospholipid. If heat exchanger is added, heat energy that is reclaimed can be used by other heaters. On the basis of exchange hot water (51℃) 4m3 every minute, a factory with the productivity of powdery phospholipid being 10 ton a day can save 533.2 ton standard coal which is equivalent to 746.48 ton common coal. If this technique of saving energy and reducing emission could be widely used in correlative industries of all over the country, economic benefits will be prominent.展开更多
The preparation of crystal form of Al(OH)3 from the deposited residues of anodizing lines in the process of producing aluminum was studied. Alkali is used to dissolve the residue, and then blow CO2 is bellowed in, f...The preparation of crystal form of Al(OH)3 from the deposited residues of anodizing lines in the process of producing aluminum was studied. Alkali is used to dissolve the residue, and then blow CO2 is bellowed in, finally a kind of useful crystal Al(OH)3 is accessed by hydrolysis. The yield of the crystal Al(OH)3 was affected by temperature, pH and flow rate of CO2. The experimental results showed that under constant stirring, the optimized conditions was to control the temperature of 75-85℃, pH 7.5-9.0, CO/flow rate 60-80 mL/min. Using this method, the purpose of recovering valuable resources of Al, cleaning up the environment, and recycling of the by-product of Na2CO3 was achieved. It was of good economic and social benefits.展开更多
Leather industry is an important light industry in China.Leather making requires a series of chemical treatment.Degreasing,unhairing and chrome tanning wastewaters are the main portions of tannery wastewater.Reclaimin...Leather industry is an important light industry in China.Leather making requires a series of chemical treatment.Degreasing,unhairing and chrome tanning wastewaters are the main portions of tannery wastewater.Reclaiming and reusing these wastewaters can eliminate 80% of COD,75% of BOD,95% of chromium and 93% of sulfuret,furthermore reduce environment impact,decrease treatment costs,save chemicals and water.Some application methods of wastewater reclamation and reuse for different operations were reported.The suitable reclamation and reuse technologies can enable leather making processes more rational,and realize the recovery and recycle of several chemicals in the tannery.Resourceful utilization of tannery wastewater should mate with renovating production technology,updating equipment,and must be guaranteed sufficiently by environmental protection measures.展开更多
This paper reports a generation and composition analysis of household solid waste in Mexico, using as a reference the characterization study performed in two communities, one urban and one rural. Data obtained are fun...This paper reports a generation and composition analysis of household solid waste in Mexico, using as a reference the characterization study performed in two communities, one urban and one rural. Data obtained are fundamental parameters for the planning of urban solid waste management systems in Mexico, complying this way with the established policy in the National Program for Waste Management and Prevention 2009-2012. The study was carried out during five days and two main parameters were assessed: (1) the daily generation rate per person and (2) the waste composition. The per capita waste generation was 0.958 kg for the urban community and 0.631 kg for the rural. The results showed that the mean composition of waste from both locations was statistically similar (a = 0.05). In both locations the most important contribution was the fraction of food waste. In both locations more than 60% of the waste is potentially recyclable. The results of this study will be used by the municipal waste authorities in order to establish an integrated waste management plan.展开更多
This paper discussed the comprehensive treatment of coking plant effluent.Cyanide containing and phenol wastewater was first recovered and utilized respectively, and then, mixed it with other low harmful wastewater fo...This paper discussed the comprehensive treatment of coking plant effluent.Cyanide containing and phenol wastewater was first recovered and utilized respectively, and then, mixed it with other low harmful wastewater for destroying treatment.Treated water was reused in quenching coke.展开更多
基金Project(51564034)supported by the National Science Fund for Distinguished Regional Scholars,China
文摘This paper mainly investigated the antimony recovery from antimony-bearing dusts through reduction roasting process after the dust firstly oxidation roasted.CO–CO2 mixture gas was used as reducing agent,and the antimony-containing phase was reduced into Sb4O6,volatilized into smoke,and finally recovered through the cooling cylinder.The antimony recovery rate increased from 66.00 wt%to 73.81 wt%in temperature range of 650 to 800°C,and decreased with temperature increased further to 900°C due to the reduction of Sb4O6 to the nonvolatile Sb.Similarly,the CO partial pressure also played a double role in this test.Under optimized conditions of roasting temperature of 800°C,CO partial pressure of 7.5 vol%and roasting time of 120 min,98.40 wt%of arsenic removal rate and 80.40 wt%antimony recovery rate could be obtained.In addition,the“As2O3”product could be used for preparing ferric arsenate which realized the harmless treatment of it.
基金Projects 50574094 supported by the National Natural Science Foundation of ChinaCPEUKF06-11 by the Key Laboratory Open Project of Education Ministry of China200600242 by the Science and Technology Innovation Project of Xuzhou
文摘Disassembly and recycling of E-waste creates a series of environmental problems. The selection of a technologically reliable, environmentally friendly, economically affordable and socially acceptable recycling technology for E-waste is a significant question. This study establishes a Monte-Carlo mathematical model of cost minimization, given the constraints of environmentally sound handling of the e-waste, in the context of Crystal Ball risk assessment and evaluation software. By following the streams of the different treatment processes, which consist of various technologies including disassembly, recycling and disposal, the econom-ics of various possibilities were identified and the optimal recycling technology proposed. The key factors of the proposed scenarios were determined by using sensitivity analysis. The results of this study show that, for discarded refrigerators, the operating life span plays the key role. The model supports maintenance and resale of the short lived refrigerators. For the longer lived refrigerators material recycling is recommended by the model. Sensitivity analysis shows that purchase cost, plastic sale price, condenser sale price and disassembly costs are the main effects. This study provides a significant technical support for policy making in E-waste management.
基金supported by Key Laboratory for Ecological Metallurgy of Multimetallic Mineral (Ministry of Education) Open Subjectthe National Natural Science Foundation of China-China Baowu Steel Group Joint Research Fund for Iron and Steel (No.U1860203)the National Natural Science Foundation of China (No.U1760109)。
文摘Titanium aluminum(TiAl)scraps with a high oxygen content were treated with yttrium(Y)in a liquid chemical deoxidization process for recycling.The Gibbs free energy and the equilibrium constant of the deoxidization reaction were calculated,and the effects of the yttrium content and the system pressure on the oxygen content in the product were determined.The results showed that the oxygen in TiAl scraps could be removed by yttrium,and the oxygen content of the deoxidized TiAl scraps had only 10%of the original content after deoxidization.Furthermore,the oxygen content of the deoxidized TiAl scraps was decreased with the increase of yttrium addition.The higher the chamber pressure,the greater the oxygen content in the final TiAl alloys.These results were consistent with calculated values.The microstructure of the deoxidized alloys was akin to that of the original material;however,Y_(2)O_(3) particles were observed in the deoxidized alloys.
文摘The copper consumption by the Chinese cable industry amounted to 354×104 t in 2006, taking over 70 % of the total copper consumption in China in that year. At present, making copper rod directly from recovered scrap copper and saving copper with aluminum have become topics of general interests in the Chinese cable industry. The quality of the copper conductors in the industry is declining, resulting in sharp decrease in the rate of qualified wire and cable products. More and more copper wires are drawn from the rods made directly from scrap copper. The manufacturers know well some of the wires or rods are unqualified products though, they continue to use or produce products not complying with standards in order to make profits. Now the consumption of copper-clad-aluminum and copper-clad-steel is growing gradually. In 2006, the consumption of copper-clad-aluminum in China amounted to ca. 5×104 t. But in some applications, neither the common understanding between buyer and supplier nor the results of feasibility study are achieved in the product orientation and technical/economic feasibility in terms of saving copper with aluminum. This paper presents the status-quo, problems arisen and suggestions in terms of making copper rod directly from recovered scrap copper and saving copper with aluminum, in a view to promote these two topics of general interests to go toward a virtuous circle.
文摘An optimal design of wastewater reuse for a University is concerned in this paper. The raw water and the capacity of wastewater reuse were determined according to the wastewater characteristic of a university; the treatment process was chosen by building a cost-benefit model; and the modeling test was performed about the operation effect of the proposed project and the recommended water quality of reclaimed water. It is estimated that 3.4×10^5 m^3/a tap water and 6.1×10^5 Yuan/a will be saved if the project was put into operation and the proposed project will reduce the total quantity of pollutant efficiently and bring lots of social and economic benefits.
文摘Management of solid wastes has become a critical issue for almost all the major cities in Nigeria. Although the responsibility for solid waste management remains primarily with the local government councils, several other stakeholders are playing significant roles in the system. In Zaria, the scavengers, waste pickers and collectors eke out a living by collecting waste and selling recyclable materials out of the urban solid wastes. The paper utilized data collected using questionnaire survey, in-depth discussion guides and open-ended interviews to examine the socio-economic characteristics, the functions, aspects of involvement of children, the working conditions and problems of waste collectors and pickers in Zaria. The paper found that the sector is the only means of solid waste collection in several sections of the town and is a source of livelihood for the poor. The activities help in realizing the aim of modern waste management, that is to move up the solid waste management hierarchy by reducing reliance on disposal and increasing recycling. In spite of these important functions, informal waste collection and recycling are associated with problems of unsanitary conditions and health risks to the communities and the waste collectors. Recommendations have been made to integrate the informal sector into the formal waste management by incorporating the employment needs of the urban poor and enhancing the efficiency of government in addressing the main problems.
文摘The temperature is 56.5℃when acetone gas is rectified during the production of powdery phospholipid. If heat exchanger is added, heat energy that is reclaimed can be used by other heaters. On the basis of exchange hot water (51℃) 4m3 every minute, a factory with the productivity of powdery phospholipid being 10 ton a day can save 533.2 ton standard coal which is equivalent to 746.48 ton common coal. If this technique of saving energy and reducing emission could be widely used in correlative industries of all over the country, economic benefits will be prominent.
文摘The preparation of crystal form of Al(OH)3 from the deposited residues of anodizing lines in the process of producing aluminum was studied. Alkali is used to dissolve the residue, and then blow CO2 is bellowed in, finally a kind of useful crystal Al(OH)3 is accessed by hydrolysis. The yield of the crystal Al(OH)3 was affected by temperature, pH and flow rate of CO2. The experimental results showed that under constant stirring, the optimized conditions was to control the temperature of 75-85℃, pH 7.5-9.0, CO/flow rate 60-80 mL/min. Using this method, the purpose of recovering valuable resources of Al, cleaning up the environment, and recycling of the by-product of Na2CO3 was achieved. It was of good economic and social benefits.
文摘Leather industry is an important light industry in China.Leather making requires a series of chemical treatment.Degreasing,unhairing and chrome tanning wastewaters are the main portions of tannery wastewater.Reclaiming and reusing these wastewaters can eliminate 80% of COD,75% of BOD,95% of chromium and 93% of sulfuret,furthermore reduce environment impact,decrease treatment costs,save chemicals and water.Some application methods of wastewater reclamation and reuse for different operations were reported.The suitable reclamation and reuse technologies can enable leather making processes more rational,and realize the recovery and recycle of several chemicals in the tannery.Resourceful utilization of tannery wastewater should mate with renovating production technology,updating equipment,and must be guaranteed sufficiently by environmental protection measures.
文摘This paper reports a generation and composition analysis of household solid waste in Mexico, using as a reference the characterization study performed in two communities, one urban and one rural. Data obtained are fundamental parameters for the planning of urban solid waste management systems in Mexico, complying this way with the established policy in the National Program for Waste Management and Prevention 2009-2012. The study was carried out during five days and two main parameters were assessed: (1) the daily generation rate per person and (2) the waste composition. The per capita waste generation was 0.958 kg for the urban community and 0.631 kg for the rural. The results showed that the mean composition of waste from both locations was statistically similar (a = 0.05). In both locations the most important contribution was the fraction of food waste. In both locations more than 60% of the waste is potentially recyclable. The results of this study will be used by the municipal waste authorities in order to establish an integrated waste management plan.
文摘This paper discussed the comprehensive treatment of coking plant effluent.Cyanide containing and phenol wastewater was first recovered and utilized respectively, and then, mixed it with other low harmful wastewater for destroying treatment.Treated water was reused in quenching coke.