Physicochemical and mineralogical characteristics of an alkali leaching residue of wolframite were studied by XRD,SEM−EDS,chemical phase analysis,mineral liberation analyzer(MLA),and TG−DSC methods.Batch leaching test...Physicochemical and mineralogical characteristics of an alkali leaching residue of wolframite were studied by XRD,SEM−EDS,chemical phase analysis,mineral liberation analyzer(MLA),and TG−DSC methods.Batch leaching tests,toxicity characteristic leaching procedure(TCLP)tests and Chinese standard leaching tests(CSLT)were conducted to determine the environmental mobility of toxic elements.The results show that,due to the high contents of W,Fe,Mn,Sn,and Nb,the residue is with high resource value,but the content of a toxic element,As,is also high.The existing minerals of the investigated elements mainly occur as monomer particles,but it is difficult to extract these valuable metals by conventional acid leaching due to their mineral properties.The release of As increases over time in acidic environment.The leaching concentration of all investigated harmful elements through TCLP is within the limiting value,while the leaching concentration of As through CSLT exceeds the limiting value by more than 4 times,so the residue is classified as hazardous solid waste based on the Chinese standard.A process for valuable metals recovery from this residue was proposed.Preliminary experimental results indicated that the main valuable metals could be extracted effectively.展开更多
The flotation characteristics of Shenfu coal macerals was researched. Taking flotation recovery and enrichment of macerals as the evaluation objects, the influence of the agent dosage, pulp concentration, impeller spe...The flotation characteristics of Shenfu coal macerals was researched. Taking flotation recovery and enrichment of macerals as the evaluation objects, the influence of the agent dosage, pulp concentration, impeller speed and aeration rate on the separating effect was investigated. And the optimum process conditions of flotation were confirmed. The results show that the agent dosage, pulp concentration, impeller speed and aeration rate have a significant impact on flotation recovery and en- richment of macerals. The float recovery was 73.28% and enrichment ratio of vitrinite was 83.89% when CTAB dosage of 1.0 kg/t, pulp concentration of 100 g/L, impeller speed of 1 700 r/min and aeration rate of 0.25 m3/（m2·min） were used. The tailings yield was 60.30% and enrichment ratio of inertinite was 61.44% when CTAB dosage of 0.5 kg/t, pulp concentration of 100 g/L, impeller speed of I 700 r/min and aeration rate of 0.20 m3/（m2·min） were used.展开更多
Waste heat recovery for internal combustion engine(ICE)has been considered as an important strategy to improve efficiency and promote fuel economy,thus alleviating the problems of energy shortage and environmental pol...Waste heat recovery for internal combustion engine(ICE)has been considered as an important strategy to improve efficiency and promote fuel economy,thus alleviating the problems of energy shortage and environmental pollution.This paper investigates the characteristics of various kinds of waste heat energy,namely,waste heat in exhaust,cooling water and charge air,over the engine’s whole operating region.Based on the energy balance experiments,the energy distribution of a conventional heavy-duty diesel engine is obtained under mapping characteristics.According to exergy analysis,the energy recovery potential for waste heat is studied as well.The experimental results indicate that exhaust energy increases with engine speed and load,while cooling water energy is more sensitive to load,especially at low and middle speed.Charge air energy,on the other hand,mainly counts on speed rather than load.Exhaust energy possesses the highest recovery potential in terms of both quantity and quality.Through waste heat recovery,a dramatic improvement in engine efficiency is achievable,actually,the maximum value can amount to 60%or even more.展开更多
Objectives： To observe the surface characteristics and mechanical behavior of retrieved microimplants under clinically simulating experimental conditions and to investigate the feasibility of rouse of microimplants. ...Objectives： To observe the surface characteristics and mechanical behavior of retrieved microimplants under clinically simulating experimental conditions and to investigate the feasibility of rouse of microimplants. Materials and methods： The microimplants, inserted at different angles, were retrieved from the patients （RMIP） and the artificial bone （RMIA）. Surface characteristics, including morphologic changes of tips and thread edges, length reduction, and surface compositional variation, were evaluated using a field emission scanning electron microscope, a stereoscopic microscope, and energy-dispersive X-ray spectroscopy, respectively. Mechanical behavior comprising maximum insertion torque （MIT） and insertion time was tested with the artificial bone under clinically simulating conditions. Results： The tips and thread edges were worn out to various degrees in retrieved microimplants and thin deposits were observed on the surface in the RMIP group. Traces of foreign elements, such as iron, sulphur, and calcium, were detected on the surface of RMIP. Both MIT and insertion time of retrieved microimplants were increased compared to their initial use, and were much greater in RMIP. The increases of MIT were seen in all groups inserted at the insertion angle of 45~ compared with 90~, although the differences were not statistically significant. Conclusions： Retrieved microimplants exhibited different degrees of changes on surface characteristics and mechanical behavior, with more changes in RMIP. The reuse of microimplants for immediate relocation in the same patient may be acceptable; however, postponed relocation and allogeneic reuse of microimplants are not recommended in clinical practice.展开更多
基金the financial supports from the National Key R&D Program of China(No.2019YFC1907400)the National Natural Science Foundation of China(Nos.51904351,51620105013)。
文摘Physicochemical and mineralogical characteristics of an alkali leaching residue of wolframite were studied by XRD,SEM−EDS,chemical phase analysis,mineral liberation analyzer(MLA),and TG−DSC methods.Batch leaching tests,toxicity characteristic leaching procedure(TCLP)tests and Chinese standard leaching tests(CSLT)were conducted to determine the environmental mobility of toxic elements.The results show that,due to the high contents of W,Fe,Mn,Sn,and Nb,the residue is with high resource value,but the content of a toxic element,As,is also high.The existing minerals of the investigated elements mainly occur as monomer particles,but it is difficult to extract these valuable metals by conventional acid leaching due to their mineral properties.The release of As increases over time in acidic environment.The leaching concentration of all investigated harmful elements through TCLP is within the limiting value,while the leaching concentration of As through CSLT exceeds the limiting value by more than 4 times,so the residue is classified as hazardous solid waste based on the Chinese standard.A process for valuable metals recovery from this residue was proposed.Preliminary experimental results indicated that the main valuable metals could be extracted effectively.
文摘The flotation characteristics of Shenfu coal macerals was researched. Taking flotation recovery and enrichment of macerals as the evaluation objects, the influence of the agent dosage, pulp concentration, impeller speed and aeration rate on the separating effect was investigated. And the optimum process conditions of flotation were confirmed. The results show that the agent dosage, pulp concentration, impeller speed and aeration rate have a significant impact on flotation recovery and en- richment of macerals. The float recovery was 73.28% and enrichment ratio of vitrinite was 83.89% when CTAB dosage of 1.0 kg/t, pulp concentration of 100 g/L, impeller speed of 1 700 r/min and aeration rate of 0.25 m3/（m2·min） were used. The tailings yield was 60.30% and enrichment ratio of inertinite was 61.44% when CTAB dosage of 0.5 kg/t, pulp concentration of 100 g/L, impeller speed of I 700 r/min and aeration rate of 0.20 m3/（m2·min） were used.
基金supported by the National Natural Science Foundation of China(Grant No.51206117)
文摘Waste heat recovery for internal combustion engine(ICE)has been considered as an important strategy to improve efficiency and promote fuel economy,thus alleviating the problems of energy shortage and environmental pollution.This paper investigates the characteristics of various kinds of waste heat energy,namely,waste heat in exhaust,cooling water and charge air,over the engine’s whole operating region.Based on the energy balance experiments,the energy distribution of a conventional heavy-duty diesel engine is obtained under mapping characteristics.According to exergy analysis,the energy recovery potential for waste heat is studied as well.The experimental results indicate that exhaust energy increases with engine speed and load,while cooling water energy is more sensitive to load,especially at low and middle speed.Charge air energy,on the other hand,mainly counts on speed rather than load.Exhaust energy possesses the highest recovery potential in terms of both quantity and quality.Through waste heat recovery,a dramatic improvement in engine efficiency is achievable,actually,the maximum value can amount to 60%or even more.
文摘Objectives： To observe the surface characteristics and mechanical behavior of retrieved microimplants under clinically simulating experimental conditions and to investigate the feasibility of rouse of microimplants. Materials and methods： The microimplants, inserted at different angles, were retrieved from the patients （RMIP） and the artificial bone （RMIA）. Surface characteristics, including morphologic changes of tips and thread edges, length reduction, and surface compositional variation, were evaluated using a field emission scanning electron microscope, a stereoscopic microscope, and energy-dispersive X-ray spectroscopy, respectively. Mechanical behavior comprising maximum insertion torque （MIT） and insertion time was tested with the artificial bone under clinically simulating conditions. Results： The tips and thread edges were worn out to various degrees in retrieved microimplants and thin deposits were observed on the surface in the RMIP group. Traces of foreign elements, such as iron, sulphur, and calcium, were detected on the surface of RMIP. Both MIT and insertion time of retrieved microimplants were increased compared to their initial use, and were much greater in RMIP. The increases of MIT were seen in all groups inserted at the insertion angle of 45~ compared with 90~, although the differences were not statistically significant. Conclusions： Retrieved microimplants exhibited different degrees of changes on surface characteristics and mechanical behavior, with more changes in RMIP. The reuse of microimplants for immediate relocation in the same patient may be acceptable; however, postponed relocation and allogeneic reuse of microimplants are not recommended in clinical practice.
