注浆加固顶升中隧道回沉现象的初步分析

针对注浆加固顶升工程中普遍存在的回沉现象 ,初步分析了其产生的原因 ,认为是粘土 -浆液的流变性所引起的 ,本文采用粘弹性反演分析方法对隧道的回沉量进行了计算和预测 ,并结合一实际工程对现场施工进行了预测和指导 ,取得了很好的效果。

粘弹性动态增量反演分析在软土隧道注浆加固顶升中的应用

针对注浆加固顶升工程中普遍存在的回沉现象 ,采用粘弹性动态增量反演分析的方法 ,对粘土—浆液的流变性进行了分析 ,并结合一实际工程 ,对现场施工进行了预测和指导 ,取得了很好的效果。

注浆加固工程中浆液固化前的流变性分析

本文根据注浆加固工程中经常出现的回沉现象,对固化前浆液的流变性进行了分析,总结了它的变化规律并据此对一实际工程的现场施工进行了预测和指导,取得较好的效果。

Recovery of Co and Li from spent lithium-ion batteries by combination method of acid leaching and chemical precipitation

Cathode material of spent lithium-ion batteries was refined to obtain high value-added cobalt and lithium products based on the chemical behaviors of metal in different oxidation states. The active substances separated from the cathode of spent lithium-ion batteries were dissolved in H2SO4 and H2O2 solution, and precipitated as CoC2O4·2H2O microparticles by addition of （NH4）2C2O4. After collection of the CoC2O4·2H2O product by filtration, the Li2CO3 precipitates were obtained by addition of Na2CO3 in the left filtrate. The experimental study shows that 96.3% of Co （mass fraction） and 87.5% of Li can be dissolved in the solution of 2 mol/L H2SO4 and 2.0% H2O2 （volume fraction）, and 94.7% of Co and 71.0% of Li can be recovered respectively in the form of CoC2O4·2H2O and Li2CO3.

Ge and Cu recovery from precipitating vitriol supernatant in zinc plant

A novel technology using Fe powder as reducing agent for Ge and Cu recovery from precipitating vitriol supernatant in Zn hydrometallurgical plant was investigated. The results show that reaction time, temperature, agitation speed, initial pH value of solution and the amount of reducing Fe have significant effects on recovering Ge and Cu, and the optimum process operating parameters are established as follows： time 120 min, initial pH value 1.5, the dosage of reducing Fe powder 4 g/L, agitation speed 600 r/min and temperature 80 °C. Under these experimental conditions, the recovery ratios of Ge and Cu from precipitating vitriol supernatant in Zn hydrometallurgical plant can reach 96% and 100%, respectively. The content of Ge in the reduced residue reaches up to 2.06% （mass fraction）, indicating that the separation and enrichment of Ge from the Zn sulfate solution is realized. The grade of Ge and Cu can reach up to 4.88% and 56.75%, respectively, when the reduced residue is further processed.

Separation and enrichment of elemental sulfur and mercury from hydrometallurgical zinc residue using sodium sulfide

The separation and enrichment of mercury and the recovery of elemental sulfur from flotation sulfur concentrate in zinc pressure leaching process were carried out by sodium sulfide leaching and carbon dioxide precipitating. The results show that the leaching rate of elemental sulfur is more than 98%, and 98.13% of mercury is enriched in the residue, under the optimized conditions of sodium sulfide concentration 1.5 mol/L, liquid/solid ratio 6：1 and leaching time 30 min at room temperature. In addition, the content of mercury is enriched 5.23 times that in the leaching residue. The elemental sulfur is precipitated from leaching solution under conditions of carbon dioxide flow rate 200 mL/min and blowing time 150 min, while solution is stirred adequately. The recovery efficiency of elemental sulfur reaches 97.67%, and the purity of elemental sulfur is 99.75%, meeting the requirements of industrial first-rate product standard according to the national standard of GB/T 2449-2006 （PRC）.

Recovery of high purity silicon from SoG crystalline silicon cutting slurry waste

The composition and size distribution of cutting waste were characterized. The Si-rich powders were obtained from the cutting waste using a physical sedimentation process, and then further purified by removing impurity using acid leaching. The effects of process parameters such as acid leaching time, temperature and the ratio of solid to liquid on the purification efficiency were investigated, and the parameters were optimized. Afterwards, the high-purity Si ingot was obtained by melting the Si-rich powders in vacuum furnace. Finally, the high purity Si with 99.96%Si, 1.1×10^-6 boron （B）, and 4.0×10^-6 phosphorus （P） were obtained. The results indicate that it is feasible to extract high-purity Si, and further produce SoG-Si from the cutting slurry waste.

Sedimentary system characteristics and depositional filling model of Upper Permian——Lower Triassic in South Yellow Sea Basin

In the South Yellow Sea Basin,Mesozoic–Paleozoic marine strata are generally well developed with large thickness,and no substantial breakthroughs have been made in hydrocarbon exploration.Through research,it is believed that the Upper Permian–Lower Triassic can be regarded as a long-term base-level cycle.Based on drilling data,characteristics of the lithology–electric property combination cyclicity,and the special lithology,the long-term base-level cycle was divided into five medium-term base-level cycles(MC1–MC5).On this basis,the Permian–Triassic sedimentary systems and their filling model were analyzed in accordance with the change of base-level cycle and transition of sedimentary environment,as well as characteristics of the drilling sedimentary facies and seismic facies.The results show that there were six sedimentary systems(fluvial,delta,tidal flat,open platform,restricted platform,and continental shelf)developed in the Upper Permian–Lower Triassic,the sedimentary systems were distributed such that the water was deep in the northwest and shallow in the southeast,and there were two base-level cycle filling models(a relatively stable tidal flat facies and a rapidly transgressive continental shelf facies to stable platform facies)developed in the Upper Permian–Lower Triassic.These models can provide a basis for evaluation of the Mesozoic–Paleozoic hydrocarbon geology in the South Yellow Sea Basin.

Settlement characteristics of bridge approach embankment based on scale model test

In order to analyze the effects of backfill materials, geometries and slab setting on the settlement of bridge approach embankment, scale model was built based on the structural characteristics of bridge approach embankment, and scale model tests were carried out under different conditions. The results show that when graded gravels were selected as the backfill materials, the effect of setting approach slab to reduce the differential settlement is more prominent. When lime soils were selected as the backfill material, approach slab can moderate the longitudinal settlement slope. When using different backfill materials, the ultimate settlement of the positive trapezoidal backfill geometries is less than that of the inverted trapezoid, and the backfill geometries have little effect on the settlement slope.

Surface mining subsidence control based on grouting-recovery ratio theory

From an analysis of the relationships of grouting coefficients under the conditions of grouting reducing subsidence, it is concluded that the reducing subsidence rate is in direct proportion to the grouting-recovery ratio, and its proportional coefficient depends on the coefficient of reducing subsidence and collapsing coefficient.The coefficient for reducing subsidence volume φ=ΔV/V_(ash) is related to overburden lithology.The coefficient for reducing subsidence volume φ is always larger than 1.This improves the reducing subsidence rate,the grouting-recovery ratio, and the coefficient for reducing subsidence volume, which can maximize the control of surface subsidence.

Recovery of copper sulfate after treating As-containing wastewater by precipitation method

The solid sodium hydroxide neutralized acidic As-containing wastewater till pH value was 6. Green copper arsenite was prepared after copper sulfate was added into the neutralized wastewater when the molar ratio of Cu to As was 2：1 and pH value of the neutralized wastewater was adjusted to 8.0 by sodium hydroxide. The arsenious acid solution and red residue were produced after copper arsenite mixed with water according to the ratio of liquid to solid of 4：1 and copper arsenite was reduced by SO2 at 60℃ for 1 h. The white powder was gained after the arsenious acid solution was evaporated and cooled. Copper sulfate solution was obtained after the red residue was leached by H2SO4 solution under the action of air. The results show that red residue is Cu3（SO3）2·2H2O and the white powder is As2O3. The leaching rate of Cu reaches 99.00% when the leaching time is 1.5 h, molar ratio of H2SO4 to Cu is 1.70, H2SO4 concentration is 24% and the leaching temperature is 80 ℃. The direct recovery rate of copper sulfate is 79.11% and the content of CuSOa·5H2O is up to 98.33% in the product after evaporating and cooling the copper sulfate solution.

Electrochemical recycling of Pd and Ag from simulated high-level liquid waste

For the recycling of Pd and Ag from high-level liquid waste(HLLW), the electrochemical behaviors of Pd and Ag in the simulated HNO_(3) solutions were investigated by cyclic voltammetry and potentiostatic deposition.Scanning electron microscopy(SEM) and X-ray diffraction(XRD) were used to-observe the deposits morphology and to evaluate their composition. The results indicate that the formation of NO_(2)^(-)electrodeposited. When Pd and Ag are electrodeposited together, more metals are gained in the same time, and the deposited Ag does not dissolve in this situation. The metals are electrodeposited completely at the potentials from -0.4 to -0.6 V(vs MSE) and the deposits contai-n Ag and PdHx. The electrodeposition of Pd can boost h-ydrogen evolution,and then the reaction between H;and NO_(2)^(-)is sped up, thereby lowering the concentration of NO_(2)^(-)and inhibiting the dissolution of Ag.

Astronomical forcing of sedimentary cycles of Late Eocene Liushagang Formation in the Bailian Sag, Fushan Depression, Beibuwan Basin, South China Sea

Sediments in the Liushagang Formation of Late Eocene form a group of key hydrocarbon play fairways in the Beibuwan Basin,South China Sea.As an important reservoir-forming combination,the Liushagang Formation consists of deltaic siliciclastic and show clear sedimentary cyclicity.According to paleontology research and stratigraphic correlation,the boundary between Liushagang Formation(Els)and Weizhou Formation(Ewz)is regarded as the Eocene-Oligocene boundary.The oxygen isotope dating for well cores from the top of the first Member of Liushagang Formation(Els1)and the bottom of the third Member of Weizhou Formation(Ewz3)give an isochron age of 35.2 Ma.Here,we use GR logging data as a paleoenvironmental proxy to conduct a detailed cyclostratigraphic study of the Els1 in the Bailian Sag,Fushan Depression.Power spectra,evolutionary fast Fourier transformation and wavelet analysis all reveal significant sedimentary cycles in Els1.The ratios of cycle wavelengths in these stratigraphic units are 21?5?2.8?1.2?1,and are interpreted as Milankovitch cycles of 400 ka and 96 ka eccentricity,52 ka obliquity,22ka and 19 ka precession cycles,respectively.An astronomical time scale is established by tuning filtered 96 ka eccentricity cycles to a target curve of Well L2 in the Bailian Sag.Based on regional stratigraphic framework,combined with seismic,cores and logging data,the HST of the first member of the Liushagang Formation(Els1)delta in Well L2 was divided into six parasequence sets named Ps1-Ps6.According to the spectrum analysis by Simple Lomb periodogram from PAST program packages,the sediment accumulation rate of each parasequence sets first increased and then decreased as time went by.The sediment accumulation rate of Ps4 reached the maximum(0.127 m/ka)during the most prosperous period of delta prograding.Finally,the duration of each period of parasequence sets and more accurate geological age were calculated on the basis of sediment accumulation rate.The ages of each depth are precisely estimated and provide new constraints on the Late Eocene.

Treatment of submerged hollow fiber ultrafiltration membrane for reuse of sludge water

To lower the costs of wastewater treatment, the submerged hollow fiber ultrafiltration membrane was employed to reuse the filter backwash water and settling tank sludge water. Experimental study indicates that the submerged hollow fiber uhrafihration membrane can condense the concentration of sludge from 0. 1% -0. 3% to 2.5%. At 20 ℃, the system can operate continuously for 80 clays with daily online backwashing with chemical additions only once, and the membrane flux can be recovered up to 97% by using NaClO and NaOH as chemical additions. The results show that the membrane flux is mainly affected by temperature,and has a positive lin- ear relation to temperature with a slope of 0. 368. After treated by submerged hollow fiber uhrafihration membrane, the effluent can reach the National Standard for Drinking Water（ GB5749 -85 ） , especially for the sludge water from sedimentation tanks and the backwashing Water from filters in water supply plants.

Structural effect of a soft-hard backfill wall in a gob-side roadway

The stability of a backfill wall is critical to implement gob-side entry driving technology in which a small coal pillar is substituted by a waste backfill wall. Based on features of surrounding rock structures in the backfill wall, we propose a mechanical model on the structural effect of a soft-hard backfill wall using theory analysis, physical experiments and a numerical simulation. The results show thatChe deformation of the structure of the soft-hard backfill wall is coordinated with the roof and floor. The soft structure on the top of the backfill wall can absorb the energy in the roof by its large deformation and adapt to the given deformation caused by the rotation and subsidence of a key rock block. The hard structure at the bottom of the backfill wall can absorb the strong supporting resistance from the top surrounding rock. The soft structure on the top protecting the hard bottom structure by its large deformation contributes to the stability of the entire backfill wall. An application indicated that the stress in the backfill wall effec- tively decreased and its deformation was significantly reduced after the top coal remained. This ensured the stability of the backfill wall.

Settlement Prediction for Buildings Surrounding Foundation Pits Based on a Stationary Auto-regression Model

To ensure the safety of buildings surrounding foundation pits, a study was made on a settlement monitoring and trend prediction method. A statistical testing method for analyzing the stability of a settlement monitoring datum has been discussed. According to a comprehensive survey, data of 16 stages at operating control point, were verified by a standard t test to determine the stability of the operating control point. A stationary auto-regression model, AR(p), used for the observation point settlement prediction has been investigated. Given the 16 stages of the settlement data at an observation point, the applicability of this model was analyzed. Settlement of last four stages was predicted using the stationary auto-regression model AR (1); the maximum difference between predicted and measured values was 0.6 mm, indicating good prediction results of the model. Hence, this model can be applied to settlement predictions for buildings surrounding foundation pits.

A method to calculate displacement factors using SVM

In order to improve the precision of mining subsidence prediction, a mathematical model using Support Vector Machine （SVM） was established to calculate the displacement factor. The study is based on a comprehensive analysis of factors affecting the displacement factor, such as mechanical properties of the cover rock, the ratio of mining depth to seam thickness, dip angle of the coal seam and the thickness of loose layer. Data of 63 typical observation stations were used as a training and testing sample set. A SVM regression model of the displacement factor and the factors affecting it was established with a kernel function, an insensitive loss factor and a properly selected penalty factor. Given an accurate calculation algorithm for testing and analysis, the results show that an SVM regression model can calcu- late displacement factor precisely and reliable precision can be obtained which meets engineering requirements. The experimental results show that the method to calculation of the displacement factor, based on the SVM method, is feasible. The many factors affecting the displacement factor can be consid- ered with this method. The research provides an efficient and accurate approach for the calculation of displacement in mining subsidence orediction.

Separation and recovery of copper in Cu-As-bearing copper electrorefining black slime by oxidation acid leaching and sulfide precipitation

A new hydrometallurgical route for separation and recovery of Cu from Cu-As-bearing copper electrorefining black slime was developed. The proposed process comprised oxidation acid leaching of Cu-As-bearing slime and selective sulfide precipitation of Cu from the leachate. The effects of various process parameters on the leaching and precipitation of Cu and As were investigated. At the first stage, Cu extraction of 95.2% and As extraction of 97.6% were obtained at 80 ℃ after 4 h with initial H2 SO4 concentration of 1.0 mol/L and liquid-to-solid ratio of 10 mL/g. In addition, the leaching kinetics of Cu and As was successfully reproduced by the Avrami model, and the apparent activation energies were found to be 33.6 and 35.1 kJ/mol for the Cu and As leaching reaction, respectively, suggesting a combination of chemical reaction and diffusion control. During the selective sulfide precipitation, about 99.4% Cu was recovered as CuS, while only 0.1% As was precipitated under the optimal conditions using sulfide-to-copper ratio of 2.4:1, time of 1.5 h and temperature of 25 ℃.

Flotation tree analysis for recovery of sillimanite from red sediments

In this paper an attempt is made to recover sillimanite by flotation tree analysis process and conventional flotation process from non magnetic fraction of red sediments.The experimental results of both the processes are presented.The data reveal that the deslimed sample contains 33.2%(by weight) total heavy minerals and out of which the sillimanite mineral content is 3.6%(by weight).It is observed that flotation tree analysis needs 10 cells to get five output products and where as conventional flotation process needs 15 cells to recover similar grade of five output products.Thus,flotation tree analysis is not only economic process but also efficient process(to say efficient process,the tree analysis product should be higher grade).