The utilization of arsenic-containing gold dressing tailings is an urgent issue faced by gold production companies worldwide.The thermodynamic analysis results indicate that ferrous arsenate(FeAsO_(4)),pyrite(FeS_(2))...The utilization of arsenic-containing gold dressing tailings is an urgent issue faced by gold production companies worldwide.The thermodynamic analysis results indicate that ferrous arsenate(FeAsO_(4)),pyrite(FeS_(2))and sodium cyanide(NaCN)in the arsenic-containing gold metallurgical tailings can be effectively removed using straight grate process,and the removal of pyrite and sodium cyanide is basically completed during the preheating stage,while the removal of ferrous arsenate requires the roasting stage.The pellets undergo a transformation from magnetite to hematite during the preheating process,and are solidified through micro-crystalline bonding and high-temperature recrystallization of hematite(Fe_(2)O_(3))during the roasting process.Ultimately,pellets with removal rates of 80.77% for arsenic,88.78% for sulfur,and 99.88% for cyanide are obtained,as well as the iron content is 61.1% and the compressive strength is 3071 N,meeting the requirements for blast furnace burden.This study provides an industrially feasible method for treating arsenic-containing gold smelting tailings,benefiting gold production enterprises.展开更多
Based on the monitoring and discovery service 4 (MDS4) model, a monitoring model for a data grid which supports reliable storage and intrusion tolerance is designed. The load characteristics and indicators of comput...Based on the monitoring and discovery service 4 (MDS4) model, a monitoring model for a data grid which supports reliable storage and intrusion tolerance is designed. The load characteristics and indicators of computing resources in the monitoring model are analyzed. Then, a time-series autoregressive prediction model is devised. And an autoregressive support vector regression( ARSVR) monitoring method is put forward to predict the node load of the data grid. Finally, a model for historical observations sequences is set up using the autoregressive (AR) model and the model order is determined. The support vector regression(SVR) model is trained using historical data and the regression function is obtained. Simulation results show that the ARSVR method can effectively predict the node load.展开更多
In order to solve the citrus peel resource waste problem protopectinase-overproducing strain CD-01 for pectin production and minimize the drawbacks of chemical extraction of pectin, a was isolated from a pit soil dump...In order to solve the citrus peel resource waste problem protopectinase-overproducing strain CD-01 for pectin production and minimize the drawbacks of chemical extraction of pectin, a was isolated from a pit soil dumped with perished orange in Changde City, Hunan Province of China. The strain CD-01 had the same morphology and 28S rRNA gene sequence (FJ184995) as that of Aspergillus niger (ATCC 64028). It was thus identified and named as Aspergillus niger CD-01. The fermentation condition was optimized based on L9(34) orthogonal experimental design and the variances analyses. The results show that the optimal condition for producing pectin is as follows: time 36 h, temperature 35 ℃, pH 5, and urea as the nitrogen source. Under this condition, the pectin yield can reach up to 24.5%. This shows a great potential of Aspergillus niger CD-01 in pectin extraction from citrus.展开更多
China’s coal,petroleum,natural gas and electric power industries are in different stages.Coal has a falling share in China’s energy mix,and clean coal is on the rise.While China’s petroleum production stagnates,the...China’s coal,petroleum,natural gas and electric power industries are in different stages.Coal has a falling share in China’s energy mix,and clean coal is on the rise.While China’s petroleum production stagnates,the natural gas and electric power industries are developing rapidly.Amid the changing energy industries,China’s energy regulatory system has evolved from vertical to integrated management,and energy administrative and supervisory functions have become integrated over time.These changes have played different roles during specific periods,either enhancing or hampering a highefficient development of China’s energy industry.Over the past seven decades,China’s energy industry has acquired important capabilities to support the nation’s social and economic development.With industrial prowess in clean energy and energy efficiency,China has become a leader in global low-carbon and clean energy transition.In the future,China'should attach great importance to the adverse short-term effects of energy transition on its energy security.By deepening energy institutional reform,China'should enhance its energy security through energy transition.展开更多
In this study,a roasting enhanced flotation process was proposed to recover LiMn_(2)O_(4) and grapite from waste lithium-ion batteries(LIBs).The effects of roasting temperature and time on the surface modification was...In this study,a roasting enhanced flotation process was proposed to recover LiMn_(2)O_(4) and grapite from waste lithium-ion batteries(LIBs).The effects of roasting temperature and time on the surface modification was investigated,and a series of analytical technologies were used to reveal process mechanism.The results indicate that LiMn_(2)O_(4) can be effectively separated from graphite via flotation after the roasting.The flotation grade of LiMn_(2)O_(4) was significantly increased from 63.10%to 91.36%after roasting at 550℃for 2 h.The TG-DTG analysis demonstrates that the difficulty in flotation separation of LiMn_(2)O_(4) from graphite is caused by the organic binder and electrolytes coating on their surfaces.The XRD,SEM,XPS,and contact angle analyses confirm that the organic films on the surfaces of those materials can be effectively removed by roasting,after which the wettability of LiMn_(2)O_(4) is regained and thus the surface wettability difference between the cathode and anode materials is increased significantly.The closed-circuit flotation test indicates that a LiMn_(2)O_(4) sample with high grade of 99.81%is obtained,while the recovery of LiMn_(2)O_(4) is as high as 99.40%.This study provides an economical and eco-friendly way to recycling waste LIBs.展开更多
Recycling useful materials such as Ag, Al, Sn, Cu and Si from waste silicon solar cell chips is a sustainable project to slow down the ever-growing amount of waste crystalline-silicon photovoltaic panels. However, the...Recycling useful materials such as Ag, Al, Sn, Cu and Si from waste silicon solar cell chips is a sustainable project to slow down the ever-growing amount of waste crystalline-silicon photovoltaic panels. However, the recovery cost of the above-mentioned materials from silicon chips via acid-alkaline treatments outweights the gain economically.Herein, we propose a new proof-of-concept to fabricate Si-based anodes with waste silicon chips as raw materials.Nanoparticles from waste silicon chips were prepared with the high-energy ball milling followed by introducing carbon nanotubes and N-doped carbon into the nanoparticles, which amplifies the electrochemical properties. It is explored that Al and Ag elements influenced electrochemical performance respectively. The results showed that the Al metal in the composite possesses an adverse impact on the electrochemical performance. After removing Al, the composite was confirmed to possess a pronounced durable cycling property due to the presence of Ag, resulting in significantly more superior property than the composite having both Al and Ag removed.展开更多
It is an emerging realistic problem on how to promote a high level of technology in the coal industry, find new upgrading powers and create new competitive advantages, which are also the core problems to efficient tra...It is an emerging realistic problem on how to promote a high level of technology in the coal industry, find new upgrading powers and create new competitive advantages, which are also the core problems to efficient transformation pattern of economic growth for coal industry in the ''twelfth five-year'' period, involving the key to China's energy supply and energy security. Through field surveys and inductive analyses, analyzing of the content of upgrading the coal industry as an entry point, this paper analyzes the sustainable development mechanisms for the coal industry from the aspects of work force, power, methods, goals, and so on; and puts forward corresponding developmental modes according to the mechanisms which can improve resource recovery and mineral resources utilization rates by putting them into practice.展开更多
Energy saving has been an important concept in modern industry especially to the countries and regions with energy shortage such as China and Japan. Utilization of Coal-Water Slurry (CWS) can improve the burning eff...Energy saving has been an important concept in modern industry especially to the countries and regions with energy shortage such as China and Japan. Utilization of Coal-Water Slurry (CWS) can improve the burning efficiency of coal and reduce the pollutions of soot, sulfide and the nitride by burning lump coal directly. The CWS is a promising energy saving technique and the effectual substitute of oil. The study on the preparation and application of the CWS has made progresses in many aspects. The present paper studied the basal problems for applying the CWS on the rotary kilns during the calcining-dolomite process in the magnesium factory, summarized the key points for the application process of the CWS and gave the corresponding solutions.展开更多
In this paper we address the topic of energy and water optimization in the production of bioethanol from corn and switchgrass. We show that in order for these manufacturing processes to be attractive,there is a need t...In this paper we address the topic of energy and water optimization in the production of bioethanol from corn and switchgrass. We show that in order for these manufacturing processes to be attractive,there is a need to go beyond traditional heat integration and water recycling techniques. Thus,we propose a strategy based on mathe-matical programming techniques to model and optimize the structure of the processes,and perform heat integration including the use of multi-effect distillation columns and integrated water networks to show that the energy effi-ciency and water consumption in bioethanol plants can be significantly improved. Specifically,under some circum-stances energy can even be produced and the water consumption can be reduced below the values required for the production of gasoline.展开更多
This paper shares experiences of the southern and eastern Africa rainwater network on rainwater harvesting.It also shares the lessons drawn from policy research awareness creation and networking building of national n...This paper shares experiences of the southern and eastern Africa rainwater network on rainwater harvesting.It also shares the lessons drawn from policy research awareness creation and networking building of national networks and assessment of promising water harvesting techniques in the Sub-Saharan Africa.The concerted promotional effort of the southern and eastern Africa rainwater network has resulted in the general acceptance of rainwater harvesting as a viable option for boosting domestic water supply agricultural production and environmental sustainability.To date twelve nationally registered rainwater harvesting associations have been established which are providing leadership and capacity building in rainwater harvesting.Governments and donors are also aligning their policies towards providing increased financial institutional and technical support for upscaling rainwater-harvesting techniques. This paper concludes that diligent land and water management is necessary for yielding the highest benefits from rainwater.In addition to enabling policies and institutions there must be ample budgetary support to increase adoption of the technology.展开更多
Predicting heartbeat message arrival time is crucial for the quality of failure detection service over intemet. However, intemet dynamic characteristics make it very difficult to understand message behavior and accura...Predicting heartbeat message arrival time is crucial for the quality of failure detection service over intemet. However, intemet dynamic characteristics make it very difficult to understand message behavior and accurately predict heartbeat arrival time. To solve this problem, a novel black-box model is proposed to predict the next heartbeat arrival time. Heartbeat arrival time is modeled as auto-regressive process, heartbeat sending time is modeled as exogenous variable, the model' s coefficients are estimated based on the sliding window of observations and this result is used to predict the next heartbeat arrival time. Simulation shows that this adaptive auto-regressive exogenous (ARX) model can accurately capture heartbeat arrival dynamics and minimize prediction error in different network environments.展开更多
An electrochemical study on the redox behavior of indium in the eutectic LiCl-KCl system at 450 ℃ was carried out with the transient techniques of cyclic voltammetry and chronopotentiometry on an inert molybdenum ele...An electrochemical study on the redox behavior of indium in the eutectic LiCl-KCl system at 450 ℃ was carried out with the transient techniques of cyclic voltammetry and chronopotentiometry on an inert molybdenum electrode. The reduction of In(Ⅲ) was found to be a two-step process involving In(Ⅲ)/In(Ⅰ) and In(Ⅰ)/In couples at the potentials of about-0.4 and-0.8 V versus Ag/AgCl, respectively. The redox mechanism was further confirmed by the theoretical evaluation of the number of transferred electrons based on cyclic voltammetry and characterizations of the precipitates generated by the potentiostatic electrolysis. The diffusion coefficients of indium ions in the eutectic LiCl-KCl melt at 450 ℃ were estimated by cyclic voltammetry and chronopotentiometry. The results obtained through the two methods are in fair agreement, delivering an average diffusion coefficient of approximately 1.8×10^(-5)cm^(2)/s for In(Ⅲ), and 1.4×10^(-4)cm^(2)/s for In(Ⅰ).展开更多
Potentials range is determined in which the cobalt-tungsten alloy phase selectively dissolved in solutions of phosphoric acid to form soluble compounds of these metals, while the tungsten carbide phase remains in the ...Potentials range is determined in which the cobalt-tungsten alloy phase selectively dissolved in solutions of phosphoric acid to form soluble compounds of these metals, while the tungsten carbide phase remains in the precipitate. It shows that tungsten ores and concentrates are decomposed at 1,050℃-1,100℃ in sodium chloride-sodium metasilicate melts to form two immiscible phases, namely, halide-tungstate, containing 96% to 99% of tungsten, and silicate, containing 90% of the rest ore components.展开更多
基金Project(52274343)supported by the National Natural Science Foundation of ChinaProjects(2023YFC3903900,2023YFC3903904)supported by the National Key R&D Program of China。
文摘The utilization of arsenic-containing gold dressing tailings is an urgent issue faced by gold production companies worldwide.The thermodynamic analysis results indicate that ferrous arsenate(FeAsO_(4)),pyrite(FeS_(2))and sodium cyanide(NaCN)in the arsenic-containing gold metallurgical tailings can be effectively removed using straight grate process,and the removal of pyrite and sodium cyanide is basically completed during the preheating stage,while the removal of ferrous arsenate requires the roasting stage.The pellets undergo a transformation from magnetite to hematite during the preheating process,and are solidified through micro-crystalline bonding and high-temperature recrystallization of hematite(Fe_(2)O_(3))during the roasting process.Ultimately,pellets with removal rates of 80.77% for arsenic,88.78% for sulfur,and 99.88% for cyanide are obtained,as well as the iron content is 61.1% and the compressive strength is 3071 N,meeting the requirements for blast furnace burden.This study provides an industrially feasible method for treating arsenic-containing gold smelting tailings,benefiting gold production enterprises.
基金The National High Technology Research and Development Program of China (863 Program) (No2007AA01Z404)
文摘Based on the monitoring and discovery service 4 (MDS4) model, a monitoring model for a data grid which supports reliable storage and intrusion tolerance is designed. The load characteristics and indicators of computing resources in the monitoring model are analyzed. Then, a time-series autoregressive prediction model is devised. And an autoregressive support vector regression( ARSVR) monitoring method is put forward to predict the node load of the data grid. Finally, a model for historical observations sequences is set up using the autoregressive (AR) model and the model order is determined. The support vector regression(SVR) model is trained using historical data and the regression function is obtained. Simulation results show that the ARSVR method can effectively predict the node load.
基金Projects(50621063, 50674101) supported by the National Natural Science Foundation of China
文摘In order to solve the citrus peel resource waste problem protopectinase-overproducing strain CD-01 for pectin production and minimize the drawbacks of chemical extraction of pectin, a was isolated from a pit soil dumped with perished orange in Changde City, Hunan Province of China. The strain CD-01 had the same morphology and 28S rRNA gene sequence (FJ184995) as that of Aspergillus niger (ATCC 64028). It was thus identified and named as Aspergillus niger CD-01. The fermentation condition was optimized based on L9(34) orthogonal experimental design and the variances analyses. The results show that the optimal condition for producing pectin is as follows: time 36 h, temperature 35 ℃, pH 5, and urea as the nitrogen source. Under this condition, the pectin yield can reach up to 24.5%. This shows a great potential of Aspergillus niger CD-01 in pectin extraction from citrus.
文摘China’s coal,petroleum,natural gas and electric power industries are in different stages.Coal has a falling share in China’s energy mix,and clean coal is on the rise.While China’s petroleum production stagnates,the natural gas and electric power industries are developing rapidly.Amid the changing energy industries,China’s energy regulatory system has evolved from vertical to integrated management,and energy administrative and supervisory functions have become integrated over time.These changes have played different roles during specific periods,either enhancing or hampering a highefficient development of China’s energy industry.Over the past seven decades,China’s energy industry has acquired important capabilities to support the nation’s social and economic development.With industrial prowess in clean energy and energy efficiency,China has become a leader in global low-carbon and clean energy transition.In the future,China'should attach great importance to the adverse short-term effects of energy transition on its energy security.By deepening energy institutional reform,China'should enhance its energy security through energy transition.
基金Project(2021JJ20062) supported by the Natural Science Foundation of Hunan Province,ChinaProject(2019XK2304) supported by Landmark Innovation Demonstration Project of Hunan Province,China+3 种基金Project(2022GK4058) supported by High-tech Industry Science and Technology Innovation Leading Project of Hunan Province,ChinaProject(2020CX038) supported by the Innovation Driven Project of Central South University,ChinaProject(2019YFC1907301) supported by the National Key R&D Program of ChinaProject(202006375018) supported by the China Scholarship Council。
文摘In this study,a roasting enhanced flotation process was proposed to recover LiMn_(2)O_(4) and grapite from waste lithium-ion batteries(LIBs).The effects of roasting temperature and time on the surface modification was investigated,and a series of analytical technologies were used to reveal process mechanism.The results indicate that LiMn_(2)O_(4) can be effectively separated from graphite via flotation after the roasting.The flotation grade of LiMn_(2)O_(4) was significantly increased from 63.10%to 91.36%after roasting at 550℃for 2 h.The TG-DTG analysis demonstrates that the difficulty in flotation separation of LiMn_(2)O_(4) from graphite is caused by the organic binder and electrolytes coating on their surfaces.The XRD,SEM,XPS,and contact angle analyses confirm that the organic films on the surfaces of those materials can be effectively removed by roasting,after which the wettability of LiMn_(2)O_(4) is regained and thus the surface wettability difference between the cathode and anode materials is increased significantly.The closed-circuit flotation test indicates that a LiMn_(2)O_(4) sample with high grade of 99.81%is obtained,while the recovery of LiMn_(2)O_(4) is as high as 99.40%.This study provides an economical and eco-friendly way to recycling waste LIBs.
基金Project(51774343) supported by the National Natural Science Foundation of China。
文摘Recycling useful materials such as Ag, Al, Sn, Cu and Si from waste silicon solar cell chips is a sustainable project to slow down the ever-growing amount of waste crystalline-silicon photovoltaic panels. However, the recovery cost of the above-mentioned materials from silicon chips via acid-alkaline treatments outweights the gain economically.Herein, we propose a new proof-of-concept to fabricate Si-based anodes with waste silicon chips as raw materials.Nanoparticles from waste silicon chips were prepared with the high-energy ball milling followed by introducing carbon nanotubes and N-doped carbon into the nanoparticles, which amplifies the electrochemical properties. It is explored that Al and Ag elements influenced electrochemical performance respectively. The results showed that the Al metal in the composite possesses an adverse impact on the electrochemical performance. After removing Al, the composite was confirmed to possess a pronounced durable cycling property due to the presence of Ag, resulting in significantly more superior property than the composite having both Al and Ag removed.
文摘It is an emerging realistic problem on how to promote a high level of technology in the coal industry, find new upgrading powers and create new competitive advantages, which are also the core problems to efficient transformation pattern of economic growth for coal industry in the ''twelfth five-year'' period, involving the key to China's energy supply and energy security. Through field surveys and inductive analyses, analyzing of the content of upgrading the coal industry as an entry point, this paper analyzes the sustainable development mechanisms for the coal industry from the aspects of work force, power, methods, goals, and so on; and puts forward corresponding developmental modes according to the mechanisms which can improve resource recovery and mineral resources utilization rates by putting them into practice.
文摘Energy saving has been an important concept in modern industry especially to the countries and regions with energy shortage such as China and Japan. Utilization of Coal-Water Slurry (CWS) can improve the burning efficiency of coal and reduce the pollutions of soot, sulfide and the nitride by burning lump coal directly. The CWS is a promising energy saving technique and the effectual substitute of oil. The study on the preparation and application of the CWS has made progresses in many aspects. The present paper studied the basal problems for applying the CWS on the rotary kilns during the calcining-dolomite process in the magnesium factory, summarized the key points for the application process of the CWS and gave the corresponding solutions.
基金the Center for Advanced Process Decision-making at Carnegie Mellon University and NSF Grant CBET096654
文摘In this paper we address the topic of energy and water optimization in the production of bioethanol from corn and switchgrass. We show that in order for these manufacturing processes to be attractive,there is a need to go beyond traditional heat integration and water recycling techniques. Thus,we propose a strategy based on mathe-matical programming techniques to model and optimize the structure of the processes,and perform heat integration including the use of multi-effect distillation columns and integrated water networks to show that the energy effi-ciency and water consumption in bioethanol plants can be significantly improved. Specifically,under some circum-stances energy can even be produced and the water consumption can be reduced below the values required for the production of gasoline.
文摘This paper shares experiences of the southern and eastern Africa rainwater network on rainwater harvesting.It also shares the lessons drawn from policy research awareness creation and networking building of national networks and assessment of promising water harvesting techniques in the Sub-Saharan Africa.The concerted promotional effort of the southern and eastern Africa rainwater network has resulted in the general acceptance of rainwater harvesting as a viable option for boosting domestic water supply agricultural production and environmental sustainability.To date twelve nationally registered rainwater harvesting associations have been established which are providing leadership and capacity building in rainwater harvesting.Governments and donors are also aligning their policies towards providing increased financial institutional and technical support for upscaling rainwater-harvesting techniques. This paper concludes that diligent land and water management is necessary for yielding the highest benefits from rainwater.In addition to enabling policies and institutions there must be ample budgetary support to increase adoption of the technology.
基金the National Basic Research Program of China(No.2003CB314806)China Next Generation Intemet Project(CNGI-04-6-2T)
文摘Predicting heartbeat message arrival time is crucial for the quality of failure detection service over intemet. However, intemet dynamic characteristics make it very difficult to understand message behavior and accurately predict heartbeat arrival time. To solve this problem, a novel black-box model is proposed to predict the next heartbeat arrival time. Heartbeat arrival time is modeled as auto-regressive process, heartbeat sending time is modeled as exogenous variable, the model' s coefficients are estimated based on the sliding window of observations and this result is used to predict the next heartbeat arrival time. Simulation shows that this adaptive auto-regressive exogenous (ARX) model can accurately capture heartbeat arrival dynamics and minimize prediction error in different network environments.
基金the National Natural Science Foundation of China(Nos.51904003,U1703130,51704011)the China Postdoctoral Science Foundation(No.2019M651466)the Foundation of Anhui Province Key Laboratory of Metallurgical Engineering&Resources Recycling of China(Nos.SKF18-01,SKF19-05).
文摘An electrochemical study on the redox behavior of indium in the eutectic LiCl-KCl system at 450 ℃ was carried out with the transient techniques of cyclic voltammetry and chronopotentiometry on an inert molybdenum electrode. The reduction of In(Ⅲ) was found to be a two-step process involving In(Ⅲ)/In(Ⅰ) and In(Ⅰ)/In couples at the potentials of about-0.4 and-0.8 V versus Ag/AgCl, respectively. The redox mechanism was further confirmed by the theoretical evaluation of the number of transferred electrons based on cyclic voltammetry and characterizations of the precipitates generated by the potentiostatic electrolysis. The diffusion coefficients of indium ions in the eutectic LiCl-KCl melt at 450 ℃ were estimated by cyclic voltammetry and chronopotentiometry. The results obtained through the two methods are in fair agreement, delivering an average diffusion coefficient of approximately 1.8×10^(-5)cm^(2)/s for In(Ⅲ), and 1.4×10^(-4)cm^(2)/s for In(Ⅰ).
文摘Potentials range is determined in which the cobalt-tungsten alloy phase selectively dissolved in solutions of phosphoric acid to form soluble compounds of these metals, while the tungsten carbide phase remains in the precipitate. It shows that tungsten ores and concentrates are decomposed at 1,050℃-1,100℃ in sodium chloride-sodium metasilicate melts to form two immiscible phases, namely, halide-tungstate, containing 96% to 99% of tungsten, and silicate, containing 90% of the rest ore components.