By the directional solidification of metal-gas eutectic method(GASAR),porous Cu-Mn alloy with oriented pores was fabricated successfully.The variation of pore structure was studied by experiments.The results show th...By the directional solidification of metal-gas eutectic method(GASAR),porous Cu-Mn alloy with oriented pores was fabricated successfully.The variation of pore structure was studied by experiments.The results show that the pore structure is primarily dependent on the solidification mode(planar,columnar cellular,columnar dendritic,equiaxed dendritic),which is controlled by the solidification process.By numerical simulation,it is noted that along with solidification,the solidification mode of the alloy transforms from cellular to columnar dendritic and finally to equiaxed dendritic.Through increasing melt temperature and mold preheating,the range of equiaxed dendrite could be decreased,which helps to extend the region of oriented pore structure.展开更多
Based on the solid-gas eutectic unidirectional solidification technique and the principle of unidirectional solidification of single-phase alloy, a new method for evaluating the diffusion coefficient of hydrogen in li...Based on the solid-gas eutectic unidirectional solidification technique and the principle of unidirectional solidification of single-phase alloy, a new method for evaluating the diffusion coefficient of hydrogen in liquid metals was proposed. Taking Cu-H2 system for example, the influences of argon partial pressure and superheat degree of melt on the diffusion coefficient of hydrogen in liquid metal were studied and the predicted values were similar to each other. The obtained temperature-dependent equation for diffusion coefficient of hydrogen in liquid copper is comparable with experimental data in literature, which validates the effectiveness of this method. The temperature-dependent equations for diffusion coefficient of hydrogen in liquid Mg, Si and Cu-34.6%Mn alloy were also evaluated by this method, along with the values at the melting point of each metal and alloy.展开更多
基金Project(U0837603)supported by the NSFC-Yunnan Joint Foundation of ChinaProject(2092017)supported by the Natural Science Foundation of Beijing,China
文摘By the directional solidification of metal-gas eutectic method(GASAR),porous Cu-Mn alloy with oriented pores was fabricated successfully.The variation of pore structure was studied by experiments.The results show that the pore structure is primarily dependent on the solidification mode(planar,columnar cellular,columnar dendritic,equiaxed dendritic),which is controlled by the solidification process.By numerical simulation,it is noted that along with solidification,the solidification mode of the alloy transforms from cellular to columnar dendritic and finally to equiaxed dendritic.Through increasing melt temperature and mold preheating,the range of equiaxed dendrite could be decreased,which helps to extend the region of oriented pore structure.
基金Project(51271096)supported by the National Natural Science Foundation of ChinaProject(NCET-12-0310)supported by Program for New Century Excellent Talents in University,China
文摘Based on the solid-gas eutectic unidirectional solidification technique and the principle of unidirectional solidification of single-phase alloy, a new method for evaluating the diffusion coefficient of hydrogen in liquid metals was proposed. Taking Cu-H2 system for example, the influences of argon partial pressure and superheat degree of melt on the diffusion coefficient of hydrogen in liquid metal were studied and the predicted values were similar to each other. The obtained temperature-dependent equation for diffusion coefficient of hydrogen in liquid copper is comparable with experimental data in literature, which validates the effectiveness of this method. The temperature-dependent equations for diffusion coefficient of hydrogen in liquid Mg, Si and Cu-34.6%Mn alloy were also evaluated by this method, along with the values at the melting point of each metal and alloy.