The conventional Ni cermet anode suffers from severe carbon deposition and sulfur poisoning when fossil fuels are used. Alternative anode materials are desired for high performance hydrocarbon fuel solid oxide fuel ce...The conventional Ni cermet anode suffers from severe carbon deposition and sulfur poisoning when fossil fuels are used. Alternative anode materials are desired for high performance hydrocarbon fuel solid oxide fuel cells （SOFCs）. We report the rational design of a very active Ni doped La0.6Sr0.4FeO3‐δ（LSFN） electrode for hydrocarbon fuel SOFCs. Homogeneously dispersed Ni‐Fe alloy nanoparticles were in situ extruded onto the surface of the LSFN particles during the operation of the cell. Sym‐metric SOFC single cells were prepared by impregnating a LSFN precursor solution onto a YSZ （yt‐tria stabilized zirconia） monolithic cell with a subsequent heat treatment. The open circuit voltage of the LSFN symmetric cell reached 1.18 and 1.0 V in humidified C3H8 and CH4 at 750？？, respective‐ly. The peak power densities of the cells were 400 and 230 mW/cm2 in humidified C3H8 and CH4, respectively. The electrode showed good stability in long term testing, which revealed LSFN has good catalytic activity for hydrocarbon fuel oxidation.展开更多
Vermicomposting is a biotechnological process that enables the recycling of organic waste materials into manure through the combined action of earthworms and mesophilic microorganisms. In this study, a 13-week experim...Vermicomposting is a biotechnological process that enables the recycling of organic waste materials into manure through the combined action of earthworms and mesophilic microorganisms. In this study, a 13-week experiment was carried to vermiprocess food industry sludge mixed with different bedding materials including two weeds, water hyacinth and parthenium, as well as cow dung, in different combinations employing earthworms of the species Eisenia fetida. Eight vermibins containing one kilogram of the waste mixtures （dry weight basis） were established for vermicomposting. Vermiprocessing significantly increased nitrogen, phosphorous, and potassium contents of the mixtures. However, a decrease in pH, organic carbon, and C：N ratio was observed after vermiprocessing. The heavy metal contents in the vermicomposts were higher than the initial values but within permissible limits. These results indicated that the studied wastes can be converted into good quality manure by vermiprocessing, which indicated their agricultural values as a soil conditioner if mixed with weeds in appropriate ratios.展开更多
基金supported by the National Natural Science Foundation of China (51372271,51172275)the National Basic Research Program of China (973 Program,2012CB215402)~~
文摘The conventional Ni cermet anode suffers from severe carbon deposition and sulfur poisoning when fossil fuels are used. Alternative anode materials are desired for high performance hydrocarbon fuel solid oxide fuel cells （SOFCs）. We report the rational design of a very active Ni doped La0.6Sr0.4FeO3‐δ（LSFN） electrode for hydrocarbon fuel SOFCs. Homogeneously dispersed Ni‐Fe alloy nanoparticles were in situ extruded onto the surface of the LSFN particles during the operation of the cell. Sym‐metric SOFC single cells were prepared by impregnating a LSFN precursor solution onto a YSZ （yt‐tria stabilized zirconia） monolithic cell with a subsequent heat treatment. The open circuit voltage of the LSFN symmetric cell reached 1.18 and 1.0 V in humidified C3H8 and CH4 at 750？？, respective‐ly. The peak power densities of the cells were 400 and 230 mW/cm2 in humidified C3H8 and CH4, respectively. The electrode showed good stability in long term testing, which revealed LSFN has good catalytic activity for hydrocarbon fuel oxidation.
基金Supported by the University Grants Commission(UGC),India
文摘Vermicomposting is a biotechnological process that enables the recycling of organic waste materials into manure through the combined action of earthworms and mesophilic microorganisms. In this study, a 13-week experiment was carried to vermiprocess food industry sludge mixed with different bedding materials including two weeds, water hyacinth and parthenium, as well as cow dung, in different combinations employing earthworms of the species Eisenia fetida. Eight vermibins containing one kilogram of the waste mixtures （dry weight basis） were established for vermicomposting. Vermiprocessing significantly increased nitrogen, phosphorous, and potassium contents of the mixtures. However, a decrease in pH, organic carbon, and C：N ratio was observed after vermiprocessing. The heavy metal contents in the vermicomposts were higher than the initial values but within permissible limits. These results indicated that the studied wastes can be converted into good quality manure by vermiprocessing, which indicated their agricultural values as a soil conditioner if mixed with weeds in appropriate ratios.
