Powder mixture of pure Al and oxidized Si C was consolidated into 10%（mass fraction） Si Cp/Al composites at 250 °C by equal channel angular pressing and torsion（ECAP-T）. The valence states of Si for Si C part...Powder mixture of pure Al and oxidized Si C was consolidated into 10%（mass fraction） Si Cp/Al composites at 250 °C by equal channel angular pressing and torsion（ECAP-T）. The valence states of Si for Si C particulates and Al for the as-consolidated composites were detected by X-ray photoelectron spectroscopy（XPS）. The interfacial bondings of the composites were characterized by scanning electron microscopy（SEM）. The elements at the interface were linearly scanned by energy dispersive spectroscopy（EDS） and the EDS mappings of Si and Al were also obtained. The values of the nanohardness at different positions within 2 μm from the boundary of Si C particulate were measured. The results show that after ECAP-T, interfacial reaction which inhibits injurious interfacial phase occurs between Al and the oxide layer of Si C, and the element interdiffusion which can enhance interfacial bonding exists between Al and Si C. As ECAP-T passes increase, the reaction degree is intensified and the element interdiffusion layer is thickened, leading to the more smooth transition of the hardness from Si C to Al.展开更多
Through alloy sampling combined with diffusion triple technique, phase equilibria in Al-Ti-Zr ternary system at 1073 Kwere experimentally determined with electron probe microanalysis （EPMA）. Experimental results sho...Through alloy sampling combined with diffusion triple technique, phase equilibria in Al-Ti-Zr ternary system at 1073 Kwere experimentally determined with electron probe microanalysis （EPMA）. Experimental results show that there is a solid solutionβ（Ti,Zr） which dissolves Al up to 16.3% （mole fraction）. Ti and Zr can substitute each other in most Ti-Al and Al-Zr binaryintermediate phases to a certain degree while the maximum solubility of Zr in Ti3Al and TiAl reaches up to 17.9% and 4.0% （molefraction）, respectively. The isothermal section consists of 16 single-phased regions, 27 two-phased regions and 14 three-phasedregions. No ternary phase was detected.展开更多
Phase equilibria in Ti?Ni?Pt ternary system have been experimentally determined through diffusion triple technique combined with alloy samples approach.Assisted with electron probe microanalysis(EPMA)and X-ray diffrac...Phase equilibria in Ti?Ni?Pt ternary system have been experimentally determined through diffusion triple technique combined with alloy samples approach.Assisted with electron probe microanalysis(EPMA)and X-ray diffraction(XRD)techniques,isothermal sections at 1073 and 1173 K of this system were constructed and existence of ternary phase Ti2(Ni,Pt)3 was confirmed.In addition,binary compounds Ti3Pt5 and TiPt3-were found to be stable at 1073 and 1173 K,and remarkable ternary solubility in some binary compounds was detected,e.g.,solubility of Pt in TiNi can be up to about 36%(molar fraction)at 1073 K and 40%(molar fraction)at 1173 K.Furthermore,a ternary invariant transition reaction TiNi3+Ti3Pt5→Ti2(Ni,Pt)3+TiPt3+at a temperature between 1073 and 1173 K was deduced.展开更多
基金Project(51175138)supported by the National Natural Science Foundation of ChinaProjects(2012HGZX0030,2013HGCH0011)supported by the Fundamental Research Funds for the Central Universities,ChinaProject(20100111110003)supported by the Specialized Research Fund for the Doctoral Program of Higher Education,China
文摘Powder mixture of pure Al and oxidized Si C was consolidated into 10%（mass fraction） Si Cp/Al composites at 250 °C by equal channel angular pressing and torsion（ECAP-T）. The valence states of Si for Si C particulates and Al for the as-consolidated composites were detected by X-ray photoelectron spectroscopy（XPS）. The interfacial bondings of the composites were characterized by scanning electron microscopy（SEM）. The elements at the interface were linearly scanned by energy dispersive spectroscopy（EDS） and the EDS mappings of Si and Al were also obtained. The values of the nanohardness at different positions within 2 μm from the boundary of Si C particulate were measured. The results show that after ECAP-T, interfacial reaction which inhibits injurious interfacial phase occurs between Al and the oxide layer of Si C, and the element interdiffusion which can enhance interfacial bonding exists between Al and Si C. As ECAP-T passes increase, the reaction degree is intensified and the element interdiffusion layer is thickened, leading to the more smooth transition of the hardness from Si C to Al.
基金Project(51171210)supported by the National Natural Science Foundation of ChinaProject(2014CB6644002)supported by the Major State Basic Research Development Program of China
文摘Through alloy sampling combined with diffusion triple technique, phase equilibria in Al-Ti-Zr ternary system at 1073 Kwere experimentally determined with electron probe microanalysis （EPMA）. Experimental results show that there is a solid solutionβ（Ti,Zr） which dissolves Al up to 16.3% （mole fraction）. Ti and Zr can substitute each other in most Ti-Al and Al-Zr binaryintermediate phases to a certain degree while the maximum solubility of Zr in Ti3Al and TiAl reaches up to 17.9% and 4.0% （molefraction）, respectively. The isothermal section consists of 16 single-phased regions, 27 two-phased regions and 14 three-phasedregions. No ternary phase was detected.
基金Project(2016YFB0701404)supported by the National Key Research and Development Program of ChinaProject(51171210)supported by the National Natural Science Foundation of China
文摘Phase equilibria in Ti?Ni?Pt ternary system have been experimentally determined through diffusion triple technique combined with alloy samples approach.Assisted with electron probe microanalysis(EPMA)and X-ray diffraction(XRD)techniques,isothermal sections at 1073 and 1173 K of this system were constructed and existence of ternary phase Ti2(Ni,Pt)3 was confirmed.In addition,binary compounds Ti3Pt5 and TiPt3-were found to be stable at 1073 and 1173 K,and remarkable ternary solubility in some binary compounds was detected,e.g.,solubility of Pt in TiNi can be up to about 36%(molar fraction)at 1073 K and 40%(molar fraction)at 1173 K.Furthermore,a ternary invariant transition reaction TiNi3+Ti3Pt5→Ti2(Ni,Pt)3+TiPt3+at a temperature between 1073 and 1173 K was deduced.
