The thixocasting process was chosen to produce the impellers as it is capable of producing castings with extremely high internal quality.Slugs cut from the DC cast bars are re-heated to the semi-solid casting temperat...The thixocasting process was chosen to produce the impellers as it is capable of producing castings with extremely high internal quality.Slugs cut from the DC cast bars are re-heated to the semi-solid casting temperature, and a specially-designed runner and gating system is used to prevent oxide from the surface of the slugs from becoming incorporated into the impeller.The technology used to produce the semi-solid impellers is described in detail.The semi-solid cast impellers, produced from an Al-Si-Mg-Cu alloy, are heat treated to the T6 temper.Results from testing are presented demonstrating that the impellers are free of porosity and other internal defects.Both mechanical property and fatigue data are presented showing that the semi-solid impellers have better properties than impellers produced by conventional casting and similar properties to forged and machined impellers.A short study is also described which identified suitable processing parameters to minimize hot tearing in the complex-shaped turbocharger impellers semi-solid cast from alloy 201.The surfaces of the impellers were examined using penetrant testing, and the results of modifying processing parameters on the propensity for surface cracking are presented.An aging study was performed to identify optimum mechanical strength.展开更多
The influence of fly ash on the fresh properties, mechanical properties and carbonation properties were studied in this paper. The performance of a kind of curing agent which was applied to the hardened concrete surfa...The influence of fly ash on the fresh properties, mechanical properties and carbonation properties were studied in this paper. The performance of a kind of curing agent which was applied to the hardened concrete surface was evaluated. Incorporating large volume of fly ash will risk the concrete carbonation. The curing agent could prevent the concrete carbonation, and the mechanism was explained.展开更多
In this study, a novel bio-based thermosetting system has been developed from epoxy resin （EP）, with rosin-sourced anhydrides （maleopimaric acid, RAM） as curing agent and imidazole type latent catalyst （two amino...In this study, a novel bio-based thermosetting system has been developed from epoxy resin （EP）, with rosin-sourced anhydrides （maleopimaric acid, RAM） as curing agent and imidazole type latent catalyst （two amino imidazole salt complex, IMA）, to be used as matrix for hot-melt prepreg curing at mid-temperature. For comparison, the epoxy resin system with petroleum sourced hardener methylhexahydrophthalicanhydride （MHHPA） was also examined. The curing behaviour and mechanism were investigated by non-isothermal differential scanning calorimeter （DSC） analysis and Fourier transform infrared （FTIR） spectra. The results showed that the curing course of bio-based epoxy resin system containing RAM included two stages, which were the reaction between the free carboxyl group of RAM and oxirane ring under the acceleration of IMA, and the main reaction attributed to the reaction between anhydride and oxirane. According to Kissinger method, the reaction activation energy （E,） of two stages were 68.9 and 86.5kJmo1-1, respectively. The Eo of EP/MHHPA and EP/IMA resin system were 81.04 and 77.9kJmol-I. The processing property of EP/RAM/IMA system, i.e. the relationship between viscosity-temperature-time, was characterized by cone-plate viscometer aim to decide the processing parameter ofprepreg preparation. The effect of RAM content on mechanical performance and dynamic mechanical property was investigated. Noteworthily, compared with the laminates with EP/MHHPA as matrix, the laminates with RAM as hardeners achieved a 44%, 73% and 70℃ increase in bending strength, bending modulus and the glass transition temperature, respectively, due to the bulky hydrogenated phenanthrene ring structure incorporated into the cross-linking networks. When the fiber volume fraction reached 47%, the mechanical property of the laminates prepared with hot melt prepreg was superior or comparable to that of composites with pure petroleum sourced matrix. RAM as cross-linking agent of epoxy resin holds a great potential to satisfy the requirement of composites such as structure and secondary structure parts preparation.展开更多
文摘The thixocasting process was chosen to produce the impellers as it is capable of producing castings with extremely high internal quality.Slugs cut from the DC cast bars are re-heated to the semi-solid casting temperature, and a specially-designed runner and gating system is used to prevent oxide from the surface of the slugs from becoming incorporated into the impeller.The technology used to produce the semi-solid impellers is described in detail.The semi-solid cast impellers, produced from an Al-Si-Mg-Cu alloy, are heat treated to the T6 temper.Results from testing are presented demonstrating that the impellers are free of porosity and other internal defects.Both mechanical property and fatigue data are presented showing that the semi-solid impellers have better properties than impellers produced by conventional casting and similar properties to forged and machined impellers.A short study is also described which identified suitable processing parameters to minimize hot tearing in the complex-shaped turbocharger impellers semi-solid cast from alloy 201.The surfaces of the impellers were examined using penetrant testing, and the results of modifying processing parameters on the propensity for surface cracking are presented.An aging study was performed to identify optimum mechanical strength.
基金Key Prograns for Science and Technology Development of Chinese Transportation Industry( No. 2008-353-332-140)
文摘The influence of fly ash on the fresh properties, mechanical properties and carbonation properties were studied in this paper. The performance of a kind of curing agent which was applied to the hardened concrete surface was evaluated. Incorporating large volume of fly ash will risk the concrete carbonation. The curing agent could prevent the concrete carbonation, and the mechanism was explained.
基金supported by the China-EU co-funded project ECO-COMPASS(Grant No.MJ2015-HG-103)
文摘In this study, a novel bio-based thermosetting system has been developed from epoxy resin （EP）, with rosin-sourced anhydrides （maleopimaric acid, RAM） as curing agent and imidazole type latent catalyst （two amino imidazole salt complex, IMA）, to be used as matrix for hot-melt prepreg curing at mid-temperature. For comparison, the epoxy resin system with petroleum sourced hardener methylhexahydrophthalicanhydride （MHHPA） was also examined. The curing behaviour and mechanism were investigated by non-isothermal differential scanning calorimeter （DSC） analysis and Fourier transform infrared （FTIR） spectra. The results showed that the curing course of bio-based epoxy resin system containing RAM included two stages, which were the reaction between the free carboxyl group of RAM and oxirane ring under the acceleration of IMA, and the main reaction attributed to the reaction between anhydride and oxirane. According to Kissinger method, the reaction activation energy （E,） of two stages were 68.9 and 86.5kJmo1-1, respectively. The Eo of EP/MHHPA and EP/IMA resin system were 81.04 and 77.9kJmol-I. The processing property of EP/RAM/IMA system, i.e. the relationship between viscosity-temperature-time, was characterized by cone-plate viscometer aim to decide the processing parameter ofprepreg preparation. The effect of RAM content on mechanical performance and dynamic mechanical property was investigated. Noteworthily, compared with the laminates with EP/MHHPA as matrix, the laminates with RAM as hardeners achieved a 44%, 73% and 70℃ increase in bending strength, bending modulus and the glass transition temperature, respectively, due to the bulky hydrogenated phenanthrene ring structure incorporated into the cross-linking networks. When the fiber volume fraction reached 47%, the mechanical property of the laminates prepared with hot melt prepreg was superior or comparable to that of composites with pure petroleum sourced matrix. RAM as cross-linking agent of epoxy resin holds a great potential to satisfy the requirement of composites such as structure and secondary structure parts preparation.
