Natural rutile and gaseous chlorine with carbon as reductant were used to prepare titanium tetrachloride. Thermodynamics and kinetics of chlorination of Kenya natural rutile particles in a batch-type fluidized bed wer...Natural rutile and gaseous chlorine with carbon as reductant were used to prepare titanium tetrachloride. Thermodynamics and kinetics of chlorination of Kenya natural rutile particles in a batch-type fluidized bed were studied at 1173-1273 K. Thermodynamic analysis of this system revealed that the equation of producing CO was dominant at high temperatures. Based on the gas-solid multi-phase reaction theory and a two-phase model for the fluidized bed, the mathematical description for the chlorination reaction of rutile was proposed. The reaction parameters and the average concentration of gaseous chlorine in the emulsion phase were estimated. The average concentration of emulsion phase in the range of fluidized bed was calculated as 0.3 mol/m^3. The results showed that the chlorination of natural rutile proceeded principally in the emulsion phase, and the reaction rate was mainly controlled by the surface reaction.展开更多
A mathematical model considering free nuclei was developed to reveal the migration behavior of the free nuclei. Numerical simulation results show that most of the nuclei on the top surface of the melt move downwards a...A mathematical model considering free nuclei was developed to reveal the migration behavior of the free nuclei. Numerical simulation results show that most of the nuclei on the top surface of the melt move downwards and distribute randomly inside the Al melt, which induces more nucleation sites resulting in grain refinement. At the same time, the effect of nuclei size on the nuclei distribution and refinement employing electric current pulse （ECP） was also investigated. The smaller nuclei migrate a short distance with the Al melt at lower speed. But for the larger nuclei, the migration downwards with higher speed benefits the refinement of interior grains of the melt. The research results help to better understand the refinement process and provide a more reasonable explanation of the grain refinement mechanism using ECP.展开更多
[Objective] This study aimed to explore the impact of climate change on wheat cropping by using province-specific historical data during 1996-2007. [Method] We established a panel data econometric model with lagged wh...[Objective] This study aimed to explore the impact of climate change on wheat cropping by using province-specific historical data during 1996-2007. [Method] We established a panel data econometric model with lagged wheat cropping area and province-specific fixed-effects model to control the unobserved factors. [Result] The results showed that the temperature positively affects wheat cropping area, while precipitation does not have such impact. [Conclusion] The study provided empirical evidence for analysis of the determinants of wheat cropping area in China.展开更多
In this paper we analyze the characteristics of a flow transducer based on polarized charge. The effects of the charged particles in pneumatic pipeline on the measurement pipe potential are discussed in detail and the...In this paper we analyze the characteristics of a flow transducer based on polarized charge. The effects of the charged particles in pneumatic pipeline on the measurement pipe potential are discussed in detail and the equivalent circuits of the potential measurement are presented. On this bases, the relationships between mass flowrate and the electrical potential are obtained for different time constants of the measurement circuit. A satisfactory model is presented based on the characteristics of gas solid two phase flow. The linearity of the model is verified by the experiment results. The transducer, which is coaxially connected with the transport pipeline, does not disturb the flow state and has the features of ruggedness and durability, it is especially suitable for industry process control.展开更多
Anchoring mechanism and failure characteristics of composite soft rock with weak interface usually exhibit remarkable difference from those in single rock mass.In order to fully understand the reinforcement mechanism ...Anchoring mechanism and failure characteristics of composite soft rock with weak interface usually exhibit remarkable difference from those in single rock mass.In order to fully understand the reinforcement mechanism of composite soft roof in western mining area of China,a mechanical model of composite soft rock with weak interface and rock bolt which considering the transverse shear sliding between different rock layers was established firstly.The anchoring effect was quantified by a factor defined as anchoring effect coefficient and its evolution equation was further deduced based on the deformation relationship and homogenized distribution assumption of stress acting on composite structure.Meanwhile,the numerical simulation model of composite soft rock with shear joint was prompted by finite element method.Then detailed analysis were carried out for the deformation features,stress distribution and failure behavior of rock mass and rock bolt near the joint under transverse load.The theoretical result indicates that the anchoring effect of rock-bolt through weak joint changes with the working status of rock mass and closely relates with the physical and geometric parameters of rock mass and rock bolt.From the numerical results,the bending deformation of rock bolt accurately characterized by Doseresp model is mainly concentrated between two plastic hinges near the shear joint.The maximum tensile and compression stresses distribute in the plastic hinge.However,the maximum shear stress appears at the positions of joint surface.The failure zones of composite rock are produced firstly at the joint surface due to the reaction of rock bolt.The above results laid a theoretical and computational foundation for further study of anchorage failure in composite soft rock.展开更多
Swept volume solid modeling has been applied to many areas such as NC machining simulation and verification, robot workspace analysis, collision detection, and CAD. But self-intersections continue to be a challenging ...Swept volume solid modeling has been applied to many areas such as NC machining simulation and verification, robot workspace analysis, collision detection, and CAD. But self-intersections continue to be a challenging problem in the boundary representation of swept volume solids. A novel algorithm is presented in this paper to trim self-intersection regions in swept volume solids modeling. This trimming algorithm consists of two major steps: (1) roughly detecting self-intersection regions by checking intersections or overlapping of the envelop profiles; (2) splitting the whole envelop surfaces of the swept volume solid into separate non-self-intersecting patches to trim global self-intersections, and to trim local self-intersections, dividing local self-intersecting regions into patches and replacing self-intersecting patches with non-self-intersecting ones. Examples show that our algorithm is efficient and robust.展开更多
基金Projects(51374064,51004033,51074044)supported by the National Natural Science Foundation of ChinaProject(2012AA062303)supported by High-tech Research and Development Program of China
文摘Natural rutile and gaseous chlorine with carbon as reductant were used to prepare titanium tetrachloride. Thermodynamics and kinetics of chlorination of Kenya natural rutile particles in a batch-type fluidized bed were studied at 1173-1273 K. Thermodynamic analysis of this system revealed that the equation of producing CO was dominant at high temperatures. Based on the gas-solid multi-phase reaction theory and a two-phase model for the fluidized bed, the mathematical description for the chlorination reaction of rutile was proposed. The reaction parameters and the average concentration of gaseous chlorine in the emulsion phase were estimated. The average concentration of emulsion phase in the range of fluidized bed was calculated as 0.3 mol/m^3. The results showed that the chlorination of natural rutile proceeded principally in the emulsion phase, and the reaction rate was mainly controlled by the surface reaction.
基金Project(SELF-2011-01)supported by the Open Project of Shanghai Key Laboratory of Modern Metallurgy and Materials Processing,ChinaProjects(51204109,51035004)supported by the National Natural Science Foundation of China
文摘A mathematical model considering free nuclei was developed to reveal the migration behavior of the free nuclei. Numerical simulation results show that most of the nuclei on the top surface of the melt move downwards and distribute randomly inside the Al melt, which induces more nucleation sites resulting in grain refinement. At the same time, the effect of nuclei size on the nuclei distribution and refinement employing electric current pulse （ECP） was also investigated. The smaller nuclei migrate a short distance with the Al melt at lower speed. But for the larger nuclei, the migration downwards with higher speed benefits the refinement of interior grains of the melt. The research results help to better understand the refinement process and provide a more reasonable explanation of the grain refinement mechanism using ECP.
基金Supported by the National Natural Science Foundation of China (41101165)~~
文摘[Objective] This study aimed to explore the impact of climate change on wheat cropping by using province-specific historical data during 1996-2007. [Method] We established a panel data econometric model with lagged wheat cropping area and province-specific fixed-effects model to control the unobserved factors. [Result] The results showed that the temperature positively affects wheat cropping area, while precipitation does not have such impact. [Conclusion] The study provided empirical evidence for analysis of the determinants of wheat cropping area in China.
文摘In this paper we analyze the characteristics of a flow transducer based on polarized charge. The effects of the charged particles in pneumatic pipeline on the measurement pipe potential are discussed in detail and the equivalent circuits of the potential measurement are presented. On this bases, the relationships between mass flowrate and the electrical potential are obtained for different time constants of the measurement circuit. A satisfactory model is presented based on the characteristics of gas solid two phase flow. The linearity of the model is verified by the experiment results. The transducer, which is coaxially connected with the transport pipeline, does not disturb the flow state and has the features of ruggedness and durability, it is especially suitable for industry process control.
基金Projects(51774196,41472280,51578327)supported by the National Natural Science Foundation of ChinaProject(2016M592221)supported by the China Postdoctoral Science FoundationProject(BJRC20160501)supported by the SDUST Young Teachers Teaching Talent Training Plan,China
文摘Anchoring mechanism and failure characteristics of composite soft rock with weak interface usually exhibit remarkable difference from those in single rock mass.In order to fully understand the reinforcement mechanism of composite soft roof in western mining area of China,a mechanical model of composite soft rock with weak interface and rock bolt which considering the transverse shear sliding between different rock layers was established firstly.The anchoring effect was quantified by a factor defined as anchoring effect coefficient and its evolution equation was further deduced based on the deformation relationship and homogenized distribution assumption of stress acting on composite structure.Meanwhile,the numerical simulation model of composite soft rock with shear joint was prompted by finite element method.Then detailed analysis were carried out for the deformation features,stress distribution and failure behavior of rock mass and rock bolt near the joint under transverse load.The theoretical result indicates that the anchoring effect of rock-bolt through weak joint changes with the working status of rock mass and closely relates with the physical and geometric parameters of rock mass and rock bolt.From the numerical results,the bending deformation of rock bolt accurately characterized by Doseresp model is mainly concentrated between two plastic hinges near the shear joint.The maximum tensile and compression stresses distribute in the plastic hinge.However,the maximum shear stress appears at the positions of joint surface.The failure zones of composite rock are produced firstly at the joint surface due to the reaction of rock bolt.The above results laid a theoretical and computational foundation for further study of anchorage failure in composite soft rock.
基金Project supported by the National Natural Science Foundation of China (No. 60473106)the Hi-Tech Research and Development Program (863) of China (Nos. 2007AA01Z311 and 2007AA04Z1A5)the National Research Foundation for the Doctoral Program of Higher Education of China (No. 20060335114)
文摘Swept volume solid modeling has been applied to many areas such as NC machining simulation and verification, robot workspace analysis, collision detection, and CAD. But self-intersections continue to be a challenging problem in the boundary representation of swept volume solids. A novel algorithm is presented in this paper to trim self-intersection regions in swept volume solids modeling. This trimming algorithm consists of two major steps: (1) roughly detecting self-intersection regions by checking intersections or overlapping of the envelop profiles; (2) splitting the whole envelop surfaces of the swept volume solid into separate non-self-intersecting patches to trim global self-intersections, and to trim local self-intersections, dividing local self-intersecting regions into patches and replacing self-intersecting patches with non-self-intersecting ones. Examples show that our algorithm is efficient and robust.
