水化硫铝酸钙和水化铝酸钙对内掺、外渗氯离子的固结机理及能力

为研究单硫型水化硫铝酸钙(AFm)和水化铝酸钙(C_(3)AH_(6))的Cl^(–)固结能力和机理,通过人工合成的方法采用C3A制备了高纯AFm与C_(3)AH_(6),并研究了内掺、外渗Cl^(-)条件下2种物质固结Cl^(-)后的产物类型、微观形貌、Cl^(-)固结量和固结率.结果表明:C_(3)AH_(6)对内掺Cl^(-)的固结能力(最高可达75%)远高于AFm(稳定约为17%),该差异在内掺Cl^(-)含量相对较低的情况下尤为显著;对比AFm,Cl^(-)与C3AH6的反应更迅速且更为彻底;C_(3)AH_(6)的固氯产物一致为Friedel盐,AFm则根据Cl^(-)浓度及其不同引入方式分为Hc、Kuzel盐、Friedel盐以及高硫型水化硫铝酸钙(Aft).

Effect of consolidation parameters on mechanical properties of Cu-based bulk amorphous alloy consolidated by hot pressing

Cu50Zr40Ti10 bulk amorphous alloys were fabricated by hot pressing gas-atomized Cu50Zr40Ti10 amorphous powder under different consolidation conditions without vacuum and inert gas protection. The consolidation conditions of the Cu50Zr40Ti10 amorphous powder were investigated based on an L9（34） orthogonal design. The compression strength and strain limit of the Cu50Zr40Ti10 bulk amorphous alloys can reach up to 1090.4 MPa and 11.9 %, respectively. The consolidation pressure significantly influences the strain limit and compression strength of the compact. But the mechanical properties are not significantly influenced by the consolidation temperature. In addition, the preforming pressure significantly influences not the compression strength but the strain limit. The optimum consolidation condition for the Cu50Zr40Ti10 amorphous powder is first precompacted under the pressure of 150 MPa, and then consolidated under the pressure of 450 MPa and the temperature of 380 °C.

Experimental research on unloading properties of clay under high stress

Abstract： Mechanical properties of clay under high stress are quite different from those under low stress. It is necessary to investi- gate unloading properties of clay under high stress for the design and construction of deep underground engineering projects. A series of experiments were conducted to investigate the unloading properties of clay under high confining pressures by using a SKA-1 high pressure consolidation instrument designed by us. The stress versus strain relationship and the way that K0 values of clay change during the loading-unloading process were discovered. The results show that there are clear differences in the state of stress and deformation behavior of the clay along different unloading paths.

Influence of subsequent curing on water sorptivity and pore structure of steam-cured concrete

Steam-cured condition is found to cause larger porosity and worse properties of concrete compared with normal curing condition. For the sake of seeking effective measurements to eliminate this bad effect of steam-cured condition on concrete, the water sorptivity and pore structure of steam-cured concretes exposed to different subsequent curing conditions were investigated after steam-curing treatment. The capillary absorption coefficient and porosity of the corresponding concretes were analyzed, and their mechanisms were also discussed. The results indicate that water sorptivity and pore structure of steam-cured concrete are greatly influenced by the curing condition used in subsequent ages. Exposure steam-cured concrete to air condition has an obviously bad effect on its properties and microstructures. Adopting subsequent curing of immersing steam-cured concrete into about 20℃ water after steam curing period can significantly decrease its capillary absorption coefficient and porosity. Steam-cured concrete with 7 d water curing has minimum capillary absorption coefficient and total porosity. Its water sorptivity is decreased by 23% compared with standard curing concrete and the porosity is 9.6% lower. Moreover, the corresponding gradient of water sorptivity and porosity of steam-cured concrete both decrease, thus mictostructure of concrete becomes more homogeneous.

Structural safety criteria for blasting vibration based on wavelet packet energy spectra

Given multi-resolution decomposition of wavelet packet transforms,wavelet packet frequency band energy has been deduced from different bands of blasting vibration signals.Our deduction reflects the total effect of all three key elements（intensity,frequency and duration of vibration）of blasting vibration. We considered and discuss the dynamic response of structures and the effect of inherent characteristics of controlled structures to blasting vibration.Frequency band response coefficients for controlled structures by blasting vibration have been obtained.We established multi-factor blasting vibration safety criteria,referred to as response energy criteria.These criteria reflect the total effect of intensity, frequency and duration of vibration and the inherent characteristics（natural frequency and damping ratio）of dynamic responses from controlled structures themselves.Feasibility and reliability of the criteria are validated by an example.

Controlling the solid-state luminescence of gold(I) N-heterocyclic carbene complexes through changes in the structure of molecular aggregates

Thermally stable, solid-state luminescent organic materials are highly desired for the development of practical applications.Herein we synthesized new gold(I) complexes with N-heterocyclic carbene ligands, which have the ability to form strong metalorganic bond. Consequently, their thermochemical stability is enhanced at temperatures around 300 °C. Precise design of the molecular structure of the ligands, with a focus on ensuring low steric hindrance around Au atoms in order to limit disturbances to Au/Au interactions, provided a complex with a densely packed crystal with a shorter intermolecular Au–Au distance(3.17 ?)than the typical distance. In the solid state, this complex exhibited strong aurophilic interactions, which generated intense phosphorescence even in air at room temperature(quantum yield=16%) in spite of absence of any phosphorescence in solution.This behavior is characteristic for solid-state luminescence referred to as aggregation-controlled emission. Furthermore, the gold(I) complex displays capacity for mechano-and vapo-chromism—that is, the ability to change color reversibly in response to the application of external stimuli. We believe that the proposed design framework, which involves controlling thermal stability and luminescence property separately, provides a new opportunity for the development of practical applications using solid-state luminescent organic molecules.