Fixed ammonium contents and fixation capacities of some representative cultivated soils collectedfrom 16 provinces of China were studied. Results showed that the contents of fixed ammonium in soilsranged from 35 to 5...Fixed ammonium contents and fixation capacities of some representative cultivated soils collectedfrom 16 provinces of China were studied. Results showed that the contents of fixed ammonium in soilsranged from 35 to 573 mg N kg￣(-1), with an average of 198 mg N kg￣(-1). The content of fixed ammoniumcorrelated very significantly with mica content for tropical and subtropical soils, whereas this was not thecase for soils in the temperate zone. At the end of K-exhansting experiment the fixed ammonium contentincreased in most soils studied. However, it decreased in some temperate soils. Generally, fixation of addedNH could not be found either before or after K-exhausting experiment for highly weathered soils, includingtropical soils and soils derived from granite-gneiss or Quaternary red clays in the subtropic zonet while formost soils in the Yangtze River dalta the NH fixation capacity was rather high and increased siguificantlyin the K-exhausted soils.展开更多
The contents, affecting factors, seasonal changes and availability of fixed ammonium in major types ofpaddy soils derived from different parent materials in Hunan Province, China, were studied using the Silva-Bremner ...The contents, affecting factors, seasonal changes and availability of fixed ammonium in major types ofpaddy soils derived from different parent materials in Hunan Province, China, were studied using the Silva-Bremner method by laboratory and pot experiments. Results showed that the content of fixed ammoniumin the plough horizons ranged from 88.3 mg kg-1 to 388.1 mg kg-1, with 273.2 ± 77.7 mg kg-1 on average,accounting for 11.2% of total soil N on average. Content of fixed ammonium decreased in the order of newlylacustrine clayey paddy soil ＞ alluvial sandy paddy soil ＞ purple clayey paddy soil ＞ newly alluvial sandypaddy soil ＞ yellow clayey paddy soil ＞ reddish-yellow clayey paddy soil ＞ granitic sandy paddy soil. Therewere four distribution patterns of fixed ammonium in the profiles to 1-m depth, i.e., increase with the depth,decrease with increasing depth, no distinct change with the depth, and abrupt increase or decrease in somehorizon. Percentage of fixed ammonium in total N increased with the depth in most of the soils. Fixationof NH4+ by soil was higher at 30 ℃ than at 20 ℃ and 40 ℃, and continuous submergence benefited thefixation of NH4+ in newly alluvial sandy paddy soil, purple clayey paddy soil and alluvial sandy paddy soil,while alternating wetting and drying contributed to the fixation of NH4+ in yellow clayey paddy soil mostly.Fixed ammonium content in the test paddy soils was significantly correlated with ＜ 0.01 mm clay content(P ＜ 0.05), but not with ＜ 0.001 mm clay content, total N, organic N and organic matter. Fixed ammoniumcontent varied with rice growth stages. Application of N fertilizer promoted fixation of NH4+ by soil, and Nuptake by rice plant promoted release of fixed ammonium from the soil. Recently fixed ammonium in paddysoil after N fertilizer application was nearly 100% available to rice plant, while native fixed ammonium wasonly partly available, varying with the soil type and rice type.展开更多
Ten soils collected from different parts of China were used in a series of experiments to study fixation of NH￣+_4 and K￣+ by soils. When K￣+ was added concurrently with or prior to NH￣+_4, the soils were found to...Ten soils collected from different parts of China were used in a series of experiments to study fixation of NH￣+_4 and K￣+ by soils. When K￣+ was added concurrently with or prior to NH￣+_4, the soils were found to fix more moles of NH￣+_4 than those of K￣+, irrespective of the mole ratios of NH￣+_4 to K￣+ that were added.展开更多
Two soils with relatively high (Soil 1) and low (Soil 2) ammonium fixation capacities were used in thisstudy to extalne the effect of ammonium fixation on the determination of N mineralised from soil ndcrobialbiomass....Two soils with relatively high (Soil 1) and low (Soil 2) ammonium fixation capacities were used in thisstudy to extalne the effect of ammonium fixation on the determination of N mineralised from soil ndcrobialbiomass. organism suspellsioll was quantitatively introduced to Soil 1 at various rates. Both fumigation-incubation (FI) and fumigation-ext raction (FE ) met hods were used to t reat t he soil. The amount of ffeedNH4+-N increased with increasing rate of organism-N addition. A close correlation was found between theamoun of fixed aznmonium and the rate of organism-N addition. The net increso of fixed NH4+-N wereequivalent to 38% and 12% of the added organism-N for FI and FE treatments, respectively in this specificsoil. To provide isotopic evidence, 15N-labelled organism-N was added to Soils 1 and 2 at 121.4 mg N kg-1.In FI treatment, 22 and 3 mg N kg-1 of labelled N were found in the fraction of fixed NH4+-N in Soils 1 and2 respectively; while in FE treatment, 9 mg N kg-1 of labelled N was found in the fraction of fixed NH4+-Nin Soil 1 only. There was no labelled N in the fraction of fixed NH4+-N in Soil 2. In all of the unfumigated(check) soils, there was little or no labelled N in the fixed fractions, probably because the organism-N addedwas easily mineralized and nitrified. A mean of 0.64 for KN value, the fraction of N ndneralized in the killedmicrobial biomass, was obtained with inclusion of the net increase of fixed NH4+-N. The corresponding valuecalculated with exclusion of the net increase of fixed NH4+-N was 0.46. It was concluded that ammniumfixation was a problem in determination of KN, particularly for soils with a high ammonium fixation capacity.Results also showed that microbial biomass N measurement by FE method was less affected by ammoniumprocess than that by FI method.展开更多
Effects of temperature and drying and wetting alternation(DWA)on ammonium fixation in manured loessial soil were studied by means of Batch Equilibrium with Varying concentration solutions of ammonium chloride,ammonium...Effects of temperature and drying and wetting alternation(DWA)on ammonium fixation in manured loessial soil were studied by means of Batch Equilibrium with Varying concentration solutions of ammonium chloride,ammonium fixation time,and soil clay contents.The purpose of the research was to find out the pattern of ammonium fixation ted by the varying factors.The results showed a remarkable variation in ammonium fixation.Fixed ammonium increased with temperature and treatments of DWA.The ammonium fixation in manured loessial soil was characterized by the effect of temperature and DWA.展开更多
Some thermodynamic properties of NHk fixation by loess soil in plowing and clay layers are discussed.The. results indicate that the four ion adsorption equations commonly used can describe the properties of NHk fixati...Some thermodynamic properties of NHk fixation by loess soil in plowing and clay layers are discussed.The. results indicate that the four ion adsorption equations commonly used can describe the properties of NHk fixation in these soils under constant temperature. Among the four adsorption equations, the singlesurface Langmuir equation is the best. When the concentration of NH4Cl solution is 10-1 mol below, the Freundlich equation can be used.The changes of apparent standard free energy (△Go), enthalpy (△Ho) and entropy (△So) illustrate that NHk fixation in soil is an endothermic adsorption and spontaneous reaction, and the process can be enhanced by a higher temperature and clay content in soil.The "proper value of NHk fixation by soil (K1×qm) increased with increasing clay content and temperature. The heat of NHk fixation in soil (Qm) confirms the conclusions made in this paper.展开更多
The effect of ammonium fixation on the estimation of soil microbial biomass N was studied bv thestandard fumigation-incubation (FI) and fumigation-extraction (FE) methods. NO_3-N content of fumigatedsoil changed littl...The effect of ammonium fixation on the estimation of soil microbial biomass N was studied bv thestandard fumigation-incubation (FI) and fumigation-extraction (FE) methods. NO_3-N content of fumigatedsoil changed little during incubation, while the fixed NH in soils capable of fixing NH increased withthe increase of K_2SO_4-extractable NH_4-N. One day fumigation increased both extractable NH and fixedNH. However, prolonged fumigation gave no further increase. One day fumigation caused significant loss ofNO_3-N, while prolonged fumigation caused no further loss. For soils tested, the net increases of fixed NHin fumigated soil equaled to 0-94% of NH_4-N flush measured by the FI method, and 1-74% of extractable Nmeasured by the FE method, depending on different soils. It is concluded that the ammonium fixation wasone of the processes taking place in soils during fumigation as well as incubation after fumigation and shouldnot be neglected in the estimation of microbial biomass nitrogen by either FI or FE method.展开更多
Dynamics of fixed NH in NH-treated soils incubated with glucose at 37±2℃ during the course ofincubation and factors affecting it were studied. Results showed that content of fixed NH in soil reached aminimun on ...Dynamics of fixed NH in NH-treated soils incubated with glucose at 37±2℃ during the course ofincubation and factors affecting it were studied. Results showed that content of fixed NH in soil reached aminimun on day 7 after incubation and then increased gradually regardless of the amount of glucose addedand the kind of soil tested. However, the amount of fixed NH released from the soil at the given time variedwith both the amount of glucose added and the kind of soil examined. In cases glucose was added at a rateof 10.0g C/kg soil, the amount of fixed NH retained in soil after 7 days of incubation was almost identicalto that found by Neubauer test. Addition of K￣+ depressed the release of fixed NH significantly. Based onthe results obtained a method for determining the content of available fixed NH in soils was proposed andthe amount of N as available fixed NH in two soils measured by this method on an area profile-depth basiswas presented.展开更多
文摘Fixed ammonium contents and fixation capacities of some representative cultivated soils collectedfrom 16 provinces of China were studied. Results showed that the contents of fixed ammonium in soilsranged from 35 to 573 mg N kg￣(-1), with an average of 198 mg N kg￣(-1). The content of fixed ammoniumcorrelated very significantly with mica content for tropical and subtropical soils, whereas this was not thecase for soils in the temperate zone. At the end of K-exhansting experiment the fixed ammonium contentincreased in most soils studied. However, it decreased in some temperate soils. Generally, fixation of addedNH could not be found either before or after K-exhausting experiment for highly weathered soils, includingtropical soils and soils derived from granite-gneiss or Quaternary red clays in the subtropic zonet while formost soils in the Yangtze River dalta the NH fixation capacity was rather high and increased siguificantlyin the K-exhausted soils.
基金Froject supported by the Scientific Research Foundation of Hunan Province(No.20012-2000C168).
文摘The contents, affecting factors, seasonal changes and availability of fixed ammonium in major types ofpaddy soils derived from different parent materials in Hunan Province, China, were studied using the Silva-Bremner method by laboratory and pot experiments. Results showed that the content of fixed ammoniumin the plough horizons ranged from 88.3 mg kg-1 to 388.1 mg kg-1, with 273.2 ± 77.7 mg kg-1 on average,accounting for 11.2% of total soil N on average. Content of fixed ammonium decreased in the order of newlylacustrine clayey paddy soil ＞ alluvial sandy paddy soil ＞ purple clayey paddy soil ＞ newly alluvial sandypaddy soil ＞ yellow clayey paddy soil ＞ reddish-yellow clayey paddy soil ＞ granitic sandy paddy soil. Therewere four distribution patterns of fixed ammonium in the profiles to 1-m depth, i.e., increase with the depth,decrease with increasing depth, no distinct change with the depth, and abrupt increase or decrease in somehorizon. Percentage of fixed ammonium in total N increased with the depth in most of the soils. Fixationof NH4+ by soil was higher at 30 ℃ than at 20 ℃ and 40 ℃, and continuous submergence benefited thefixation of NH4+ in newly alluvial sandy paddy soil, purple clayey paddy soil and alluvial sandy paddy soil,while alternating wetting and drying contributed to the fixation of NH4+ in yellow clayey paddy soil mostly.Fixed ammonium content in the test paddy soils was significantly correlated with ＜ 0.01 mm clay content(P ＜ 0.05), but not with ＜ 0.001 mm clay content, total N, organic N and organic matter. Fixed ammoniumcontent varied with rice growth stages. Application of N fertilizer promoted fixation of NH4+ by soil, and Nuptake by rice plant promoted release of fixed ammonium from the soil. Recently fixed ammonium in paddysoil after N fertilizer application was nearly 100% available to rice plant, while native fixed ammonium wasonly partly available, varying with the soil type and rice type.
文摘Ten soils collected from different parts of China were used in a series of experiments to study fixation of NH￣+_4 and K￣+ by soils. When K￣+ was added concurrently with or prior to NH￣+_4, the soils were found to fix more moles of NH￣+_4 than those of K￣+, irrespective of the mole ratios of NH￣+_4 to K￣+ that were added.
文摘Two soils with relatively high (Soil 1) and low (Soil 2) ammonium fixation capacities were used in thisstudy to extalne the effect of ammonium fixation on the determination of N mineralised from soil ndcrobialbiomass. organism suspellsioll was quantitatively introduced to Soil 1 at various rates. Both fumigation-incubation (FI) and fumigation-ext raction (FE ) met hods were used to t reat t he soil. The amount of ffeedNH4+-N increased with increasing rate of organism-N addition. A close correlation was found between theamoun of fixed aznmonium and the rate of organism-N addition. The net increso of fixed NH4+-N wereequivalent to 38% and 12% of the added organism-N for FI and FE treatments, respectively in this specificsoil. To provide isotopic evidence, 15N-labelled organism-N was added to Soils 1 and 2 at 121.4 mg N kg-1.In FI treatment, 22 and 3 mg N kg-1 of labelled N were found in the fraction of fixed NH4+-N in Soils 1 and2 respectively; while in FE treatment, 9 mg N kg-1 of labelled N was found in the fraction of fixed NH4+-Nin Soil 1 only. There was no labelled N in the fraction of fixed NH4+-N in Soil 2. In all of the unfumigated(check) soils, there was little or no labelled N in the fixed fractions, probably because the organism-N addedwas easily mineralized and nitrified. A mean of 0.64 for KN value, the fraction of N ndneralized in the killedmicrobial biomass, was obtained with inclusion of the net increase of fixed NH4+-N. The corresponding valuecalculated with exclusion of the net increase of fixed NH4+-N was 0.46. It was concluded that ammniumfixation was a problem in determination of KN, particularly for soils with a high ammonium fixation capacity.Results also showed that microbial biomass N measurement by FE method was less affected by ammoniumprocess than that by FI method.
文摘Effects of temperature and drying and wetting alternation(DWA)on ammonium fixation in manured loessial soil were studied by means of Batch Equilibrium with Varying concentration solutions of ammonium chloride,ammonium fixation time,and soil clay contents.The purpose of the research was to find out the pattern of ammonium fixation ted by the varying factors.The results showed a remarkable variation in ammonium fixation.Fixed ammonium increased with temperature and treatments of DWA.The ammonium fixation in manured loessial soil was characterized by the effect of temperature and DWA.
文摘Some thermodynamic properties of NHk fixation by loess soil in plowing and clay layers are discussed.The. results indicate that the four ion adsorption equations commonly used can describe the properties of NHk fixation in these soils under constant temperature. Among the four adsorption equations, the singlesurface Langmuir equation is the best. When the concentration of NH4Cl solution is 10-1 mol below, the Freundlich equation can be used.The changes of apparent standard free energy (△Go), enthalpy (△Ho) and entropy (△So) illustrate that NHk fixation in soil is an endothermic adsorption and spontaneous reaction, and the process can be enhanced by a higher temperature and clay content in soil.The "proper value of NHk fixation by soil (K1×qm) increased with increasing clay content and temperature. The heat of NHk fixation in soil (Qm) confirms the conclusions made in this paper.
文摘The effect of ammonium fixation on the estimation of soil microbial biomass N was studied bv thestandard fumigation-incubation (FI) and fumigation-extraction (FE) methods. NO_3-N content of fumigatedsoil changed little during incubation, while the fixed NH in soils capable of fixing NH increased withthe increase of K_2SO_4-extractable NH_4-N. One day fumigation increased both extractable NH and fixedNH. However, prolonged fumigation gave no further increase. One day fumigation caused significant loss ofNO_3-N, while prolonged fumigation caused no further loss. For soils tested, the net increases of fixed NHin fumigated soil equaled to 0-94% of NH_4-N flush measured by the FI method, and 1-74% of extractable Nmeasured by the FE method, depending on different soils. It is concluded that the ammonium fixation wasone of the processes taking place in soils during fumigation as well as incubation after fumigation and shouldnot be neglected in the estimation of microbial biomass nitrogen by either FI or FE method.
文摘Dynamics of fixed NH in NH-treated soils incubated with glucose at 37±2℃ during the course ofincubation and factors affecting it were studied. Results showed that content of fixed NH in soil reached aminimun on day 7 after incubation and then increased gradually regardless of the amount of glucose addedand the kind of soil tested. However, the amount of fixed NH released from the soil at the given time variedwith both the amount of glucose added and the kind of soil examined. In cases glucose was added at a rateof 10.0g C/kg soil, the amount of fixed NH retained in soil after 7 days of incubation was almost identicalto that found by Neubauer test. Addition of K￣+ depressed the release of fixed NH significantly. Based onthe results obtained a method for determining the content of available fixed NH in soils was proposed andthe amount of N as available fixed NH in two soils measured by this method on an area profile-depth basiswas presented.
