Fixed ammonium contents and fixation capacities of some representative cultivated soils collectedfrom 16 provinces of China were studied. Results showed that the contents of fixed ammonium in soilsranged from 35 to 5...Fixed ammonium contents and fixation capacities of some representative cultivated soils collectedfrom 16 provinces of China were studied. Results showed that the contents of fixed ammonium in soilsranged from 35 to 573 mg N kg￣(-1), with an average of 198 mg N kg￣(-1). The content of fixed ammoniumcorrelated very significantly with mica content for tropical and subtropical soils, whereas this was not thecase for soils in the temperate zone. At the end of K-exhansting experiment the fixed ammonium contentincreased in most soils studied. However, it decreased in some temperate soils. Generally, fixation of addedNH could not be found either before or after K-exhausting experiment for highly weathered soils, includingtropical soils and soils derived from granite-gneiss or Quaternary red clays in the subtropic zonet while formost soils in the Yangtze River dalta the NH fixation capacity was rather high and increased siguificantlyin the K-exhausted soils.展开更多
Some thermodynamic properties of NHk fixation by loess soil in plowing and clay layers are discussed.The. results indicate that the four ion adsorption equations commonly used can describe the properties of NHk fixati...Some thermodynamic properties of NHk fixation by loess soil in plowing and clay layers are discussed.The. results indicate that the four ion adsorption equations commonly used can describe the properties of NHk fixation in these soils under constant temperature. Among the four adsorption equations, the singlesurface Langmuir equation is the best. When the concentration of NH4Cl solution is 10-1 mol below, the Freundlich equation can be used.The changes of apparent standard free energy (△Go), enthalpy (△Ho) and entropy (△So) illustrate that NHk fixation in soil is an endothermic adsorption and spontaneous reaction, and the process can be enhanced by a higher temperature and clay content in soil.The "proper value of NHk fixation by soil (K1×qm) increased with increasing clay content and temperature. The heat of NHk fixation in soil (Qm) confirms the conclusions made in this paper.展开更多
文摘Fixed ammonium contents and fixation capacities of some representative cultivated soils collectedfrom 16 provinces of China were studied. Results showed that the contents of fixed ammonium in soilsranged from 35 to 573 mg N kg￣(-1), with an average of 198 mg N kg￣(-1). The content of fixed ammoniumcorrelated very significantly with mica content for tropical and subtropical soils, whereas this was not thecase for soils in the temperate zone. At the end of K-exhansting experiment the fixed ammonium contentincreased in most soils studied. However, it decreased in some temperate soils. Generally, fixation of addedNH could not be found either before or after K-exhausting experiment for highly weathered soils, includingtropical soils and soils derived from granite-gneiss or Quaternary red clays in the subtropic zonet while formost soils in the Yangtze River dalta the NH fixation capacity was rather high and increased siguificantlyin the K-exhausted soils.
文摘Some thermodynamic properties of NHk fixation by loess soil in plowing and clay layers are discussed.The. results indicate that the four ion adsorption equations commonly used can describe the properties of NHk fixation in these soils under constant temperature. Among the four adsorption equations, the singlesurface Langmuir equation is the best. When the concentration of NH4Cl solution is 10-1 mol below, the Freundlich equation can be used.The changes of apparent standard free energy (△Go), enthalpy (△Ho) and entropy (△So) illustrate that NHk fixation in soil is an endothermic adsorption and spontaneous reaction, and the process can be enhanced by a higher temperature and clay content in soil.The "proper value of NHk fixation by soil (K1×qm) increased with increasing clay content and temperature. The heat of NHk fixation in soil (Qm) confirms the conclusions made in this paper.
