The reaction of an aqueous solution of sodium molybdate with iron powder at low pH (～0.184) gives rise to the formation of a six-member Mo ring-shape cluster with an Fe (II) encapsulated at the center, [Na4(H2O)7][Fe...The reaction of an aqueous solution of sodium molybdate with iron powder at low pH (～0.184) gives rise to the formation of a six-member Mo ring-shape cluster with an Fe (II) encapsulated at the center, [Na4(H2O)7][Fe(OH)6Mo6O18](1), which is further linked to a remarkable three-dimensional network via sodium ions.展开更多
基金the State Key Lab. of Structural Chemistry, the Chinese Academy of Sciences and the State Personnel Ministry.
文摘The reaction of an aqueous solution of sodium molybdate with iron powder at low pH (～0.184) gives rise to the formation of a six-member Mo ring-shape cluster with an Fe (II) encapsulated at the center, [Na4(H2O)7][Fe(OH)6Mo6O18](1), which is further linked to a remarkable three-dimensional network via sodium ions.
