In order to more efficiently utilize gypsum to improve meadow alkali soil slightly salinized by soda and sulfate chloride, a total of 27 treatments were de- signed from the perspectives of field capacity, alkalinity, ...In order to more efficiently utilize gypsum to improve meadow alkali soil slightly salinized by soda and sulfate chloride, a total of 27 treatments were de- signed from the perspectives of field capacity, alkalinity, alkaline salt content, optimal irrigation, gypsum conversion, gypsum and soil treatment and improvement depth. The ions on the obtained filtrate were analyzed in terms of salts. The improving ef- ficiency of gypsum for meadow alkali soil was analyzed through comparing the con- tents of soluble salts in pre-improvement and post-improvement soil by reasoning and calculation. The results showed that, (1) the dissolved amount and conversion amount of gypsum were increased, and the soil alkalinity was decreased corre- spondingly with the increased irrigation amount. However, after reaching a certain extent, the linear relationships became unobvious gradually. Therefore, the irrigation amount should be arranged reasonably for different treatment. (2) Compared with those at low temperature, the dissolved amount of gypsum at high temperature was increased by 1.47-1.50 times, the release amount of exchangeable sodium was in- creased by 2.98-4.70 times, and the release amount of exchangeable magnesium was increased by 2.07-2.90 times. In overall, the improving efficiency of gypsum in summer was better. However, gypsum had two shortcomings in summer. First, a large amount of gypsum leaked away. Second, a large amount of exchangeable magnesium, along with exchangeable sodium, was substituted by gypsum. (3) Compared with the other two treatments, treatment B (mixing gypsum and top 20- cm soil) showed the best improving efficiency, and it was characterized by stepwise dealkalization from top to down. In addition, mixing gypsum and topsoil is more practical in the production.展开更多
Due to the complexity of earthwork allocation system for the construction of high concrete face rockfill dam,traditional allocation and planning are not able to function properly in the construction process with stron...Due to the complexity of earthwork allocation system for the construction of high concrete face rockfill dam,traditional allocation and planning are not able to function properly in the construction process with strong randomness.In this paper,the working mechanism of earthwork dynamic allocation system is analyzed comprehensively and a solution to fuzzy earthwork dynamic allocation is proposed on the basis of uncertain factors in the earthwork allocation of a hydropower project.Under the premise of actual situation and the experience of the construction site,an all-coefficient-fuzzy linear programming mathematical model with fuzzy parameters and constraints for earthwork allocation is established according to the structure unit weighted ranking criteria.In this way,the deficiency of certain allocation model can be overcome.The application results indicate that the proposed method is more rational compared with traditional earthwork allocation.展开更多
The construction of Three Gorges Project (TGP) is characterized by large construction scale,high construction intensity and complexity in technology.In view of various technical difficulties such as navigation in cons...The construction of Three Gorges Project (TGP) is characterized by large construction scale,high construction intensity and complexity in technology.In view of various technical difficulties such as navigation in construction period,two river closures,high-intensity concrete and earth-rock construction,high-intensity construction and demolition of RCC (roller compacted concrete) cofferdam in stage III and immediate navigation of double-line five-step shiplock after impoundment of reservoir,the scheme of river diversion during construction is adopted,namely "diversion in 3 stages,open channel navigation and cofferdam power generation".The practice and innovation achievements in river diversion during construction as well as earth-rock and concrete construction are presented emphatically.展开更多
Topography and land use affect soil organic carbon(SOC) storage, stabilization, and turnover, through several biogeochemical processes. This study investigated the aggregate composition and SOC content of bulk soils a...Topography and land use affect soil organic carbon(SOC) storage, stabilization, and turnover, through several biogeochemical processes. This study investigated the aggregate composition and SOC content of bulk soils and aggregates at different slope positions under different land uses in a typical karst catchment of southwestern China. Our results show that the proportion of macro-aggregates and the SOC content of bulk soils and aggregates at different slope positions decreased from the upper to the lower slope. The SOC content generally increased with an increase in the mean weight diameter and proportion of macro-aggregates under different land uses. Our results indicate that macro-aggregates in forest and grassland soils make a greater contribution to both aggregate composition and SOC content than that in arable land soils. Therefore,converting farmland to forest or grassland can facilitate the accumulation of macro-aggregates as well as the storage of SOC.展开更多
The leaching of rare earth elements (REEs) including cerium, lanthanum and neodymium from apatite concentrate obtained from iron ore wastes by nitric acid was studied. The effects of nitric acid concentration, soli...The leaching of rare earth elements (REEs) including cerium, lanthanum and neodymium from apatite concentrate obtained from iron ore wastes by nitric acid was studied. The effects of nitric acid concentration, solid to liquid ratio and leaching time on the recoveries of Ce, La and Nd were investigated using response surface methodology. The results showed that the acid concentration and solid to liquid ratio have significant effect on the leaching recoveries while the time has a little effect. The maximum REE leaching recoveries of 66.1%, 56.8% and 51.7% for Ce, La and Nd, respectively were achieved at the optimum leaching condition with 18% nitric acid concentration, 0.06 solid to liquid ratio and 38 min leaching time. The kinetics of cerium leaching was investigated using shrinking core model. It was observed that the leaching is composed of two stages. In the first stage a sharp increase in cerium leaching recovery was observed and at the longer time the leaching became slower. It was found that in the first stage the diffusion of reactants from ash layer is the rate controlling mechanism with an apparent activation energy of 6.54 kJ/mol, while in the second stage the mass transfer in the solution is the controlling mechanism.展开更多
The carbon pool stored in soil carbonate is comparable to the soil organic carbon.Therefore,secondary calcite precipitation in supersaturated catchment could be an important,yet poorly constrained,carbon sink within t...The carbon pool stored in soil carbonate is comparable to the soil organic carbon.Therefore,secondary calcite precipitation in supersaturated catchment could be an important,yet poorly constrained,carbon sink within the modern global carbon cycle.The chemical analysis of some dissolved species transported by rivers,such as elevated Sr/Ca and Mg/Ca ratios but also heavy stable Ca isotopic compositions,witness the formation of secondary calcite in rivers draining arid regions.However,in areas affected by active tectonics and rapid physical erosion,co-variations in the fluvial Sr/Ca and Mg/Ca ratios could also be related to incongruent carbonate weathering processes.Here,we present a model to assess the roles played by incongruent carbonate dissolution and secondary calcite precipitation in modern weathering processes.We tested and applied the model to rivers draining the Himalayan–Tibetan region.The results suggest that regional aridity in the drainage basin promotes carbon sequestration as secondary carbonate but that for a given runoff,incongruent dissolution of carbonate possibly related to rapid physical erosion amplifies such sequestration.The isotopic compositions(^(13)C/^(12)C and^(18)O/^(16)O)of detrital carbonate transported by the main rivers in South and South-East Tibet imply that around 1%of the suspended material transported by those rivers corresponds to secondary carbonate and can represent between 5%and 15%of the alkalinity flux.Most of these alkalinity transported as particulate material is,nevertheless related to the weathering of carbonate lithologies and is also subjected to dissolution prior its final storage in sedimentary basins.However,on glacial-interglacial timescale this will amplify the significant role of mountain weathering on climatic variations.展开更多
Granular HApB composite adsorbents, with dimensions of 4 mm × 4 mm, were prepared for the removal of lead from an aqueous solution. The effectiveness of the composites for Pb2+ removal from an aqueous solution w...Granular HApB composite adsorbents, with dimensions of 4 mm × 4 mm, were prepared for the removal of lead from an aqueous solution. The effectiveness of the composites for Pb2+ removal from an aqueous solution with different initial concentrations, adsorbent doses and reaction times were examined. The Langmuir isotherms, Freundlich isotherm models and pseudo-second order kinetic model were used in this analysis. It was found that the Langmuir model fitted the experimental data better than the Freundlich model, with a maximum adsorption capacity of 93.37 mg.g-1. The pseudo-second order kinetic model also fit the experiment data well with an adsorption capacity of 70.73 mg.g-1 after being reused for 3 times. Furthermore, the composites may possibly be used in processes for industrial water treatment.展开更多
Monthly discharge of four rivers with various permafrost coverage and little anthropogenic influence was used to identify effects of permafrost degradation during the last 50 years,which has occurred because of signif...Monthly discharge of four rivers with various permafrost coverage and little anthropogenic influence was used to identify effects of permafrost degradation during the last 50 years,which has occurred because of significant increases in air temperature in the river regions.The basins of the Shule,Heihe,Shiyang and upper Yellow Rivers in northwestern China have 73%,58%,33% and 43% permafrost coverage,respectively.There is snow cover in the basins and no rain to supply rivers during winter. The monthly recession coefficient(RC) in winter reflects groundwater conditions.The RC has increased obviously for the Shule and Heihe rivers with 73% and 58% permafrost coverage,respectively,but did not increase for the Shiyang River,and decreased insignificantly for the upper Yellow River,which had less permafrost coverage.There is a distinct positive relationship between RC and annual negative degree-day temperature(NDDT) at the meteorological stations in the basins with high permafrost coverage.These results imply that permafrost degradation due to climate warming affects hydrological processes in winter.The effect is obvious in the basins with high permafrost coverage but negligible in those with low permafrost coverage. Permafrost degradation increases infiltration,enlarges the groundwater reservoir,and leads to slow discharge recession.The result means that hydrological processes are affected strongly by permafrost degradation in river basins with high permafrost coverage,but less in river basins with less permafrost coverage.展开更多
Addition of clay-rich subsoil to sandy soil results in heterogeneous soil with clay peds (2-mm) or finely ground (〈 2 mm) clay soil (FG), which may affect the nutrient availability. The aim of this study was to...Addition of clay-rich subsoil to sandy soil results in heterogeneous soil with clay peds (2-mm) or finely ground (〈 2 mm) clay soil (FG), which may affect the nutrient availability. The aim of this study was to assess the effect of clay soil particle size (FG or peds) and properties on nutrient availability and organic C binding in sandy soil after addition of residues with low (young kikuyu grass, KG) or high (faba bean, FB) C/N ratio. Two clay soils with high and low smectite percentage, clay and exchangeable Fe and A1 were added to a sandy soil at a rate of 20% (weight/weight) either as FG or peds. Over 45 d, available N and P as well as microbial biomass N and P concentrations and cumulative respiration were greater in soils with residues of KG than FB. For soils with KG residues, clay addition increased available N and initial microbial biomass C and N concentrations, but decreased cumulative respiration and P availability compared to sandy soil without clay. Differences in measured parameters between clay type and size were inconsistent and varied with time except the increase in total organic C in the 〈 53 μm fraction during the experiment, which was greater for soils with FG than with peds. We concluded that the high exchangeable Fe and A1 concentrations in the low-smectite clay soil can compensate a lower clay concentration and proportion of smectite with respect to binding of organic matter and nutrients.展开更多
The Lower Cambrian on the Yangtze Platform in South China (internationally equivalent to the Nerreneuvian and 2nd series of the Cambrian) is valuable for understanding the early evolution of life, the global biogeoc...The Lower Cambrian on the Yangtze Platform in South China (internationally equivalent to the Nerreneuvian and 2nd series of the Cambrian) is valuable for understanding the early evolution of life, the global biogeochemical circles, and the major changes of the ocean. In particular, a precise radiometric calibration of the Lower Cambrian of this region is a critical realm in its multidisciplinary studies. A SHRIMP U-Pb geochronology study of the K-bentonite in the topmost Laobao Formation at the Pingyin section, Guizhou, South China yielded an age of 536±5 Ma (MSWD -- 0.75), suggesting that the K-bentonite here can be correlated with the intensely studied K-bentonite within the middle Zhongyicun Member (Bed 5) of the Zhujiaqing For- mation at the Meishucun section in Yunnan. Such a regional correlation result reveals that the Bed 5 K-bentonite also extends into deeper-water environments rather than being deposited merely in the shallow platform interior of the Yangtze Platform. The age of the K-bentonite at the Pingyin section also implies that its overlying polymetallic Ni-Mo layer should be younger than 536e5 Ma. Hence the previous placement of the Precambrian/Cambrian boundary at this layer is inappropriate. Combined with the results of stratigraphic correlations, it is suggested that the K-bentonites in the middle Zhongyicun Member of the Zhujiaqing Formation (or the equivalents) and the base of the Shiyantou Formation (or its equivalents), together with the polymetallic Ni-Mo layer, serve as three important marker beds. Their self-consistent radiometric ages have established an im- proved geochronologic framework for the Lower Cambrian in South China.展开更多
基金Supported by National Natural Science Foundation of China(41401559)Project of Hubei Provincial Science and Technology Department(2014CFB558)Project of Hubei Provincial Department of Education(D20141001)~~
文摘In order to more efficiently utilize gypsum to improve meadow alkali soil slightly salinized by soda and sulfate chloride, a total of 27 treatments were de- signed from the perspectives of field capacity, alkalinity, alkaline salt content, optimal irrigation, gypsum conversion, gypsum and soil treatment and improvement depth. The ions on the obtained filtrate were analyzed in terms of salts. The improving ef- ficiency of gypsum for meadow alkali soil was analyzed through comparing the con- tents of soluble salts in pre-improvement and post-improvement soil by reasoning and calculation. The results showed that, (1) the dissolved amount and conversion amount of gypsum were increased, and the soil alkalinity was decreased corre- spondingly with the increased irrigation amount. However, after reaching a certain extent, the linear relationships became unobvious gradually. Therefore, the irrigation amount should be arranged reasonably for different treatment. (2) Compared with those at low temperature, the dissolved amount of gypsum at high temperature was increased by 1.47-1.50 times, the release amount of exchangeable sodium was in- creased by 2.98-4.70 times, and the release amount of exchangeable magnesium was increased by 2.07-2.90 times. In overall, the improving efficiency of gypsum in summer was better. However, gypsum had two shortcomings in summer. First, a large amount of gypsum leaked away. Second, a large amount of exchangeable magnesium, along with exchangeable sodium, was substituted by gypsum. (3) Compared with the other two treatments, treatment B (mixing gypsum and top 20- cm soil) showed the best improving efficiency, and it was characterized by stepwise dealkalization from top to down. In addition, mixing gypsum and topsoil is more practical in the production.
基金Supported by the Science Fund for Creative Research Groups of National Natural Science Foundation of China(No.51021004)Tianjin Research Program of Application Foundation and Advanced Technology(No.12JCZDJC29200)National Key Technology R and D Program in the 12th Five-Year Plan of China(No.2011BAB10B06)
文摘Due to the complexity of earthwork allocation system for the construction of high concrete face rockfill dam,traditional allocation and planning are not able to function properly in the construction process with strong randomness.In this paper,the working mechanism of earthwork dynamic allocation system is analyzed comprehensively and a solution to fuzzy earthwork dynamic allocation is proposed on the basis of uncertain factors in the earthwork allocation of a hydropower project.Under the premise of actual situation and the experience of the construction site,an all-coefficient-fuzzy linear programming mathematical model with fuzzy parameters and constraints for earthwork allocation is established according to the structure unit weighted ranking criteria.In this way,the deficiency of certain allocation model can be overcome.The application results indicate that the proposed method is more rational compared with traditional earthwork allocation.
文摘The construction of Three Gorges Project (TGP) is characterized by large construction scale,high construction intensity and complexity in technology.In view of various technical difficulties such as navigation in construction period,two river closures,high-intensity concrete and earth-rock construction,high-intensity construction and demolition of RCC (roller compacted concrete) cofferdam in stage III and immediate navigation of double-line five-step shiplock after impoundment of reservoir,the scheme of river diversion during construction is adopted,namely "diversion in 3 stages,open channel navigation and cofferdam power generation".The practice and innovation achievements in river diversion during construction as well as earth-rock and concrete construction are presented emphatically.
基金supported jointly by the National Natural Science Foundation of China(4132501041571130042)the State’s Key Project of Research and Development Plan of China(2016YFA0601002)
文摘Topography and land use affect soil organic carbon(SOC) storage, stabilization, and turnover, through several biogeochemical processes. This study investigated the aggregate composition and SOC content of bulk soils and aggregates at different slope positions under different land uses in a typical karst catchment of southwestern China. Our results show that the proportion of macro-aggregates and the SOC content of bulk soils and aggregates at different slope positions decreased from the upper to the lower slope. The SOC content generally increased with an increase in the mean weight diameter and proportion of macro-aggregates under different land uses. Our results indicate that macro-aggregates in forest and grassland soils make a greater contribution to both aggregate composition and SOC content than that in arable land soils. Therefore,converting farmland to forest or grassland can facilitate the accumulation of macro-aggregates as well as the storage of SOC.
文摘The leaching of rare earth elements (REEs) including cerium, lanthanum and neodymium from apatite concentrate obtained from iron ore wastes by nitric acid was studied. The effects of nitric acid concentration, solid to liquid ratio and leaching time on the recoveries of Ce, La and Nd were investigated using response surface methodology. The results showed that the acid concentration and solid to liquid ratio have significant effect on the leaching recoveries while the time has a little effect. The maximum REE leaching recoveries of 66.1%, 56.8% and 51.7% for Ce, La and Nd, respectively were achieved at the optimum leaching condition with 18% nitric acid concentration, 0.06 solid to liquid ratio and 38 min leaching time. The kinetics of cerium leaching was investigated using shrinking core model. It was observed that the leaching is composed of two stages. In the first stage a sharp increase in cerium leaching recovery was observed and at the longer time the leaching became slower. It was found that in the first stage the diffusion of reactants from ash layer is the rate controlling mechanism with an apparent activation energy of 6.54 kJ/mol, while in the second stage the mass transfer in the solution is the controlling mechanism.
文摘The carbon pool stored in soil carbonate is comparable to the soil organic carbon.Therefore,secondary calcite precipitation in supersaturated catchment could be an important,yet poorly constrained,carbon sink within the modern global carbon cycle.The chemical analysis of some dissolved species transported by rivers,such as elevated Sr/Ca and Mg/Ca ratios but also heavy stable Ca isotopic compositions,witness the formation of secondary calcite in rivers draining arid regions.However,in areas affected by active tectonics and rapid physical erosion,co-variations in the fluvial Sr/Ca and Mg/Ca ratios could also be related to incongruent carbonate weathering processes.Here,we present a model to assess the roles played by incongruent carbonate dissolution and secondary calcite precipitation in modern weathering processes.We tested and applied the model to rivers draining the Himalayan–Tibetan region.The results suggest that regional aridity in the drainage basin promotes carbon sequestration as secondary carbonate but that for a given runoff,incongruent dissolution of carbonate possibly related to rapid physical erosion amplifies such sequestration.The isotopic compositions(^(13)C/^(12)C and^(18)O/^(16)O)of detrital carbonate transported by the main rivers in South and South-East Tibet imply that around 1%of the suspended material transported by those rivers corresponds to secondary carbonate and can represent between 5%and 15%of the alkalinity flux.Most of these alkalinity transported as particulate material is,nevertheless related to the weathering of carbonate lithologies and is also subjected to dissolution prior its final storage in sedimentary basins.However,on glacial-interglacial timescale this will amplify the significant role of mountain weathering on climatic variations.
文摘Granular HApB composite adsorbents, with dimensions of 4 mm × 4 mm, were prepared for the removal of lead from an aqueous solution. The effectiveness of the composites for Pb2+ removal from an aqueous solution with different initial concentrations, adsorbent doses and reaction times were examined. The Langmuir isotherms, Freundlich isotherm models and pseudo-second order kinetic model were used in this analysis. It was found that the Langmuir model fitted the experimental data better than the Freundlich model, with a maximum adsorption capacity of 93.37 mg.g-1. The pseudo-second order kinetic model also fit the experiment data well with an adsorption capacity of 70.73 mg.g-1 after being reused for 3 times. Furthermore, the composites may possibly be used in processes for industrial water treatment.
基金supported by National Basic Research Program of China(Grant No.2007CB411502)Key Research Project of the Knowledge Innovation Project of Chinese Academy of Sciences(Grant No.KZCX2-YW-301)+1 种基金Special Trade Project for Commonweal of Water Resource(Grant No.200701046)Hundred Talents Program of Chinese Academy of Sciences
文摘Monthly discharge of four rivers with various permafrost coverage and little anthropogenic influence was used to identify effects of permafrost degradation during the last 50 years,which has occurred because of significant increases in air temperature in the river regions.The basins of the Shule,Heihe,Shiyang and upper Yellow Rivers in northwestern China have 73%,58%,33% and 43% permafrost coverage,respectively.There is snow cover in the basins and no rain to supply rivers during winter. The monthly recession coefficient(RC) in winter reflects groundwater conditions.The RC has increased obviously for the Shule and Heihe rivers with 73% and 58% permafrost coverage,respectively,but did not increase for the Shiyang River,and decreased insignificantly for the upper Yellow River,which had less permafrost coverage.There is a distinct positive relationship between RC and annual negative degree-day temperature(NDDT) at the meteorological stations in the basins with high permafrost coverage.These results imply that permafrost degradation due to climate warming affects hydrological processes in winter.The effect is obvious in the basins with high permafrost coverage but negligible in those with low permafrost coverage. Permafrost degradation increases infiltration,enlarges the groundwater reservoir,and leads to slow discharge recession.The result means that hydrological processes are affected strongly by permafrost degradation in river basins with high permafrost coverage,but less in river basins with less permafrost coverage.
文摘Addition of clay-rich subsoil to sandy soil results in heterogeneous soil with clay peds (2-mm) or finely ground (〈 2 mm) clay soil (FG), which may affect the nutrient availability. The aim of this study was to assess the effect of clay soil particle size (FG or peds) and properties on nutrient availability and organic C binding in sandy soil after addition of residues with low (young kikuyu grass, KG) or high (faba bean, FB) C/N ratio. Two clay soils with high and low smectite percentage, clay and exchangeable Fe and A1 were added to a sandy soil at a rate of 20% (weight/weight) either as FG or peds. Over 45 d, available N and P as well as microbial biomass N and P concentrations and cumulative respiration were greater in soils with residues of KG than FB. For soils with KG residues, clay addition increased available N and initial microbial biomass C and N concentrations, but decreased cumulative respiration and P availability compared to sandy soil without clay. Differences in measured parameters between clay type and size were inconsistent and varied with time except the increase in total organic C in the 〈 53 μm fraction during the experiment, which was greater for soils with FG than with peds. We concluded that the high exchangeable Fe and A1 concentrations in the low-smectite clay soil can compensate a lower clay concentration and proportion of smectite with respect to binding of organic matter and nutrients.
基金supported by National Natural Science Foundation of China(Grant Nos.4096300240672053&40803016)
文摘The Lower Cambrian on the Yangtze Platform in South China (internationally equivalent to the Nerreneuvian and 2nd series of the Cambrian) is valuable for understanding the early evolution of life, the global biogeochemical circles, and the major changes of the ocean. In particular, a precise radiometric calibration of the Lower Cambrian of this region is a critical realm in its multidisciplinary studies. A SHRIMP U-Pb geochronology study of the K-bentonite in the topmost Laobao Formation at the Pingyin section, Guizhou, South China yielded an age of 536±5 Ma (MSWD -- 0.75), suggesting that the K-bentonite here can be correlated with the intensely studied K-bentonite within the middle Zhongyicun Member (Bed 5) of the Zhujiaqing For- mation at the Meishucun section in Yunnan. Such a regional correlation result reveals that the Bed 5 K-bentonite also extends into deeper-water environments rather than being deposited merely in the shallow platform interior of the Yangtze Platform. The age of the K-bentonite at the Pingyin section also implies that its overlying polymetallic Ni-Mo layer should be younger than 536e5 Ma. Hence the previous placement of the Precambrian/Cambrian boundary at this layer is inappropriate. Combined with the results of stratigraphic correlations, it is suggested that the K-bentonites in the middle Zhongyicun Member of the Zhujiaqing Formation (or the equivalents) and the base of the Shiyantou Formation (or its equivalents), together with the polymetallic Ni-Mo layer, serve as three important marker beds. Their self-consistent radiometric ages have established an im- proved geochronologic framework for the Lower Cambrian in South China.