水泥基土壤固化剂固化土的微观结构特征

采用扫描电镜和能谱分析测试手段,对水泥基土壤固化剂固化土的微观结构和固化剂的水化产物进行了研究.结果表明:水泥基土壤固化剂水化产物包括水化硅酸钙(C-S-H)凝胶、氢氧化钙、碳酸钙、三硫型水化硫铝酸钙(AFt)等物质,其中C-S-H凝胶、AFt是构成固化土强度的主体;六方棱柱状的AFt晶体和纤维状的C-S-H凝胶(Ⅰ)纵横交替搭接成网状结构,插入或填充于土颗粒孔隙之中;网络状或其他形状的C-S-H凝胶附着在土颗粒表面并将其包裹起来,或将相近的土颗粒黏结起来.水泥基土壤固化剂水化产物的填充、挤密、黏结等作用,使呈松散状态的土颗粒逐渐成为较致密的整体,从而改善了土体的工程技术性能.

水泥基土壤固化剂固化土的物理化学作用

采用击实试验、液塑限联合测定界限含水率试验、蜡封法测定干密度试验、二氧化碳气量法、交换性钠离子百分比试验等方法,结合黏土矿物组成与结构特点,研究了水泥基土壤固化剂固化土的物理化学作用。试验结果表明:随着固化剂剂量的增加,混合料的最大干密度增大,最优含水率降低;固化土混合料经过养护后,塑性指数降低,干密度增大,碳酸盐含量增加,交换性钠离子百分比升高;黏土矿物在强碱性和钙离子作用下被激活,形成各种水化硅酸盐和铝酸盐。研究认为:在土-固化剂-水-气系统中通过液相和气相向固相的转变以及各类水化产物的填充、挤密、胶结等作用,混合料逐渐形成较致密的整体;离子交换反应对土体的加固作用在后期起负效应;铝硅酸盐黏土矿物在强碱性和钙离子存在条件下被分解,参与水化硅酸盐和铝酸盐的反应。

土壤聚合物水泥

土壤聚合物水泥的原料和水化产物中存在大量含硅铝链的“无机聚合物” ,是一种新型胶凝材料。其性能优异 ,相对硅酸盐水泥而言 ,生产能耗低、几乎无污染 ,是环保型“绿色建筑材料”。介绍了土壤聚合物水泥的物理化学性能和基本生产工艺 。

土聚水泥的研究

以粘土为原料 ,在碱性激发剂和外加剂的作用下 ,获得了土壤聚合物水泥。采用XRD和SEM等手段 ,分析了土聚水泥的反应机理。结果表明 :经适当措施处理得到的土聚水泥 ,硬化浆体为沸石型凝胶 ,具有早强、高强、耐酸。

深层搅拌水泥土挡墙在基坑围护工程中的应用

本文通过工程实例，说明水泥挡土墙在基坑围护结构中的应用具有较好的效益。

碱胶凝材料形成的物理化学基础（Ⅰ）

碱胶凝材料是近年来较引人注目的新型材料之一。其特点为各种建筑性能良好；生产工艺简单；原料丰富；可以利用更多的工业废渣；减少环境污染。本文从理论上证明了元素周期表中第一族碱金属元素（或与第二族碱土金属元素共同）完全可以与第三、四族元素反应生成具有胶凝性质的碱－碱土铝硅酸盐的复合物。正是从这一观点出发，综合了碱胶凝材料产生的历史、现状、各种碱胶凝材料体系的性能，并从物理、化学的基础，介绍了碱胶凝材料的形成理论、水化生成物的特性和机理。其中介绍了较多的前苏联、俄罗斯和乌克兰共和国在这一材料领域研究的成果。

Assessment of strength development in cement-admixed artificial organic soil with GX07

To explore the stabilization effect of stabilizing agent GX07 on treating organic soil and the influence of organic matter on the strength development of stabilized soil,artificial organic soil with various organic matter content was obtained by adding different amounts of fulvic acid into non-organic clay,and then liquid-plastic limit tests were carried out on the artificial organic soil.Meanwhile,unconfined compressive strength(UCS) tests were performed on cement-only soil and composite stabilized soil,respectively.The test results indicate that the plastic limit of soil samples increases linearly,and the liquid limit increases exponentially as the organic matter content increases.The strength of stabilized soil is well correlated with the organic matter content,cement content,stabilizing agent content and curing time.When the organic matter content is 6%,as the cement content varies in the range of 10%-20%,the strength of cement-only soil increases from 88.5 to 280.8 kPa.Once 12.6% GX07 is added into the mix,the strength of stabilized soil is 4.93 times compared with that of cement-only soil.GX07 can obviously improve the strength of cemented-soil and has a good economic applicability.A strength model is proposed to predict strength development.

Effect of Alkaline-Stabilised Sewage Sludge on Extractable Organic Carbon and Copper in Soils

An incubation experiment was conducted to evaluate the potential for water contamination with sludge-derived organic substances and copper following land application of alkaline-stabilised sewage sludge. Twocontrasting sludge-amended soils were studied. Both soils were previously treated with urban and ruralalkaline biosolids separately at sludge application rates of 0, 30 and 120 t ha-1 fresh product. The air-driedsoil/sludge mixtures were wetted with distilled water, maintained at 40 % of water-holding capacity andequilibrated for three weeks at 4 ℃ before extraction. Subsamples were extracted with either distilled wateror 0.5 mol L-1 K2SO4 solution. The concentrations of organic C in the aqueous and chemical extractswere determined directly with a total organic carbon (TOC) analyser. The concentrations of Cu in the twoextracts were also determined by atomic absorption spectrophotometry The relationship between the twoextractable organic C fractions was examined, together with that between extractable organic C concentrationand extractable Cu concentration. Application of alkaline biosolids increased the concentrations of soil mobileorganic substances and Cu. The results are discussed in terms of a possible increase in the potential forleaching of sludge-derived organics and Cu in the sludge-amended soils.

Mechanized Tunneling in Soft Soils： Choice of Excavation Mode and Application of Soil-Conditioning Additives in Glacial Deposits

The history of the formation of the alpine region is affected by the activities of the glaciers, which have a strong influence on underground works in this area. Mechanized tunneling must adapt to the presence of sound and altered rock, as well as to inhomogeneous soil layers that range from permeable gravel to soft clay sediments along the same tunnel. This article focuses on past experiences with tunnel-boring machines （TBMs） in Switzerland, and specifically on the aspects of soil conditioning during a passage through inhomogeneous soft soils. Most tunnels in the past were drilled using the slurry mode （SM）, in which the application of different additives was mainly limited to difficult zones of high permeability and stoppages for tool change and modification. For drillings with the less common earth pressure balanced mode （EPBM）, continuous foam conditioning and the additional use of polymer and bentonite have proven to be successful. The use of conditioning additives led to new challenges during separation of the slurries （for SM） and disposal of the excavated soil （for EPBM）. If the disposal of chemically treated soft soil mate- rial from the earth pressure balanced （EPB） drive in a manner that is compliant with environmental legislation is considered early on in the design and evaluation of the excavation mode, the EPBM can be beneficial for tunnels bored in glacial deposits.

Weathering Characteristics of Sloping Fields in the Three Gorges Reservoir Area, China

For the purpose of understanding the weathering characteristics of surface layers in purple mudstone sloping fields of the Three Gorges Reservoir area of China, oxide content of major elements, composition of clay minerals, magnetic susceptibility, and difference in weathering characteristics of surface layers under different slope gradients were determined. The results showed that the oxide content of Si, Al, and Fe ranged from 60% to 75% and the weathering coefficient with depth showed no trend along the slope gradient. Also, for gentle (10° and 15°) and intermediate (25° and 40°) slopes the clay relative diffraction peak for kaolinite at the surface between 0-10 cm and 10-20 cm declined with an increase in slope gradient, while the relative diffraction peak for kaolinite in weathered layers on steep slopes (50° and 60°) disappeared altogether. Magnetic susceptibility decreased with increasing depth and, for a given depth layer, decreased with an increase in slope gradient. Analysis of the oxide content, weathering coefficients, clay minerals, and magnetic susceptibility showed that in the Three Gorges Reservoir area, the pedogenesis of the weathering layer in purple mudstone sloping fields was weak with weaker soil formation going from gentle slope to steep slope.

Sewage Sludge Usage in Cotton Crop: I. Influence on SoilProperties

A field experiment with cotton was conducted on a well drained, calcareous, clay loamy Typic Xerochreptto investigate the utility of sewage sludge as a partial substitute for fertilizers and the influence of its application on the basic soil properties and heavy metal concentrations. The experimental design was completelyrandomized blocks with five treatments replicated four times each. Sewage sludge came from the treatmentplant of the municipality of Volos, Central Greece, with the following characteristics: organic matter content36.6 %, pH (H2O 1:5) 6.89, CaCO3 53.4 g kg-1 , total N 26.5 g kg--1, total P 33.5 g kg--1 , and total K 968mg kg--1 soil. Heavy metal concentrations were Cd 5.24, Pb 442, Ni 38, Cu 224, Zn 1 812, and Mn 260 mgkg--1 dry weight, respectively. The soil was high in potassium (K) and poor in available phosphorus (P). Theresults showed that sewage sludge application increased cotton yield and K and P concentrations in cottonleaves. Soil pH was reduced in the case of higher sewage sludge rate. Electrical conductivity, organic mattercontent, total N, and available P were significantly increased. Total concentrations of Zn, Pb, and Cu wereslightly increased. DTPA-extractable Zn, Cu and Mn were also significantly increased. Available forms ofall heavy metals, except Cd, were significantly correlated with organic matter content in a positive way andnegatively with soil pH.

Key parameters controlling electrical resistivity and strength of cement treated soils

The improvement of question soils with cement shows great technical, economic and environmental advantages. And interest in introducing electrical resistivity measurement to assess the quality of cement treated soils has increased markedly recently due to its economical, non-destructive, and relatively non-invasive advantages. This work aims to quantify the effect of cement content （aw）, porosity （nt）, and curing time（T） on the electrical resistivity （p） and unconfined compression strength （UCS） of cement treated soil. A series of electrical resistivity tests and UCS tests of cement treated soil specimen after various curing periods were carried out. A modified Archie empirical law was proposed taking into account the effect of cement content and curing period on the electrical resistivity of cement treated soil. The results show that nt/（aw·T） and nt/（aw·T^1/2） ratio are appropriate parameters to assess electrical resistivity and UCS of cement treated soil, respectively. Finally, the relationship between UCS and electrical resistivity was also established.

Effect of clay content to the strength of gravel soil in the source region of debris flow

The production of runoff in the source area of a debris flow is the consequence of a reduction in soil strength. Gravel soil is widely distributed in the source region, and the influence of its clay content on soil strength is one of the important questions regarding the formation mechanism of debris flows. In this paper, the clay content in gravel soil is divided into groups of low clay content(1%, 2, 5%), moderate clay content(3.75%, 5.00%, 6.25%, 7.5%) and high clay content(10.0%, 12.5%, 15%). Tests of the unconsolidated undrained shear strength and consolidated drained shear strength were performed. The unconsolidated undrained shearing(UU) experiment simulates the rapid shear failure of loose gravel soil under the conditions of brief heavy rainfall. The consolidated drained shearing(CD) experiment simulates creep failure of consolidated sediment during extended rainfall. The pore water pressure first increased and then decreased as the clay content increased, and the increase in pore pressure was relatively high in the gravel soil sample when the clay content is in the range of 3.25-7.50%, and stress in the gravel soil is relatively low for a moderate clay content. Gravelly soils with a moderate clay content are moreprone to debris-flow initiation. This paper presents a mathematical formula for the maximum shear stress and clay content of gravel soil under two conditions. The key processes whereby the soil fails and triggers a debris flow—volume contraction of soil, expansion of clay soil, and rise of pore pressure―cause reductions in the soil friction force and enhancement of the water content in the clay particles, and subsurface erosion of soil reduces the soil viscosity, which eventually reduces the soil strength so that the soil loses its stability, liquefies and generates a debris flow.

Scaling of Soil Carbon,Nitrogen,Phosphorus and C:N:P Ratio Patterns in Peatlands of China

Inspired by the importance of Redfield-type C:N:P ratios in global soils,we looked for analogous patterns in peatlands and aimed at deciphering the potential affecting factors.By analyzing a suite of peatlands soil data(n = 1031),mean soil organic carbon(SOC),total nitrogen(TN) and total phosphorous(TP) contents were 50.51%,1.45% and 0.13%,respectively,while average C:N,C:P and N:P ratios were 26.72,1186.00 and 46.58,respectively.C:N ratios showed smaller variations across different vegetation coverage and had less spatial heterogeneity than C:P and N:P ratios.No consistent C:N:P ratio,though with a general value of 1245:47:1,was found for entire peatland soils in China.The Northeast China,Tibet,Zoigê Plateau and parts of Xinjiang had high soil SOC,TN,TP,and C:P ratio.Qinghai,parts of the lower reaches of the Yangtze River,and the coast zones have low TP and N:P ratio.Significant differences for SOC,TN,TP,C:N,C:P and N:P ratios were observed across groups categorized by predominant vegetation.Moisture,temperature and precipitation all closely related to SOC,TN,TP and their pairwise ratios.The hydrothermal coefficient(RH),defined as annual average precipitation divided by temperature,positively and significantly related to C:N,C:P and N:P ratios,implying that ongoing climate change may prejudice peatlands as carbon sinks during the past 50 years in China.

Effects of Composted and Thermally Dried Sewage Sludges on Soil and Soil Humic Acid Properties

The effect of annual additions of composted sewage sludge (CS) and thermally dried sewage sludge (TS) at 80 t ha-1 on soil chemical properties was investigated for three years in a field experiment under semiarid conditions. Humic acids (HAs) isolated by conventional procedures from CS, TS, and unamended (SO) and sludge amended soils were analysed for elemental (C, H, N, S and O) and acidic functional groups (carboxylic and phenolic) and by ultraviolet-visible, Fourier transform infrared and fluorescence spectroscopies. With respect to CS, TS had similar pH and total P and K contents, larger dry matter, total organic C, total N and C/N ratio and smaller ash content and electrical conductivity. Amendment with both CS and TS induced a number of modifications in soil properties, including an increase of pH, electrical conductivity, total organic C, total N, and available P. The CS-HA had greater O, total acidity, carboxyl, and phenolic OH group contents and smaller C and H contents than TS-HA. The CS-HA and TS-HA had larger N and S contents, smaller C, O and acidic functional group contents, and lower aromatic polycondensation and humification degrees than SO-HA. Amended soil-HAs showed C, H, N and S contents larger than SO-HA, suggesting that sludge HAs were partially incorporated into soil HAs. These effects were more evident with increasing number of sludge applications.

Effect of Irradiated Sewage Sludge on Crop Yield and Soil Nitrogen

A field experiment was conducted to study the feasibility of irradiated and non-irradiated sewage sludge as a fertilizer for the growth of wheat and rice. The irradiated and non-irradiated sewage sludge were applied at rates of 0 (CK), 75, 150, 225 and 300 kg N ha-1 for wheat, and 0 (CK), 112.5, 225, 337.5 and 450 kg N ha-1 for rice, respectively. (NH4)2SO4 at a rate of 150 kg N ha-1 for wheat, and 225 kg N ha-1 for rice were added to the control treatments. Additionally, 20 kg 15N ha-1 in the form of (NH4)2SO4 was added to each treatment for wheat to study the effect of sewage sludge on chemical nitrogen fertilizer recovery. The results showed that the irradiation of sewage sludge by gamma ray at a dosage of 5 kGy increased crop yield by 11%～27% as compared to the non-irradiated treatments. Irradiation stimulated mineralization of organic nitrogen in the sludge and improved seedling growth. It was found that addition of irradiated sludge could reduce the leaching loss of chemical nitrogen fertilizer. Both irradiated and non-irradiated sewage sludge could increase the content of soil total nitrogen. Based on the preliminary results, it was concluded that irradiated sewage sludge could partly substitute for chemical nitrogen fertilizer in crop production.

Pull-out tests and slope stability analyses of nailing systems comprising single and multi rebars with grouted cement

The pull-out capacities for soil nailing systems comprising of one single 29 mm diameter(type A) and four 16 mm diameter(type B) rebars with grouted cement were examined.A field test and numerical analysis for the type A and type B systems were carried out to investigate the pull-out capacities and the slope stability reinforcement efficiency in soil and rock slopes.The results of the pull-out tests show the mobilized shear force and load transfer characteristics with respect to soil depth.The load-displacement relationship was examined for both type A and type B systems.Slope stability analyses were carried out to study the relationships between soil and nail reinforcement and bending stiffness as well as combined axial tension and shear forces.Factors of safety were calculated in relation to the number of nails and their outside diameters.Both soil and rock slopes were included in this evaluation.

Evaluating the Effectiveness of Best Management Practices in Gilgel Gibe Basin WatershedmEthiopia

Soil erosion/sedimentation is an immense problem threatening the live storage capacity of dam reservoirs in Ethiopia. This in turn reduces the power generation capacities of hydropower reservoirs. Therefore, studies which give insight into soil erosion/sedimentation mechanisms and mitigation methods is important. The high rate of soil erosion/sedimentation threats the lifespan of Gilgel Gibe-I hydropower reservoir, The problem of sedimentation in Gilgel Gibe-I will also affect Gilgel Gibe-2 which uses the water released from Gilgel Gibe-1. The sustainability of these hydropower plants needs catchment management practices that will reduce soil erosion. This paper presents the results of monthly and yearly sediment yield simulations experiments conducted for Gilgel Gibe-1 under different BMP （best management practice） scenarios. The scenarios applied in this paper are： （1） maintaining existing conditions; （2） introducing filter strips; （3） applying stone/soil bunds; （4） reforestation. The SWAT （soil and water assessment tool） was used to model soil erosion, identify soil erosion prone areas and assess the impact of BMPs on sediment reduction via simulations. The simulation results showed that applying filter strips, stone bunds and reforestation scenarios could reduce the current sediment yields at soil erosion prone areas and at the outlet of the catchment area which is the inlet to Gilgel Gibe-I reservoir.

深基坑支护中常见问题及处理对策

随着当前阶段我国工程规模以及工程结构的不断扩大和复杂化,在当前的工程建设过程中规范化的深基坑支护工作往往能够有效的保证工程的安全性以及在实施工程过程中的稳定性,为我国的工程建设的可持续发展奠定坚实的基础。在当前来看深基坑支护的作用主要是为了保证在工程结构安装过程中的结构稳定性,同时避免其出现一定的结构变形等现象。但是从目前深基坑支护实施过程中非常容易出现周边建筑的沉降现象等,影响到深基坑支护的治疗。因此本文笔者主要基于上述原因来深入分析深基坑支护在实际的建设过程中的常见问题以及具体的问题处理对策。

Changing Concentrations of Heavy Metals in Stream Water as a Result of Slurry Application to Soil

Several studies focused on nutrients have shown that land use and management practices have a strong influence on stream chemistry. Much less is known about the relationship between heavy metal concentrations in stream water and land use. We compared the variability of trace element concentrations in the stream of a catchment exposed to different types of management practices and land use. This is a small catchment with previous agricultural diffuse and accidental pollution mainly due to the spreading of slurry. The agricultural land was reforested in July 1998. The concentrations of Fe, Mn, Cu and Zn in dissolved phase from surface water samples collected at the catchment outlet were determined over a period of approximately six years. The results suggest that dissolved metal concentrations, especially Cu and Mn, are controlled by the land use and management practices. The median concentrations of studied metals were the highest in the agricultural period. It was also during this period when they all presented the highest concentration peaks, coinciding with a time of heavy application of manure to the soil. Dissolved Fe and Mn showed high dependence of flow rate, whereas Cu and Zn concentrations seemed to be independent of flow.