Effects of organic acids (oxalic, acetic, and citric) on adsorption characteristics of Cadmium (Cd) on soil clay minerals (kaolinite, goethite, and bayerite) were studied under different concentrations and different p...Effects of organic acids (oxalic, acetic, and citric) on adsorption characteristics of Cadmium (Cd) on soil clay minerals (kaolinite, goethite, and bayerite) were studied under different concentrations and different pH values. Although the types of organic acids and minerals were different, the effects of the organic acids on the adsorption of Cd on the minerals were similar, i.e., the amount of adsorbed Cd with an initial solution pH of 5.0 and initial Cd concentration of 35 mg L-1 increased with increasing concentration of the organic acid in solution at lower concentrations, and decreased at higher concentrations. The percentage of Cd adsorbed on the minerals in the presence of the organic acids increased considerably with increasing pH of the solution. Meanwhile, different Cd adsorption in the presence of the organic acids, due to different properties on both organic acids and clay minerals, on kaolinite, goethite, or bayerite for different pHs or organic acid concentrations was found.展开更多
The characteristics of the reflectance spectra of clay minerals and their influences on the reflectancespectra of soils are dealt with in the paper. The results showed that dominant clay minerals in soils couldbe dist...The characteristics of the reflectance spectra of clay minerals and their influences on the reflectancespectra of soils are dealt with in the paper. The results showed that dominant clay minerals in soils couldbe distinguished in light of the spectral-form parameters of the reflectance spectra of soils, thus making itpossible to develop a quick method to determine clay minerals by means of reflectance spectra of soils in thelab. and providing a theoretic basis for retnote sensing of clay minerals in soils with a high resolution imagingspectrometer.展开更多
A tillage experiment, consisting of moldboard plow (MP), ridge tillage (RT), and no-tillage (NT), was performed in a randomized complete block design with four replicates to study the effect of 3-year tillage ma...A tillage experiment, consisting of moldboard plow (MP), ridge tillage (RT), and no-tillage (NT), was performed in a randomized complete block design with four replicates to study the effect of 3-year tillage management on SOC content and its distribution in surface layer (30 cm) of a clay loam soil in northeast China. NT did not lead to significant increase of SOC in topsoil (0-5 cm) compared with MP and RT; however, the SOC content in NT soil was remarkably reduced at a depth of 5-20 cm. Accordingly, short-term (3-year) NT management tended to stratify SOC concentration, but not necessarily increase its storage in the plow layer for the soil.展开更多
Based on three typical mediums(sandy loam, loam and sandy clay loam) in Hebei Plain, this paper designs phreatic evaporation experiments under different lithology and phreatic depth. Based on the analysis of experimen...Based on three typical mediums(sandy loam, loam and sandy clay loam) in Hebei Plain, this paper designs phreatic evaporation experiments under different lithology and phreatic depth. Based on the analysis of experimental data, the phreatic evaporation law and influencing factors of three mediums were studied. The results showed that:(1) The shallower the phreatic depth, the larger the phreatic evaporation.(2) Sandy clay loam has the biggest response to the increase of the phreatic depth, sandy loam is the second and loam is the smallest.(3) The limit depth of phreatic evaporation of sandy clay loam is about 3 m and that of loam and sandy loam is about 2 m and 3 m, seperately.(4) By fitting the daily evaporation of phreatic water and phreatic depth, the results showed that sandy loam and sandy clay loam are exponential functions and loam is power functions.展开更多
Soil organic carbon (SOC) plays an important role in global carbon cycles.Large spatial variations in SOC contents result in uncertain estimates of the SOC pool and its changes.In the present study,the key variables e...Soil organic carbon (SOC) plays an important role in global carbon cycles.Large spatial variations in SOC contents result in uncertain estimates of the SOC pool and its changes.In the present study,the key variables explaining the SOC contents of croplands (CPs) and non-croplands (NCPs) in Chinese provinces were investigated.Data on SOC and other soil properties (obtained from the Second National Soil Survey conducted in the late 1970s to the early 1990s),climate parameters,as well as the proportion of the CP to the total land area (Pcp) were used.SOC content variations within a province were larger than those among provinces.Soil clay and total phosphorus content,ratio of annual precipitation to mean temperature,as well as Pcp were able to explain 75% of the SOC content variations in whole soil samples.Soil pH,mean temperature during the growing season from May to October,and mean annual wind velocity were able to explain 63% of the SOC content variations in NCP soils.Compared with NCP soils,CP soils had lower SOC contents,with smaller variations within and among provinces and lower C/N ratios.Stepwise regression showed that the soil clay content was a unique factor significantly correlated with the SOC content of CP soils.However,this factor only explained 24% of the variations.This result suggested that variables related to human activities had greater effects on SOC content variations in CP soils than soil properties and climate parameters.Based on SOC contents directly averaged from soil samples and estimated by regression equations,the total SOC pool in the topsoil (0-20 cm) of China was estimated at 60.02 Pg and 57.6 Pg.Thousands of years of intensive cultivation in China resulted in CP topsoil SOC loss of 4.34-4.98 Pg.展开更多
Ectomycorrhizal fungi, including Cenococcum geophilum SIV (Cg SIV), and Pisolithus tinctorius 2144 (Pt 2144), 441 (Pt 441) and XC1 (Pt XC1), were cultured in Pachlewski liquid medium with H2KPO4,KCl- saturated vermicu...Ectomycorrhizal fungi, including Cenococcum geophilum SIV (Cg SIV), and Pisolithus tinctorius 2144 (Pt 2144), 441 (Pt 441) and XC1 (Pt XC1), were cultured in Pachlewski liquid medium with H2KPO4,KCl- saturated vermiculite and mica as K sources, respectively, to investigate the mechanism of K absorption and mobilization by the fungi. Fungal growth rate, K absorption and mobilization varied significantly among the fungal species. Faster growth and greater K accumulation in Pt XC1 than Pt 2 144, Pt 441 and Cg siv were observed. Ectomycorrhizal fungi depressed HCl-soluble K in minerals after successive extractions by water and NH4OAc. Ratio of the total amount of K, including water-, NH4OAc- and HCI-soluble K, lost from substrates to the K accumulated in fungal colonies was less than 60%. These reveal that the ectomycorrhizal fungi could utilize K in interlayer and structural pools, which are usually unavailable for plants in short period. Large differences in the depletion of K in interlayer and structural pools by fungi were observed at fungal harvest. Taking into account the nutrient absorption by ectomycorrhizal fungi in symbionts and the direct contact between hyphae and soils, the fungi species colonized on the root surfaces seemed to be related to the effectiveness of mycorrhizas to utilize K in soils. Ectomycorrhizal fungi differed in the efflux of protons and oxalate. Pt XC1 was observed to have greatest ability to effuse protons and oxalate among the fungi adopted in the experiment. Furthermore, the higher the concentrations of protons and oxalate in the liquid culture solutions, the larger the depletion of K in interlayer and structural pools in minerals by fungi. Protons could replace interlayer K and chelation of oxalate with Fe and Al in crystal lattice could cause weathering of clay minerals. So, protons and oxalate produced by ectomycorrhizal fungi might play an important role in K mobilization in these two pools.展开更多
One dimensional and triaxial compression tests of air-dried and oven-dried Fujinomori clay and Pisa clay were carried out. Water content is less than 4.5% and 1.0% for air-dried and oven-dried clay specimens, respecti...One dimensional and triaxial compression tests of air-dried and oven-dried Fujinomori clay and Pisa clay were carried out. Water content is less than 4.5% and 1.0% for air-dried and oven-dried clay specimens, respectively. In all tests, axial strain rate was changed stepwise many times and drained creep tests were performed several times during monotonic loading at a constant strain rate. Global unloading (and also reloading in some tests) was applied during which creep loading tests were performed several times. Cyclic loading with small stress amplitude and several cycles was also performed to calculate the modulus of elasticity of the clay in tests. Local displacement transducer was used in triaxial compression test to increase measuring accuracy of axial strain. The results show that air-dried and oven-dried clay have noticeable viscous properties; during global unloading, creep deformation changes from positive to negative, i.e. there exist neutral points (zero creep deformation or no creep deformation point) in global unloading part of strain-stress curve; viscous property of Fujinomori clay decreases when water content decreases, i.e. viscous property of air-dried Fujinomori clay is more significant than that of oven-dried Fujinomori clay.展开更多
Two time-domain reflectometry (TDR) systems and a new impedance measuring instrument, Thetaprobe,which are based on determination of soil dielectric constant, were used to measure water content of clayeyred soil to er...Two time-domain reflectometry (TDR) systems and a new impedance measuring instrument, Thetaprobe,which are based on determination of soil dielectric constant, were used to measure water content of clayeyred soil to eraluate the accuracy of these instruments. The results indicated that these instruments shouldbe carefUlly re-calibrated before being applied in clayey red soil. With a new calibration curve fed into one ofthe TDR systems tested, nase system, the measured data compared well with tho8e by standard oven-dryingmethod.展开更多
The clay minerals of more than 200 soil samples collected from various sites of Fujian Province were studied by the X-ray diffraction method and transmission electron microscopy to study their distribution and evoluti...The clay minerals of more than 200 soil samples collected from various sites of Fujian Province were studied by the X-ray diffraction method and transmission electron microscopy to study their distribution and evolution. Montmorillonite was found in coastal solonchak, paddy soils derived from marine deposit, lacustrine deposit and river deposit, and some latentic red soil, red soil and yellow soil with a low weathering degree. Chlorite existed mainly in coastal solonchak and paddy soil developed from marine deposit. 1.4 nm intergradient mineral appeared frequently in yellow soil, red soil and latentic red soil. The content of l.4 nm intergradient mineral increased with the decrease of weathering degree from latentic red soil to red soil to yellow soil. Hydrous micas were more in coastal solonchak, paddy soils derived from marine deposit, lacustrine deposit and river deposit, and purple soil from purple shale than in other soils. Kaolinite was the most important clay mineral in the soils in this province. The higher the soil weathering degree, the more the kaolinite existed. From yellow soil to red soil to latentic red soil, kaolinite increased gradually. Kaolinite was the predominant clay mineral accompanied by few other minerals in typical latentic red soil. Tubular halloysite was a widespread clay mineral in soils of Fujian Province with varying quantities. The soil derived from the parent rocks rich in feldspar contained more tubular halloysite. Spheroidal halloysite was found in a red soil and a paddy soil developed from olivine basalt. Gibbsite in the soils in this district was largely 'primary gibbsite' which formed in the early weathering stage. Gibbsite decreased with the increase of weathering degree from yellow soil to red soil to latentic red soil. Goethite also decreased in the same sequence while hematite increased.展开更多
The van Genuchten (vG) function is often used to describe the soil water retention curve (SWRC) of unsaturated soils and fractured rock. The objective of this study was to develop a method to determine the vG model pa...The van Genuchten (vG) function is often used to describe the soil water retention curve (SWRC) of unsaturated soils and fractured rock. The objective of this study was to develop a method to determine the vG model parameter m from the fractal dimension. We compared two approaches previously proposed by van Genuchten and Lenhard et al. for estimating m from the pore size distribution index of the Brooks and Corey (BC) model. In both approaches we used a relationship between the pore size distribution index of the BC model and the fractal dimension of the SWRC. A dataset containing 75 samples from the UNSODA unsaturated soil hydraulic database was used to evaluate the two approaches. The statistical parameters showed that the approach by Lenhard et al. provided better estimates of the parameter m. Another dataset containing 72 samples from the literature was used to validate Lenhard's approach in which the SWRC fractal dimension was estimated from the clay content. The estimated SWRC of the second dataset was compared with those obtained with the Rosetta model using sand, silt, and clay contents. Root mean square error values of the proposed fractal approach and Rosetta were 0.081 and 0.136, respectively, indicating that the proposed fractal approach performed better than the Rosetta model.展开更多
Offshore jacket-type platforms are attached to the seabed by long batter piles. In this paper, results from a finite element analysis, verified against experimental data, are used to study the effect of the pile's in...Offshore jacket-type platforms are attached to the seabed by long batter piles. In this paper, results from a finite element analysis, verified against experimental data, are used to study the effect of the pile's inclination angle, and its interaction with the geometrical properties of the pile and the geotechnical characteristics of the surrounding soil on the behavior of the inclined piles supporting the jacket platforms. Results show that the inclination angle is one of the main parameters affecting the behavior of an offshore pile. We investigated the effect of the inclination angle on the maximum von Mises stress, maximum von Mises elastic strain, maximum displacement vector sum, maximum displacement in the horizontal direction, and maximum displacement in the vertical direction. Results indicate that the pile's operationally optimal degree of inclination is approximately 5°. By exceeding this value, the instability in the surrounding soil under applied loads grows extensively in all the geotechnical properties considered. Cohesive soils tend to display poorer results compared to grained soils.展开更多
Consecutive differential movements of ground to the dryness and the rehydration of the sols are irregular movements of ground related to the phenomenon of withdrawal-swelling. By risk of withdrawal-swelling, one under...Consecutive differential movements of ground to the dryness and the rehydration of the sols are irregular movements of ground related to the phenomenon of withdrawal-swelling. By risk of withdrawal-swelling, one understands the phenomenon "natural" likely to occur, with a probability of more or less large occurrence. For the phenomenon of withdrawal-swelling of the argillaceous grounds, one will speak about strong, average or weak risk. This article returns within the framework's study of risk withdrawal-swelling or dryness-humidification of the argillaceous Mames of the area of Ouled Fayet and Cheraga of Algiers.展开更多
The changes of clay mineral association after high-gradient magnetic separation (HGMS) treatment, and the effects of chemical and physical technologies on concentrating Fe oxides for main soils in central and southern...The changes of clay mineral association after high-gradient magnetic separation (HGMS) treatment, and the effects of chemical and physical technologies on concentrating Fe oxides for main soils in central and southern China were investigated by means of X-ray diffraction (XRD) and chemical analysis methods. Results indicated that the concentrating times of Fe oxides by HGMS treatment were the largest for 0.2-2 μmsize fractions in the examined soils. For the soils in which 2: 1 phyllosilicates were dominant, concentrating times of iron oxides by HGMS treatment were larger than by 5 mol L-1 NaOH treatment. Phyllosili-cates were decreased after HGMS treatment; however, the decrease was less than that of kaorolinite. The goet bite / (goethite + hematie) values in Fe oxides of the soils kept virtually constant after HGMSt reatment.展开更多
Soil stabilization has been found to be very effective in upgrading the bearing capacity of weak soils for construction purposes. The stabilizing agent, for cost efficiency, ought to provide a cheaper alternative to o...Soil stabilization has been found to be very effective in upgrading the bearing capacity of weak soils for construction purposes. The stabilizing agent, for cost efficiency, ought to provide a cheaper alternative to other possible processes. With the rapid industrialization efforts around the globe, enormous quantities of waste materials are generated and there has not been adequate mechanism for recycling and re-use of such wastes to reduce the consequent environmental problems and hazardous situations created as a result. The objective of the study is to upgrade expansive soils from Eke Obinagu, Ugwuaji in Enugu State and Egbede in Abia State Nigeria, as constructions material using RHA (rice husk ash). Expansive clay soils were mixed with this ash, remolded and tested to examine the effect on the OMC (optimum moisture content) and the CBR (California Bearing Ratio). The characterization of the soils was done in accordance with BS1377 and 1990b, with respect to their engineering properties which include OMC, MDD, Soaked CBR, Liquid Limit, Classification and Sieve Analysis. The rice husk was burnt and prepared in a cylindrical incinerator to form the ash. The results of classification showed A-7-5, A-6, A-2-7 soils for Eke Obinagu, Egbede and Ugwuaji, respectively. The CBR values showed increase from 5% to 29%, 7% to 13% and 5% to 23% for A-7-5, A-6 ~nd A-2-7 respectively at optimal value of 17.5% stabilization. There was also an appreciable increase in the OMC values from 15% to 33%, 14% to 25% and 15% to 31% for A-7-5, A-6 and A-2-7 soils respectively at 17.5% stabilization. Empirical models based on Scheffe's model were developed with the experimental results and the equations resulting from the second degree polynomials of Scheffe's models were solved using the least square method. The models developed showed close correlation with the experimental results for the A-7-5 and A-6 soils and will form good guide in pavement and foundation designs in the study areas.展开更多
The clay mineral association, oxides of clay fraction and surface charge properties of 7 soils, which are developed from granite, located at different altitudes of the Tianbao Mountains were studied. Results indicate ...The clay mineral association, oxides of clay fraction and surface charge properties of 7 soils, which are developed from granite, located at different altitudes of the Tianbao Mountains were studied. Results indicate that with the increase in altitude, 1) the weathering process and desilicification of soil clay minerals became weaker, whereas the leaching depotassication and the formation process of hydroxy-aluminum interlayer got stronger; 2) the contents of amorphous and complex aluminum and iron, and the activity of aluminum and iron oxides for soil clay fraction increased; and 3) the amount of variable negative charge, anion exchange capacity and the values of PZC and PZNC also increased. The activity of aluminum and iron oxides, the accumulation of aluminum, and surface charge characteristics and their relation to clay oxides of the vertical zone soils were observed and recorded.展开更多
基金Supported by the National Key Basic Research Support Foundation of China (No. 2002CB410804) the National Natural Science Foundation of China (No. 40201026).
文摘Effects of organic acids (oxalic, acetic, and citric) on adsorption characteristics of Cadmium (Cd) on soil clay minerals (kaolinite, goethite, and bayerite) were studied under different concentrations and different pH values. Although the types of organic acids and minerals were different, the effects of the organic acids on the adsorption of Cd on the minerals were similar, i.e., the amount of adsorbed Cd with an initial solution pH of 5.0 and initial Cd concentration of 35 mg L-1 increased with increasing concentration of the organic acid in solution at lower concentrations, and decreased at higher concentrations. The percentage of Cd adsorbed on the minerals in the presence of the organic acids increased considerably with increasing pH of the solution. Meanwhile, different Cd adsorption in the presence of the organic acids, due to different properties on both organic acids and clay minerals, on kaolinite, goethite, or bayerite for different pHs or organic acid concentrations was found.
文摘The characteristics of the reflectance spectra of clay minerals and their influences on the reflectancespectra of soils are dealt with in the paper. The results showed that dominant clay minerals in soils couldbe distinguished in light of the spectral-form parameters of the reflectance spectra of soils, thus making itpossible to develop a quick method to determine clay minerals by means of reflectance spectra of soils in thelab. and providing a theoretic basis for retnote sensing of clay minerals in soils with a high resolution imagingspectrometer.
基金Project supported by the National Natural Science Foundation of China (Nos.40271108 and 40471125).
文摘A tillage experiment, consisting of moldboard plow (MP), ridge tillage (RT), and no-tillage (NT), was performed in a randomized complete block design with four replicates to study the effect of 3-year tillage management on SOC content and its distribution in surface layer (30 cm) of a clay loam soil in northeast China. NT did not lead to significant increase of SOC in topsoil (0-5 cm) compared with MP and RT; however, the SOC content in NT soil was remarkably reduced at a depth of 5-20 cm. Accordingly, short-term (3-year) NT management tended to stratify SOC concentration, but not necessarily increase its storage in the plow layer for the soil.
基金supported by the basic research fund of the GAGS(YYWF201624)Hebei graduate's innovative funding(CXZZSS20181)
文摘Based on three typical mediums(sandy loam, loam and sandy clay loam) in Hebei Plain, this paper designs phreatic evaporation experiments under different lithology and phreatic depth. Based on the analysis of experimental data, the phreatic evaporation law and influencing factors of three mediums were studied. The results showed that:(1) The shallower the phreatic depth, the larger the phreatic evaporation.(2) Sandy clay loam has the biggest response to the increase of the phreatic depth, sandy loam is the second and loam is the smallest.(3) The limit depth of phreatic evaporation of sandy clay loam is about 3 m and that of loam and sandy loam is about 2 m and 3 m, seperately.(4) By fitting the daily evaporation of phreatic water and phreatic depth, the results showed that sandy loam and sandy clay loam are exponential functions and loam is power functions.
基金Under the auspices of National Social Science Foundation of China(No.09CJL026)Talentgaining Program of Hubei Normal University(No.2008F19)+1 种基金National Natural Science Foundation of China(No.40621001)CAS Research Program on Soil Biosystems and Agro-Product Safety(No.CXTD-Z2005-4)
文摘Soil organic carbon (SOC) plays an important role in global carbon cycles.Large spatial variations in SOC contents result in uncertain estimates of the SOC pool and its changes.In the present study,the key variables explaining the SOC contents of croplands (CPs) and non-croplands (NCPs) in Chinese provinces were investigated.Data on SOC and other soil properties (obtained from the Second National Soil Survey conducted in the late 1970s to the early 1990s),climate parameters,as well as the proportion of the CP to the total land area (Pcp) were used.SOC content variations within a province were larger than those among provinces.Soil clay and total phosphorus content,ratio of annual precipitation to mean temperature,as well as Pcp were able to explain 75% of the SOC content variations in whole soil samples.Soil pH,mean temperature during the growing season from May to October,and mean annual wind velocity were able to explain 63% of the SOC content variations in NCP soils.Compared with NCP soils,CP soils had lower SOC contents,with smaller variations within and among provinces and lower C/N ratios.Stepwise regression showed that the soil clay content was a unique factor significantly correlated with the SOC content of CP soils.However,this factor only explained 24% of the variations.This result suggested that variables related to human activities had greater effects on SOC content variations in CP soils than soil properties and climate parameters.Based on SOC contents directly averaged from soil samples and estimated by regression equations,the total SOC pool in the topsoil (0-20 cm) of China was estimated at 60.02 Pg and 57.6 Pg.Thousands of years of intensive cultivation in China resulted in CP topsoil SOC loss of 4.34-4.98 Pg.
基金Project (No. 3967002) supported by the National Natural Science Foundation of China.
文摘Ectomycorrhizal fungi, including Cenococcum geophilum SIV (Cg SIV), and Pisolithus tinctorius 2144 (Pt 2144), 441 (Pt 441) and XC1 (Pt XC1), were cultured in Pachlewski liquid medium with H2KPO4,KCl- saturated vermiculite and mica as K sources, respectively, to investigate the mechanism of K absorption and mobilization by the fungi. Fungal growth rate, K absorption and mobilization varied significantly among the fungal species. Faster growth and greater K accumulation in Pt XC1 than Pt 2 144, Pt 441 and Cg siv were observed. Ectomycorrhizal fungi depressed HCl-soluble K in minerals after successive extractions by water and NH4OAc. Ratio of the total amount of K, including water-, NH4OAc- and HCI-soluble K, lost from substrates to the K accumulated in fungal colonies was less than 60%. These reveal that the ectomycorrhizal fungi could utilize K in interlayer and structural pools, which are usually unavailable for plants in short period. Large differences in the depletion of K in interlayer and structural pools by fungi were observed at fungal harvest. Taking into account the nutrient absorption by ectomycorrhizal fungi in symbionts and the direct contact between hyphae and soils, the fungi species colonized on the root surfaces seemed to be related to the effectiveness of mycorrhizas to utilize K in soils. Ectomycorrhizal fungi differed in the efflux of protons and oxalate. Pt XC1 was observed to have greatest ability to effuse protons and oxalate among the fungi adopted in the experiment. Furthermore, the higher the concentrations of protons and oxalate in the liquid culture solutions, the larger the depletion of K in interlayer and structural pools in minerals by fungi. Protons could replace interlayer K and chelation of oxalate with Fe and Al in crystal lattice could cause weathering of clay minerals. So, protons and oxalate produced by ectomycorrhizal fungi might play an important role in K mobilization in these two pools.
文摘One dimensional and triaxial compression tests of air-dried and oven-dried Fujinomori clay and Pisa clay were carried out. Water content is less than 4.5% and 1.0% for air-dried and oven-dried clay specimens, respectively. In all tests, axial strain rate was changed stepwise many times and drained creep tests were performed several times during monotonic loading at a constant strain rate. Global unloading (and also reloading in some tests) was applied during which creep loading tests were performed several times. Cyclic loading with small stress amplitude and several cycles was also performed to calculate the modulus of elasticity of the clay in tests. Local displacement transducer was used in triaxial compression test to increase measuring accuracy of axial strain. The results show that air-dried and oven-dried clay have noticeable viscous properties; during global unloading, creep deformation changes from positive to negative, i.e. there exist neutral points (zero creep deformation or no creep deformation point) in global unloading part of strain-stress curve; viscous property of Fujinomori clay decreases when water content decreases, i.e. viscous property of air-dried Fujinomori clay is more significant than that of oven-dried Fujinomori clay.
文摘Two time-domain reflectometry (TDR) systems and a new impedance measuring instrument, Thetaprobe,which are based on determination of soil dielectric constant, were used to measure water content of clayeyred soil to eraluate the accuracy of these instruments. The results indicated that these instruments shouldbe carefUlly re-calibrated before being applied in clayey red soil. With a new calibration curve fed into one ofthe TDR systems tested, nase system, the measured data compared well with tho8e by standard oven-dryingmethod.
文摘The clay minerals of more than 200 soil samples collected from various sites of Fujian Province were studied by the X-ray diffraction method and transmission electron microscopy to study their distribution and evolution. Montmorillonite was found in coastal solonchak, paddy soils derived from marine deposit, lacustrine deposit and river deposit, and some latentic red soil, red soil and yellow soil with a low weathering degree. Chlorite existed mainly in coastal solonchak and paddy soil developed from marine deposit. 1.4 nm intergradient mineral appeared frequently in yellow soil, red soil and latentic red soil. The content of l.4 nm intergradient mineral increased with the decrease of weathering degree from latentic red soil to red soil to yellow soil. Hydrous micas were more in coastal solonchak, paddy soils derived from marine deposit, lacustrine deposit and river deposit, and purple soil from purple shale than in other soils. Kaolinite was the most important clay mineral in the soils in this province. The higher the soil weathering degree, the more the kaolinite existed. From yellow soil to red soil to latentic red soil, kaolinite increased gradually. Kaolinite was the predominant clay mineral accompanied by few other minerals in typical latentic red soil. Tubular halloysite was a widespread clay mineral in soils of Fujian Province with varying quantities. The soil derived from the parent rocks rich in feldspar contained more tubular halloysite. Spheroidal halloysite was found in a red soil and a paddy soil developed from olivine basalt. Gibbsite in the soils in this district was largely 'primary gibbsite' which formed in the early weathering stage. Gibbsite decreased with the increase of weathering degree from yellow soil to red soil to latentic red soil. Goethite also decreased in the same sequence while hematite increased.
基金Supported by the National Natural Science Foundation of China (Nos.50979106 and 50779067)
文摘The van Genuchten (vG) function is often used to describe the soil water retention curve (SWRC) of unsaturated soils and fractured rock. The objective of this study was to develop a method to determine the vG model parameter m from the fractal dimension. We compared two approaches previously proposed by van Genuchten and Lenhard et al. for estimating m from the pore size distribution index of the Brooks and Corey (BC) model. In both approaches we used a relationship between the pore size distribution index of the BC model and the fractal dimension of the SWRC. A dataset containing 75 samples from the UNSODA unsaturated soil hydraulic database was used to evaluate the two approaches. The statistical parameters showed that the approach by Lenhard et al. provided better estimates of the parameter m. Another dataset containing 72 samples from the literature was used to validate Lenhard's approach in which the SWRC fractal dimension was estimated from the clay content. The estimated SWRC of the second dataset was compared with those obtained with the Rosetta model using sand, silt, and clay contents. Root mean square error values of the proposed fractal approach and Rosetta were 0.081 and 0.136, respectively, indicating that the proposed fractal approach performed better than the Rosetta model.
文摘Offshore jacket-type platforms are attached to the seabed by long batter piles. In this paper, results from a finite element analysis, verified against experimental data, are used to study the effect of the pile's inclination angle, and its interaction with the geometrical properties of the pile and the geotechnical characteristics of the surrounding soil on the behavior of the inclined piles supporting the jacket platforms. Results show that the inclination angle is one of the main parameters affecting the behavior of an offshore pile. We investigated the effect of the inclination angle on the maximum von Mises stress, maximum von Mises elastic strain, maximum displacement vector sum, maximum displacement in the horizontal direction, and maximum displacement in the vertical direction. Results indicate that the pile's operationally optimal degree of inclination is approximately 5°. By exceeding this value, the instability in the surrounding soil under applied loads grows extensively in all the geotechnical properties considered. Cohesive soils tend to display poorer results compared to grained soils.
文摘Consecutive differential movements of ground to the dryness and the rehydration of the sols are irregular movements of ground related to the phenomenon of withdrawal-swelling. By risk of withdrawal-swelling, one understands the phenomenon "natural" likely to occur, with a probability of more or less large occurrence. For the phenomenon of withdrawal-swelling of the argillaceous grounds, one will speak about strong, average or weak risk. This article returns within the framework's study of risk withdrawal-swelling or dryness-humidification of the argillaceous Mames of the area of Ouled Fayet and Cheraga of Algiers.
文摘The changes of clay mineral association after high-gradient magnetic separation (HGMS) treatment, and the effects of chemical and physical technologies on concentrating Fe oxides for main soils in central and southern China were investigated by means of X-ray diffraction (XRD) and chemical analysis methods. Results indicated that the concentrating times of Fe oxides by HGMS treatment were the largest for 0.2-2 μmsize fractions in the examined soils. For the soils in which 2: 1 phyllosilicates were dominant, concentrating times of iron oxides by HGMS treatment were larger than by 5 mol L-1 NaOH treatment. Phyllosili-cates were decreased after HGMS treatment; however, the decrease was less than that of kaorolinite. The goet bite / (goethite + hematie) values in Fe oxides of the soils kept virtually constant after HGMSt reatment.
文摘Soil stabilization has been found to be very effective in upgrading the bearing capacity of weak soils for construction purposes. The stabilizing agent, for cost efficiency, ought to provide a cheaper alternative to other possible processes. With the rapid industrialization efforts around the globe, enormous quantities of waste materials are generated and there has not been adequate mechanism for recycling and re-use of such wastes to reduce the consequent environmental problems and hazardous situations created as a result. The objective of the study is to upgrade expansive soils from Eke Obinagu, Ugwuaji in Enugu State and Egbede in Abia State Nigeria, as constructions material using RHA (rice husk ash). Expansive clay soils were mixed with this ash, remolded and tested to examine the effect on the OMC (optimum moisture content) and the CBR (California Bearing Ratio). The characterization of the soils was done in accordance with BS1377 and 1990b, with respect to their engineering properties which include OMC, MDD, Soaked CBR, Liquid Limit, Classification and Sieve Analysis. The rice husk was burnt and prepared in a cylindrical incinerator to form the ash. The results of classification showed A-7-5, A-6, A-2-7 soils for Eke Obinagu, Egbede and Ugwuaji, respectively. The CBR values showed increase from 5% to 29%, 7% to 13% and 5% to 23% for A-7-5, A-6 ~nd A-2-7 respectively at optimal value of 17.5% stabilization. There was also an appreciable increase in the OMC values from 15% to 33%, 14% to 25% and 15% to 31% for A-7-5, A-6 and A-2-7 soils respectively at 17.5% stabilization. Empirical models based on Scheffe's model were developed with the experimental results and the equations resulting from the second degree polynomials of Scheffe's models were solved using the least square method. The models developed showed close correlation with the experimental results for the A-7-5 and A-6 soils and will form good guide in pavement and foundation designs in the study areas.
基金Project supported by the National Natural Science Foundation of China
文摘The clay mineral association, oxides of clay fraction and surface charge properties of 7 soils, which are developed from granite, located at different altitudes of the Tianbao Mountains were studied. Results indicate that with the increase in altitude, 1) the weathering process and desilicification of soil clay minerals became weaker, whereas the leaching depotassication and the formation process of hydroxy-aluminum interlayer got stronger; 2) the contents of amorphous and complex aluminum and iron, and the activity of aluminum and iron oxides for soil clay fraction increased; and 3) the amount of variable negative charge, anion exchange capacity and the values of PZC and PZNC also increased. The activity of aluminum and iron oxides, the accumulation of aluminum, and surface charge characteristics and their relation to clay oxides of the vertical zone soils were observed and recorded.