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土壤因子对三氯乙烯土-气分配系数的影响
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作者 王兴华 李小倩 +2 位作者 谢晓涵 何宁洁 喻涵雨 《地质科技通报》 CAS CSCD 北大核心 2024年第5期272-278,共7页
土壤-空气(简称土-气)分配是影响挥发性有机污染物环境归宿的重要环节,是形成呼吸暴露风险的重要过程。以黄土、红土、黑土和砂土4种典型土壤为研究对象,识别了影响三氯乙烯土-气分配的土壤因子,并通过单因素控制批实验定量探究了三氯... 土壤-空气(简称土-气)分配是影响挥发性有机污染物环境归宿的重要环节,是形成呼吸暴露风险的重要过程。以黄土、红土、黑土和砂土4种典型土壤为研究对象,识别了影响三氯乙烯土-气分配的土壤因子,并通过单因素控制批实验定量探究了三氯乙烯在土-气界面的分配行为,构建了三氯乙烯土-气分配系数与土壤因子的定量关系。结果表明,4种典型土壤原样的三氯乙烯土-气分配系数存在显著差异(黑土>红土>砂土>黄土),黑土分配系数的影响因子主要是土壤粒径、含水率、有机质含量,其他3种土壤分配系数的影响因子主要是土壤粒径、含水率。黑土中三氯乙烯的土-气分配系数(K_(SA))与土壤影响因子的关系可定量表示为:K_(SA)=-0.744X_(1)-0.224X_(2)+0.704X_(3);而在砂土中为:K_(SA)=-0.724X_(1)-0.222X_(2);在黄土中为:K_(SA)=-0.291X_(1)-0.268X_(2);在红土中为:K_(SA)=-0.589X_(1)-0.338X_(2)(X_(1)为土壤含水率;X_(2)为粒径;X_(3)为有机质含量)。研究成果有利于深入认识三氯乙烯在我国典型土壤中土-气界面上的分配行为及土壤因子对其产生影响的规律,为土-气分配过程中多因素耦合影响量化和健康风险评估提供理论依据。 展开更多
关键词 土-气分配 三氯乙烯 界面分配 壤因子 多元回归
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有机氯农药土-气交换的研究进展 被引量:5
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作者 刘红霞 祁士华 +4 位作者 邢新丽 胡英 瞿程凯 张莉 黄焕芳 《安全与环境工程》 CAS 北大核心 2014年第5期1-10,15,共11页
土-气交换是控制有机氯农药(OCPs)在地区和全球尺度上迁移传输和环境归宿的关键过程。本文对OCPs土-气交换的研究方法、交换现状以及影响因素进行了综述。研究方法主要有土-气分配系数(KSA)、逸度商(fS/fA)及逸度比率(ff)、土-气交换通... 土-气交换是控制有机氯农药(OCPs)在地区和全球尺度上迁移传输和环境归宿的关键过程。本文对OCPs土-气交换的研究方法、交换现状以及影响因素进行了综述。研究方法主要有土-气分配系数(KSA)、逸度商(fS/fA)及逸度比率(ff)、土-气交换通量、农药手性分析以及环境模型等;OCPs土-气交换现状表明,土壤仍是OCPs主要储存地;而影响OCPs土-气交换的主要因素是温度、土壤有机质以及化合物的辛醇-空气分配系数(KOA)。最后,针对目前OCPs土-气交换研究中存在的不足,为深入开展该研究提出了思路和研究方向。 展开更多
关键词 有机氯农药 -交换 土-气分配系数 逸度 被动采样速率 环境模型
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Redistribution of Soil Organic Carbon Triggered by Erosion at Field Scale Under Subhumid Climate,Hungary
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作者 Zoltan SZALAI Judit SZABO +7 位作者 Jozsef KOVACS Erzsebet MESZAROS Gaspar ALBERT Csaba CENTERI Boglarka SZABO Balazs MADARASZ Dora ZACHARY Gergely JAKAB 《Pedosphere》 SCIE CAS CSCD 2016年第5期652-665,共14页
Soil organic carbon(SOC) has primary importance in terms of soil physics, soil fertility and even of climate change control. One hundred soil samples were taken from an intensively cultivated Cambisol to quantify SOC ... Soil organic carbon(SOC) has primary importance in terms of soil physics, soil fertility and even of climate change control. One hundred soil samples were taken from an intensively cultivated Cambisol to quantify SOC redistribution triggered by soil erosion under a subhumid climate, by the simultaneous application of diffuse reflectance(240–1 900 nm) and traditional physico-chemical methods.The representative sample points were collected from the solum along the slopes at the depth of 20–300 cm with a mean SOC content of 12 g kg^(-1). Hierarchical cluster analyses were performed based on the determined SOC results. The spatial pattern of the groups created were similar, and even though the classifications were not the same, diffuse reflectance had proven to be a suitable method for soil/sediment classification even within a given arable field. Both organic and inorganic carbon distributions were found to be a proper tool for estimations of past soil erosion processes. The SOC enrichment was found on two sedimentary spots with different geomorphological positions. Soil organic matter composition also differed between the two spots due to selective deposition of the delivered organic matter. The components with low-molecular-weight reached the bottom of the slope where they could leach into the profile, while the more polymerised organic matter compositions were delivered and deposited even before on a higher segment of the slope in an aggregated form. This spatial difference appeared below the uppermost tilled soil layer as well, referring the lower efficiency of conventional ploughing tillage in soil spatial homogenisation. 展开更多
关键词 CAMBISOL carbon sequestration diffuse reflectance selective erosion soil organic matter composition
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