In situ coal gasification poses a potential environmental risk to groundwater pollution although it depends mainly on local hydrogeological conditions. In our investigation,the possible processes of groundwater pollut...In situ coal gasification poses a potential environmental risk to groundwater pollution although it depends mainly on local hydrogeological conditions. In our investigation,the possible processes of groundwater pollution origi-nating from underground coal gasification (UCG) were analyzed. Typical pollutants were identified and pollution con-trol measures are proposed. Groundwater pollution is caused by the diffusion and penetration of contaminants generated by underground gasification processes towards surrounding strata and the possible leaching of underground residue by natural groundwater flow after gasification. Typical organic pollutants include phenols,benzene,minor components such as PAHs and heterocyclics. Inorganic pollutants involve cations and anions. The natural groundwater flow after gasification through the seam is attributable to the migration of contaminants,which can be predicted by mathematical modeling. The extent and concentration of the groundwater pollution plume depend primarily on groundwater flow ve-locity,the degree of dispersion and the adsorption and reactions of the various contaminants. The adsorption function of coal and surrounding strata make a big contribution to the decrease of the contaminants over time and with the distance from the burn cavity. Possible pollution control measures regarding UCG include identifying a permanently,unsuitable zone,setting a hydraulic barrier and pumping contaminated water out for surface disposal. Mitigation measures during gasification processes and groundwater remediation after gasification are also proposed.展开更多
Through the analysis of the surrounding rock, coal seam burial depth, coal quality and hydrologic geological condition, the methane-bearing property characteristics of the coal reservoir in the Gemudi syncline were el...Through the analysis of the surrounding rock, coal seam burial depth, coal quality and hydrologic geological condition, the methane-bearing property characteristics of the coal reservoir in the Gemudi syncline were elucidated. Most of the wall rock of the coal reservoir is mudstone and silt, which is a favourable enclosing terrane. Burial depth of the main excavating coat seam is moderate. The groundwater activity is thin, and there are absolute groundwater systems between each coal seam, which make poor intercon- nections to accelerate CBM enrichment. In our research, the area coal reservoir meta- morphosis is high, CBM content is high, hole-cranny system development degree is high, and permeability of the great mass of the main coal seam exceeds 0.1×10^-3 μm2, The result demonstrates that the southeast of the Gemudi syncline has the best conditions for prospecting and exploiting CBM.展开更多
Underground coal gasification is one of the clean technologies of in-situ coal utilization.Hydrogen production from underground gasification of lignite was investigated in this study based on simulation experiments.Py...Underground coal gasification is one of the clean technologies of in-situ coal utilization.Hydrogen production from underground gasification of lignite was investigated in this study based on simulation experiments.Pyrolysis of lignite, gasification activity, oxygen-steam gasification and the effect of groundwater influx were studied.As well, the advantages of lignite for stable underground gasification were analyzed.The results indicate that lignite has a high activity for gasification.Coal pyrolysis is an important source of hydrogen emission.Under special heating conditions, hydrogen is released from coal seams at temperatures above 350 °C and reaches its maximum value between 725 and 825 °C.Gas with a hydrogen concentration of 40% to 50% can be continuously obtained by oxygen-steam injection at an optimum ratio of steam to oxygen, while lignite properties will ensure stable gasification.Groundwater influx can be utilized for hydrogen preparation under certain geological conditions through pressure control.Therefore, enhanced-hydrogen gas production through underground gasification of lignite has experimentally been proved.展开更多
基金Projects 20207014 and 50674084 supported by the National Natural Science Foundation of China
文摘In situ coal gasification poses a potential environmental risk to groundwater pollution although it depends mainly on local hydrogeological conditions. In our investigation,the possible processes of groundwater pollution origi-nating from underground coal gasification (UCG) were analyzed. Typical pollutants were identified and pollution con-trol measures are proposed. Groundwater pollution is caused by the diffusion and penetration of contaminants generated by underground gasification processes towards surrounding strata and the possible leaching of underground residue by natural groundwater flow after gasification. Typical organic pollutants include phenols,benzene,minor components such as PAHs and heterocyclics. Inorganic pollutants involve cations and anions. The natural groundwater flow after gasification through the seam is attributable to the migration of contaminants,which can be predicted by mathematical modeling. The extent and concentration of the groundwater pollution plume depend primarily on groundwater flow ve-locity,the degree of dispersion and the adsorption and reactions of the various contaminants. The adsorption function of coal and surrounding strata make a big contribution to the decrease of the contaminants over time and with the distance from the burn cavity. Possible pollution control measures regarding UCG include identifying a permanently,unsuitable zone,setting a hydraulic barrier and pumping contaminated water out for surface disposal. Mitigation measures during gasification processes and groundwater remediation after gasification are also proposed.
基金Supported by the"973"Key Foundation of China(2009CB219605)the National Natural Science Foundation of China(40730422,40802032)the Special of Major National Science and Technology of China(2008ZX05034)
文摘Through the analysis of the surrounding rock, coal seam burial depth, coal quality and hydrologic geological condition, the methane-bearing property characteristics of the coal reservoir in the Gemudi syncline were elucidated. Most of the wall rock of the coal reservoir is mudstone and silt, which is a favourable enclosing terrane. Burial depth of the main excavating coat seam is moderate. The groundwater activity is thin, and there are absolute groundwater systems between each coal seam, which make poor intercon- nections to accelerate CBM enrichment. In our research, the area coal reservoir meta- morphosis is high, CBM content is high, hole-cranny system development degree is high, and permeability of the great mass of the main coal seam exceeds 0.1×10^-3 μm2, The result demonstrates that the southeast of the Gemudi syncline has the best conditions for prospecting and exploiting CBM.
基金Projects 50876112 and 50674084 supported by the National Natural Science Foundation of China
文摘Underground coal gasification is one of the clean technologies of in-situ coal utilization.Hydrogen production from underground gasification of lignite was investigated in this study based on simulation experiments.Pyrolysis of lignite, gasification activity, oxygen-steam gasification and the effect of groundwater influx were studied.As well, the advantages of lignite for stable underground gasification were analyzed.The results indicate that lignite has a high activity for gasification.Coal pyrolysis is an important source of hydrogen emission.Under special heating conditions, hydrogen is released from coal seams at temperatures above 350 °C and reaches its maximum value between 725 and 825 °C.Gas with a hydrogen concentration of 40% to 50% can be continuously obtained by oxygen-steam injection at an optimum ratio of steam to oxygen, while lignite properties will ensure stable gasification.Groundwater influx can be utilized for hydrogen preparation under certain geological conditions through pressure control.Therefore, enhanced-hydrogen gas production through underground gasification of lignite has experimentally been proved.
