山西省石墙区铝土矿地质与地球化学特征研究

山西省原平市石墙区铝土矿属于典型的喀斯特型铝土矿。含矿岩系自下而上包括铁质粘土层、铝土矿层、粘土层,且含矿岩系一般包含两个明显的沉积旋回。矿体主体呈层状、似层状产出,矿石结构以隐晶质结构为主,局部出现碎屑和豆鲕粒结构。矿石构造大都为块状构造。矿物学分析显示,硬水铝石、针铁矿、锐钛矿、高岭石是主要的组成矿物,另外还含有石英、伊利石、绿泥石等矿物。地球化学分析显示,主量元素主要包括Al2O3、SiO2、Fe2O3、H2O+及TiO2,微量元素中碱性和碱土元素Li、Sr、Be、Cs、Ba及酸土元素Zr、Hf、Nb、Ta、W均表现为明显富集,且Zr和Hf之间以及Nb和Ta之间具有高度的相关性。地球化学指标Zr/Hf、Nb/Ta以及Eu/Eu*-TiO2/Al2O3图解显示,底板碳酸盐岩是山西省原平市石墙区铝土矿的重要源岩。

Composition and Origin of Ferromanganese Crusts from Equatorial Western Pacific Seamounts

In the equatorial western Pacific, iron-manganese oxyhydroxide crusts(Fe-Mn crusts) and nodules form on basaltic seamounts and on the top of drowned carbonate platform guyots that have been swept free of pelagic sediments. To date, the Fe-Mn crusts have been considered to be almost exclusively of abiotic origin. However, it has recently been suggested that these crusts may be a result of biomineralization. Although the Fe-Mn crust textures in the equatorial western Pacific are similar to those constructed by bacteria and algae, and biomarkers also document the existence of bacteria and algae dispersed within the Fe-Mn crusts, the precipitation, accumulation and distribution of elements, such as Fe, Mn, Ni and Co in Fe-Mn crusts are not controlled by microbial activity. Bacteria and algae are only physically incorporated into the crusts when dead plankton settle on the ocean floor and are trapped on the crust surface. Geochemical evidence suggests a hydrogenous origin of Fe-Mn crusts in the equatorial western Pacific, thus verifying a process for Fe-Mn crusts that involves the precipitation of colloidal phases from seawater followed by extensive scavenging of dissolved trace metals into the mineral phase during crust formation.

Accurate and precise determination of lead isotope composition in selected geochemical reference materials

Lead(Pb)isotopes have been extensively employed in tracing sources of Pb and its transport pathways through the environment.However,Pb isotopic ratios in related geochemical reference materials are scarce.Here,we report high-precision Pb isotopic ratios measured by Nu Plasma II MC-ICP-MS using calibrated ^(205)Tl/^(203)Tl=2.38865(NIST SRM 997)for mass discrimination correction.The long-term external precision(2SD)for NISTSRM 981 of Pb,BCR-2,and BHVO-2 are 0.31‰(n=105),0.42‰(n=11),and 0.25‰(n=5)for ^(208)Pb/ ^(206)Pb and 0.16‰,0.53‰,and 0.07‰for ^(206)Pb/ ^(207)Pb,both respectively,and their Pb isotopic ratios are in excellent agreement with the recommended values.Using this method,we report for the first time Pb isotopic compositions in shale SGR-1b(USGS);coal CLB-1(USGS);stream sediments GSD-17,-21,and-23(IGGE);soils GSS-12,-13,-14,-15,and-16(IGGE);plants GSV-1,-2,and-3(IGGE);and human hair GSH-1(IGGE).

Key nitrogen biogeochemical processes revealed by the nitrogen isotopic composition of dissolved nitrate in the Changjiang River estuary, China

Seasonal variations in the nitrogen isotopic composition of dissolved nitrate （δ15NO3） were investigated in the surface waters of the Changjiang River estuary in 2009 and 2010. δ15NO3 varied between -4.6‰ and 8.9%0 with changes in temperature, salinity, dissolved oxygen concentrations, and the composition of the dissolved inorganic nitrogen pool. In February, biological processes decreased because of low temperature, and the mean δ15NO3 near the river mouth was 2.4%0. In May, δ15NO3 was the highest in the surface waters among all seasons. Analysis on the conservative mixing revealed assimilation, and this finding is supported by positive relationship between Chl a and δ15NO3. The fractionation factor of assimilation was estimated to be 2.0‰ by the Rayleigh equation. Nitrification was supported based on the mixing behaviors in November 2010 and the low δ15NO3 values in May and November 2009. The high ammonium concentrations in the adjacent marine area and positive relationships between total organic nitrogen and δ15NO3 in November 2010 indicated that mineralization was taking place.

Tillage Pedogenesis of Purple Soils in Southwestern China

Land cultivation and tillage process, and their consequent impacts on soil erosion, have been criticized as the main cause of degradation of land or soil quality. However, purple soils, classified as Regosols in FAO Taxonomy or Entisols in USDA Taxonomy, are formed from purple rocks of the Trias- Cretaceous system, have been developed or at least accelerated the development due to continual tillage operation, especially digging and ridging. The present study took micromorphological investigation on the sedimentary rocks and the soils under different operations of tillage. Results show that the purple rock of Feixiangguan Formation of the Trias system （Tlf） is the easiest to physical weathering and the most fertile soil material enriched in nutrients, and it has been, therefore, mostly cultivated and intensively tilled around the year. It has the fastest soil formation rate. Soil formation rate in the cropland with conventional tillage is higher than that in the forestiand and the grassland. It implies that the artificial brokenness and tillage disturbance play a great role in physical weathering and initiating soil formation processes.

Geochronology, petrogenesis and tectonic significance of Dahongliutan pluton in Western Kunlun orogenic belt, NW China

The Dahongliutan granitic pluton,in the eastern part of the West Kunlun orogenic belt,provides significant insights for studying the tectonic evolution of West Kunlun.This paper presents a systematic study of LA-ICP-MS zircon U Pb age,major and trace elements,Sr-Nd-Hf isotopes,and the first detailed Li isotope analysis of the Dahongliutan pluton.LA-ICP-MS zircon U Pb dating shows that the Dahongliutan granites were emplaced in the Late Triassic((213±2.1)Ma).Geochemical data show relatively high SiO2 contents(68.45 wt%73.62 wt%)and aluminum saturation index(A/CNK=1.111.21)indicates peraluminous high-K calc-alkaline granite.The Dahongliutan granites are relatively high in light rare earth elements(LREE)and large ion lithophile elements(LILEs)(e.g.,Rb,K,Th),and relatively depleted in high field strength elements(HFSEs)(e.g.,Nb,Ta,P,Ti).TheεNd(t)values range from 8.71 to 4.73,and(87Sr/86Sr)i=0.70870.71574.Zircons from the pluton yield 176Hf/177Hf values of 0.2826181 to 0.2827683,andεHf(t)values are around 0;the two-stage Hf model ages range from 0.974 to 1.307 Ga.Theδ7Li values are 0.76‰3.25‰,with an average of 2.53‰.Isotopic compositions of the pluton suggest a mixed trend between the partial melting of the Middle Proterozoic ancient crustal material and a juvenile mantle-derived material.This study infers that the Dahongliutan rock mass is formed in the post-collisional extension environment,when the collision between South Kunlun and the Tianshuihai terranes results in the closure of the Palaeo-Tethys.The mantle-derived magma results in partial melting of the lower crust.

The Impacts of the Interannual Variability of Vegetation on the Interannual Variability of Global Evapotranspiration: A Modeling Study

The impact of the interannual variability (IAV) of vegetation on the IAV of evapotranspiration is investigated with the Community Land Model (CLM3.0) and modified Dynamic Global Vegetation Model (DGVM). Two sets of 50-year off-line simulations are used in this study. The simulations begin with the same initial surface-water and heat states and are driven by the same atmospheric forcing data. The vegetation exhibits interannual variability in one simulation but not in the other simulation. However, the climatological means for the vegetation are the same. The IAV of the 50-year annual total evapotranspiration and its three partitions (ground evaporation, canopy evaporation, and transpiration) are analyzed. The global distribution of the evapotranspiration IAV and the statistics of evapotranspiration and its components in different ecosystems show that the IAV of ground evaporation is generally large in areas dominated by grass and deciduous trees, whereas the IAV of canopy evaporation and transpiration is large in areas dominated by bare soil and shrubs. For ground evaporation, canopy evaporation, and transpiration, the changes in IAV are larger than the mean state over most grasslands and shrublands. The study of two sites with the same IAV in the leaf area index (LAI) shows that the component with the smaller contribution to the total evapotranspiration is more sensitive to the IAV of vegetation. The IAV of the three components of evapotranspiration increases with the IAV of the fractional coverage (FC) and the LAI. The ground evaporation IAV shows the greatest increase, whereas the canopy evaporation shows the smallest increase.

The Role of Aerosol in Climate Change,the Environment,and Human Health

Aerosol is an important component of the atmosphere,and its source,composition,distribution,and effects are highly complicated.Governments and scientists have given much attention to aerosol problems,and it has become a hot topic due to the important role it plays in climate change and the Earth's environment.In this paper,1) the importance of aerosol in climate change,the atmospheric environment,and human health is summarized;2) the recent serious problems of aerosol pollution and the shortage of current aerosol research in China are pointed out;and 3) the necessity to enhance aerosol research in China is emphasized.

The Moon

Recent geochemical and geophysical data from the Moon enable a revision of earlier interpretations regarding lunar origin, structure and bulk composition. Earth and Moon show many similarities among their isotopic compositions, but they have evolved in totally dissimilar ways, probably related to the deficiency of water and volatile elements in the Moon as well as the vast differences in size and internal pressure. Some global geochemical differences from the Earth such as volatile depletion based on K/U ratios have been established. However, all current lunar samples come from differentiated regions, making the establishment of a bulk composition more reliant on bulk geophysical properties or isotopic similarities; it remains unclear how the latter arose or relate to whole Moon composition. The lack of fractionation effects among the refractory and super-refractory elements indicates that the proto-lunar material seems unlikely to have been vaporized while the presence of volatile elements may place lower limits on proto-lunar temperatures. The apparent lack of geochemical evidence of an impacting body enables other possible impactors, such as comets, to be considered. Although the origin of the Moon remains currently unknown, it is generally believed that the Moon originated as the result of a giant impact on the Earth.

Soil organic carbon dynamics study bias deduced from isotopic fractionation in corn plant

Carbon stable isotope techniques were extensively employed to trace the dynamics of soil organic carbon(SOC)across a land-use change involving a shift to vegetation with different photosynthetic pathways.Based on the isotopic mass balance equation,relative contributions of new versus old SOC,and SOC turnover rate in corn fields were evaluated world-wide.However,most previous research had not analyzed corn debris left in the field,instead using an average corn plant δ^(13)C value or a measured value to calculate the proportion of corn-derived SOC,either of which could bias results.This paper carried out a detailed analysis of isotopic fractionation in corn plants and deduced the maximum possible bias of SOC dynamics study.The results show approximately 3‰ isotopic fractionation from top to bottom of the corn leaf.The ^(13)C enrichment sequence in corn plant was tassel﹥stalk or cob﹥root﹥leaves.Individual parts accounting for the total dry mass of corn returned distinct values.Consequently,the average δ^(13)C value of corn does not represent the actual isotopic composition of corn debris.Furthermore,we deduced that the greater the fractionation in corn plant,the greater the possible bias.To alleviate bias of SOC dynamics study,we suggest two measures:analyze isotopic compositions and proportions of each part of the corn and determine which parts of the corn plant are left in the field and incorporated into SOC.

Description of desertification evolution in Fuxin district of Liaoning province based on fractal theory

Desertification is the most serious environmental problem in the world today. Fractal feature of granularity composition was studied by using the fractal theory in view of desertification soil in Fuxin district, thereby evolution patterns of desertification was promulgated. The result shows that the self-formation degree of the developing desertification areas is higher than the relatively steady desertification areas. Evolution of desertification is beginning of forming sandy soil of framework composition, and then the sandy soil be came complex by the effect of environment, climate and anthropo-activity.

Genesis and Quality of Groundwater in the Southeastern Region of Southern Vietnam

The origin and quality of groundwater in the Southeastern region （belongs to Southern Plain） were identified by using isotopic techniques and geochemical analysis. Groundwater samples were collected from 7 aquifers： the Holocene, upper Pleistocene, middle Pleistocene, lower Pleistocene, upper Pliocene, middle Pliocene and Miocene aquifers. The water isotopic compositions （82H and 8180） were determined to elucidate the origin and the interaction between surface water and groundwater studies. Transit time （age） of the groundwater samples was determined to explain the direction of groundwater flow. The dating techniques included 3H and ^14C isotopes measurement, followed by a correction for the initial ^14C-activity by the ^13C-composition （^13C） in TDIC （Total Dissolved Inorganic Carbon）. Geochemical parameters of the groundwater samples were measured either directly in the field or in the laboratory. The results showed that the groundwater from the Holocene and upper Pleistocene aquifers was most recharged from the local meteorological and hydrological systems, including local precipitation, fiver and reservoirs. Thus, it has short transit time and its stable isotopic composition is spread around the local meteoric waterline and lines for rivers or reservoirs water. The groundwater in the deeper aquifers： middle and lower Pleistocene, and Neogene aquifers has old age up to 22.5 ka BP. Its water seems to be recharged from the areas with an altitude from 600 to 700 m higher to the Neogene deposit layer altitude. The groundwater in the SE SP （South-Eastern Southern Plain） region has a high quality. The water type is Na-Ca-Mg-HCO3 with low content of chloride and TDS （Total Dissolved Solids）. Calcite/dolomite and gypsum dissolution, organic matter decomposition and sequence of red-ox reactions proceeding through different electron acceptors sediment were controlled the chemistry of the groundwater in the study region.

Path of public cultural service system construction of Ethnic Frontier Regions

The border areas of public culture construction, as an important part ot socialist CUlture construction, to promote me national culture, national spirit and the spirit of the times, the rich cultural life of the people of all ethnic groups, to promote national unity and safeguard national unity, strengthen cohesion of the Chinese nation, cohesion and creativity, play an irreplaceable role. To this end, exploring the path of public cultural service system construction of Ethnic Frontier Regions, play an important role in stabilizing cultural security of Ethnic Frontier Regions and enhancing national cultural soft power.

Variability in the composition and export of silica in the Huanghe River Basin

Concentrations of suspended particle material(SPM), dissolved silicate(DSi), biogenic silica(BSi), phytoliths(plant produced siliceous microscopic structures), and other parameters were analyzed to examine the influence of both natural processes and human activities on silica delivery to the estuary of the Huanghe River(Yellow River). Our results indicate that the concentrations of DSi in the river decreased significantly since 1986. Approximately 34% of dissolved silica was trapped in the basin between 1986 and 2010 due to a reduction of soil erosion. Phytoliths comprised 67.2%–96.3% of BSi, with the smoothing bar type being the dominant form. Concentrations of BSi are significantly higher in the Huanghe River compared to other major rivers throughout the world due to its high sediment yield. We also found that the ratios of BSi/(BSi+DSi) and BSi/SPM were approximately 0.5 and 0.003 at Lijin near the river mouth, indicating that BSi carried in suspension by the Huanghe River was an important component of the rivers silica load. Significant amounts of BSi were also composed of phytoliths in Bohai Sea sediments near the Huanghe River estuary with the smoothing bar form again being the most abundant. The relatively high specific fluxes of BSi in the Huanghe River reflect its high turbidity and high erosion rates in the basin. The high sediment load originating on the Loess Plateau is likely responsible for the higher BSi flux, in agreement with a general trend of increasing BSi flux with increasing sediment flux in global river systems. This study demonstrates that BSi transported by rivers can be composed largely of phytoliths originating from the erosion of topsoils. The flux of phytoliths in river's suspended sediment load may therefore represent a significant contribution to the biogeochemical cycle of silica in coastal waters.

Geochemical processes and origin of boron isotopes in geothermal water in the Yunnan-Tibet geothermal zone

Boron concentrations and isotope compositions have been measured for 93 water samples from the hot springs and drill-holes in the geothermal system in the Yunnan-Tibet Geothermal Belt(YTGB),China.Boron concentrations range from 0.036–472.4ppm,and theδ11B values range from -16.0‰to 13.1‰,indicating the non-marine origin for each geothermal system.We observed a clear binary mixing relationship between the B concentrations and B isotope compositions in Tibet geothermal area.This relationship can be well explained by two sources,i.e.,marine carbonate rocks and magmatic rocks,for the Tibet geothermal water.No evidence supports a mantle contribution to B.In addition,we found that the precipitation only plays a dilution role for B of geothermal waters.δ11B values for the precipitation across the southern Tibetan Plateau area range from -6.0‰ to -6.8‰at least.Due to data scarcity in Yunnan geothermal area,we observed possible different boron sources from the Tibet geothermal system.Comparing it with other geothermal systems in the world,we found that the samples from YTGB have the lowestδ11B values and the largest range of B concentration,which might be related to their special geological background.On the whole,the world geothermalδ11B-Cl/B relation suggests a mixing process between marine and non-marine sources.Additionally,we suggest that B source of B-enriched geothermal waters is mainly from B-enriched crustal country-rocks,instead of mantle.

Petrogenesis of the concealed Daqiling intrusion in Guangxi and its tectonic significance: Constraints from geochemistry, zircon U-Pb dating and Nd-Hf isotopic compositions

The samples from the hidden Daqiling muscovite monzonite granite, which has recently been recognized within the Limu Sn-polymetallic ore field, have been analyzed for zircon U-Pb ages and whole rock geochemical and Nd-Hf isotopic compositions to discuss its genesis, source, and tectonic setting. LA-ICP-MS zircon U-Pb dating indicates that the granite crystallized in the late Indosinian（224.8±1.6 Ma）. The granite is enriched in SiO2 and K2 O and low in CaO and Na2 O. It is strongly peraluminous with the A/CNK values of 1.09–1.20 and 1.4 vol%–2.7 vol% normal corundum. Chondrite-normalized REE patterns show slightly right-dipping shape with strongly negative Eu anomalies（δEu =0.08–0.17）. All samples show enrichment of LILEs（Cs, Rb and K） and HFSEs（U, Pb, Ce and Hf）, but have relatively low contents of Ba, Sr and Ti. The zircon saturation temperatures（Tzr） are from 711 to 740°C, which are slightly lower than the average value of typical S-type granite（764°C）. The granite has negative εNd（t） and εHf（t） values, which change from ？9.1 to ？10.1 with the peak values of ？9.2 to ？9.0 and from ？3.7 to ？12.6 with the peak values of ？6 to ？5, respectively. The C DMT（Nd） and C DMT（Hf） values are 1.74–1.82 Ga with the peak values of 1.73–1.75 Ga and 1.49–2.04 Ga with the peak values of 1.5–1.6 Ga, respectively. These characteristics reveal that the source region of the granite is dominantly late Paleoproterozoic to early Mesoproterozoic crustal materials. Seven inherited magmatic zircons are dated at the age of 248.6±4.3 Ma, which suggests the existence of the early Indosinian granite in Limu area. These zircons have the εHf（t） values of ？6.7– ？2.3, similar to those of the Daqiling granite, implying the involvement of the early Indosinian granite during the formation of the Daqiling granite. Inherited zircon of 945±11 Ma has the εHf（t） and TDM（Hf） values of 8.7 and 1.14 Ga, respectively, compatible with those of the Neoproterozoic arc magmatic rocks in the eastern Jiangnan orogenic belt. Therefore we inferred that Neoproterozoic arc magma might have been involved in the formation of the Daqiling granite, and that the Neoproterozoic arc magma belt and continent-arc collision belt between the Yangtze and Cathaysia Blocks might have extended westsouthward to Limu region. It is proposed that the underplating of mantle materials triggered by crustal extension and thinning resulted in partial melting of crustal materials to form the Daqiling granite in the late Indosinian under post-collisional tectonic setting.

Mineral weathering and element cycling in soil-microorganism-plant system

Soil is an essential part of the critical zone,and soil-microbe-plant system serves as a key link among lithosphere,biosphere,atmosphere and hydrosphere.As one of the habitats with the richest biodiversity,soil plays a critical role in element biogeochemistry on the earth surface(weathered crust).Here we review the soil biological processes that are relevant to mineral weathering,element cycling,and transformation,with an emphasis on rock weathering mediated by soil microbes,plant root and the rhizosphere.

Detection and indication of 1,3,4-C27-29 triol in the sediment of northern South China Sea

After the detection of the 1,20,21-C29 long-chain triol in some sediments and freshwater pteridophytes, in this study a new homologous long-chain triol, 1,3,4-C27-29, is detected for the first time in the Site4B core sediment in the northern South China Sea. The hydroxyl location and length of the carbon chain of this newly discovered triol differ from those of 1,20,21-C29 triol. The test results of its molecular distribution and individual carbon isotope reveal that 1,3,4-C29triol has a good correlation with n-C26-30 even carbon-numbered long-chain fatty alcohols, with R2 （n=68） values of 0.905, 0.929 and 0.903, respectively, and its carbon isotope composition, at -32.3%o_1.9%o, is similar to that of rt-C26.30, at -29.13%o^0.87%o, -32.98%o^1.28%o, and -32.98%o^1.28%o. 1,3,4-C29 triol from the Site4B core sediment and terrigenous long-chain fatty alcohol （n-C26.34） show highly consistent distribution trends in the entire section; thus, the former could serve as a proxy indicator of the terrigenous input. Considering that the 1,20,21-C29 triol in previous research belongs to Azolla, which are fresh water pteridophytes, the 1,3,4-C27-29 triol identified in this study might have similar biogenetic derivation. Thus, determination of its biogenic area and growing environment could provide potential organic geochemical evidence supporting the terrigenous input and source in the northern South China Sea.

New records of Jurassic petrified wood in Jianchang of western Liaoning,China and their palaeoclimate implications

Diverse and rich fossil wood records have been documented from the Mesozoic of Liaoning Province, NE China. The Tiaojishan Formation(mainly distributed in Beipiao, Chaoyang, Fuxin and Jianchang regions) is one of the most significant horizons for the Jurassic petrified wood in Liaoning Province. Previously, wood fossils of this formation were mainly reported in Beipiao and Chaoyang regions, whereas fossil wood record was merely known in Jianchang region. Here we describe new fossil wood specimens from the Tiaojishan Formation in Jianchang County, western Liaoning. Two fossil wood taxa, i.e., Protaxodioxylon jianchangense Tian et Wang sp. nov. and Xenoxylon peidense Zheng et Zhang were recognized on the basis of anatomical features. These fossil wood records add new data for understanding the fossil wood diversity, floral composition and palaeoclimate of the Tiaojishan Formation. The occurrence of Xenoxylon and Protaxodioxylon implies a cool temperate, wet and seasonal climate condition with interannual variations during the Middle to Late Jurassic transition in western Liaoning region.

Source of the condensates from the Hetianhe Field and the genetic relationship between the condensates and their associated gases

A detailed correlation of Hetianhe condensates versus typical source rocks from the Tarim Basin was established. Moreover, the genetic relationship between the condensates and their associated gases was also studied based on their geochemical com- positions and fluid inclusion data. Hetianhe condensates are characterized by high pristine/phytane （Pr/Ph） ratios, high relative abundances of Czs regular steranes, C26-C27 triaromatic steroids, and triaromatic dinosteranes, and relatively heavy stable car- bon isotopic compositions. They geochemically correlate well with the Cambrian source rocks, indicating that these conden- sates are derived from the Cambrian rocks. Based on several molecular maturity parameters, the condensates are recognized as being moderately to highly mature, which are too low in maturity to extensively crack into gases. The gases and condensates of the Hetianhe Field are derived from the same source rocks and the gases are from oil-cracking; however, clear evidence indi- cates that the gases were not cracked from their associated condensates and that the gas generation from oil-cracking did not occur in the present reservoirs. The liquid condensates produced from wellheads were likely dissolved in their associated gases underground and carried into the reservoirs by the gases.