This study focuses on drawing a hydrothermal synthesis process map for Co3O4 nanoparticles with various morphologies and investigating the effects of Co3O4 nanocatalyst morphology on CO oxidation.A series of cobalt-hy...This study focuses on drawing a hydrothermal synthesis process map for Co3O4 nanoparticles with various morphologies and investigating the effects of Co3O4 nanocatalyst morphology on CO oxidation.A series of cobalt-hydroxide-carbonate nanoparticles with various morphologies(i.e.,nanorods,nanosheets,and nanocubes) were successfully synthesized,and Co3O4 nanoparticles were obtained by thermal decomposition of the cobalt-hydroxide-carbonate precursors.The results suggest that the cobalt source is a key factor for controlling the morphology of cobalt-hydroxide-carbonate at relatively low hydrothermal temperatures(≤ 140℃).Nanorods can be synthesized in CoCl2 solution,while Co(NO3)2 solution promotes the formation of nanosheets.Further increasing the synthesis temperature(higher than 140 ℃) results in the formation of nanocubes in either Co(NO3)2 or CoCl2 solution.The reaction time only affects the size of the obtained nanoparticles.The presence of CTAB could improve the uniformity and dispersion of particles.Co3O4 nanosheets showed much higher catalytic activity for CO oxidation than nanorods and nanocubes because it has more abundant Co^(3+) on the surface,much higher reducibility,and better oxygen desorption capacity.展开更多
In order to release the tension and shear effect of the superjacent rock strata movement during excavation in coal mine,protect the surface borehole case from fracturing fast and make a good use of the surface borehol...In order to release the tension and shear effect of the superjacent rock strata movement during excavation in coal mine,protect the surface borehole case from fracturing fast and make a good use of the surface borehole during goaf methane drawing,a common synthesis tension deformation fracture model was set up based on the synthesis tension effect of the rock strata,and the deformation rule of the surface borehole case with time and space was researched.The results suggest that,to reduce the deformation the surface borehole should be built between the boundary of the stope and the knee of subsidence curve.At the same time,a 3DEC simulation model and an engineering example were carried out to examine the rules of theoretical model.The result suggests that the model and the rules accord to the test and have good building and protection engineering application values to the surface borehole.展开更多
One-sided ascending or descending Synthetic Aperture Radar(SAR) stereoradargrammetry has limited accuracy of topographic mapping due to the short spatial baseline(-100 km) and small intersection angle. In order to...One-sided ascending or descending Synthetic Aperture Radar(SAR) stereoradargrammetry has limited accuracy of topographic mapping due to the short spatial baseline(-100 km) and small intersection angle. In order to improve the performance and reliability of generating digital elevation model(DEM) from spaceborne SAR radargrammetry, an exploration of two-sided stereoradargrammetry from the combination of ascending and descending orbits with geometric configuration of long spatial baseline(-1000 km) was conducted in this study. The slant-range geometry between SAR sensors to the earth surface and the Doppler positioning equations were employed to establish the stereoscopic intersection model. The measurement uncertainty of two-sided radargrammetric elevation was estimated on the basis of radar parallax of homogeneous points between input SAR images. Two stereo-pairs of ALOS/PALSAR(Advanced Land Observing Satellite/Phased Array type L-band Synthetic Aperture Radar) acquisitions with the orbital separation almost 1080 km over the west Sichuan foreland basin with rolling topography in southwestern China were employed in the study to obtain the up-to-date terrain data after the 2008 Wenchuan earthquake that hit this area. Thequantitative accuracy assessment of two-sided radargrammetric DEM was performed with reference to field GPS observations. The experimental results show that the elevation accuracy reaches 5.5 m without ground control points(GCPs) used, and the accuracy is further improved to 1.5 m with only one GPS GCP used as the least constraint. The theoretical analysis and testing results demonstrate that the twosided long baseline SAR radargrammetry from the ascending and descending orbits can be a very promising technical alternative for large-area and high accuracy topographic mapping.展开更多
The Changling fault depression passed through three stages of evolution: a period of faulting, a period of subsidence, and an inversion period. The fault lifted the whole area and the formation was eroded during the l...The Changling fault depression passed through three stages of evolution: a period of faulting, a period of subsidence, and an inversion period. The fault lifted the whole area and the formation was eroded during the late Yingcheng formation, the late Nenjiang formation, and the late Mingshui formation. The denudation quantity of eight wells located in the study area is estimated by the interval transit time method and by the formation trend extension method using seismic and drilling data. Inversion back stripping technology with de-compaction correction was used to restore the original sedimentary thickness step by step and to recover the burial history at a single well. Two profiles were selected for the recovery and study of the tectonic evolution. The study confirmed that the primary major gas bearing structure formed due to thermal shrinkage lifting during the late Yingcheng formation. Successive development in a pattern during the late Mingshui formation led to the formation of the primary gas pool. Vertical differential uplift during the late Nenjiang formation formed the Fulongquan structure during the late Paleogene. At this same time a secondary gas pool formed. A large scale reverse developed late in the Mingshui formation that provided the impetus for formation of a secondary gas pool. It is thought that the migration and accumulation of oil and gas was controlled by lithologic character, fracture, and structure. The local uplift in the vicinity of the hydrocarbon recession is most conducive to the collection of hydrocarbon gas.展开更多
基金supported by the National Natural Science Foundation of China (51374004,51204083)the Candidate Talents Training Fund of Yun-nan Province (2012HB009,2014HB006)+2 种基金the Applied Basic Research Program of Yunnan Province (2014FB123)a School-Enterprise Cooperation Project from Jinchuan Corporation (Jinchuan 201115)the Talents Training Program of Kunming University of Science and Technology (KKZ3201352038)~~
文摘This study focuses on drawing a hydrothermal synthesis process map for Co3O4 nanoparticles with various morphologies and investigating the effects of Co3O4 nanocatalyst morphology on CO oxidation.A series of cobalt-hydroxide-carbonate nanoparticles with various morphologies(i.e.,nanorods,nanosheets,and nanocubes) were successfully synthesized,and Co3O4 nanoparticles were obtained by thermal decomposition of the cobalt-hydroxide-carbonate precursors.The results suggest that the cobalt source is a key factor for controlling the morphology of cobalt-hydroxide-carbonate at relatively low hydrothermal temperatures(≤ 140℃).Nanorods can be synthesized in CoCl2 solution,while Co(NO3)2 solution promotes the formation of nanosheets.Further increasing the synthesis temperature(higher than 140 ℃) results in the formation of nanocubes in either Co(NO3)2 or CoCl2 solution.The reaction time only affects the size of the obtained nanoparticles.The presence of CTAB could improve the uniformity and dispersion of particles.Co3O4 nanosheets showed much higher catalytic activity for CO oxidation than nanorods and nanocubes because it has more abundant Co^(3+) on the surface,much higher reducibility,and better oxygen desorption capacity.
基金supports for this work provided by the NationalScience and Technology Major Project (No. 2011ZX05040-004)the National Great Research Foundation of China (No.2011CB201203)the National Natural Science Foundation of China(No. 50904034)
文摘In order to release the tension and shear effect of the superjacent rock strata movement during excavation in coal mine,protect the surface borehole case from fracturing fast and make a good use of the surface borehole during goaf methane drawing,a common synthesis tension deformation fracture model was set up based on the synthesis tension effect of the rock strata,and the deformation rule of the surface borehole case with time and space was researched.The results suggest that,to reduce the deformation the surface borehole should be built between the boundary of the stope and the knee of subsidence curve.At the same time,a 3DEC simulation model and an engineering example were carried out to examine the rules of theoretical model.The result suggests that the model and the rules accord to the test and have good building and protection engineering application values to the surface borehole.
基金supported by the National Natural Science Foundation of China(Grant Nos.41472255,51178404)Open Research Fund by Sichuan Engineering Research Center for Emergency Mapping & Disaster Reduction(Program K2014B006)Fundamental Research Funds for the Central Universities(Grant Nos.SWJTU12ZT07,2682014BR014)
文摘One-sided ascending or descending Synthetic Aperture Radar(SAR) stereoradargrammetry has limited accuracy of topographic mapping due to the short spatial baseline(-100 km) and small intersection angle. In order to improve the performance and reliability of generating digital elevation model(DEM) from spaceborne SAR radargrammetry, an exploration of two-sided stereoradargrammetry from the combination of ascending and descending orbits with geometric configuration of long spatial baseline(-1000 km) was conducted in this study. The slant-range geometry between SAR sensors to the earth surface and the Doppler positioning equations were employed to establish the stereoscopic intersection model. The measurement uncertainty of two-sided radargrammetric elevation was estimated on the basis of radar parallax of homogeneous points between input SAR images. Two stereo-pairs of ALOS/PALSAR(Advanced Land Observing Satellite/Phased Array type L-band Synthetic Aperture Radar) acquisitions with the orbital separation almost 1080 km over the west Sichuan foreland basin with rolling topography in southwestern China were employed in the study to obtain the up-to-date terrain data after the 2008 Wenchuan earthquake that hit this area. Thequantitative accuracy assessment of two-sided radargrammetric DEM was performed with reference to field GPS observations. The experimental results show that the elevation accuracy reaches 5.5 m without ground control points(GCPs) used, and the accuracy is further improved to 1.5 m with only one GPS GCP used as the least constraint. The theoretical analysis and testing results demonstrate that the twosided long baseline SAR radargrammetry from the ascending and descending orbits can be a very promising technical alternative for large-area and high accuracy topographic mapping.
基金the Marine Prospective Project of China Petrochemical Corporation (No.G0800-06-ZS324) for the financial support
文摘The Changling fault depression passed through three stages of evolution: a period of faulting, a period of subsidence, and an inversion period. The fault lifted the whole area and the formation was eroded during the late Yingcheng formation, the late Nenjiang formation, and the late Mingshui formation. The denudation quantity of eight wells located in the study area is estimated by the interval transit time method and by the formation trend extension method using seismic and drilling data. Inversion back stripping technology with de-compaction correction was used to restore the original sedimentary thickness step by step and to recover the burial history at a single well. Two profiles were selected for the recovery and study of the tectonic evolution. The study confirmed that the primary major gas bearing structure formed due to thermal shrinkage lifting during the late Yingcheng formation. Successive development in a pattern during the late Mingshui formation led to the formation of the primary gas pool. Vertical differential uplift during the late Nenjiang formation formed the Fulongquan structure during the late Paleogene. At this same time a secondary gas pool formed. A large scale reverse developed late in the Mingshui formation that provided the impetus for formation of a secondary gas pool. It is thought that the migration and accumulation of oil and gas was controlled by lithologic character, fracture, and structure. The local uplift in the vicinity of the hydrocarbon recession is most conducive to the collection of hydrocarbon gas.