The use of high As-bearing coals has caused more than 3,000 cases of arsenosis patients in southwest Guizhou Province, China. The mode of occurrence of arsenic in coal is an important key role in understanding its beh...The use of high As-bearing coals has caused more than 3,000 cases of arsenosis patients in southwest Guizhou Province, China. The mode of occurrence of arsenic in coal is an important key role in understanding its behavior during usage and damage pathway to human health. Coal samples from endemic arsenosis areas were analyzed with INAA, EMPA, SEM-EDX, LTA, XRD, XAFS, and sequential leaching experiment. Arsenic in pyrite is from under the limit of EMPA to 1.75%, and in most cases, the content of arsenic is lower than 0.5%. Besides pyrite and arsenopyrite, SEM-EDX combined with LTA and XRD find that sulfates, clay and phosphates also contain arsenic. XAFS shows that arsenic mainly exists in the form of As^5+. More than 50% of arsenic stayes in residual solid and combined with organic matrix in two samples, but most arsenic is leached out in other samples. The occurrence of such exceptionally high As contents in coal and the fact that the arsenic is dominantly organically associated are unique observations.展开更多
Based on the quasi-steady-state approximation, the dynamic equation of char combustion in the oxidation zone of underground coal gasification (UCG) was derived. The parameters of the dynamic equation were determined a...Based on the quasi-steady-state approximation, the dynamic equation of char combustion in the oxidation zone of underground coal gasification (UCG) was derived. The parameters of the dynamic equation were determined at 900℃ using a thermo-gravimetric (TG) analyzer connected to a flue gas analyzer and this equation. The equation was simplified for specific coals, including high ash content, low ash content, and low ash fusibility ones. The results show that 1) the apparent reaction rate constant increases with an increase in volatile matter value as dry ash-free basis,2) the effective coefficient of diffusion decreases with an increase in ash as dry basis, and 3) the mass transfer coefficient is independent of coal quality on the whole. The apparent reaction rate constant, mass-transfer coefficient and effective coefficient of diffusion of six char samples range from 7.51×104 m/s to 8.98×104 m/s, 3.05×106 m/s to 3.23×106 m/s and 5.36×106 m2/s to 8.23×106 m2/s at 900℃, respectively.展开更多
In seismic exploration for coal, seismic waves are very difficult to transmit downward because of high velocity protective layers, making the reflection information very hard to receive above ground. Based on the Snel...In seismic exploration for coal, seismic waves are very difficult to transmit downward because of high velocity protective layers, making the reflection information very hard to receive above ground. Based on the Snell law and the Zoeppritz equation, we studied the relationship between the incidence angle and reflection seismic wave energy using a forward model of level media. The result shows that the seismic wave energy has a sudden increase at the critical angle. Based on the energy propagation rule, using big offset to receive the seismic wave energy under a protective layer can effectively reduce its protection effect.展开更多
The effect of geological uncertainty on the development and mining of underground coal deposits is a key issue for longwall mining, as the presence of faults generates substantial monetary losses. This paper develops ...The effect of geological uncertainty on the development and mining of underground coal deposits is a key issue for longwall mining, as the presence of faults generates substantial monetary losses. This paper develops a method for the conditional simulation of fault systems and uses the method to quantify and assess fault uncertainty. The method is based on the statistical modelling of fault attributes and the simulation of the locations of the centres of the fault traces. Fault locations are generated from the thinning of a Poisson process using a spatially correlated probability field. The proposed algorithm for simulating fault traces takes into account soft data such as geological interpretations and geomechanical data. The simulations generate realisations of fault populations that reproduce observed faults, honour the statistics of the fault attributes, and respect the constraints of soft data, providing the means to thereby model and assess the related fault uncertainty.展开更多
The dynamic updating of the model included: the change of space border,addi- tion and reduction of spatial component (disappearing,dividing and merging),the change of the topological relationship and synchronous dynam...The dynamic updating of the model included: the change of space border,addi- tion and reduction of spatial component (disappearing,dividing and merging),the change of the topological relationship and synchronous dynamic updating of database.Firstly, arming at the deficiency of OO-Solid model in the aspect of dynamic updating,modeling primitives of OO-Solid model were modified.And then the algorithms of dynamic updating of 3D geological model with the node data,line data or surface data change were dis- cussed.The core algorithms was done by establishing space index,following the way of facing the object from bottom to top,namely the dynamic updating from the node to arc, and then to polygon,then to the face of the component and finally to the geological object. The research has important theoretical and practical values in the field of three dimen- sional geological modeling and is significant in the field of mineral resources.展开更多
With the characteristics of coal seam geology and gas occurrence,a'ground-underground' integrated gas drainage method was formed,which can relieve gaspressure and increase permeability by mining the protection...With the characteristics of coal seam geology and gas occurrence,a'ground-underground' integrated gas drainage method was formed,which can relieve gaspressure and increase permeability by mining the protection seams in conditional regions.After coal seam gas drainage,high gas outburst seam was converted to low gas safetyseam.In the coal face mining process,safety and high efficient coal mining were realizedby the measure of gas-suction over mining.In addition to the drainage gas for civil gasand gas power generation,the Huaibei Mining Group has actively carried out research onthe utilization technology of methane drainage by ventilation.On the one hand,it can saveprecious energy;on the other hand,it can protect the environment for people's survival.In2007,the amount of coal mine gas drainage was 120 hm3;the rate of coal mine gasdrainage was 44%.Compared with the year 2002,the amount of coal mine gas drainageincreased by two times.Meanwhile,the utilization rate of gas increased rapidly.展开更多
Geologic surface approximation is profoundly affected by the presence, density and location of scattered geologic input data. Many studies have recognized the importance of utilizing varied sources of information when...Geologic surface approximation is profoundly affected by the presence, density and location of scattered geologic input data. Many studies have recognized the importance of utilizing varied sources of information when reconstructing a surface. This paper presents an improved geologic surface approximation method using a multiquadric function and borehole data. Additional information, i.e., inequality elevation and dip-strikes data extracted from outcrops or mining faces, is introduced in the form of physical constraints that control local changes in the estimated surface. Commonly accepted hypothesis states that geologic surfaces can be approximated to any desired degree of exactness by the summation of regular, mathematically defined, surfaces: in particular displaced quadric forms. The coefficients of the multiquadric functions are traditionally found by a least squares method. The addition of physical constraints in this work makes such an approach into a non-deterministic polynomial time problem. Hence we propose an objective function that represents the quality of the estimated surface and that includes the additional constraints by incorporation of a penalty function. Maximizing the smoothness of the estimated surface and its fitness to the additional constraints then allows the coefficients of the multiquadric function to be obtained by iterative methods. This method was implemented and demonstrated using data collected from the 81'st coal mining area of the Huaibei Coal Group.展开更多
Based on the dynamic simulation of the 3 D structure the sedimentary modeling, the unit entity model has been adopted to transfer the heterogeneous complex passage system into limited simple homogeneous entity, and th...Based on the dynamic simulation of the 3 D structure the sedimentary modeling, the unit entity model has been adopted to transfer the heterogeneous complex passage system into limited simple homogeneous entity, and then the traditional dynamic simulation has been used to calculate the phase and the drive forces of the hydrocarbon , and the artificial neural network(ANN) technology has been applied to resolve such problems as the direction, velocity and quantity of the hydrocarbon migration among the unit entities. Through simulating of petroleum migration and accumulation in Zhu Ⅲ depression, the complex mechanism of hydrocarbon migration and accumulation has been opened out.展开更多
文摘The use of high As-bearing coals has caused more than 3,000 cases of arsenosis patients in southwest Guizhou Province, China. The mode of occurrence of arsenic in coal is an important key role in understanding its behavior during usage and damage pathway to human health. Coal samples from endemic arsenosis areas were analyzed with INAA, EMPA, SEM-EDX, LTA, XRD, XAFS, and sequential leaching experiment. Arsenic in pyrite is from under the limit of EMPA to 1.75%, and in most cases, the content of arsenic is lower than 0.5%. Besides pyrite and arsenopyrite, SEM-EDX combined with LTA and XRD find that sulfates, clay and phosphates also contain arsenic. XAFS shows that arsenic mainly exists in the form of As^5+. More than 50% of arsenic stayes in residual solid and combined with organic matrix in two samples, but most arsenic is leached out in other samples. The occurrence of such exceptionally high As contents in coal and the fact that the arsenic is dominantly organically associated are unique observations.
基金Projects 59906014, 50276066 and 20207014 supported by National Natural Science Foundation of China
文摘Based on the quasi-steady-state approximation, the dynamic equation of char combustion in the oxidation zone of underground coal gasification (UCG) was derived. The parameters of the dynamic equation were determined at 900℃ using a thermo-gravimetric (TG) analyzer connected to a flue gas analyzer and this equation. The equation was simplified for specific coals, including high ash content, low ash content, and low ash fusibility ones. The results show that 1) the apparent reaction rate constant increases with an increase in volatile matter value as dry ash-free basis,2) the effective coefficient of diffusion decreases with an increase in ash as dry basis, and 3) the mass transfer coefficient is independent of coal quality on the whole. The apparent reaction rate constant, mass-transfer coefficient and effective coefficient of diffusion of six char samples range from 7.51×104 m/s to 8.98×104 m/s, 3.05×106 m/s to 3.23×106 m/s and 5.36×106 m2/s to 8.23×106 m2/s at 900℃, respectively.
基金Projects 40574058 supported by the National Natural Science Foundation of China2005cb221500 by the National Basic Research Program of China 03(2007) by the Scientific and Technological Project about Geology and Mineral Resources of Henan Land Resources Department
文摘In seismic exploration for coal, seismic waves are very difficult to transmit downward because of high velocity protective layers, making the reflection information very hard to receive above ground. Based on the Snell law and the Zoeppritz equation, we studied the relationship between the incidence angle and reflection seismic wave energy using a forward model of level media. The result shows that the seismic wave energy has a sudden increase at the critical angle. Based on the energy propagation rule, using big offset to receive the seismic wave energy under a protective layer can effectively reduce its protection effect.
文摘The effect of geological uncertainty on the development and mining of underground coal deposits is a key issue for longwall mining, as the presence of faults generates substantial monetary losses. This paper develops a method for the conditional simulation of fault systems and uses the method to quantify and assess fault uncertainty. The method is based on the statistical modelling of fault attributes and the simulation of the locations of the centres of the fault traces. Fault locations are generated from the thinning of a Poisson process using a spatially correlated probability field. The proposed algorithm for simulating fault traces takes into account soft data such as geological interpretations and geomechanical data. The simulations generate realisations of fault populations that reproduce observed faults, honour the statistics of the fault attributes, and respect the constraints of soft data, providing the means to thereby model and assess the related fault uncertainty.
基金the National Natural Science Foundation of China(40572165)
文摘The dynamic updating of the model included: the change of space border,addi- tion and reduction of spatial component (disappearing,dividing and merging),the change of the topological relationship and synchronous dynamic updating of database.Firstly, arming at the deficiency of OO-Solid model in the aspect of dynamic updating,modeling primitives of OO-Solid model were modified.And then the algorithms of dynamic updating of 3D geological model with the node data,line data or surface data change were dis- cussed.The core algorithms was done by establishing space index,following the way of facing the object from bottom to top,namely the dynamic updating from the node to arc, and then to polygon,then to the face of the component and finally to the geological object. The research has important theoretical and practical values in the field of three dimen- sional geological modeling and is significant in the field of mineral resources.
文摘With the characteristics of coal seam geology and gas occurrence,a'ground-underground' integrated gas drainage method was formed,which can relieve gaspressure and increase permeability by mining the protection seams in conditional regions.After coal seam gas drainage,high gas outburst seam was converted to low gas safetyseam.In the coal face mining process,safety and high efficient coal mining were realizedby the measure of gas-suction over mining.In addition to the drainage gas for civil gasand gas power generation,the Huaibei Mining Group has actively carried out research onthe utilization technology of methane drainage by ventilation.On the one hand,it can saveprecious energy;on the other hand,it can protect the environment for people's survival.In2007,the amount of coal mine gas drainage was 120 hm3;the rate of coal mine gasdrainage was 44%.Compared with the year 2002,the amount of coal mine gas drainageincreased by two times.Meanwhile,the utilization rate of gas increased rapidly.
基金provided by the National Science and Technology Major Project of China (Nos.2009ZX05039-004 and 2009ZX 05039-002)the National Natural Science Foundation of China (Nos.40771167 and 70621001)
文摘Geologic surface approximation is profoundly affected by the presence, density and location of scattered geologic input data. Many studies have recognized the importance of utilizing varied sources of information when reconstructing a surface. This paper presents an improved geologic surface approximation method using a multiquadric function and borehole data. Additional information, i.e., inequality elevation and dip-strikes data extracted from outcrops or mining faces, is introduced in the form of physical constraints that control local changes in the estimated surface. Commonly accepted hypothesis states that geologic surfaces can be approximated to any desired degree of exactness by the summation of regular, mathematically defined, surfaces: in particular displaced quadric forms. The coefficients of the multiquadric functions are traditionally found by a least squares method. The addition of physical constraints in this work makes such an approach into a non-deterministic polynomial time problem. Hence we propose an objective function that represents the quality of the estimated surface and that includes the additional constraints by incorporation of a penalty function. Maximizing the smoothness of the estimated surface and its fitness to the additional constraints then allows the coefficients of the multiquadric function to be obtained by iterative methods. This method was implemented and demonstrated using data collected from the 81'st coal mining area of the Huaibei Coal Group.
文摘Based on the dynamic simulation of the 3 D structure the sedimentary modeling, the unit entity model has been adopted to transfer the heterogeneous complex passage system into limited simple homogeneous entity, and then the traditional dynamic simulation has been used to calculate the phase and the drive forces of the hydrocarbon , and the artificial neural network(ANN) technology has been applied to resolve such problems as the direction, velocity and quantity of the hydrocarbon migration among the unit entities. Through simulating of petroleum migration and accumulation in Zhu Ⅲ depression, the complex mechanism of hydrocarbon migration and accumulation has been opened out.