The Henry＇s Law constant （k） for phosphine in seawater was determined by multiple phase equilibration combined with headspace gas chromatography. The effects of pH, temperature, and salinity on k were studied. The ...The Henry＇s Law constant （k） for phosphine in seawater was determined by multiple phase equilibration combined with headspace gas chromatography. The effects of pH, temperature, and salinity on k were studied. The k value for phosphine in natural seawater was 6.415 at room temperature （approximately 23℃）. This value increases with increases in temperature and salinity, but no obvious change was observed at different pH levels. At the same temperature, there was no significant difference between the k for phosphine in natural seawater and that in artificial seawater. This implies that temperature and salinity are major determining factors for k in marine environment. Double linear regression with Henry＇s Law constants for phosphine as a function of temperature and salinity confirmed our observations. These results provide a basis for the measurement of trace phosphine concentrations in seawater, and will be helpful for future research on the status of phosphine in the oceanic biogeochemical cycle of phosphorus.展开更多
For the last two decades the world has undergone a population explosion which has been accompanied by a speeding up of urbanization and land use for industrial and agricultural products. These involve a vast increase ...For the last two decades the world has undergone a population explosion which has been accompanied by a speeding up of urbanization and land use for industrial and agricultural products. These involve a vast increase in the discharge of pollutants into very different receiving water bodies, and have had adverse effects on the various components of the environment. For a long time, human has concerned a little of the natural environment. It is obvious that this variation in surface temperature of the earth increases the level of sea due to snowmelt. So climate change is manifested by many phenomena： floods, droughts, fires, tornadoes, cyclones, earthquakes, volcanic eruptions, diseases etc.. The statement today is dramatic. Entire regions were devastated and many rivers and lakes have become polluted around the world. Pollution has it nature which is hard to be absorbed. Where did the different pollutants come from？ What are the risks to the aquatic environment？ To prevent and combat the general decline of these ecosystems, it is important to distinguish and determine the effects of different sources of pollution and any changes that may suffer the physical environment. The climate depends primarily on changes in earth orbit parameters, which affect the solar radiation received by the earth surface. Therefore, human participates strongly to these changes, for example, pollution is the main reason to argue the greenhouse effect, an increase of anthropogenic carbon dioxide （CO2） into the atmosphere, which promotes global warming to the planet. These modifications are already applied in order to ensure durable development in water resources by controlling discharges into streams to preserve water resources for future generations and to ensure reconciliation between man-climate and environment.展开更多
All long-duration spacecraft in low-earth-orbit are subject to high velocity impacts by meteoroids and space debris. Such impacts are expected to occur at non-normal incidence angles and can cause severe damage to the...All long-duration spacecraft in low-earth-orbit are subject to high velocity impacts by meteoroids and space debris. Such impacts are expected to occur at non-normal incidence angles and can cause severe damage to the spacecraft and its external flight-critical systems and possibly lead to catastrophic failure of the spacecraft. In order to ensure crew safety and proper function of internal and external spacecraft systems, the characteristics of a debris cloud generated by such impacts must be known. An analytical model is therefore developed for the characterization of the penetration and ricochet debris clouds created by the hypervelocity impact of an aluminum spherical projectile on an aluminum plate. This model employs normal and oblique shock wave theory to characterize the penetration and ricochet processes. The prediction results of center-of-mass trajectory and leading velocity of penetration and ricochet debris clouds are obtained and compared with numerical and experimental results in figures.展开更多
Taxi drivers' cruising patterns are learnt with GPS trajectory data collected in Shenzhen, China. By employing Ripley's K function, the impacts of land use and pick-up experience on taxis' cruising behavio...Taxi drivers' cruising patterns are learnt with GPS trajectory data collected in Shenzhen, China. By employing Ripley's K function, the impacts of land use and pick-up experience on taxis' cruising behavior are investigated concerning about both intensity of influence and radius of influence. The results indicate that, in general, taxi drivers tend to learn more from land use characteristics than from pick-up experience. The optimal radius of influence of land use points and previous pick-up points is 14.18 km and 9.93 km, respectively. The findings also show that the high-earning drivers or thorough drivers pay more attention to land use characteristics and tend to cruise in high-density area, while the low-earning drivers or focus drivers prefer to learn more from previous pick-up experience and select the area which is far away from the high-density area. These findings facilitate the development of measures of managing taxi's travel behavior by providing useful insights into taxis' cruising patterns. The results also provide useful advice for taxi drivers to make efficient cruising decision, which will contribute to the improvement of cruising efficiency and the reduction of negative effects.展开更多
基金Supported by the National Natural Science Foundation of China (Nos.30970522,40576058)the National Natural Science Foundation of China for Creative Research Groups (No.41121064)
文摘The Henry＇s Law constant （k） for phosphine in seawater was determined by multiple phase equilibration combined with headspace gas chromatography. The effects of pH, temperature, and salinity on k were studied. The k value for phosphine in natural seawater was 6.415 at room temperature （approximately 23℃）. This value increases with increases in temperature and salinity, but no obvious change was observed at different pH levels. At the same temperature, there was no significant difference between the k for phosphine in natural seawater and that in artificial seawater. This implies that temperature and salinity are major determining factors for k in marine environment. Double linear regression with Henry＇s Law constants for phosphine as a function of temperature and salinity confirmed our observations. These results provide a basis for the measurement of trace phosphine concentrations in seawater, and will be helpful for future research on the status of phosphine in the oceanic biogeochemical cycle of phosphorus.
文摘For the last two decades the world has undergone a population explosion which has been accompanied by a speeding up of urbanization and land use for industrial and agricultural products. These involve a vast increase in the discharge of pollutants into very different receiving water bodies, and have had adverse effects on the various components of the environment. For a long time, human has concerned a little of the natural environment. It is obvious that this variation in surface temperature of the earth increases the level of sea due to snowmelt. So climate change is manifested by many phenomena： floods, droughts, fires, tornadoes, cyclones, earthquakes, volcanic eruptions, diseases etc.. The statement today is dramatic. Entire regions were devastated and many rivers and lakes have become polluted around the world. Pollution has it nature which is hard to be absorbed. Where did the different pollutants come from？ What are the risks to the aquatic environment？ To prevent and combat the general decline of these ecosystems, it is important to distinguish and determine the effects of different sources of pollution and any changes that may suffer the physical environment. The climate depends primarily on changes in earth orbit parameters, which affect the solar radiation received by the earth surface. Therefore, human participates strongly to these changes, for example, pollution is the main reason to argue the greenhouse effect, an increase of anthropogenic carbon dioxide （CO2） into the atmosphere, which promotes global warming to the planet. These modifications are already applied in order to ensure durable development in water resources by controlling discharges into streams to preserve water resources for future generations and to ensure reconciliation between man-climate and environment.
文摘All long-duration spacecraft in low-earth-orbit are subject to high velocity impacts by meteoroids and space debris. Such impacts are expected to occur at non-normal incidence angles and can cause severe damage to the spacecraft and its external flight-critical systems and possibly lead to catastrophic failure of the spacecraft. In order to ensure crew safety and proper function of internal and external spacecraft systems, the characteristics of a debris cloud generated by such impacts must be known. An analytical model is therefore developed for the characterization of the penetration and ricochet debris clouds created by the hypervelocity impact of an aluminum spherical projectile on an aluminum plate. This model employs normal and oblique shock wave theory to characterize the penetration and ricochet processes. The prediction results of center-of-mass trajectory and leading velocity of penetration and ricochet debris clouds are obtained and compared with numerical and experimental results in figures.
基金Project(NCET-14-0318) supported by the Humanity and Social Science Youth Foundation of Ministry of Education,ChinaProject supported by the Training Program for Outstanding Young Teachers in Jilin University,ChinaProject(2014M551191) supported by China Postdoctoral Science Foundation
文摘Taxi drivers' cruising patterns are learnt with GPS trajectory data collected in Shenzhen, China. By employing Ripley's K function, the impacts of land use and pick-up experience on taxis' cruising behavior are investigated concerning about both intensity of influence and radius of influence. The results indicate that, in general, taxi drivers tend to learn more from land use characteristics than from pick-up experience. The optimal radius of influence of land use points and previous pick-up points is 14.18 km and 9.93 km, respectively. The findings also show that the high-earning drivers or thorough drivers pay more attention to land use characteristics and tend to cruise in high-density area, while the low-earning drivers or focus drivers prefer to learn more from previous pick-up experience and select the area which is far away from the high-density area. These findings facilitate the development of measures of managing taxi's travel behavior by providing useful insights into taxis' cruising patterns. The results also provide useful advice for taxi drivers to make efficient cruising decision, which will contribute to the improvement of cruising efficiency and the reduction of negative effects.
