探析等离子体质谱法在地矿分析中的应用

应用等离子体质谱法(ICP-MS)测定地矿化学样品是当前的新型分析方法。其中,四级质谱仪的离子源是ICP,同时ICP的分析器是四极质谱计,其中的ICP具有准确灵敏的质谱分析能力以及同时进行多种元素测定的功能。和其它相关技术对比,例如中子活化、等离子体光谱以及火花源质谱相比较,该方法具有检出限低、操作简单、精密度高、准确度高、分析快速等特点,具有较大的优势,值得推广。

进口分析仪器的计算机升级改造综述

我国现有的为科学研究服务的分析仪器绝大多数依赖于进口,随着时间的推移,近半数仪器的使用时间达10年以上,性能下降和故障明显增多,一旦仪器出现故障。

Predicting pillar stability for underground mine using Fisher discriminant analysis and SVM methods

The purpose of this study is to apply some statistical and soft computing methods such as Fisher discriminant analysis （FDA） and support vector machines （SVMs） methodology to the determination of pillar stability for underground mines selected from various coal and stone mines by using some index and mechanical properties, including the width, the height, the ratio of the pillar width to its height, the uniaxial compressive strength of the rock and pillar stress. The study includes four main stages： sampling, testing, modeling and assessment of the model performances. During the modeling stage, two pillar stability prediction models were investigated with FDA and SVMs methodology based on the statistical learning theory. After using 40 sets of measured data in various mines in the world for training and testing, the model was applied to other 6 data for validating the trained proposed models. The prediction results of SVMs were compared with those of FDA as well as the measured field values. The general performance of models developed in this study is close; however, the SVMs exhibit the best performance considering the performance index with the correct classification rate Prs by re-substitution method and Pcv by cross validation method. The results show that the SVMs approach has the potential to be a reliable and practical tool for determination of pillar stability for underground mines.

Analysis of Water Insulating Effect of Compound Water-Resisting Key Strata in Deep Mining

The problem of water preservation in mining and the prevention of water-bursts has been one of the more important issues in deep mining. Based on the concept of water-resisting key strata, the mechanics model of the key strata is established given the structural characteristics and the mechanical properties of the roof rock layers of the working face in a particular coal mine. Four other models were derived from this model by rearranging the order of the layers in the key strata. The distribution characteristics of stress, deformation, pore pressure and the flow vector of all the models are computed using the analytical module of fluid-structure interaction in the FLAC software and the corresponding risks of a water-burst are analyzed. The results indicate that the water-insulating ability of the key strata is related to the arrangement of soft and hard rocks. The water-insulating ability of the compound water-resisting key strata (CWKS) with a hard-hard-soft-hard-soft compounding order is the best under the five given simulated conditions.

MECHANISM OF WATER-SOIL COUPLED ACTION DURING MINING SUBSIDENCE

This paper,on the basis of the scientific research of engineering geological exploration in a mining area,systematically studies the reasons and influence factors of consolidation and deformation of the saturated soil included in the thick loose water-bearing overburden due to mining subsidence,and analyses the dissipation of hyperstatic pore water pressure during the change of original stress and strain state of the soil. Again,by means of the coupled model based on Cambridge model and Biot's three-dimensional consolidation theory,adopting a great many physico-mechanical parameters measured in various soil layers,the paper analyses the consolidation and deformation of saturated soil affected by mining subsidence with elasto-plastic finite element method.Thus,the research not only reveals the regulation of stress,strain,displacement and hyperstatic pore water pressure dissipation in overlying soil mass,but also opens up a new direction and way for the research of mining subsidence.

Superposition model for analyzing the dynamic ground subsidence in mining area of thick loose layer

The dynamic ground subsidence due to underground mining is a complicated time-dependent and rate- dependent process. Based. on the theory of rock rheology and probability integral method, this study developed the superposltlOn model for the prediction and analysis of the ground dynamic subsidence in mining area of thick !oose layer. The model consists of two parts （the prediction of overlying bedrock and the prediction of thick loose layer）. The overlying bedrock is regarded as visco-elastic beam, of which the dynamic subsidence is predicted by the Kelvin visco-elastic rheological model. The thick loose layer is regarded as random medium, and the ground dynamic subsidence, is predicted by the probability integral model. At last, the two prediction models are vertically stacked in the same coordinate system, and the bedrock dynamic subsidence is regarded as a variable mining thickness input into the prediction model of ground dynamic subsidence. The prediction results obtained were compared w^th actual movement and deformation data from Zhao I and Zhao II mine, central China. The agreement of the prediction results with the. field measurements.show that the superposition model （SM） is more satisfactory and the formulae obtained are more effective than the classical single probability Integral model（SPIM）, and thus can be effectively used for predicting the ground dynamic subsidence in mining area of thick loose layer.

Quantitative analysis of geological ore-controlling factors and stereoscopic quantitative prediction of concealed ore bodies

To address the issues for assessing and prospecting the replaceable resource of crisis mines, a geological ore-controlling field model and a mineralization distribution field model were proposed from the viewpoint of field analysis. By dint of solving the field models through transferring the continuous models into the discrete ones, the relationship between the geological ore-controlling effect field and the mineralization distribution field was analyzed, and the quantitative and located parameters were extracted for describing the geological factors controlling mineralization enrichment. The method was applied to the 3-dimensional localization and quantitative prediction for concealed ore bodies in the depths and margins of the Daehang mine in Guangxi, China, and the 3-dimensional distribution models of mineralization indexes and ore-controlling factors such as magmatic rocks, strata, faults, lithology and folds were built. With the methods of statistical analysis and the non-linear programming, the quantitative index set of the geological ore-controlling factors was obtained. In addition, the stereoscopic located and quantitative prediction models were set up by exploring the relationship between the mineralization indexes and the geological ore-controlling factors. So far, some concealed ore bodies with the resource volume of a medium-sized mineral deposit are found in the deep parts of the Dachang Mine by means of the deep prospecting drills following the prediction results, from which the effectiveness of the predication models and results is proved.

"Nonlinear" characteristics of the static earth pressure coefficient in thick alluvium

Exact calculations of the static earth pressure from a thick alluvium require accurate/Co values. These calculations influence the sinking cost and the safety of the freezing method. The static earth pressure coefficient （K0） of thick and deep soil was analyzed using laboratory tests. The results show that the static earth pressure coefficient of thick and deep soils is nonlinear and different from that of superficial soils. The constant of superficial soils is usually invariant and the total stress or incremental stress definitions used in traditional geo-meehanics give the same value. The influence of load increments when calculating for superficial soil is ignored. The difference in values of K0 for thick alluvium defimed by the total stress or the incremental stress methods is over 10%. The effects of the thick alluvium on K0 should be considered during the design of frozen shaft projects. Such things as the frozen shaft thickness and the excavated section height should be chosen to assure the rationality of the design and to avoid potential faults and accidents.

DISASTER ANALYSIS AND COUNTERMEASURES OF LAND SUBSIDENCE CAUSED BY COAL CUTTING IN CHINA

In recent years, many coal-producing countries have paid great atte ntion to the land subsidence caused by coal cutting. In China, because of the de nse population in coalfield areas, the land subsidence hazard is more serious. A fter a brief analysis on the mechanism of land subsidence, this paper gives a co mprehensive and systematical account on all kinds of hazards caused by the land subsidence in China. The study shows that land subsidence has endangered land, b uildings, traffic and communication lines, dykes and dams. It also causes damage to ecological and social environment. In order to lessen the hazard of land sub sidence, preventive measures should be taken to reduce the collapse amount, such as extraction with stowing, banded mining system, succession and coordination m ining system, or high-pressure mudflow between rock strata. Measures of reinfor cing or moving certain buildings should also be taken to reduce the destructive degree. In order to harness the subsidence land and bring them under control for farming, measures should be taken such as filling with spoil or fine breeze, ex cavating the deeper and covering the shallower land.

Field analysis of metallogenic information and its application

Focusing on the issue to deal with inadequate extraction of metallogenic information especially geological information,a new method of extracting metallogenic information based on field model,i.e.the field analysis method of metallogenic information,was proposed.In addition,a case study by using the method of the extraction of metallogenic information from the west Guangxi and southeast Yunnan district as an example was performed.The representation method for the field models of metallogenic information,including the metallogenic influence field model and the metallogenic distance field model,was discussed by introducing the concept of the field theory,based on the characteristic analysis of the distance gradualness and the influence superposition of metallogenic information.According to the field theory superposition principle and the spatial distance analysis method,the mathematical models for the metallogenic influence field and the metallogenic distance field of point,line and area geological bodies were derived out by using parameter equation and calculus.Based on the metallogenic background analysis,the metallogenic information field models of synsedimentary faults and manganese sedimentary basins were built.The relationship between the metallogenic information fields and the manganese mineralization distribution was also investigated by using the method of metallogenic information field analysis.The instance study indicates that the proposed method of metallogenic information field analysis is valid and useful for extracting the ore-controlling information of synsedimentary faults and manganese sedimentary basins in the study area,with which the extraction results are significant both statistically and geologically.

Clay mineral distribution in surface sediments of the South China Sea and its significance for in sediment sources and transport

Clay minerals of surface sediments in the South China Sea （SCS） are analyzed with X-ray diffraction, and their transport is explored with a grain size trend analysis （GSTA） model. Results show that clay mineral types in various sedimentary environments have different sediment sources and transport routes. Sediments in the northern SCS （north of 20°N） between the southwest of Taiwan Island and the outer mouth of the Pearl River have high contents of illite and chlorite, which are derived mainly from sediments on Taiwan Island and/or the Yangtze River. Sediments from the Pearl River are characterized by high kaolinite and low smectite content, and most are distributed in the area between the mouth of the Pearl River and northeast of Hainan Island and transported vertically from the continental shelf to the slope. Characterized by high illite content, sediments from Kalimantan Island are transported toward the Nansha Trough. Sediments from Luzon Island are related with volcanic materials, and are transported westwards according to smectite distribution. On the Sunda Shelf, sediments from the Mekong River are transported southeast in the north while sediments from the Indonesian islands are transported northward in the south. Ascertaining surface sediment sources and their transport routes will not only improve understanding of modem transportation and depositional processes, but also aid paleoenvironmental and paleoclimatic analysis of the SCS.

Analysis of the current rib support practices and techniques in U.S. coal mines

Design of rib support systems in U.S. coal mines is based primarily on local practices and experience. A better understanding of current rib support practices in U.S. coal mines is crucial for developing a sound engineering rib support design tool. The objective of this paper is to analyze the current practices of rib control in U.S. coal mines. Twenty underground coal mines were studied representing various coal basins,coal seams,geology,loading conditions,and rib control strategies. The key findings are:(1) any rib design guideline or tool should take into account external rib support as well as internal bolting;(2) rib bolts on their own cannot contain rib spall,especially in soft ribs subjected to significant load—external rib control devices such as mesh are required in such cases to contain rib sloughing;(3) the majority of the studied mines follow the overburden depth and entry height thresholds recommended by the Program Information Bulletin 11-29 issued by the Mine Safety and Health Administration;(4) potential rib instability occurred when certain geological features prevailed—these include draw slate and/or bone coal near the rib/roof line,claystone partings,and soft coal bench overlain by rock strata;(5) 47% of the studied rib spall was classified as blocky—this could indicate a high potential of rib hazards; and(6) rib injury rates of the studied mines for the last three years emphasize the need for more rib control management for mines operating at overburden depths between 152.4 m and 304.8 m.

Optimum mining method selection using fuzzy analytical hierarchy process–Qapiliq salt mine,Iran

Mining method selection is the first and the most critical problem in mine design and depends on some parameters such as geotechnical and geological features and economic and geographic factors. In this paper, the factors affecting mining method selection are determined. These factors include shape, thick- ness, depth, slope, RMR and RSS of the orebody, RMR and RSS of the hanging wall and footwall. Then, the priorities of these factors are calculated. In order to calculate the priorities of factors and select the best mining method for Qapiliq salt mine, Iran, based on these priorities, fuzzy analytical hierarchy process （AHP） technique is used. For this purpose, a questionnaire was prepared and was given to the associated experts. Finally, after a comparison carried out based on the effective factors, between the four mining methods including area mining, room and pillar, cut and fill and stope and pillar methods, the stope and nillar mining method was selected as the most suitable method to this mine.

MESOZOIC-CENOZOIC INVERSION OF THE TURPAN-HAMI BASIN, NORTHWEST CHINA

The Turpan-Hami basin, rich in coal and petroleum, is a superimposed basin of three types basins in different tectonic environments. This coal, oil and gas basin has undergone a complex tectonic-sedimentary evolution, in which two important stages were the negative inversion from a foredeep to a extensional basin during Early Mesozoic and the positive inversion to a thrust foreland basin in Late MesozoicEarly Cenozoic. The early normal faults residues are recognized with the addition of tectonic-sedimentary analysis to confirm the basin extension during Jurassic time and its tectonic inversion subsequently.

Finite layer and triangular prism element method to subsidence prediction and stress analysis in underground mining

The application of the finite layer & triangular prism element method to the 3D ground subsidence and stress analysis caused by mining is presented. The layer elements and the triangular prism elements have been alternatively used in the numerical simulation system, the displacement pattern, strain matrix, elastic matrix, stiffness matrix, load matrix and the stress matrix of the layer element and triangular prism element have been presented. By means of the Fortran90 programming language, a numerical simulation system based on finite layer & triangular prism element have been built up, and this system is suitable for subsidence prediction and stress analysis of all mining condition and mining methods. Comparing with the infinite element method, this approach dramatically reduces the size of the set of equations that need to be solved, and greatly reduces the amount of data preparation required. It not only saves the internal storage, and the computation time, but also decreases the cost.

THE "STRUCTURE-STRATIGRAPHY ANALYSIS" METHOD APPLIED IN THE PREDICTION OF SMALLER-SCALED STRUCTURE IN UNDERGROUND MINING

Structure-stratigraphy analysis" is a new method used in the study and prediction of and small-scaled structures in coal mines. The object of this method is coalbed structure that includes the folds and fracture occurred in the vicinity of coal-seams. It emphases the analysis on the relationship between structural deformation and stratal lithologic combination.Based on the statistics of a series of related parameters in stratigraphy and structure,comprehensive analysis and drawing, this method may provide a good means for the quantitative evaluation and prediction of small scale structure in coal mines.

ON SOME KEY GEOLOGICAL PROBLEMS RELATED TO THE LINGLONG-JIAOJIA ORE-CENTRALIZED DISTRICT IN SHANDONG PROVINCE,CHINA

The Linglong-Jiaojia ore-centralized district is controlled by the tectonic stress field characterized by the combination of extension and strike-slip, and the dip, dip angle, pitch and pitch angle of the ore bodies are all constrained by the dynamic conditions of the tectonics. The metallotectonic series for the ore-centralized district belong to the type of a combination of extension and strike-slip and can be subdivided into four sub-series. The ore-forming process in the brittle regime can be disintegrated into two stages, i.e., the embryonic fracture stage and the megascopic fracture stage, and ore-forming process is rather common in the ore-centralized district at the former stage. Moreover, several key structural patterns and their features were discussed and a preliminary assessment about the ore-forming prospect in this district was made in the paper.

An improved method to assess the required strength of cemented backfill in underground stopes with an open face

Backfill is increasingly used in underground mines to reduce the surface impact from the wastes produced by the mining operations. But the main objectives of backfilling are to improve ground stability and reduce ore dilution. To this end, the backfill in a stope must possess a minimum strength to remain self-standing during mining of an adjacent stope. This required strength is often estimated using a solution proposed by Mitchell and co-workers, which was based on a limit equilibrium analysis of a wedge exposed by the open face. In this paper, three dimensional numerical simulations have been performed to assess the behavior of the wedge model. A new limit equilibrium solution is proposed, based on the backfill displacements obtained from the simulations. Comparisons are made between the proposed solution and experimental and numerical modeling results. Compared with the previous solution, a better agreement is obtained between the new solution and experimental results for the required cohesion and factor of safety. For large scale(field) conditions, the results also show that the required strength obtained from the proposed solution corresponds quite well to the simulated backfill response.

Determination and stability analysis of ultimate open-pit slope under geomechanical uncertainty

In open-pit mines,pit slope as one of the important parameters affects the mine economy and total minable reserve,and it is also affected by different uncertainties which arising from many sources.One of the most critical sources of uncertainty effects on the pit slope design is rock mass geomechanical properties.By comparing the probability of failure resulted from deterministic procedure and probabilistic one,this paper investigated the effects of aforesaid uncertainties on open-pit slope stability in metal mines.In this way,to reduce the effect of variance,it implemented Latin Hypercube Sampling(LHS)technique.Furthermore,a hypothesis test was exerted to compare the effects on two cases in Middle East.Subsequently,the investigation approved high influence of geomechanical uncertainties on overall pit steepness and stability in both iron and copper mines,though on the first case the effects were just over.

Petrological evidence of kaolinite transformation to dawsonite

Clay minerals, especially authigene kaolinite, are abundant in the dawsonite-bearing sandstone from the Gudian and Qian＇an regions in the southern Songliao Basin. The relationship between dawsonite and kaolinite has been investigated based on drilling data from 50 wells in the Jilin Oil Field and petrological cbaracteristics analyses on 23 core samples from the Gudian and Qian＇an regions. The study revealed a negative relationship between the content of dawsonite and kaolinite, suggesting that kaolinite was replaced by the dawsonite. Combined with thermodynamics and geochemical analysis published previously, it is concluded that kaolinite is unstable under CO2-rich environments and can transform into dawsonite.