The spatial distributions and interannual variations of aerosol concentrations, aerosol optical depth （AOD）, aerosol direct radiative forcings, and their responses to heterogeneous reactions on dust surfaces over Ea...The spatial distributions and interannual variations of aerosol concentrations, aerosol optical depth （AOD）, aerosol direct radiative forcings, and their responses to heterogeneous reactions on dust surfaces over East Asia in March 2006-10 were investigated by utilizing a regional coupled climate-chemistry/aerosol model. Anthropogenic aerosol concentrations （inorganic ＋ carbonaceous） were higher in March 2006 and 2008, whereas soil dust reached its highest levels in March 2006 and 2010, resulting in stronger aerosol radiative forcings in these periods. The domain and five-year （2006-10） monthly mean concentrations of anthropogenic and dust aerosols, AOD, and radiative forcings at the surface （SURF） and at the top of the atmosphere （TOA） in March were 2.4 μg m 3 13.1 lag m^-3, 0.18, -19.0 W m^-2, and -7.4 W m^-2, respectively. Heterogeneous reactions led to an increase of total inorganic aerosol concentration; however, the ambient inorganic aerosol concentration decreased, resulting in a smaller AOD and weaker aerosol radiative forcings. In March 2006 and 2010, the changes in ambient inorganic aerosols, AOD, and aerosol radiative forcings were more evident. In terms of the domain and five-year averages, the total inorganic aerosol concentrations increased by 13.7% （0.17 μg m^-3） due to heterogeneous reactions, but the ambient inorganic aerosol concentrations were reduced by 10.5% （0.13 lag m-3）. As a result, the changes in AOD, SURF and TOA radiative forcings were estimated to be -3.9% （-0.007）, -1.7% （0.34 W m^-2）, and -4.3% （0.34 W m^-2）, respectively, in March over East Asia.展开更多
Based on the data from typical sites in the Jianghuai region,many kinds of soil layer seismic response are modeled by increasing and decreasing the measured values of shear velocity to a certain scale. The seismic res...Based on the data from typical sites in the Jianghuai region,many kinds of soil layer seismic response are modeled by increasing and decreasing the measured values of shear velocity to a certain scale. The seismic response of soil layer sites are calculated using the one-dimensional equivalent linear method in the frequency domain by choosing the Taft,Kobe and El-centro records as the ground motion input. The results show that the impact of shear velocity variability on the surface ground motion is in relation to the soil layer structure and ground motion input parameters such as amplitude and spectral characteristic. With the increase of shear velocity,the PGA( peak ground acceleration)on the surface of site will increase,however,the characteristic period of the acceleration response spectra is decreasing.展开更多
The cold-island effect of urban wetlands has received increasing attention in recent years due to its important role in the alleviation of urban heat islands.Hangzhou,a representative rapidly urbanizing city with rich...The cold-island effect of urban wetlands has received increasing attention in recent years due to its important role in the alleviation of urban heat islands.Hangzhou,a representative rapidly urbanizing city with rich wetlands in China,was selected as a case study for researching the changes that the urban wetlands have undergone and their impact on the urban thermal environment.Land surface temperature(LST) was acquired from the thermal infrared data of Landsat 5 Thematic Mapper(TM) images in 1990,1995,2000,2006,and 2010,using the single-channel method.The results are as follows:1) considering the changes in land use,the urban wetlands located to the west of Hangzhou have decreased significantly during 1990–2010 because of rapid urbanization.In the Xixi Wetland,the change in land use was relatively small and most of the water body and vegetation were preserved.However,to the east of the Xixi Wetland,large areas of water body and vegetation have been replaced by built-up land as a result of the urbanization process;2) considering the change in LST,it was found from land surface temperature retrieval that the changing spatial pattern of the thermal field was highly correlated with land use changes.Low temperature regions of the eastern Xixi Wetland were gradually eroded by high temperature regions,and the centroid of the heat island in East Xixi was found to be constantly shifting westward.In addition,the difference in LST between the Xixi Wetland and East Xixi has increased;3) considering the impact factors for this area,land use structure and patch shape were found to have a significant impact on LST,shown by the results of multiple linear stepwise regressions.Increasing the size of the wetlands in urban planning is considered to be the most effective measure in alleviating the urban heat island effect.Moreover,reducing the spatial complexity of landscape patches also contributes to the alleviation of the urban heat island effect.展开更多
Thioredoxin （Trx） proteins are involved in many biological processes especially the regulation of cellular redox homeostasis. In this study, two Trx cDNAs were cloned from the mussel Mytilus galloprovincialis using ...Thioredoxin （Trx） proteins are involved in many biological processes especially the regulation of cellular redox homeostasis. In this study, two Trx cDNAs were cloned from the mussel Mytilus galloprovincialis using rapid amplification of cDNA ends-polymerase chain reaction （RACE-PCR）. The two cDNAs were named MgTrxl and MgTrx2, respectively. The open reading frames of MgTrxl and MgTrx2 were 318 and 507 base pairs （bp） and they encoded proteins of 105 and 168 amino acids with estimated molecular masses of 11.45 and 18.93 kDa, respectively. Sequence analysis revealed that both proteins possessed the conserved active site dithiol motif Cys-Gly-Pro-Cys. In addition, MgTrx2 also possessed a putative mitochondrial targeting signal suggesting that it is located in the mitochondria. Quantitative real-time polymerase chain reaction （qPCR） revealed that both MgTrxl and MgTrx2 were constitutively expressed in all tissues examined. The MgTrxl transcript was most abundant in hemocytes and gills, whereas the MgTrx2 transcript was most abundant in gonad, hepatopancreas, gill and hemocytes. Following Vibrio anguillarum challenge, the expression of MgTrxl was up-regulated and reached its peak, at a value 10-fold the initial value, at 24 h. Subsequently, expression returned back to the original level. In contrast, the expression level of MgTrx2 was down-regulated following bacterial stimulation, with one fifth of the control level evident at 12 h post challenge. These results suggest that MgTrxl and MgTrx2 may play important roles in the response ofM. galloprovincialis to bacterial challenge.展开更多
The graphitic-layer encapsulated iron-containing nanoparticles(G@Fe) have been proposed as a potential type of active and stable non-precious metal electrocatalysts(NPMCs) for the oxygen reduction reaction(ORR). Howev...The graphitic-layer encapsulated iron-containing nanoparticles(G@Fe) have been proposed as a potential type of active and stable non-precious metal electrocatalysts(NPMCs) for the oxygen reduction reaction(ORR). However, the contribution of the encapsulated components to the ORR activity is still unclear compared with the well-recognized surface coordinated FeN_x/C structure. Using the strong complexing effect of the iron component with anions, cyanide(CN^-) in alkaline and thiocyanate(SCN^-) in acidic media, the metal containing active sites are electrochemically probed. Three representative catalysts are chosen for a comparison including the as-prepared encapsulated G@Fe, commercial Fe/N/C catalyst with iron–nitrogen coordinated surface functionalities and molecular iron phthalocyanine(Fe Pc) containing well-defined structures and compositions. It was found that all samples showed significant shifts of half-wave potentials indicating that surface Fe coordinated sites in all cases. The G@Fe catalyst showed the weakest poisoning effect(the lowest shifts of half-wave potential) compared to the Fe/N/C and Fe Pc catalysts in both electrolytes. These results could be explained that the encapsulated iron components influence the FeN_x/C and/or N_xC surface functionality.展开更多
基金supported by the Knowledge Innovation Program of the Chinese Academy of Sciences(Grant No. KZCX2-YW-Q11-03)the National Basic Research Program of China(Grant No.2010CB950804)100 Talents Program of the Chinese Academy of Sciences
文摘The spatial distributions and interannual variations of aerosol concentrations, aerosol optical depth （AOD）, aerosol direct radiative forcings, and their responses to heterogeneous reactions on dust surfaces over East Asia in March 2006-10 were investigated by utilizing a regional coupled climate-chemistry/aerosol model. Anthropogenic aerosol concentrations （inorganic ＋ carbonaceous） were higher in March 2006 and 2008, whereas soil dust reached its highest levels in March 2006 and 2010, resulting in stronger aerosol radiative forcings in these periods. The domain and five-year （2006-10） monthly mean concentrations of anthropogenic and dust aerosols, AOD, and radiative forcings at the surface （SURF） and at the top of the atmosphere （TOA） in March were 2.4 μg m 3 13.1 lag m^-3, 0.18, -19.0 W m^-2, and -7.4 W m^-2, respectively. Heterogeneous reactions led to an increase of total inorganic aerosol concentration; however, the ambient inorganic aerosol concentration decreased, resulting in a smaller AOD and weaker aerosol radiative forcings. In March 2006 and 2010, the changes in ambient inorganic aerosols, AOD, and aerosol radiative forcings were more evident. In terms of the domain and five-year averages, the total inorganic aerosol concentrations increased by 13.7% （0.17 μg m^-3） due to heterogeneous reactions, but the ambient inorganic aerosol concentrations were reduced by 10.5% （0.13 lag m-3）. As a result, the changes in AOD, SURF and TOA radiative forcings were estimated to be -3.9% （-0.007）, -1.7% （0.34 W m^-2）, and -4.3% （0.34 W m^-2）, respectively, in March over East Asia.
基金sponsored by the Anhui Natural Science Foundation Project(10040606Q24)the Youth Seismic Research Program of Anhui Province,China(20120707)and(20140301)
文摘Based on the data from typical sites in the Jianghuai region,many kinds of soil layer seismic response are modeled by increasing and decreasing the measured values of shear velocity to a certain scale. The seismic response of soil layer sites are calculated using the one-dimensional equivalent linear method in the frequency domain by choosing the Taft,Kobe and El-centro records as the ground motion input. The results show that the impact of shear velocity variability on the surface ground motion is in relation to the soil layer structure and ground motion input parameters such as amplitude and spectral characteristic. With the increase of shear velocity,the PGA( peak ground acceleration)on the surface of site will increase,however,the characteristic period of the acceleration response spectra is decreasing.
基金Under the auspices of National Natural Science Foundation of China(No.41101039,41371068)
文摘The cold-island effect of urban wetlands has received increasing attention in recent years due to its important role in the alleviation of urban heat islands.Hangzhou,a representative rapidly urbanizing city with rich wetlands in China,was selected as a case study for researching the changes that the urban wetlands have undergone and their impact on the urban thermal environment.Land surface temperature(LST) was acquired from the thermal infrared data of Landsat 5 Thematic Mapper(TM) images in 1990,1995,2000,2006,and 2010,using the single-channel method.The results are as follows:1) considering the changes in land use,the urban wetlands located to the west of Hangzhou have decreased significantly during 1990–2010 because of rapid urbanization.In the Xixi Wetland,the change in land use was relatively small and most of the water body and vegetation were preserved.However,to the east of the Xixi Wetland,large areas of water body and vegetation have been replaced by built-up land as a result of the urbanization process;2) considering the change in LST,it was found from land surface temperature retrieval that the changing spatial pattern of the thermal field was highly correlated with land use changes.Low temperature regions of the eastern Xixi Wetland were gradually eroded by high temperature regions,and the centroid of the heat island in East Xixi was found to be constantly shifting westward.In addition,the difference in LST between the Xixi Wetland and East Xixi has increased;3) considering the impact factors for this area,land use structure and patch shape were found to have a significant impact on LST,shown by the results of multiple linear stepwise regressions.Increasing the size of the wetlands in urban planning is considered to be the most effective measure in alleviating the urban heat island effect.Moreover,reducing the spatial complexity of landscape patches also contributes to the alleviation of the urban heat island effect.
基金Supported by the National Natural Science Foundation of China(No.31172388)the 100 Talents Program of the Chinese Academy of Sciencesthe Key Laboratory for Ecological Environment in Coastal Areas(201011),State Oceanic Administration
文摘Thioredoxin （Trx） proteins are involved in many biological processes especially the regulation of cellular redox homeostasis. In this study, two Trx cDNAs were cloned from the mussel Mytilus galloprovincialis using rapid amplification of cDNA ends-polymerase chain reaction （RACE-PCR）. The two cDNAs were named MgTrxl and MgTrx2, respectively. The open reading frames of MgTrxl and MgTrx2 were 318 and 507 base pairs （bp） and they encoded proteins of 105 and 168 amino acids with estimated molecular masses of 11.45 and 18.93 kDa, respectively. Sequence analysis revealed that both proteins possessed the conserved active site dithiol motif Cys-Gly-Pro-Cys. In addition, MgTrx2 also possessed a putative mitochondrial targeting signal suggesting that it is located in the mitochondria. Quantitative real-time polymerase chain reaction （qPCR） revealed that both MgTrxl and MgTrx2 were constitutively expressed in all tissues examined. The MgTrxl transcript was most abundant in hemocytes and gills, whereas the MgTrx2 transcript was most abundant in gonad, hepatopancreas, gill and hemocytes. Following Vibrio anguillarum challenge, the expression of MgTrxl was up-regulated and reached its peak, at a value 10-fold the initial value, at 24 h. Subsequently, expression returned back to the original level. In contrast, the expression level of MgTrx2 was down-regulated following bacterial stimulation, with one fifth of the control level evident at 12 h post challenge. These results suggest that MgTrxl and MgTrx2 may play important roles in the response ofM. galloprovincialis to bacterial challenge.
基金supported by Innovation Fond Denmark(4M Centre 0603-00527B and Non-Precious 4106-00012B)Forsk EL Program(UPCAT 2015-1-12315)
文摘The graphitic-layer encapsulated iron-containing nanoparticles(G@Fe) have been proposed as a potential type of active and stable non-precious metal electrocatalysts(NPMCs) for the oxygen reduction reaction(ORR). However, the contribution of the encapsulated components to the ORR activity is still unclear compared with the well-recognized surface coordinated FeN_x/C structure. Using the strong complexing effect of the iron component with anions, cyanide(CN^-) in alkaline and thiocyanate(SCN^-) in acidic media, the metal containing active sites are electrochemically probed. Three representative catalysts are chosen for a comparison including the as-prepared encapsulated G@Fe, commercial Fe/N/C catalyst with iron–nitrogen coordinated surface functionalities and molecular iron phthalocyanine(Fe Pc) containing well-defined structures and compositions. It was found that all samples showed significant shifts of half-wave potentials indicating that surface Fe coordinated sites in all cases. The G@Fe catalyst showed the weakest poisoning effect(the lowest shifts of half-wave potential) compared to the Fe/N/C and Fe Pc catalysts in both electrolytes. These results could be explained that the encapsulated iron components influence the FeN_x/C and/or N_xC surface functionality.
