西北准噶尔地区碱性花岗岩体中角闪石的地质地球化学意义

角闪石的种类、化学组成、微量元素特征显示所研究的碱性花岗岩分为两类 :达拉布特型和恰库尔特型。前者结晶温度为 6 6 5～ 750℃、定位深度为 4 .95～ 8.2 5km,形成于相对封闭的环境中 ,岩浆演化晚期水 -岩作用不强烈 ;角闪石主要为钙质角闪石 ,富 Fe、Co、Cr、Rb、Sc、Cs、Hf,贫 Ta、Zn;其球粒陨石标准化稀土模式曲线呈左高右低的台阶式“V”型。后者结晶温度相对较高、定位较浅 ,形成于开放环境中 ,岩浆演化晚期水 -岩作用强烈 ;角闪石为钠 -钙质角闪石和碱性角闪石 ,富 Ta、Zn,中组稀土亏损 ,球粒陨石标准化稀土模式曲线呈山谷状“V”

矿产地球化学地质调查样本密度理论分析

矿产资源是我国重要的基础能源,对于社会经济发展以及人民日常生活具有重要的贡献。然而,在调查矿产地球化学材料密度时,工作人员需要考虑诸多因素,如地球化学、景观水系、分布地貌、发展阶段等,还需综合考虑水流密度、流域面积、比较系数等因素的影响。因此,为了更好地挖掘和开发矿产资源,本文基于矿产地球化学地质调查样本密度理论,对目标区域的地质特征进行详细分析,并提供有效的措施、明确采样布局和后续工作方案,以帮助工作人员开展后续的调查工作。

Rock-forming mechanism of Qingshanjiao intrusion in Dongguashan copper(gold) deposit, Tongling area, Anhui province, China

Dongguashan deposit is a large porphyry-skarn copper（gold） deposit in Tongling ore district. The Qingshanjiao intermediate acid intrusion of Yanshanian had a direct genetic relationship with mineralization. The magma origin, rock-forming dynamic background and rock-forming process were studied, and the rock-forming mechanism of Qingshanjiao intrusion was discussed, based on geological characteristics, detailed observation of petrography and systematic investigation of petrochemistry, trace elements and REE geochemistry characteristics of Qingshanjiao intrusion. The results show that Qingshanjiao rock body belongs to high-K calc-alkaline series with higher LREE elements, Th, Rb and Sr abundance, but depleted in HREE elements, Ba, Nb and Ta. The primary magma originated from the mantle-crust mixtures which were caused by basaltic magma of mantle mixing with syenite magma of partial melting of the lower crust, and the formation environment of Qingshanjiao intrusion was emplaced in the transitional environment from compression to extension. The Harker diagram and hybrid structures of plagioclase and potassium feldspar indicate that the fractional crystallization occurred in the process of magmatic evolution. The petrochemistry, trace elements and REE geochemistry characteristics indicate that the magma was contaminated by crustal material during the rock-forming. These results suggested that the Qingshanjiao intrusion was formed by fractional crystallization and assimilation and hybridization of mantle-crust magma in the transitional environment from compression to extensional.

Geosciences in Central South University:A state-of-the-art review

In recent decades,colleagues working in the Discipline of Geological Resources and Geological Engineering at Central South University made significant progress in theoretic study and application of geophysics,ore deposit and shale gas geology,3 D predictive modeling of concealed resources,and geological engineering.In geophysics,world-class progress was achieved in the development,data processing,equipment,and scientific survey of electromagnetic method in onshore and offshore environments and the tectonic evolution of the Tibetan Plateau.Especially,advanced wide-field electromagnetic exploration method and equipment as a highlight technique won the first prize of National Science and Technology Invention of China.In ore geology,progressive and complex characteristics of most nonferrous ore deposits and the geodynamic relationship between crust-mantle reaction and mineralization in south China were revealed.Progressive metallogenic models of certain typical ore deposits were established based on the study of fluid inclusion and geochemistry.According to characteristics of complex metallogenic system of polygenetic ore deposit,key ore-controlling factors were found and summarized.The investigation on unconventional resources advanced China’s shale gas resource evaluation system.In 3 D predictive modelling of metallogenic,a large-scale location prediction model was established for exploration of crisis mines and concealed ore deposits.Our developed 3 D predictive modeling techniques for concealed orebodies were widely used to explore deep mineral resources in China.In geological engineering area,the key technologies for deep drilling into complex formations were developed.Especially the drilling fluid and tools were utilized in the fieldwork.The rock and soil mechanics analysis method and anchor technologies were also established and applied to engineering practice.

Geological and geochemical prediction on deeply-seated ore-bodies in Haigou gold deposit of Jilin,China

Lode 28 is the largest gold-bearing quartz vein in Haigou gold deposit, and the lode itself contains more than 301 of gold. Geochemical study shows that 12 trace elements related gold mineralization can be divided into 5 metallogenic factors （element assemblages）. The high values of F1 , F2 and F4 together indicate overlapped of multiple stages of gold mineralization, revealing high potential of gold mineralization at depth ; the single high value of F4 represents the root of an existing ore body while high values of F3 and F4 show the intervals of barton sectors in the lode. Comprehensive geochemical studies show the high prospeetion potential below the 14^th level and between lines 39-71. It is also prospective to look for blind ore-bodies between lines 15-29 and below the 10^th level.

Accumulation and Mixing of Oils in Jinghu Sag of Subei Basin:Constraints from Thermal Maturity Parameters

Oils in Jinghu sag are abundant with high content of polar compounds and have a low ratio of saturate to aromatic hydrocarbons and a high ratio of resin to asphaltene. The gross composition of oils in the Jinghu sag suggests typical immature to low mature characteristics. Some compounds with low thermal stability were identified. Light hydrocarbons, a carbon preference index, an odd even index, n-alkane and hopane maturity parameters show mature features and little differences in the maturity level among oils. Sterane isomerization parameters indicate an immature to low mature status of oil. Transfer of the sedimentary center during sedimentation has led to different thermal histories among subsags and thus generated oils with different maturities. On the basis of source analyses, four migration and accumulation patterns with different maturity can be classified. Combined with available information on mergers of source, reservoir and long distance oil lateral migration, mixing conditions were present in the Jinghu sag. Experimental results indicate that maturity variations are caused by mixtures of hydrocarbons with different maturity.

Annual report of IGCP Project No.440 in 2003——Rodinia assembly and breakup

With the latest information on geology, isotop chronology, geochemistry and aerial geophysics, the structural enviroment, geological event characterists and evolution history of component units of Rodinia Supercontinent on a global scale are discussed. And some neo views and genetic pattern are provided. The East Eurppean Craton had a complex evolution history between 1.7 and 0.9 Ga. The arthors propose a new reconstruction of Laurentia acient land and Siberia at ca. 1 050～1 000 Ma. The largest litho-structural record of the Meso-Neoproterozoic orogenic collage in South America made up the western border of the South American Platform African Cratons are the result of convergence of Paleoproterozoic/Archaem Cratonic blocks. A part of Eastern Antarctica attached to southern Africa in Mesoproterozoic. Neoproterozoic felsic magmatic events in New India made the western border of Rodinia Pre-Grevoillian Laurentia was established as a major continental block by the end of the Paleoproterozoic. South China is geologically plausible to be between southern Laurentia and eastern Australia. Yangzi-Tarim connection or neighborhood is proposed. According to the abovementionded, the assembly and breakup paattern of Rodinia proposed by Pisarevsky is tested. It telles that primary break up is along the western border of Laurentia ancient land, which is similar to northern Atlantic. Another characteristic is that some continents are not considered as component parts of Rodinia, eg. India, Congo and San-Francisco.

Distribution characteristic and geological signiflcance of rare earth elements in Lopingian mudstone of Permian,Panxian county,Guizhou province

In order to discuss the geochemical characteristic of REEs （rare earth elements） and their geological application, we measured the contents of rare earth elements, trace elements and minerals of 29 Lopingian （Late Permian） mudstone samples in Panxian county, carrying out ICP-MS and XRD analysis. The results show that the amount of REEs （185.56-729.46 ×10-6） is high. The ratios of w（LREE）/w（HREE） （6.84- 13.86） and W（La）N/w（Yb）N （1.01-3.02） show clear differentiation of LREEs and HREEs. ZREE has a significantly or critically positive correlation with lithophile elements Th, Nb, Ta, Ti, Ca, Sc, Cs, Zr, Hf, Sr, Be and chaicophile element Zn, a critically negative correlation with siderophile element Fe and a slightly positive correlation with illite, illite smectite mixed layers and siderite. REEs originate mainly from terrigenous minerals, in an inorganic phase, Source rocks of our samples consist of Emeishan basalt and a small part of sedimentary rocks, as suggested by the distribution patterns of REEs and w（∑REE）- w（La）/w（Yb） diagram. Moreover, abnormal surfaces near the sequence boundaries （SB2, SB3, SB4） are related wiLth the boundaries, identified by geochemical characteristics of the REEs, such as ∑REE. w（LREE）/w（HREE）, Eu/Eu＊ and Ceanom.

Characteristics and tectonic setting of volcanic rocks in Early Cretaceous Baiyingaolao Formation of Keyouzhongqi area,Inner Mongolia

The authors studied zircon LA-ICP-MS U-Pb dating,the zircon Hf isotope and geochemistry of acidic volcanic rocks in Baiyingaolao Formation of Keyouzhongqi area,Inner Mongolia,and discussed the chronology,source region and tectonic setting of the volcanic rocks in the studied area. The clear oscillatory zoning of zircons indicates a typical magmatic origin,and the results of dating show that the volcanic rocks of Baiyingaolao Formation were formed in Early Cretaceous( 121. 5 ± 1. 0 Ma). The features of major and trace elements show that the rocks are alkali-rich,poor in calcium and magnesium with enrichment in LILEs like Th,U,K and Gd and depletion in HFSEs,e. g. Nb,Ta,Sr and Ti. The fact implies that they were the products of partial melting of the crust. εHf( t) =( +6.30--+9.06) and TDM2= 600--835 Ma,suggest the magma originated from partial melting of the young crust. Combined with the evolution of regional tectonic structure,the authors conclude that the acidic volcanic rocks of Baiyingaolao Formation may be formed under the extensional environment related to the subduction of Paleo-Pacific Plate.

Petrographic characteristics coals, Mahanadi Gondwana and paleomires of Mand-Raigarh Basin, Chhattisgarh, India

Mand-Raigarh coalfield is one of the largest coalfields in the Mahanadi basin. The Geological Survey of India carried out initial study primarily on exploration. However, detailed petrographic and geochemical characters of the coals have not been done so far. This investigation is an attempt for petrographic and geochemical appraisal of the coals. Moreover, effort is also made for possible interpretation on development of coal facies. The results drawn from 30 composite coal samples suggest coals are rich in vitrinite, with collotelinite as the dominant maceral while liptinite macerals register low concentration. Dominant mineral assemblages found were clay minerals, pyrite was recorded as disseminated, framboidal and euhedral forms, carbonates recorded were mainly siderites. The vitrinite reflectance random （VRo） mean values range from 0.44 % to 0.56 %, and the rank of coal is suggested as high volatile ＇B＇ to ＇A＇ sub- bituminous in rank. The rock-eval pyrolysis reveal TOC content varying from 37 % to 68.83 %, while low hydrocarbon generating potential is evident from low $2 and Tmax values. The Hydrogen Index （HI） versus Oxygen Index （OI） plot reveal that the samples belong to Kerogen type--II-III with input dominantly from terrestrial source, some samples also fall in Kerogen type--II domain indicating lacustrine input. Vitrinite reflectance result indicate that the samples are immature and approaching oil window, which is in agreement with data of the Rock-Eval parameters. The gelification index （GI） and tissue preservation index （TPI） indicate that the coal developed in a telematic set up with high tree density. The ground water index （GWI） and vegetation index （VI） demonstrate that the peat developed as an ombrogenous bog.

Geology and geochemistry of Huanggangliang stratabound skarn deposit in Inner Mongolia,China

Over the recent three decades, exploration of a large-size Sn-Fe polymetallic ore deposit at the Huanggangliang, the Da Hinggan Mountains, Inner Mongolia, China, has been largely focused on the premise that the mineralization represents epigenetic magmatic hydrothermal ore deposit in genetic connection with the Mesozoic magmatism. The Huanggangliang Sn-Fe polymetallic ore deposits occurred in Permian strata, with silt- stone/marble of the Zhesi Formation and spilite/andesite/tuff of the Dashizhai Formation. The characteristics of geological and geochemical data demonstrated that sedimentary hydrothermal mineralization occurred during the basin evolution at the Permian, rather than representing epigenetie magmatic hydrothermal genesis with the following evidences. The ore-bearing skarus are stratiform with underlying metasedimentary rocks and overlying volcanic sedimentary rocks. Sedimentary hydrothermal textures and structures are observed in the stratabound ore-bearing skarn such as bedded-laminated skarn and magnetite ores with small-size folding or soft deforma- tion, synsedimentary breccia of skarn and magnetite ores and concentric shell structure of magnetite ores. So the stratabound ore-bearing skarns associated with magnetite ore and micro-disseminated tin, are peculiar examples of exhalite. The REE contents of the stratabound ore-bearing skarns display ∑LREE-rich （36.91×10^-6） but EHREE-depletion （6. 42 ×10^-6） , with positive Eu anomaly （Eu/Eu ＊ 1.28） and negative Ce anomaly （Ce/ Ce ＊ 0.88 ） , which is totally different from REE pattern of the Huanggang magmatic rocks（ with ∑REE 277.73 ×10^-6, ELREE 220.24 ×10^-6, ∑HREE 57.49 ×10^-6, Eu/Eu＊ 0.06, Ce/Ce＊ 1.52） , which is comparable with modern sea-floor hydrothermal fluid,sedimentary hydrothermal ore deposit and associated hydrothermal sedimentary rocks. Calcite samples with δ13CPDB from -5. 400 ‰ to -4. 397 ‰ and δ18SOSMOW from 9. 095 ‰ to 9. 364 ‰ in the stratabound ore-bearing skarns show sedimentary hydrothermal genesis of the Huanggangliang deposit. This proposition is useful not only for interpretation of the genesis of the Huanggangliang large Sn-Fe polymetallic ore deposit but also significant for mineral exploration in the area especially for finding large deposits caused by sedimentary exhalative mineralization processes.

Geochemistry of Neoproterozoic mixosedimentite in northern Anhui and its geological significance

Major oxides,as well as trace elements (including rare earth elements) compositions have been analyzed for the mixosedimentites from Neoproterozoic Jiayuan Formation in northern Anhui,China. The results show that the concentrations of elements are closely related to the relative proportions of carbonates and terrigenous detritus (varying from 2/3 to 1/9 based on petrographic study). The ratios between some immobile elements (e.g. La,Th,Zr and Sc) are constant and then can be used as tracers for the discrimination of provenance and tectonic setting of terrigenous detritus. The results indicate that the terrigenous detritus mainly came from the felsic volcanics related to continental arc,with minor contribution from the old basement. Combined with recent research progresses,these mixosedimentites imply that the Neoproterozoic sedimentation in northern Anhui was probably taken place in a back arc basin during the convergence of Rodinia super continent between 1.0 and 0.8 Ga.

Thoughts and effects for substituted resource prospecting in Laozuoshan gold deposit in Heilongjiang

According to the Geological settings and the distributed laws of ore bodies and previous research re- suits, combining with latest theories and new methods of geological prospecting, the authors proposed prospec- ting thoughts for substituted resources in Laozuoshan gold deposit. After ore prospecting in two years, nine new blind ore bodies were found, among which four ore bodies contain 4218. 1 kg inferred intrinsic economic re- sources （ 333 ）, and mitigate the crisis situation of mine reserves. At the same time, lots of significant geophysi- cal and geochemical anomalies were found in the peripheral, which provide a basis for further prospecting.

Mining-Induced Seismicity in the Kola Peninsula Mines

Mining-induced seismicity is a reflection of rock geomechanical evolution of geological environment in the natural and man-made systems and in the mining-technical systems. In order to predict and prevent mining-induced seismicity, it is necessary to research geodynamics and stress state of intact rock mass, to determine possible deformations and additional stresses as a result of large-scale rock extraction, conditions of accumulated energy release. For that a geodynamical monitoring is required on every stage of deposit development and a closing. The report considers principal influencing factors of preparation and occurrence of mining-induced earthquakes. Also it estimates precursors and indicators of rock mass breaking point, and experience concerning prediction and prevention of mining-induced seismicity in the Khibiny apatite mines in the Murmansk region, which is the largest mining province.

Petrogenesis of the concealed Daqiling intrusion in Guangxi and its tectonic significance: Constraints from geochemistry, zircon U-Pb dating and Nd-Hf isotopic compositions

The samples from the hidden Daqiling muscovite monzonite granite, which has recently been recognized within the Limu Sn-polymetallic ore field, have been analyzed for zircon U-Pb ages and whole rock geochemical and Nd-Hf isotopic compositions to discuss its genesis, source, and tectonic setting. LA-ICP-MS zircon U-Pb dating indicates that the granite crystallized in the late Indosinian（224.8±1.6 Ma）. The granite is enriched in SiO2 and K2 O and low in CaO and Na2 O. It is strongly peraluminous with the A/CNK values of 1.09–1.20 and 1.4 vol%–2.7 vol% normal corundum. Chondrite-normalized REE patterns show slightly right-dipping shape with strongly negative Eu anomalies（δEu =0.08–0.17）. All samples show enrichment of LILEs（Cs, Rb and K） and HFSEs（U, Pb, Ce and Hf）, but have relatively low contents of Ba, Sr and Ti. The zircon saturation temperatures（Tzr） are from 711 to 740°C, which are slightly lower than the average value of typical S-type granite（764°C）. The granite has negative εNd（t） and εHf（t） values, which change from ？9.1 to ？10.1 with the peak values of ？9.2 to ？9.0 and from ？3.7 to ？12.6 with the peak values of ？6 to ？5, respectively. The C DMT（Nd） and C DMT（Hf） values are 1.74–1.82 Ga with the peak values of 1.73–1.75 Ga and 1.49–2.04 Ga with the peak values of 1.5–1.6 Ga, respectively. These characteristics reveal that the source region of the granite is dominantly late Paleoproterozoic to early Mesoproterozoic crustal materials. Seven inherited magmatic zircons are dated at the age of 248.6±4.3 Ma, which suggests the existence of the early Indosinian granite in Limu area. These zircons have the εHf（t） values of ？6.7– ？2.3, similar to those of the Daqiling granite, implying the involvement of the early Indosinian granite during the formation of the Daqiling granite. Inherited zircon of 945±11 Ma has the εHf（t） and TDM（Hf） values of 8.7 and 1.14 Ga, respectively, compatible with those of the Neoproterozoic arc magmatic rocks in the eastern Jiangnan orogenic belt. Therefore we inferred that Neoproterozoic arc magma might have been involved in the formation of the Daqiling granite, and that the Neoproterozoic arc magma belt and continent-arc collision belt between the Yangtze and Cathaysia Blocks might have extended westsouthward to Limu region. It is proposed that the underplating of mantle materials triggered by crustal extension and thinning resulted in partial melting of crustal materials to form the Daqiling granite in the late Indosinian under post-collisional tectonic setting.

The geobiological formation process of the marine source rocks in the Middle Permian Chihsia Formation of South China

The Chihsia Formation is one of the four sets of regional marine hydrocarbon source rocks from South China.In the past two decades,detailed geochemical and sedimentological studies have been carried out to investigate its origination,which have demonstrated that the high primary productivity plays a primary role in the deposition of sediments enriched in the organic matter.However,the mechanism of this high productivity and the path of the deposition and burial of the organic matter have always been a mystery.Based on the previous studies on the Shangsi Section in Guangyuan City,Sichuan Province,we proposed that the development of the equatorial upwelling due to the sea level rise is responsible for the relatively high productivity in the Chihsia Formation.The sea waters with high nutrient were transported by the sub-surface currents along the equator.High organic carbon flux was deposited on the deeper shelf,and then decomposed by bacteria,leading to the occurrence of anaerobic respiration.The metabolism of the microorganisms consumed the dissolved oxygen in waters,which was in favor of the preservation of the organic matter.This suggested geobiological model integrating with paleoclimatology,paleoceanography and geomicrobiology will help us to understand the causes of this particular sedimentary sequence.

Origin and geological significance of the 1.81 Ga hyalophane-rich pegmatite veins from the high-pressure granulite terrain in the Central Zone of North China Craton

Hyalophane-rich pegmatites are identified from the Manjinggou high-pressure granulite terrain in the Central Zone of North China Craton. Based on field investigation, mineral assemblage and mineral geochemistry, two types of pegmatites can be defined, i.e., hyalophane pegmatite and hyalophane-rich pegmatite. The hyalophane pegmatite is composed of pure hyalophane with 18.7 mol%-19.4 mol% celsian, whereas the hyalophane-rich pegmatite consists of clinopyroxene + titanite + epidote + hyalophane with 11.9 mol%-12.5 mol% celsian. Hyalophane-rich pegmatite has typical magmatic zircons with oscillatory zoning and high Th/U ratios, implying that this type of pegmatite crystallized from special melt similar to magma. SIMS (Cameca 1280) zircon U-Pb dating shows that the crystallization age of the hyalophane-rich pegmatite is 1812±5 Ma, younger than the regional metamorphic age (peak of ca. 1.85 Ga). Zircon δ18O (8.0 ‰-9.3 ‰) and ?Hf (-7.0 to-2.7) values measured by SIMS suggest that the high-pressure granulite terrain was the source of these veins. Therefore, the hyalophane-rich pegmatite veins were likely to be generated by melting of the high-pressure granulite terrain during post collisional uplift. A quick tectonic uplifting process with a velocity of 0.4 to 0.6 mm/a has been estimated for the high-pressure granulite terrane from the Central Zone of North China Craton.