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AZ91D镁合金新型均一化前处理化学镀Ni-P合金的研究 被引量:1
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作者 孙灿 郭兴伍 +1 位作者 王少华 丁文江 《腐蚀科学与防护技术》 CAS CSCD 北大核心 2014年第4期295-300,共6页
采用新型环保均一化前处理工艺在AZ91D镁合金表面制备了化学镀Ni-P镀层。利用扫描电镜(SEM)、能谱仪(EDS)和X射线衍射仪(XRD)研究了镀层的微观形貌、成分和相结构。通过电化学方法和热震实验评价了镀层的电化学腐蚀行为和结合力。结果表... 采用新型环保均一化前处理工艺在AZ91D镁合金表面制备了化学镀Ni-P镀层。利用扫描电镜(SEM)、能谱仪(EDS)和X射线衍射仪(XRD)研究了镀层的微观形貌、成分和相结构。通过电化学方法和热震实验评价了镀层的电化学腐蚀行为和结合力。结果表明,经前处理后基体表面的β相(Mg17Al12)被选择性去除,表面组织均一化,从而得到了均匀致密的浸Zn层。Ni-P镀层均匀致密,P含量为7.0%,具有非晶结构。与AZ91D基体相比,Ni-P镀层的自腐蚀电位正移了1.136V,自腐蚀电流密度降低了两个数量级,表明镀层具有优良的耐腐蚀性能。热震实验表明镀层与基体之间结合良好。 展开更多
关键词 AZ91D镁合金 均一化前处理 学镀NI-P 腐蚀电学行为
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Homogenization pretreatment and electroless Ni-P plating on AZ91D magnesium alloy 被引量:1
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作者 孙灿 郭兴伍 +2 位作者 王少华 郭嘉成 丁文江 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2014年第12期3825-3833,共9页
Electroless nickel plating on AZ91D substrate with a new and eco-friendly pretreatment process based on tuning an electrochemical homogeneous surface was investigated. The morphology, deposition process, chemical comp... Electroless nickel plating on AZ91D substrate with a new and eco-friendly pretreatment process based on tuning an electrochemical homogeneous surface was investigated. The morphology, deposition process, chemical composition and microstructure of Ni-P coating were studied. It is indicated that β phases are selectively removed, producing a microstructural homogeneous surface and the subsequent uniform and compact Zn immersion layer. A defect-free and well adhesive Ni-P coating can be successfully obtained due to its uniform nucleation and growth based on such pretreatment. Potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) tests reveal that Ni-P coating could significantly improve the corrosion resistance of AZ91D substrate. 展开更多
关键词 AZ91D magnesium alloy homogenization pretreatment electroless nickel plating CORROSION
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