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纳米TiO_2-甲基丙烯酸甲酯聚合物均匀分散系的制备和结构 被引量:38
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作者 张晔 周贵恩 +1 位作者 李磊 张裕恒 《材料研究学报》 EI CAS CSCD 北大核心 1998年第3期291-294,共4页
以具有不饱和双键的油酸为表面活性剂,甲基丙烯酸甲酯为活性溶剂制备了稳定的纳米TiO2溶胶,将溶胶自由基引发聚合制成了纳米TiO2粒子/聚甲基丙烯酸甲酯均匀分散系结果表明高聚物中存在以TiO2超微粒为核心交联网络结构.用透射电镜观... 以具有不饱和双键的油酸为表面活性剂,甲基丙烯酸甲酯为活性溶剂制备了稳定的纳米TiO2溶胶,将溶胶自由基引发聚合制成了纳米TiO2粒子/聚甲基丙烯酸甲酯均匀分散系结果表明高聚物中存在以TiO2超微粒为核心交联网络结构.用透射电镜观察和紫外-可见光吸收谱测量油酸包覆的纳米TiO2微粒在有机环境中的形貌、分布及尺寸变化当溶胶中TiO2的浓度小于或等于0.032%(mol百分数,下同)时,TiO2的粒径呈一窄的单分布范围为5~30nm.浓度高于0.032%时,粒子长大,粒径分布在两个区:5~30nm和50~180nm.加油酸的溶胶中TiO2颗粒形状呈类球形,未加油酸的溶胶中大部分粒子呈圆球形. 展开更多
关键词 油酸包覆 高聚物 均匀分散系 二氧化钛 PMMA
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Mechanism of heterogeneous distribution of Cr-containing dispersoids in DC casting 7475 aluminum alloy 被引量:1
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作者 Yi-ran ZHOU Ni TIAN +5 位作者 Wei LIU Yu ZENG Guang-dong WANG Shi-da HAN Gang ZHAO Gao-wu QIN 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2022年第5期1416-1427,共12页
The actual effective partition coefficients of Mg and Cr in a cross-section of a dendrite arm in a direct-chill(DC)-casting ingot of 7475 aluminum alloy are obtained.Meanwhile,by analyzing the microstructure,the mecha... The actual effective partition coefficients of Mg and Cr in a cross-section of a dendrite arm in a direct-chill(DC)-casting ingot of 7475 aluminum alloy are obtained.Meanwhile,by analyzing the microstructure,the mechanism of the heterogeneous distribution of E(Al_(18)Mg_(3)Cr_(2))dispersoids in this DC ingot is revealed.The results show that the actual effective partition coefficients of Mg and Cr are 0.650 and 1.392,respectively,and they describe the heterogeneous distributions of Mg and Cr along the direction of radius of the cross-section of the dendrite arm of the alloy.After homogenization treatment at 470℃ for 24 h,Mg diffuses uniformly,but Cr hardly diffuses.Both the concentrations of Mg and Cr and the sites of heterogeneous nucleation in the alloy are the determinants of the formation of E dispersoids simultaneously.The heat treatment at 250℃ for 72 h provides a large number of the sites of heterogeneous nucleation of the formation of fine E dispersoids that will be formed in the center of the cross-section during the subsequent heat treatment at higher temperature. 展开更多
关键词 7475 aluminum alloy direct-chill-casting ingot Al18Mg3Cr2 dispersoids heterogeneous distribution effective partition coefficient
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BIFURCATION AND SPATIOTEMPORAL PATTERNS IN A HOMOGENEOUS DIFFUSION-COMPETITION SYSTEM WITH DELAYS
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作者 JIA-FANG ZHANG WAN-TONG LI XIANG-PING YAN 《International Journal of Biomathematics》 2012年第6期19-41,共23页
A competitive LotkaVolterra reactiondiffusion system with two delays subject to Neumann boundary conditions is considered. It is well known that the positive con stant steady state of the system is globally asymptotic... A competitive LotkaVolterra reactiondiffusion system with two delays subject to Neumann boundary conditions is considered. It is well known that the positive con stant steady state of the system is globally asymptotically stable if the interspecies competition is weaker than the intraspecies one and is unstable if the interspecies com petition dominates over the intraspecies one. If the latter holds, then we show that Hopf bifurcation can occur as the parameters (delays) in the system cross some critical val ues. In particular, we prove that these Hopf bifurcations are all spatially homogeneous if the diffusive rates are suitably large, which has the same properties as Hopf bifur cation of the corresponding delayed system without diffusion. However, if the diffusive rates are suitably small, then the system generates the spatially nonhomogeneous Hopf bifurcation. Furthermore, we derive conditions for determining the direction of spatially nonhomogeneous Hopf bifurcations and the stability of bifurcating periodic solutions. These results indicate that the diffusion plays an important role for deriving the complex spatiotemporal dynamics. 展开更多
关键词 LotKa-Volterra competition system time delay spatial diffusion Hopf bifur-cation periodic solution.
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