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典型农业生物质催化气化反应动力学特性研究 被引量:11
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作者 胡松 付鹏 +3 位作者 向军 张安超 孙路石 张军营 《太阳能学报》 EI CAS CSCD 北大核心 2008年第6期716-721,共6页
以CaO、MgO和Fe_2O_3为催化剂,用程序升温热重法对典型农业生物质催化气化特性及反应动力学进行了研究。利用均相反应模型和缩核反应模型对转化率与温度的关系进行了拟和计算,得到了谷壳样在4种不同二氧化碳气化条件下热解阶段及焦炭气... 以CaO、MgO和Fe_2O_3为催化剂,用程序升温热重法对典型农业生物质催化气化特性及反应动力学进行了研究。利用均相反应模型和缩核反应模型对转化率与温度的关系进行了拟和计算,得到了谷壳样在4种不同二氧化碳气化条件下热解阶段及焦炭气化阶段的活化能和指数前因子。结果表明,在820~1000℃区间内,添加CaO的谷壳样表观活化能比谷壳的大;而添加MgO和Fe_2O_3的谷壳样表观活化能与谷壳的相比,分别下降了32.6%和17.9%以上,可以看出3种催化剂催化活性大小顺序为MgO>Fe_2O_3>CaO,活化能区间范围为15.25~123.74kJ/ mol。研究表明在低温区间(热解阶段),反应机理更趋向于均相反应模型,而在高温区间(气化阶段),反应机理更趋向于缩核反应模型。最后给出了谷壳在热解阶段及焦炭气化阶段的反应动力学方程。 展开更多
关键词 农业生物质 催化气化 动力学 均相反应模型 缩核反模型
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Study on Residual Oil HDS Process with Mechanism Model and ANN Model
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作者 Ma Chengguo Weng Huixin (Research Center of Petroleum Processing, ECUST, Shanghai 200237) 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2009年第1期39-43,共5页
Based on the Residual Oil Hydrodesulfurization Treatment Unit (S-RHT), the n-order reaction kinetic model for residual oil HDS reactions and artificial neural network (ANN) model were developed to determine the sulfur... Based on the Residual Oil Hydrodesulfurization Treatment Unit (S-RHT), the n-order reaction kinetic model for residual oil HDS reactions and artificial neural network (ANN) model were developed to determine the sulfur content of hydrogenated residual oil. The established ANN model covered 4 input variables, 1 output variable and 1 hidden layer with 15 neurons. The comparison between the results of two models was listed. The results showed that the predicted mean relative errors of the two models with three different sample data were less than 5% and both the two models had good predictive precision and extrapolative feature for the HDS process. The mean relative error of 5 sets of testing data of the ANN model was 1.62%—3.23%, all of which were smaller than that of the common mechanism model (3.47%— 4.13%). It showed that the ANN model was better than the mechanism model both in terms of fitting results and fitting difficulty. The models could be easily applied in practice and could also provide a reference for the further research of residual oil HDS process. 展开更多
关键词 residual oil hydrodesulfurization (HDS) mechanism model artificial neural network (ANN) model
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