Stability assessment of slopes has historically been performed assuming soils to be homogeneous in two-dimensional(2D) cases. In real cases, soils are usually inhomogeneous, and each slope collapse indicates a three-d...Stability assessment of slopes has historically been performed assuming soils to be homogeneous in two-dimensional(2D) cases. In real cases, soils are usually inhomogeneous, and each slope collapse indicates a three-dimensional(3D) nature. Based on a 3D rotational failure mechanism, this work develops an approach to account for the impact of the vertical strength inhomogeneity on the 3D stability of stepped slopes. Seismic actions are taken into account by introducing the concept of a horizontal seismic coefficient. An upper-bound expression for stability factors is derived in the light of the kinematic approach, and the most critical solution is obtained from an optimization programming. In comparison with the previously published solutions, the validity of the proposed method is shown. A sensitivity analysis is carried out to discuss parametric effects on the stability of 3D stepped inhomogeneous slopes.展开更多
Homogeneity and heterogeneity are two totally different concepts in nature.At the particle length scale,rocks exhibit strong heterogeneity in their constituents and porosities.When the heterogeneity of porosity obeys ...Homogeneity and heterogeneity are two totally different concepts in nature.At the particle length scale,rocks exhibit strong heterogeneity in their constituents and porosities.When the heterogeneity of porosity obeys the random uniform distribution,both the mean value and the variance of porosities in the heterogeneous porosity field can be used to reflect the overall heterogeneous characteristics of the porosity field.The main purpose of this work is to investigate the effects of porosity heterogeneity on chemical dissolution front instability in fluid-saturated rocks by the computational simulation method.The related computational simulation results have demonstrated that:1) since the propagation speed of a chemical dissolution front is inversely proportional to the difference between the final porosity and the mean value of porosities in the initial porosity field,an increase in the extent of the porosity heterogeneity can cause an increase in the mean value of porosities in the initial porosity field and an increase in the propagation speed of the chemical dissolution front.2) An increase in the variance of porosities in the initial porosity field can cause an increase in the instability probability of the chemical dissolution front in the fluid-saturated rock.3) The greater the mean value of porosities in the initial porosity field,the quicker the irregular morphology of the chemical dissolution front changes in the supercritical chemical dissolution systems.This means that the irregular morphology of a chemical dissolution front grows quicker in a porosity field of heterogeneity than it does in that of homogeneity when the chemical dissolution system is at a supercritical stage.展开更多
Based on the heterogeneity of fault plane strength,the macro rupture process of a fault plane can be treated as the rupture accumulation process of local micro-elements in the fault surface.Assuming that the strength ...Based on the heterogeneity of fault plane strength,the macro rupture process of a fault plane can be treated as the rupture accumulation process of local micro-elements in the fault surface.Assuming that the strength of the local micro-elements follows the Weibull probability distribution,the macro-fault constitutive relationship of the complete load-deformation process is derived from a statistical mechanics viewpoint.Applying a one-dimensional earthquake mechanics model and using far-field displacement a as the control variable,the problem of earthquake instability is investigated by employing the stability theory.The results show that the system stiffness ratio(stiffness ratio of fault to surroun-ding rock) β is the important parameter that affects the occurrence of earthquakes.Earthquake instability occurs only when β < 1,and the sudden stress jump appears at the displacement turning point of the equilibrium path curve.The expression of three important parameters for earthquakes(fault half-dislocation distance after earthquake,earthquake stress drop and elastic energy release) is also given.When β≥1,the earthquake does not occur and the fault only slips slowly without an earthquake.展开更多
Perfluorolyether is characterized by highly chemical inertness, oxidative stability, anticorrosion as well as radiation resistance. It can be used as lubricant especially in harsh environmental conditions. In this wor...Perfluorolyether is characterized by highly chemical inertness, oxidative stability, anticorrosion as well as radiation resistance. It can be used as lubricant especially in harsh environmental conditions. In this work, hexafluoropylene oxide was catalytically polymerized at low temperature using the methods of anionic polymerization, and perfluorolyethers were obtained with number-average degree of polymerization more than 15. CsF and RbF were used as catalysts and their catalytic activities were investigated. Experimental results show that perfluorolyethers with number-average molar masses up to 3 000 g/mol could be obtained using the two kinds of catalysts, respectively. As compared to CsF, the number-average degree of polymerization is higher and the relative molecular mass distribution interval is narrower when RbF is used as catalyst. The effect of factors such as impurities＇ content, reaction temperature and reaction time on the number-average degree of polymerization was also investigated. It is found that low impurities＇ content and low temperature are beneficial to the generation of high number-average degree of perfluorolyethers. The optimization reaction time is 24 h, and fiarther increase of reaction time does not significantly affect the average relative molecular mass. The product was characterized by IR, 19F NMR and GC-MS, and the catalytic mechanism was analyzed finally.展开更多
The growth of mixing zone on an interface induced by Richtmyer-Meshkov(RM)instability occurs frequently in natural phenomena and in engineering applications.Usually,the medium on which the RM instability happens is in...The growth of mixing zone on an interface induced by Richtmyer-Meshkov(RM)instability occurs frequently in natural phenomena and in engineering applications.Usually,the medium on which the RM instability happens is inhomogeneous,the effect of medium inhomogeneity on the growth of the mixing zone during the RM instability is still not clear.Therefore,it is necessary to investigate the RM instability in inhomogeneous medium.Based on a high-order computational scheme,the interactions of a density interface with an incident shock wave(ISW)in inhomogeneous medium are numerically simulated by solving the compressible Navier-Stokes equations.The effect of the inhomogeneity on the interface evolution after the passage of ISW through the interface is investigated.The results show that the interface morphology develops in a distinctive "spike-spike"structure in inhomogeneous medium.Particularly,the spike structure on the bottom of the interface is due to the reverse induction of RM instability by curved ISW or reflected shock wave.With the increase of inhomogeneity,the growth rate of the mixing zone width on interface increases,and the wave patterns caused by interaction between the shock wave and interface are more complex.Compared with RM instability in homogeneous medium,the inhomogeneous distribution of the density in medium further enhances the baroclinic effect and induces larger vorticity in flow field.Therefore,the interface is stretched much more significantly under the induction of enhanced vorticity in inhomogeneous medium.Based on above analyses,a model for predicting the growth of mixing zone width on the interface after the passage of ISW is proposed,in order to provide a useful method for evaluations of perturbation growth behavior during the RM instability in inhomogeneous medium.展开更多
基金Project(51378510)supported by the National Natural Science Foundation of China
文摘Stability assessment of slopes has historically been performed assuming soils to be homogeneous in two-dimensional(2D) cases. In real cases, soils are usually inhomogeneous, and each slope collapse indicates a three-dimensional(3D) nature. Based on a 3D rotational failure mechanism, this work develops an approach to account for the impact of the vertical strength inhomogeneity on the 3D stability of stepped slopes. Seismic actions are taken into account by introducing the concept of a horizontal seismic coefficient. An upper-bound expression for stability factors is derived in the light of the kinematic approach, and the most critical solution is obtained from an optimization programming. In comparison with the previously published solutions, the validity of the proposed method is shown. A sensitivity analysis is carried out to discuss parametric effects on the stability of 3D stepped inhomogeneous slopes.
基金Project(11272359)supported by the National Natural Science Foundation of China
文摘Homogeneity and heterogeneity are two totally different concepts in nature.At the particle length scale,rocks exhibit strong heterogeneity in their constituents and porosities.When the heterogeneity of porosity obeys the random uniform distribution,both the mean value and the variance of porosities in the heterogeneous porosity field can be used to reflect the overall heterogeneous characteristics of the porosity field.The main purpose of this work is to investigate the effects of porosity heterogeneity on chemical dissolution front instability in fluid-saturated rocks by the computational simulation method.The related computational simulation results have demonstrated that:1) since the propagation speed of a chemical dissolution front is inversely proportional to the difference between the final porosity and the mean value of porosities in the initial porosity field,an increase in the extent of the porosity heterogeneity can cause an increase in the mean value of porosities in the initial porosity field and an increase in the propagation speed of the chemical dissolution front.2) An increase in the variance of porosities in the initial porosity field can cause an increase in the instability probability of the chemical dissolution front in the fluid-saturated rock.3) The greater the mean value of porosities in the initial porosity field,the quicker the irregular morphology of the chemical dissolution front changes in the supercritical chemical dissolution systems.This means that the irregular morphology of a chemical dissolution front grows quicker in a porosity field of heterogeneity than it does in that of homogeneity when the chemical dissolution system is at a supercritical stage.
基金supported by the Central Public-interest Scientific Institution Basal Research Fund of Institute of Geophysics,China Earthquake Administration(DQJB08B21)
文摘Based on the heterogeneity of fault plane strength,the macro rupture process of a fault plane can be treated as the rupture accumulation process of local micro-elements in the fault surface.Assuming that the strength of the local micro-elements follows the Weibull probability distribution,the macro-fault constitutive relationship of the complete load-deformation process is derived from a statistical mechanics viewpoint.Applying a one-dimensional earthquake mechanics model and using far-field displacement a as the control variable,the problem of earthquake instability is investigated by employing the stability theory.The results show that the system stiffness ratio(stiffness ratio of fault to surroun-ding rock) β is the important parameter that affects the occurrence of earthquakes.Earthquake instability occurs only when β < 1,and the sudden stress jump appears at the displacement turning point of the equilibrium path curve.The expression of three important parameters for earthquakes(fault half-dislocation distance after earthquake,earthquake stress drop and elastic energy release) is also given.When β≥1,the earthquake does not occur and the fault only slips slowly without an earthquake.
基金Project(53110704012) supported by the Fundamental Research Funds for the Central Universities,China
文摘Perfluorolyether is characterized by highly chemical inertness, oxidative stability, anticorrosion as well as radiation resistance. It can be used as lubricant especially in harsh environmental conditions. In this work, hexafluoropylene oxide was catalytically polymerized at low temperature using the methods of anionic polymerization, and perfluorolyethers were obtained with number-average degree of polymerization more than 15. CsF and RbF were used as catalysts and their catalytic activities were investigated. Experimental results show that perfluorolyethers with number-average molar masses up to 3 000 g/mol could be obtained using the two kinds of catalysts, respectively. As compared to CsF, the number-average degree of polymerization is higher and the relative molecular mass distribution interval is narrower when RbF is used as catalyst. The effect of factors such as impurities＇ content, reaction temperature and reaction time on the number-average degree of polymerization was also investigated. It is found that low impurities＇ content and low temperature are beneficial to the generation of high number-average degree of perfluorolyethers. The optimization reaction time is 24 h, and fiarther increase of reaction time does not significantly affect the average relative molecular mass. The product was characterized by IR, 19F NMR and GC-MS, and the catalytic mechanism was analyzed finally.
文摘The growth of mixing zone on an interface induced by Richtmyer-Meshkov(RM)instability occurs frequently in natural phenomena and in engineering applications.Usually,the medium on which the RM instability happens is inhomogeneous,the effect of medium inhomogeneity on the growth of the mixing zone during the RM instability is still not clear.Therefore,it is necessary to investigate the RM instability in inhomogeneous medium.Based on a high-order computational scheme,the interactions of a density interface with an incident shock wave(ISW)in inhomogeneous medium are numerically simulated by solving the compressible Navier-Stokes equations.The effect of the inhomogeneity on the interface evolution after the passage of ISW through the interface is investigated.The results show that the interface morphology develops in a distinctive "spike-spike"structure in inhomogeneous medium.Particularly,the spike structure on the bottom of the interface is due to the reverse induction of RM instability by curved ISW or reflected shock wave.With the increase of inhomogeneity,the growth rate of the mixing zone width on interface increases,and the wave patterns caused by interaction between the shock wave and interface are more complex.Compared with RM instability in homogeneous medium,the inhomogeneous distribution of the density in medium further enhances the baroclinic effect and induces larger vorticity in flow field.Therefore,the interface is stretched much more significantly under the induction of enhanced vorticity in inhomogeneous medium.Based on above analyses,a model for predicting the growth of mixing zone width on the interface after the passage of ISW is proposed,in order to provide a useful method for evaluations of perturbation growth behavior during the RM instability in inhomogeneous medium.
