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中国地面相对湿度非均一性检验及订正 被引量:19
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作者 朱亚妮 曹丽娟 +1 位作者 唐国利 周自江 《气候变化研究进展》 CSCD 北大核心 2015年第6期379-386,共8页
利用加拿大环境部气候研究中心研发的PMTred和PMFT方法,选取均一的邻近站为参考站,使用相关系数权重平均构建参考序列,结合元数据信息,对1951—2014年中国2400多个国家级地面站月平均相对湿度进行了非均一性检验与订正,并分析了造成相... 利用加拿大环境部气候研究中心研发的PMTred和PMFT方法,选取均一的邻近站为参考站,使用相关系数权重平均构建参考序列,结合元数据信息,对1951—2014年中国2400多个国家级地面站月平均相对湿度进行了非均一性检验与订正,并分析了造成相对湿度序列非均一的主要原因。结果表明,中国地面相对湿度资料存在较严重的非均一问题,68%的台站存在断点,人工观测转自动观测、迁站和时次变化是造成序列非均一的主要原因。整套资料负订正量所占比例较高,订正范围主要集中在-5%~0之间,这种负订正量与人工转自动观测后相对湿度观测值偏低有密切关系。这也使得订正后中国平均相对湿度趋势与订正前存在明显差异,订正前中国平均相对湿度呈下降趋势,订正后相对湿度没有趋势性变化。 展开更多
关键词 相对湿度 均-性检验与订正 人工转自动 PMTred和PMFT方法
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风速对空调实验室气流分布均匀性的影响分析
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作者 韩盼 李征涛 +2 位作者 路坤 杨志明 田炜丰 《建模与仿真》 2020年第3期223-231,共9页
空调实验室温度场、速度场的均匀性的研究对被侧机的性能测试有着重要意义,本文以某企业已建成的实验室为研究对象,通过CFD (Computational Fluid Dynamics)建模将模拟的数据与实验数据进行对比,其中速度场的相对误差基本在10%以下,温... 空调实验室温度场、速度场的均匀性的研究对被侧机的性能测试有着重要意义,本文以某企业已建成的实验室为研究对象,通过CFD (Computational Fluid Dynamics)建模将模拟的数据与实验数据进行对比,其中速度场的相对误差基本在10%以下,温度场实际测量值与模拟计算值差值控制在0.05 K^0.25 K,综合考虑模型是可以用做优化分析。本文提出通过改变送风速度来改善实验室内部温度场均匀性,通过模拟发现当送风速度为3.5 m/s时,实验室内部流场均匀性明显提升,但当继续增大送风速度时,温度场变化逐渐剧烈,因此,小幅度地提高风速会使实验室内部流场更加均匀,但当风速达到一定值时,就会使实验室温度场均匀性下降。 展开更多
关键词 空调实验室 CFD 风速
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Impact of correlated private signals on continuous-time insider trading
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作者 ZHOU Yonghui XIAO Kai 《运筹学学报(中英文)》 CSCD 北大核心 2024年第3期97-107,共11页
A model of continuous-time insider trading in which a risk-neutral in-sider possesses two imperfect correlated signals of a risky asset is studied.By conditional expectation theory and filtering theory,we first establ... A model of continuous-time insider trading in which a risk-neutral in-sider possesses two imperfect correlated signals of a risky asset is studied.By conditional expectation theory and filtering theory,we first establish three lemmas:normal corre-lation,equivalent pricing and equivalent profit,which can guarantee to turn our model into a model with insider knowing full information.Then we investigate the impact of the two correlated signals on the market equilibrium consisting of optimal insider trading strategy and semi-strong pricing rule.It shows that in the equilibrium,(1)the market depth is constant over time;(2)if the two noisy signals are not linerly correlated,then all private information of the insider is incorporated into prices in the end while the whole information on the asset value can not incorporated into prices in the end;(3)if the two noisy signals are linear correlated such that the insider can infer the whole information of the asset value,then our model turns into a model with insider knowing full information;(4)if the two noisy signals are the same then the total ex ant profit of the insider is increasing with the noise decreasing,while down to O as the noise going up to infinity;(5)if the two noisy signals are not linear correlated then with one noisy signal fixed,the total ex ante profit of the insider is single-peaked with a unique minimum with respect to the other noisy signal value,and furthermore as the noisy value going to O it gets its maximum,the profit in the case that the real value is observed. 展开更多
关键词 continuous-time insider trading risk neutral private correlated signals linear bayesian equilibrium market depth residual information
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Structure uniformity and limits of grain refinement of high purity aluminum during multi-directional forging process at room temperature 被引量:6
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作者 朱庆丰 李磊 +3 位作者 班春燕 赵志浩 左玉波 崔建忠 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2014年第5期1301-1306,共6页
The effect of forging passes on the refinement of high purity aluminum during multi-forging was investigated. The attention was focused on the structure uniformity due to deformation uniformity and the grain refinemen... The effect of forging passes on the refinement of high purity aluminum during multi-forging was investigated. The attention was focused on the structure uniformity due to deformation uniformity and the grain refinement limitation with very high strains. The results show that the fine grain zone in the center of sample expands gradually with the increase of forging passes. When the forging passes reach 6, an X-shape fine grain zone is initially formed. With a further increase of the passes, this X-shape zone tends to spread the whole sample. Limitation in the structural refinement is observed with increasing strains during multi-forging process at the room temperature. The grains size in the center is refined to a certain size (110 μm as forging passes reach 12, and there is no further grain refinement in the center with increasing the forging passes to 24. However, the size of the coarse grains near the surface is continuously decreased with increasing the forging passes to 24. 展开更多
关键词 multi-directional forging high purity aluminum structure uniformity grain refinement
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Inhomogeneity of density and mechanical properties of A357 aluminum alloy backward extruded in semi-solid state 被引量:6
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作者 杜之明 陈刚 +1 位作者 程远胜 谢水生 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2011年第10期2285-2293,共9页
The inhomogeneity of density and mechanical properties of A357 aluminum alloy in the semi-solid state were investigated.Numerical simulation and backward extrusion were adopted to study the preparation of cup shells.T... The inhomogeneity of density and mechanical properties of A357 aluminum alloy in the semi-solid state were investigated.Numerical simulation and backward extrusion were adopted to study the preparation of cup shells.The results show that the relative density of the wall is the lowest in samples,and that of the base is the highest.With increasing the billet height,more time is needed for relative density of the corner to reach the maximum value,and the relative densities in every region improve evidently with increasing the pressure.The tensile stress was simulated to be the largest at the corner,and the hot tearings were forecasted to mainly appear at the corner too.By employing proper billet height and pressure,the extruded samples consisted of fine and uniform microstructures,and can obtain excellent mechanical properties and Brinell hardness. 展开更多
关键词 A357 aluminum alloy INHOMOGENEITY semi-solid state backward extrusion numerical simulation
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Study on Various Rectifiers for Fan-Filter Units 被引量:3
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作者 刘俊杰 涂光备 马九贤 《Transactions of Tianjin University》 EI CAS 2002年第2期119-124,共6页
The face velocities of the high efficiency particulate air filters and the ultra low penetration airfilters in fan filter units (FFUs) have large relative standard deviation and turbulivity. It seriously affects the ... The face velocities of the high efficiency particulate air filters and the ultra low penetration airfilters in fan filter units (FFUs) have large relative standard deviation and turbulivity. It seriously affects the unidirectivity of the flow in the unidirectional flow clean zone and cleanroom. The cross contamination in this kind of unidirectional flow area is hardly controlled. It is significant to find optional method for keeping the face velocity uniformity of FFU and reducing the face velocity turbulivity of FFU, furthermore, to keep the cleanliness level under FFUs. The normal and easy method is to add flow rectifiers under filters. FFUs with various flow rectifiers have been tested. The uniformity and turbulivity of facevelocity under the FFU are presented in this paper. The influence of the facevelocity uniformity and turbulivity on the contamination boundary of the unidirectional flow is studiedas well. 展开更多
关键词 unidirectional flow air velocity UNIFORMITY turbulivity flow rectifier fan filter unit (FFU)
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DRX rules during extrusion process of large-scale thick-walled Inconel 625 pipe by FE method 被引量:4
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作者 党利 杨合 +3 位作者 郭良刚 石磊 张君 郑文达 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第9期3037-3047,共11页
A thermal-mechanical and micro-macro coupled finite element(FE) model for the hot extrusion process of large-scale thick-walled Inconel 625 pipe was developed based on the DEFORM-2D platform.Then,the influence rules... A thermal-mechanical and micro-macro coupled finite element(FE) model for the hot extrusion process of large-scale thick-walled Inconel 625 pipe was developed based on the DEFORM-2D platform.Then,the influence rules of the key extrusion parameters on the average grain size and grain uniformity of the extruded pipe were revealed.The results show that with the increase of initial billet temperature,extrusion speed and friction coefficient,the grain uniformity is firstly improved and then deteriorated.Larger extrusion ratio leads to more uniform grain distribution.With the increase of initial billet temperature,the average grain size of the pipe first decreases and then increases.Additionally,larger extrusion ratio can bring smaller average grain size.The extrusion speed and friction coefficient have slight effects on the average grain size of the extruded pipe. 展开更多
关键词 Inconel 625 alloy large-scale thick-walled pipe extrusion dynamic recrystallization grain size grain uniformity
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Effect of melt superheat on structural uniformity of lotus-type porous metals prepared by unidirectional solidification 被引量:2
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作者 刘源 张华伟 李言祥 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第3期1004-1010,共7页
Structural uniformity is an important parameter influencing physical and mechanical properties of lotus-type porous metals prepared by directional solidification of metal-gas eutectic (Gasar). The effect of superheat ... Structural uniformity is an important parameter influencing physical and mechanical properties of lotus-type porous metals prepared by directional solidification of metal-gas eutectic (Gasar). The effect of superheat on structural uniformity as well as average porosity, pore morphology of porous metals was studied. The experimental results show that, when the superheat is higher than a critical value (ΔTc), the bubbling or boiling phenomenon will occur and the gas bubbles will form in the melt and float out of the melt. As a result, the final porosity will decrease. In addition, a higher superheat will simultaneously cause a non-uniform porous structure due to the pores coalescence and bubbling phenomenon. Finally, a theoretical model was developed to predict the critical superheat for the hydrogen to escape from the melt and the corresponding escapement ratio of hydrogen content. Considering the escapement of hydrogen, the predicted porosities are in good agreement with the experimental results. 展开更多
关键词 unidirectional solidification porous metals melt superheat structural uniformity
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Characterizing heterogeneity in vehicular traffic speed using two-step cluster analysis 被引量:3
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作者 潘义勇 孙璐 《Journal of Southeast University(English Edition)》 EI CAS 2012年第4期480-484,共5页
In order to analyze the heterogeneity in vehicular traffic speed, a new method that integrates cluster analysis and probability distribution function fitting is presented. First, for identifying the optimal number of ... In order to analyze the heterogeneity in vehicular traffic speed, a new method that integrates cluster analysis and probability distribution function fitting is presented. First, for identifying the optimal number of clusters, the two-step cluster method is applied to analyze actual speed data, which suggests that dividing speed data into two clusters can best reflect the intrinsic patterns of traffic flows. Such information is then taken as guidance in probability distribution function fitting. The normal, skew-normal and skew-t distribution functions are used to fit the probability distribution of each cluster respectively, which suggests that the skew-t distribution has the highest fitting accuracy; the second is skew-normal distribution; the worst is normal distribution. Model analysis results demonstrate that the proposed mixture model has a better fitting and generalization capability than the conventional single model. In addition, the new method is more flexible in terms of data fitting and can provide a more accurate model of speed distribution. 展开更多
关键词 speed distribution HETEROGENEITY mixture model cluster analysis
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Performance of Wavelet-Transform-Domain Adaptive Equalizers 被引量:4
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作者 吴炳洋 陈琦帆 程时昕 《Journal of Southeast University(English Edition)》 EI CAS 2002年第1期13-18,共6页
In this paper performances of wavelet transform domain (WTD) adaptive equalizers based on the least mean ̄square (LMS) algorithm are analyzed. The optimum Wiener solution, the condition of convergence, the minimum ... In this paper performances of wavelet transform domain (WTD) adaptive equalizers based on the least mean ̄square (LMS) algorithm are analyzed. The optimum Wiener solution, the condition of convergence, the minimum mean square error (MSE) and the steady state excess MSE of the WTD adaptive equalizer are obtained. Constant and time varying convergence factor adaptive algorithms are studied respectively. Computational complexities of WTD LMS equalizers are given. The equalizer in WTD shows much better convergence performance than that of the conventional in time domain. 展开更多
关键词 WAVELET transform domain wavelet transform domain LMS adaptive equalizer
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ALLIED FUZZY c-MEANS CLUSTERING MODEL 被引量:2
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作者 武小红 周建江 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI 2006年第3期208-213,共6页
A novel model of fuzzy clustering, i.e. an allied fuzzy c means (AFCM) model is proposed based on the combination of advantages of fuzzy c means (FCM) and possibilistic c means (PCM) clustering. PCM is sensitive... A novel model of fuzzy clustering, i.e. an allied fuzzy c means (AFCM) model is proposed based on the combination of advantages of fuzzy c means (FCM) and possibilistic c means (PCM) clustering. PCM is sensitive to initializations and often generates coincident clusters. AFCM overcomes this shortcoming and it is an ex tension of PCM. Membership and typicality values can be simultaneously produced in AFCM. Experimental re- suits show that noise data can be well processed, coincident clusters are avoided and clustering accuracy is better. 展开更多
关键词 fuzzy c-means clustering possibilistic c means clustering allied fuzzy c-means clustering
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A BEEM Study on Effects of Annealing Temperature on Barrier Height Inhomogeneity of CoSi_2/Si Contact Formed in Co-Ti-Si Systems 被引量:1
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作者 竺士炀 屈新萍 +1 位作者 茹国平 李炳宗 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2002年第1期6-10,共5页
Ultra thin epitaxial CoSi 2 films are fabricated by solid state reaction of a deposited bilayer of Co(3nm)/Ti (1nm) on n Si(100) substrates at different temperatures.The local barrier heights of the CoSi 2/Si cont... Ultra thin epitaxial CoSi 2 films are fabricated by solid state reaction of a deposited bilayer of Co(3nm)/Ti (1nm) on n Si(100) substrates at different temperatures.The local barrier heights of the CoSi 2/Si contacts are determined by using the ballistic electron emission microscopy (BEEM) and its spectroscopy (BEES) at low temperature.For CoSi 2/Si contact annealed at 800℃,the spatial distribution of barrier heights,which have mean barrier height of 599meV and a standard deviation of 21meV,obeys the Gaussian Function.However,for a sample that is annealed at 700℃,the barrier heights of it are more inhomogenous.Its local barrier heights range from 152meV to 870meV,which implies the large inhomogeneity of the CoSi 2 film. 展开更多
关键词 BEEM schottky barrier height SILICIDE INHOMOGENEITY
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Schottky Barrier Characteristics of Polycrystalline and Epitaxial CoSi_2/n-Si(111) Contacts Formed by Solid State Reaction
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作者 竺士炀 茹国平 +1 位作者 屈新萍 李炳宗 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2001年第6期689-694,共6页
Polycrystalline and epitaxial CoSi 2 films are formed on the n-Si (111) substrates by solid state reaction of the as-deposited Co single-layer and Co/Ti bilayer with Si,respectively at different annealing phase.The C... Polycrystalline and epitaxial CoSi 2 films are formed on the n-Si (111) substrates by solid state reaction of the as-deposited Co single-layer and Co/Ti bilayer with Si,respectively at different annealing phase.The CoSi 2/Si Schottky contacts are measured with the current-voltage and capacitance-voltage (I-V/C-V) techniques within the range of temperature from 90K to room temperature.The measured I-V characteristics have been analyzed with a model based on the inhomogeneity in Schottky barrier height,i.e.,at high temperatures (≥~200K) or low temperatures but with a large bias,the I-V curves can be described by using the thermionic emission theory with a Gaussian distributed barrier height over the whole junction,while at low temperatures and with a small bias,the current is dominated by some small patches with low barrier height.It results in a plateau-like section in the low temperature I-V curves around 10 -7 A.At room temperature,the barrier height of polycrystalline CoSi 2/Si deduced from the I-V curve is about 0 57eV.For epitaxial CoSi 2,the barrier height depends on its final annealing temperature and increases from 0 54eV to 0 60eV with the annealing temperature increasing from 700℃ to 900℃. 展开更多
关键词 Schottky barrier SILICIDE I-V/C-V INHOMOGENEITY
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NON-UNIFORM LINEAR ARRAY CONFIGURATION FOR MIMO RADAR
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作者 彭珍妮 贲德 +1 位作者 张弓 顾海光 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI 2011年第2期152-156,共5页
Array configuration of multiple-input multiple-output (MIMO) radar with non-uniform linear array (NLA) is proposed. Unlike a standard phased-array radar where NLA is used to generate thinner beam patterns, in MIMO... Array configuration of multiple-input multiple-output (MIMO) radar with non-uniform linear array (NLA) is proposed. Unlike a standard phased-array radar where NLA is used to generate thinner beam patterns, in MIMO radar the property of NLA is exploited to get more distinct virtual array elements so as to improve pa- rameter identifiability, which means the maximum number of targets that can be uniquely identified by the radar. A class of NLA called minimum redundancy linear array (MRLA) is employed and a new method to construct large MRLAs is descrihed. The numerical results verify that compared to uniform linear array (ULA) MIMO radars, NLA MIMO radars can retain the same parameter identifiability with fewer physical antennas and achieve larger aperture length and lower Cramer-Rao bound with the same number of the physical antennas. 展开更多
关键词 MIMO radar parameter identifiability non-uniform linear array virtual array element array con-figuration
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EXPERIMENTAL STUDIES ON J-DOMINANCE IN HETEROGENEOUS WELDED JOINTS BY MOIRE INTERFEROMETRY
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作者 康继东 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI 1997年第2期186-189,共4页
Moire interferometry method is introduced to study the feasibilities of J integral as a plastic singularity parameter at the tip of the notch in the welded joints. The results show that J dominance in most studied cas... Moire interferometry method is introduced to study the feasibilities of J integral as a plastic singularity parameter at the tip of the notch in the welded joints. The results show that J dominance in most studied cases is not validated in v and u displacement fields. Therefore, it can be concluded that J-integral as controlling parameter used to estimate the safety of welded structures is not always valid. 展开更多
关键词 path integrals welded joints moire interfe-rometry J-dominance heterogencity
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Short-span interleaving based selected mapping
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作者 吴炳洋 程时昕 《Journal of Southeast University(English Edition)》 EI CAS 2005年第4期385-388,共4页
A novel interleaving based selected mapping (SLM) scheme to depress the relatively high peak power of transmit signals in multicarrier communications is proposed. In the scheme, a group of bit-level interleavers spa... A novel interleaving based selected mapping (SLM) scheme to depress the relatively high peak power of transmit signals in multicarrier communications is proposed. In the scheme, a group of bit-level interleavers spanning only a few bits are used to produce multiple sequences representing the same information, and one of the sequences resulting in the lowest peak-to-average power ratio (PAPR) is selected for transmission. The implementation of the scheme including the structure of the short-span interleaver is illustrated. The performance of this PAPR reduction scheme is investigated by simulations. This scheme exhibits a good PAPR reduction performance, and for signals of high level modulation, such as 16QAM and 64QAM, it approaches the best performance of all SLM schemes. Compared to the conventional interleaving SLM, this short-span interleaving SLM results in a very short time delay, requires very few register units for buffering, and can be easily implemented by hardware. 展开更多
关键词 multicarrier communications peak-to-average power ratio selected mapping INTERLEAVING
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The Order of Approximation by(0,1,…,q) Hermite-Fejer Interpolation Polynomials at Nearly Fejer's Points
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作者 沈燮昌 王鸿飞 朱长青 《Chinese Quarterly Journal of Mathematics》 CSCD 1992年第1期81-88,共8页
Suppose that the outer mapping function of domain D has its second continuous derivatives. In this paper, the order proximation by (0,1,…,q) Hermite-Fejer interpolating polynomials at nearly Fejer's points of fun... Suppose that the outer mapping function of domain D has its second continuous derivatives. In this paper, the order proximation by (0,1,…,q) Hermite-Fejer interpolating polynomials at nearly Fejer's points of function of class A(D) are presented. Moreover in general the order of approximation is sharp. 展开更多
关键词 Hermite-Fejer interpolating Fejer's point
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Microbial Community Characteristics in the Rhizosphere of Atrazine-contaminated Soil by Dendroremediation of Poplar
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作者 姚斌 刘方 +1 位作者 刘昌勇 韦秀文 《Agricultural Science & Technology》 CAS 2017年第12期2423-2426,2519,共5页
The change of microbial community characteristics in the different rhizo- sphere zones of hybrid poplar (Populusdeltoidsxnigra, DN34) under atrazine stress were investigated by rhizo-boxes and Biolog system in a gre... The change of microbial community characteristics in the different rhizo- sphere zones of hybrid poplar (Populusdeltoidsxnigra, DN34) under atrazine stress were investigated by rhizo-boxes and Biolog system in a greenhouse experiment, with sublimed sulfur and calcium hydroxide as soil pH regulators. Data from the measurement by the Biolog ECO plate demonstrated that the value of average well color development (AWCD) and the carbon source utilization of soil microorganisms in the treatments with pH regulators were promoter than CK during the initial 30 days; while the results from the 90 days indicated that the activity and the carbon source utilization of soil microbes in acid regulator treatment began to fall down, even lower than that of poplar implant treatment, then the alkaline treatment could still stimulate and promote the activity and the carbon source utilization ability of soil microbes. Overall, the activity and community structure of soil microbes in rhizo- sphere zones of atrazine-contaminated soil did not show steady regularity during the phytoremediation process by using hybrid poplars. For the reason that the Biolog E- CO plate, which only had 31 kinds of carbon sources, could not really indicate the detail information about the function diversity of community structure of soil mi- crobes. So it's essential for us to take more sophisticated analysis tools for further study. 展开更多
关键词 POPLAR RHIZOBOX ATRAZINE Microbes Average absorbance Diversity
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Uniformity Investigation in 3C-SiC Epitaxial Layers Grown on Si Substrates by Horizontal Hot-Wall CVD
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作者 李家业 赵永梅 +6 位作者 刘兴昉 孙国胜 罗木昌 王雷 赵万顺 曾一平 李晋闽 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2007年第1期1-4,共4页
50mm 3C-SiC epilayers are grown on (100) and (111) Si substrates in a newly developed horizontal lowpressure hot-wall CVD reactor under different growth pressures and flow rates of H2 carrier gas. The structure,el... 50mm 3C-SiC epilayers are grown on (100) and (111) Si substrates in a newly developed horizontal lowpressure hot-wall CVD reactor under different growth pressures and flow rates of H2 carrier gas. The structure,electrical properties, and thickness uniformity of the 3C-SiC epilayers are investigated by X-ray diffraction (XRD) ,sheet resistance measurement, and spectroscopic ellipsometry. XRD patterns show that the 3C-SiC films have excellent crystallinity. The narrowest full widths at half maximum of the SIC(200) and (111) peaks are 0.41° and 0.21°, respectively. The best electrical uniformity of the 50mm 3C-SiC films obtained by sheet resistance measurement is 2.15%. A σ/mean value of ± 5.7% in thickness uniformity is obtained. 展开更多
关键词 3C-SIC heteroepitaxial growth horizontal hot-wall CVD UNIFORMITY
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Influence of Thermal Treatments on In-depth Compositional Uniformity of Culn(S,Se)2 Thin Films
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作者 谢海兵 刘伟丰 +3 位作者 江国顺 李欣益 严飞 朱长飞 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2012年第4期481-486,I0004,共7页
CuIn(S,Se)2 thin films were prepared by thermal crystallization of co-sputtered Cu-In alloy precursors in S/Se atmosphere. In-depth compositional uniformity is an important prereq- uisite for obtaining device-qualit... CuIn(S,Se)2 thin films were prepared by thermal crystallization of co-sputtered Cu-In alloy precursors in S/Se atmosphere. In-depth compositional uniformity is an important prereq- uisite for obtaining device-quality CuIn(S,Se)2 absorber thin films. In order to figure out the influence of heat treatments on in-depth composition uniformity of CuIn(S,Se)2 thin films, two kinds of reaction temperature profiles were investigated. One process is "one step profile", referring to formation of CuIn(S,Se)2 thin films just at elevated temperature (e.g. 500 ℃). The other is "two step profile", which allows for slow diffusion of S and Se elements into the alloy precursors at a low temperature before the formation and re-crystallization of CuIn(S,Se)2 thin films at higher temperature (e.g. first 250 ℃ then 500 ℃). X-ray diffrac- tion studies reveal that there is a discrepancy in the shape of (112) peak. Samples annealed with "one step profile" have splits on (112) peaks, while samples annealed with "two step profile" have relatively symmetrical (112) peaks. Grazing incident X-ray diffraction and en- ergy dispersive spectrum measurements of samples successively etched in bromine methanol show that CuIn(S,Se)2 thin films have better in-depth composition uniformity after "two step profile" annealing. The reaction mechanism during the two thermal processing was also investigated by X-ray diffraction and Raman spectra. 展开更多
关键词 Thermal treatment In-depth compositional uniformity CuIn(S Se)2 thin film
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